MLL Chemistry 2024
MLL Chemistry 2024
CHAPTER 1: SOLUTIONS
1. Concentrationofsolutions : (a) molality(m), molarity (M) molefraction(X) – Numericals
2. Definitions :
a. Azeotropes – Minimum boiling and maximum boiling azeotropes.
b. Colligativeproperties – Formula and numerical
c. Van'tHofffactor – Definition and numerical and conceptual question.
d. Osmosis, Desalination of sea water (reverse osmosis), osmotic pressure.
3. Henry’s law: Statement and its applications.
4. Raoult’slaw : Statement and derivation
5. Differences : (a) Ideal and non-idealsolutions (b) Solutions showing positive and
negative deviations from Raoult’s Law.
6. Graphs : Ideal and non ideal solutions, Positive and negative deviation shoving solution
7. .Important formulae for numericals:
(a) Relative lowering in vapour pressure: P0 – P =Wb x Ma
Po Mb x Wa
(b) Elevation of boiling point : ∆Tb = Kbm
(c) Depression of freezing point : ∆Tf = Kfm
(d) osmotic pressure : π = CRT
CHAPTER 2: ELECTROCHEMISTRY
ELECTROCHEMICAL CELL-
1. Galvanic cell -cell reactions, cell notation
2. Differentiate between galvanic and electrolytic cells
3. Standard electrode potential of cell (Ecell0) values and comparison of oxidising and
reducing power.
4. Numericals on calculation of standard electrode potential of cell (Ecell0).
5. Numericals on Nernst equation-calculation of Ecell.
6. Relation between Ecell0, equilibrium constant, Gibbs energy of the reaction.
(b) Average ROR and instant ROR calculation from graphical method
(c) Integrated rate equation for zero and first order reactions.
(d) To calculate order of reaction by reading language of reaction or by doing sum of
the power of the reactants in practical rate equation
(e) Formula of half-life for zero and first order kinetic reactions.
(f) Formula of Arrhenius equation and calculation of Ea by K1 and K2.
3. Graphical portion:
To draw different graphs based on integrated rate equation, half-life equation and
Arrhenius equation given in the chapter using formula
y = mx + c and y = mx
And try to correlate different graphs given in different chapters with these formula
and establish pattern between them so students can easily understand similarities
between these graphs.
CHAPTER 4: d AND f – BLOCK ELEMENTS
Electronic Configuration of 3d series elements and their ions
Physical Properties – Reasoning
Variable oxidation states
Ionisation enthalpies
Atomization Enthalpies
Melting Point
Coloured ions
Magnetic properties
Complex formation
Catalytic properties
Preparation and oxidation reactions of KMnO4.
Preparation and oxidation reactions of K2Cr2O7 .
Lanthanoids and Actinoids.
Lanthanoid contraction and actinoid contraction.
Misch metal alloys.
Comparison of Lanthanoids and Actinoids.
CHAPTER 9: AMINES
1. Arrange in Order
(i) Boiling point order
(ii) Solubility of Amines Primary, Secondary and Tertiary amines
(iii) Basic strength of Amines
2. Distinguish Tests
(i) Carbylamine test
(ii) Hinsberg’s test
(iii) Coupling reaction- Azo dye test
(iv) Hydrolysis test
3. Reagents
(i) Direct Nitration of aniline