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MSDS Eng 05 03 2018

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SAFETY DATA SHEET

Issuing Date: 05-Mar-2015 Revision Date: 05-Mar-2015 Version 1

1. IDENTIFICATION
Product Name Tide To Go Stainpen

Product ID: 95317716_RET_NG

Product Type: Finished Product - Consumer (Retail) Use Only

Recommended Use Laundry Care

Restrictions on Use Use only as directed on label.

Manufacturer PROCTER & GAMBLE - Fabric and Home Care Division. Ivorydale Technical Centre.
5289 Spring Grove Avenue, Cincinnati, Ohio 45217-1087 USA

E-mail Address [email protected]

Emergency Telephone Transportation (24 HR)


CHEMTREC - 1-800-424-9300
(U.S./ Canada) or 1-703-527-3887
Mexico toll free in country: 800-681-9531

2. HAZARD IDENTIFICATION
"Consumer Products", as defined by the US Consumer Product Safety Act and which are used as intended (typical consumer
duration and frequency), are exempt from the OSHA Hazard Communication Standard (29 CFR 1910.1200). This SDS is being
provided as a courtesy to help assist in the safe handling and proper use of the product.

This product is classifed under 29CFR 1910.1200(d) and the Canadian Hazardous Products Regulation as follows:.

Not Classified.

Hazard Statements None

Hazard pictograms None

Precautionary Statements - None


Prevention

Precautionary Statements - None


Response

Precautionary Statements - None


Storage

Precautionary Statements - None


Disposal

Hazards not otherwise classified None

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95317716_RET_NG - Tide To Go Stainpen Revision Date: 05-Mar-2015

(HNOC)

3. COMPOSITION/INFORMATION ON INGREDIENTS
Ingredients are listed according to 29CFR 1910.1200 Appendix D and the Canadian Hazardous Products Regulation

Chemical Name Synonyms Trade Secret CAS-No Weight %


Dipropylene Glycol Butoxy Ether - No 29911-28-2 1-5
Hydrogen peroxide solution - No 7722-84-1 0.5 - 1.5

4. FIRST AID MEASURES


First aid measures for different exposure routes

Eye contact Rinse with plenty of water. Get medical attention immediately if irritation persists.

Skin contact Rinse with plenty of water. Get medical attention if irritation develops and persists.

Ingestion Drink 1 or 2 glasses of water. Do NOT induce vomiting. Get medical attention immediately if
symptoms occur.

Inhalation Move to fresh air. If symptoms persist, call a physician.

Most important symptoms/effects, None under normal use conditions.


acute and delayed

Indication of immediate medical attention and special treatment needed, if necessary

Notes to Physician Treat symptomatically.

5. FIRE-FIGHTING MEASURES
Suitable extinguishing media Dry chemical, CO 2, alcohol-resistant foam or water spray. Dry chemical. Alcohol-resistant
foam.

Unsuitable Extinguishing Media None.

Special hazard None known.

Special protective equipment for As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH
fire-fighters (approved or equivalent) and full protective gear.

Specific hazards arising from the None.


chemical

6. ACCIDENTAL RELEASE MEASURES


Personal precautions, protective equipment and emergency procedures

Personal precautions Use personal protective equipment. Do not get in eyes, on skin, or on clothing.

Advice for emergency responders Use personal protective equipment as required.

Environmental precautions Keep out of waterways. Do not discharge product into natural waters without pre-treatment
or adequate dilution.

Methods and materials for containment and cleaning up

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Methods for containment Absorb with earth, sand or other non-combustible material and transfer to containers for
later disposal. Prevent product from entering drains. Prevent further leakage or spillage if
safe to do so.

Methods for cleaning up Contain spillage, and then collect with non-combustible absorbent material, (e.g. sand,
earth, diatomaceous earth, vermiculite) and place in container for disposal according to
local / national regulations (see section 13).

7. HANDLING AND STORAGE


Precautions for safe handling

Advice on safe handling Use personal protective equipment as required. Keep container closed when not in use.
Never return spills in original containers for re-use. Keep out of the reach of children.

Conditions for safe storage, including any incompatibilities

Storage Conditions Keep containers tightly closed in a dry, cool and well-ventilated place.

Incompatible products None known.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION


Control parameters

Exposure Guidelines .

Chemical Name CAS-No ACGIH TLV OSHA PEL Mexico PEL


Hydrogen peroxide solution 7722-84-1 TWA: 1 ppm TWA: 1 ppm Mexico: TWA 1 ppm
TWA: 1.4 mg/m3 Mexico: TWA 1.5 mg/m3
(vacated) TWA: 1 ppm Mexico: STEL 2 ppm
(vacated) TWA: 1.4 mg/m3 Mexico: STEL 3 mg/m3

Chemical Name CAS-No Alberta Quebec Ontario TWAEV British Columbia


Hydrogen peroxide solution 7722-84-1 TWA: 1 ppm TWA: 1 ppm TWA: 1 ppm TWA: 1 ppm
TWA: 1.4 mg/m3 TWA: 1.4 mg/m3

No relevant exposure guidelines for other ingredients

Exposure controls

Engineering Measures Distribution, Workplace and Household Settings:


Ensure adequate ventilation

Product Manufacturing Plant (needed at Product-Producing Plant ONLY):


Where reasonably practicable this should be achieved by the use of local exhaust
ventilation and good general extraction

Personal Protective Equipment

Eye Protection Distribution, Workplace and Household Settings:


No special protective equipment required

Product Manufacturing Plant (needed at Product-Producing Plant ONLY):


Use appropriate eye protection

Hand Protection Distribution, Workplace and Household Settings:


No special protective equipment required

Product Manufacturing Plant (needed at Product-Producing Plant ONLY):

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Protective gloves

Skin and Body Protection Distribution, Workplace and Household Settings:


No special protective equipment required

Product Manufacturing Plant (needed at Product-Producing Plant ONLY):


Wear suitable protective clothing

Respiratory Protection Distribution, Workplace and Household Settings:


No special protective equipment required

Product Manufacturing Plant (needed at Product-Producing Plant ONLY):


In case of insufficient ventilation wear suitable respiratory equipment

9. PHYSICAL AND CHEMICAL PROPERTIES


Physical State @20°C liquid
Appearance clear
Odor Scented
Odor threshold No information available

Property Values Note


pH value 4.8 - 5.2
Melting/freezing point No information available
Boiling point/boiling range No information available
Flash point > 76.7 °C / > 170 °F Product is an aqueous solution containing <=
24% alcohol and> 50% water
Evaporation rate No information available
Flammability (solid, gas) No information available
Flammability Limits in Air
Upper flammability limit No information available
Lower Flammability Limit No information available
Vapor pressure No information available
Vapor density No information available
Relative density 1
Water solubility soluble
Solubility in other solvents No information available
Partition coefficient: n-octanol/waterNo information available
Autoignition temperature No information available .
Decomposition temperature No information available .
Viscosity of Product No information available

VOC Content (%) Products comply with US state and federal regulations for VOC content in consumer
products.

10. STABILITY AND REACTIVITY


Reactivity None under normal use conditions.

Stability Stable under normal conditions.

Hazardous polymerization Hazardous polymerization does not occur.

Hazardous Reactions None under normal processing.

Conditions to Avoid None under normal processing.

Materials to avoid None in particular.

Hazardous Decomposition Products None under normal use.

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11. TOXICOLOGICAL INFORMATION


Product Information
Information on likely routes of exposure

Inhalation No known effect.


Skin contact No known effect.
Ingestion No known effect.
Eye contact No known effect.

Delayed and immediate effects as well as chronic effects from short and long-term exposure

Acute toxicity No known effect.


Skin corrosion/irritation No known effect.
Serious eye damage/eye irritation No known effect.
Skin sensitization No known effect.
Respiratory sensitization No known effect.
Germ cell mutagenicity No known effect.
Neurological Effects No known effect.
Reproductive toxicity No known effect.
Developmental toxicity No known effect.
Teratogenicity No known effect.
STOT - single exposure No known effect.
STOT - repeated exposure No known effect.
Target Organ Effects No known effect.
Aspiration hazard No known effect.
Carcinogenicity No known effect.

Component Information

Chemical Name CAS-No LD50 Oral LD50 Dermal LC50 Inhalation


Dipropylene Glycol Butoxy Ether 29911-28-2 2610 mg/kg bw (Similar to > 2000 mg/kg bw (OECD > 2.04 mg/L air (OECD
OECD 401; standard acute 402; standard acute 403; standard acute
method; rat) method; rat) method; rat)
Hydrogen peroxide solution 7722-84-1 693.7 mg/kg bw (OECD > 2000 mg/kg bw -
401; standard acute (Guideline: US EPA Toxic
method) Substance Health Effects
Test Guideline; standard
acute method; rabbit)

12. ECOLOGICAL INFORMATION


Ecotoxicity

The product is not expected to be hazardous to the environment.

Persistence and degradability No information available.

Bioaccumulative potential No information available.

Mobility No information available.

Other adverse effects No information available.

13. DISPOSAL CONSIDERATIONS


Waste treatment

Waste from Residues / Unused Disposal should be in accordance with applicable regional, national and local laws and
Products regulations.

Contaminated packaging Disposal should be in accordance with applicable regional, national and local laws and
regulations.

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California Hazardous Waste Codes 331


(non-household setting)

14. TRANSPORT INFORMATION

DOT Not regulated

IMDG Not regulated

IATA Not regulated

15. REGULATORY INFORMATION


U.S. Federal Regulations

SARA 313
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any
chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372

CERCLA
This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive
Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302):

Chemical Name CAS-No Hazardous Extremely Hazardous CERCLA/SARA 302


Substances RQs Substances RQs TPQ
Hydrogen peroxide solution 7722-84-1 - 1000 lb 1000 lb

Clean Air Act, Section 112 Hazardous Air Pollutants (HAPs) (see 40 CFR 61)
This product does not contain any substances regulated as hazardous air pollutants (HAPS) under Section 112 of the Clean Air Act
Amendments of 1990.

Clean Water Act


This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40
CFR 122.42)

California Proposition 65
This product is not subject to warning labeling under California Proposition 65.

U.S. State Regulations (RTK)

Chemical Name CAS-No Pennsylvania


Hydrogen peroxide solution 7722-84-1 X

International Inventories

United States
All intentionally-added components of this product(s) are listed on the US TSCA Inventory.

Canada
This product is in compliance with CEPA for import by P&G.

Legend

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TSCA - United States Toxic Substances Control Act Section 8(b) Inventory
CEPA - Canadian Environmental Protection Act

16. OTHER INFORMATION

Issuing Date: 05-Mar-2015


Revision Date: 05-Mar-2015
Disclaimer
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its
publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation,
disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific
material designated and may not be valid for such material used in combination with any other materials or in any process, unless
specified in the text

End of SDS

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