Product Name: eChem Thidiazuron 500 SC Liquid Cotton Defoliant

Page: 1 of 5
This version issued: June, 2021

Section 1 - Identification of the Material and Supplier

eChem Australia Pty Ltd Phone: 1300 781 649 (office hours)
Level 4, Lantos Place, 80 Stamford Rd Fax: 1300 781 650
Indooroopilly, Qld 4068 Emergency 1800 033 111 (any time)
Chemical nature: Suspension concentrate containing thidiazuron
Trade Name: eChem Thidiazuron 500 SC Liquid Cotton Defoliant
APVMA Code: 55963
Product Use: Agricultural herbicide for use as described on the product label.
Creation Date: November, 2016
This version issued: June, 2021 and is valid for 5 years from this date.
Poisons Information Centre: Phone 13 1126 from anywhere in Australia

Section 2 - Hazards Identification

Statement of Hazardous Nature
This product is classified as: Hazardous according to the criteria of SWA.
Not a Dangerous Good according to Australian Dangerous Goods (ADG) Code, IATA or IMDG/IMSBC criteria.
SUSMP Classification: None allocated.
ADG Classification: None allocated. Not a Dangerous Good according to Australian Dangerous Goods (ADG)
Code, IATA or IMDG/IMSBC criteria.
UN Number: None allocated

GHS Signal word: WARNING.

Acute Toxicity Dermal Category 4
Skin Corrosion /Irritation Category 2
Serious eye damage/eye irritation Category 2/2A
Acute Toxicity Inhalation Category 4
Specific Target Organ Toxicity - Single Exposure Category 3
HAZARD STATEMENT:
H312: Harmful in contact with skin.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H332: Harmful if inhaled.
H335: May cause respiratory irritation.
PREVENTION
P261: Avoid breathing fumes, mists, vapours or spray.
P262: Do not get in eyes, on skin, or on clothing.
P264: Wash contacted areas thoroughly after handling.
P271: Use only outdoors or in a well ventilated area.
P280: Wear protective gloves, protective clothing and eye or face protection.
RESPONSE
P312: Call a POISON CENTER or doctor if you feel unwell.
P337: If eye irritation persists: seek medical attention.
P362: Take off contaminated clothing and wash before reuse.
P301+P330+P331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P302+P352: IF ON SKIN: Wash with plenty of soap and water.
P304+P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.
P332+P313: If skin irritation occurs: Get medical advice.
SAFETY DATA SHEET
Issued by: eChem Australia Pty Ltd Phone: 1300 781 649 (office hours)
Poisons Information Centre: 13 1126 from anywhere in Australia, (0800 764 766 in New Zealand)
 Product Name: eChem Thidiazuron 500 SC Liquid Cotton Defoliant
Page: 2 of 5
This version issued: June, 2021

P337+P313: If eye irritation persists: Get medical advice.

P370+P378: In case of fire, use carbon dioxide, dry chemical, foam, water fog.
STORAGE
P410: Protect from sunlight.
P402+P404: Store in a dry place. Store in a closed container.
P403+P235: Store in a well-ventilated place. Keep cool.
DISPOSAL
P501: If product can not be recycled, consider controlled incineration, or contact a specialist waste disposal
company (see Section 13 of this SDS).
Emergency Overview
Physical Description & Colour: Beige liquid
Odour: Negligible odour.
Major Health Hazards: harmful if inhaled and in contact with skin, irritating to skin and respiratory system, causes
serious eye irritation.

Section 3 - Composition/Information on Ingredients

Ingredients CAS No Conc, g/L TWA (mg/m3) STEL (mg/m3)
Thidiazuron 51707-55-2 500 not set not set
Propylene glycol 57-55-6 10-100 10 not set
Other non hazardous ingredients secret to 1 L not set not set
This is a commercial product whose exact ratio of components may vary slightly. Minor quantities of other non
hazardous ingredients are also possible.
The SWA TWA exposure value is the average airborne concentration of a particular substance when calculated over a normal 8 hour working day
for a 5 day working week. The STEL (Short Term Exposure Limit) is an exposure value that may be equalled (but should not be exceeded) for no
longer than 15 minutes and should not be repeated more than 4 times per day. There should be at least 60 minutes between successive exposures
at the STEL. The term "peak "is used when the TWA limit, because of the rapid action of the substance, should never be exceeded, even briefly.

Section 4 - First Aid Measures

General Information:
You should call The Poisons Information Centre if you feel that you may have been poisoned, burned or irritated by
this product. The number is 13 1126 from anywhere in Australia (0800 764 766 in New Zealand) and is available at all
times. Have this SDS with you when you call.
Inhalation: If inhalation has occurred, and irritation has developed, remove to fresh air and observe until recovered.
If irritation becomes painful or persists more than about 30 minutes, seek medical advice.
Skin Contact: Wash gently and thoroughly with water (use non-abrasive soap if necessary) for 10 minutes or until
chemical is removed. If irritation persists, repeat flushing and obtain medical advice.
Eye Contact: If irritation does occur, flush contaminated eye(s) with lukewarm, gently flowing water for 5 minutes or
until the product is removed. Obtain medical advice if irritation becomes painful or lasts more than a few minutes.
Take special care if exposed person is wearing contact lenses.
Ingestion: If nausea or gastric upset develops, remove individual to rest area and monitor. If symptoms get worse or
if individual becomes distressed, do NOT induce vomiting; contact the Poisons Information Centre or a doctor.
Section 5 - Fire Fighting Measures
Fire and Explosion Hazards: The major hazard in fires is usually inhalation of heated and toxic or oxygen
deficient (or both), fire gases. There is no risk of an explosion from this product under normal circumstances if it is
involved in a fire.
This product is likely to decompose only after heating to dryness, followed by further strong heating.
Fire decomposition products from this product may be toxic if inhaled. Take appropriate protective measures.
Extinguishing Media: In case of fire, use dry chemical, foam, water fog.
Fire Fighting: When fighting fires involving significant quantities of this product, wear a fully encapsulated splash
suit complete with self contained breathing apparatus.
Flash point: Will not burn until water component is driven off.
Upper Flammability Limit: Does not burn.
Lower Flammability Limit: Does not burn.
Autoignition temperature: Does not burn.
SAFETY DATA SHEET
Issued by: eChem Australia Pty Ltd Phone: 1300 781 649 (office hours)
Poisons Information Centre: 13 1126 from anywhere in Australia, (0800 764 766 in New Zealand)
 Product Name: eChem Thidiazuron 500 SC Liquid Cotton Defoliant
Page: 3 of 5
This version issued: June, 2021

Flammability Class: Does not burn.

Section 6 - Accidental Release Measures

Accidental release: Minor spills do not normally need any special cleanup measures. In the event of a major spill,
prevent spillage from entering drains or water courses. Wear full protective clothing including eye/face protection. All
skin areas should be covered. See below under Personal Protection regarding Australian Standards relating to
personal protective equipment. Suitable materials for protective clothing include PVC, butyl rubber. Eye/face
protective equipment should comprise, as a minimum, protective glasses and, preferably, goggles. If there is a
significant chance that vapours or mists are likely to build up in the cleanup area, we recommend that you use a
respirator. Usually, no respirator is necessary when using this product. However, if you have any doubts consult the
Australian Standard mentioned below (section 8). Otherwise, not normally necessary.
Stop leak if safe to do so, and contain spill. Absorb onto sand, vermiculite or other suitable absorbent material. If spill
is too large or if absorbent material is not available, try to create a dike to stop material spreading or going into drains
or waterways. Sweep up and shovel or collect recoverable product into labelled containers for recycling or salvage,
and dispose of promptly. Recycle containers wherever possible after careful cleaning. Refer to product label for
specific instructions. After spills, wash area preventing runoff from entering drains. If a significant quantity of material
enters drains, advise emergency services. Full details regarding disposal of used containers, spillage and unused
material may be found on the label. If there is any conflict between this SDS and the label, instructions on the label
prevail. Ensure legality of disposal by consulting regulations prior to disposal. Thoroughly launder protective clothing
before storage or re-use. Advise laundry of nature of contamination when sending contaminated clothing to laundry.
Section 7 - Handling and Storage
Handling: Keep exposure to this product to a minimum, and minimise the quantities kept in work areas. Check
Section 8 of this SDS for details of personal protective measures, and make sure that those measures are followed.
The measures detailed below under "Storage" should be followed during handling in order to minimise risks to
persons using the product in the workplace. Also, avoid contact or contamination of product with incompatible
materials listed in Section 10.
Storage: Keep away from heat and flame. Protect this product from light. Store in the closed original container in a
dry, cool, well-ventilated area out of direct sunlight. Make sure that the product does not come into contact with
substances listed under "Incompatibilities" in Section 10. Some liquid preparations settle or separate on standing and
may require stirring before use. Check packaging - there may be further storage instructions on the label.
Section 8 - Exposure Controls and Personal Protection
The following Australian Standards will provide general advice regarding safety clothing and equipment:
Respiratory equipment: AS/NZS 1715, Protective Gloves: AS 2161, Occupational Protective Clothing: AS/NZS 4501
set 2008, Industrial Eye Protection: AS1336 and AS/NZS 1337, Occupational Protective Footwear: AS/NZS2210.
SWA Exposure Limits TWA (mg/m3) STEL (mg/m3)
Propylene glycol 10 not set
The ADI for Thidiazuron is set at 0.02mg/kg/day. The corresponding NOEL is set at 2.5mg/kg/day. ADI means
Acceptable Daily Intake; NOEL means No-observable-effect-level. Data from Australian ADI List, June 2014.
No special equipment is usually needed when occasionally handling small quantities. The following instructions are
for bulk handling or where regular exposure in an occupational setting occurs without proper containment systems.
Ventilation: This product should only be used in a well ventilated area. If natural ventilation is inadequate, use of a
fan is suggested.
Eye Protection: Eye protection such as protective glasses or goggles is recommended when this product is being
used.
Skin Protection: You should avoid contact even with mild skin irritants. Therefore you should wear suitable
impervious elbow-length gloves and facial protection when handling this product. See below for suitable material
types.
Protective Material Types: We suggest that protective clothing be made from the following materials: PVC, butyl
rubber.
Respirator: Usually, no respirator is necessary when using this product. However, if you have any doubts consult
the Australian Standard mentioned above. Otherwise, not normally necessary.
Section 9 - Physical and Chemical Properties:
Physical Description & colour: Beige liquid

SAFETY DATA SHEET

Issued by: eChem Australia Pty Ltd Phone: 1300 781 649 (office hours)
Poisons Information Centre: 13 1126 from anywhere in Australia, (0800 764 766 in New Zealand)
 Product Name: eChem Thidiazuron 500 SC Liquid Cotton Defoliant
Page: 4 of 5
This version issued: June, 2021

Odour: Negligible odour.

Boiling Point: Approximately 100°C at 100kPa.
Freezing/Melting Point: Approximately 0°C.
Volatiles: Water component.
Vapour Pressure: 2.37 kPa at 20°C (water vapour pressure).
Vapour Density: As for water.
Specific Gravity: 1.13
Water Solubility: Forms suspension in water.
pH: Approx 7.7
Volatility: No data.
Odour Threshold: No data.
Evaporation Rate: As for water.
Coeff Oil/water Distribution: No data
Autoignition temp: Does not burn.
Section 10 - Stability and Reactivity
Reactivity: This product is unlikely to react or decompose under normal storage conditions. However, if you have
any doubts, contact the supplier for advice on shelf life properties.
Conditions to Avoid: Keep away from heat, flames and sparks. Protect this product from light. Store in the closed
original container in a dry, cool, well-ventilated area out of direct sunlight.
Incompatibilities: oxidising agents.
Fire Decomposition: This product is likely to decompose only after heating to dryness, followed by further strong
heating. Combustion forms carbon dioxide, and if incomplete, carbon monoxide and possibly smoke. Water is also
formed. May form nitrogen and its compounds, and under some circumstances, oxides of nitrogen. Occasionally
hydrogen cyanide gas in reducing atmospheres. Carbon monoxide poisoning produces headache, weakness,
nausea, dizziness, confusion, dimness of vision, disturbance of judgment, and unconsciousness followed by coma
and death.
Polymerisation: This product will not undergo polymerisation reactions.

Section 11 - Toxicological Information

Local Effects:
Target Organs: There is no data to hand indicating any particular target organs.

Classification of Hazardous Ingredients

No ingredient mentioned in the HSIS Database is present in this product at hazardous concentrations.
Potential Health Effects
Inhalation:
Short Term Exposure: Available data indicates that this product is harmful if inhaled; symptoms not available.
However product may be mildly irritating, although unlikely to cause anything more than mild transient discomfort.
Long Term Exposure: No data for health effects associated with long term inhalation.
Skin Contact:
Short Term Exposure: Available data indicates that this product is harmful in contact with skin; symptoms not
available. It should present no hazards in normal use. Causes skin irritation, but is unlikely to cause anything more
than transient discomfort.
Long Term Exposure: No data for health effects associated with long term skin exposure.
Eye Contact:
Short Term Exposure: This product causes serious eye irritation. If exposure is brief, symptoms are expected to
gradually disappear once product is removed, but prolonged contact may result in long-term or permanent effects.
Long Term Exposure: No data for health effects associated with long term eye exposure.
Ingestion:
Short Term Exposure: Significant oral exposure is considered to be unlikely. This product, while believed to be not
harmful, is likely to cause headache and gastric disturbance such as nausea and vomiting if ingested in significant
quantities. This product is unlikely to cause any irritation problems in the short or long term.

SAFETY DATA SHEET

Issued by: eChem Australia Pty Ltd Phone: 1300 781 649 (office hours)
Poisons Information Centre: 13 1126 from anywhere in Australia, (0800 764 766 in New Zealand)
 Product Name: eChem Thidiazuron 500 SC Liquid Cotton Defoliant
Page: 5 of 5
This version issued: June, 2021

Long Term Exposure: No data for health effects associated with long term ingestion.
Carcinogen Status:
SWA: No significant ingredient is classified as carcinogenic by SWA.
NTP: No significant ingredient is classified as carcinogenic by NTP.
IARC: No significant ingredient is classified as carcinogenic by IARC.
Section 12 - Ecological Information
Insufficient data to be sure of status.

Section 13 - Disposal Considerations

Disposal: Special help is available for the disposal of Agricultural Chemicals. The product label will give general
advice regarding disposal of small quantities, and how to cleanse containers. However, for help with the collection of
unwanted rural chemicals, contact ChemClear 1800 008 182 http://www.chemclear.com.au/ and for help with the
disposal of empty drums, contact DrumMuster http://www.drummuster.com.au/ where you will find contact details for
your area.

Section 14 - Transport Information

UN Number: This product is not classified as a Dangerous Good by ADG, IATA or IMDG/IMSBC criteria. No special
transport conditions are necessary unless required by other regulations.
Section 15 - Regulatory Information
AICS: All of the significant ingredients in this formulation are compliant with NICNAS regulations.
Section 16 - Other Information
This SDS contains only safety-related information. For other data see product literature.
Acronyms:
th
ADG Code Australian Code for the Transport of Dangerous Goods by Road and Rail (7 edition)
AICS Australian Inventory of Chemical Substances
SWA Safe Work Australia, formerly ASCC and NOHSC
CAS number Chemical Abstracts Service Registry Number
Hazchem Code Emergency action code of numbers and letters that provide information to emergency
services especially firefighters
IARC International Agency for Research on Cancer
NOS Not otherwise specified
NTP National Toxicology Program (USA)
R-Phrase Risk Phrase
SUSMP Standard for the Uniform Scheduling of Medicines & Poisons
UN Number United Nations Number
THIS SDS SUMMARISES OUR BEST KNOWLEDGE OF THE HEALTH AND SAFETY HAZARD INFORMATION OF THE PRODUCT AND HOW
TO SAFELY HANDLE AND USE THE PRODUCT IN THE WORKPLACE. EACH USER MUST REVIEW THIS SDS IN THE CONTEXT OF HOW
THE PRODUCT WILL BE HANDLED AND USED IN THE WORKPLACE.
IF CLARIFICATION OR FURTHER INFORMATION IS NEEDED TO ENSURE THAT AN APPROPRIATE RISK ASSESSMENT CAN BE MADE,
THE USER SHOULD CONTACT THIS COMPANY SO WE CAN ATTEMPT TO OBTAIN ADDITIONAL INFORMATION FROM OUR SUPPLIERS
OUR RESPONSIBILITY FOR PRODUCTS SOLD IS SUBJECT TO OUR STANDARD TERMS AND CONDITIONS, A COPY OF WHICH IS SENT
TO OUR CUSTOMERS AND IS ALSO AVAILABLE ON REQUEST.

Please read all labels carefully before using product.

This SDS is prepared in accord with the SWA document “Preparation of Safety Data Sheets for Hazardous
Chemicals - Code of Practice” (Feb 2016)
Copyright © Kilford & Kilford Pty Ltd, June, 2021.
http://www.kilford.com.au/ Phone (02)8321 8866

SAFETY DATA SHEET

Issued by: eChem Australia Pty Ltd Phone: 1300 781 649 (office hours)
Poisons Information Centre: 13 1126 from anywhere in Australia, (0800 764 766 in New Zealand)