9517 K87fc5kub

Conforms to 91/155/EEC - 2001/58/EC - United Kingdom (UK)
SAFETY DATA SHEET

FERROFILM
1. Identification of the substance/preparation and of the company/undertaking
Product name : FERROFILM
Material Uses : Industrial applications: Corrosion and erosion inhibitor for Seawater cooled
heat exchangers
Manufacturer / Supplier :
Drew Marine Drew Marine
Ashland Specialty Chemical Company Ashland Specialty Chemical Company
Malledijk 20 One Drew Plaza
3208 LA Spijkenisse Boonton, NJ 07005
Netherlands United States
Tel. No.: Tel. No.:
+31 181 457 070 +1 (973) 263 7600
Fax: Fax:
+31 181 625 792 +1 (973) 263 4491
Emergency telephone number
(Germany) : +49 621 60-43333
Fax:
(Germany) : +49 621 60-92664
2. Composition/information on ingredients
Substance/Preparation : Preparation
Chemical characterization : Mixture containing ferrous sulphate and acrylic polymers
Chemical name* CAS No. % EC Number Classification

Ferrous sulphate, heptahydrate 7782-63-0 90-100 Xn; R22
See Section 16 for the full text of the R Phrases declared above
* Occupational Exposure Limit(s), if available, are listed in Section 8
3. Hazards identification
The preparation is classified as dangerous according to Directive 1999/45/EC and its amendments.
Classification : Harmful
R22- Harmful if swallowed.
Effects and symptoms
Inhalation : Slightly hazardous in case of inhalation (lung irritant).
Ingestion : Hazardous in case of ingestion. Ingestion may cause gastrointestinal
irritation and diarrhoea.
Skin contact : Slightly hazardous in case of skin contact (irritant). Skin inflammation is
characterized by itching, scaling, reddening, or, occasionally, blistering.
Eye Contact : Slightly hazardous in case of eye contact (irritant).
Target Organs : Contains material which causes damage to the following organs: liver,
gastrointestinal tract, upper respiratory tract, skin, eye, lens or cornea.
Date of issue : 10/16/2002. Page: 1/5

FERROFILM
4. First-aid measures
First-Aid measures
Inhalation : If inhaled, remove to fresh air. Get medical attention if symptoms appear.
Ingestion : Do NOT induce vomiting unless directed to do so by medical personnel.
Never give anything by mouth to an unconscious person. If large quantities of
this material are swallowed, call a physician immediately. Loosen tight clothing
such as a collar, tie, belt or waistband.
Skin contact : Wash with soap and water. Cold water may be used. Get medical attention if
irritation develops.
Eye Contact : Check for and remove any contact lenses. In case of contact, immediately
flush eyes with a copious amount of water for at least 15 minutes. Cold water
may be used. Get medical attention if irritation occurs.
5. Fire-fighting measures
Extinguishing Media
Suitable : Not applicable.
Unusual fire/explosion Hazards : Non combustible. Emits toxic fumes when heated to decomposition. In a fire,
the following can be released: sulphur oxides (SO2, SO3, etc.)
Hazardous thermal (de)composition : These products are carbon oxides (CO, CO2) and water, sulphur oxides (SO2,
products SO3, etc.). Some metallic oxides.
Protection of fire-fighters : Fire fighters should wear self-contained positive pressure breathing apparatus
(SCBA) and full turnout gear.
6. Accidental release measures

Personal Precautions : Splash goggles. Full suit. Dust respirator. Boots. Gloves. Suggested
protective clothing might not be sufficient; consult a specialist BEFORE
handling this product.
Environmental precautions and : Use a shovel to put the material into a convenient waste disposal container.
cleanup methods Finish cleaning by spreading water on the contaminated surface and allow to
evacuate through the sanitary system.
Note: See section 8 for personal protective equipment and section 13 for waste disposal.
7. Handling and storage

Handling : Do not breathe dust. Wear suitable protective clothing. If ingested, seek
medical advice immediately and show the container or the label.
Storage : Keep container tightly closed. Keep container in a cool, well-ventilated area.
Packaging materials
Recommended use : Use original container.
8. Exposure controls/personal protection

Engineering measures : Use process enclosures, local exhaust ventilation, or other engineering
controls to keep airborne levels below recommended exposure limits. If user
operations generate dust, fume or mist, use ventilation to keep exposure to
airborne contaminants below the exposure limit.
Hygiene measures : Wash hands, forearms, and face thoroughly after handling compounds and
before eating, smoking, using lavatory, and at the end of day.

FERROFILM
Respiratory system : Dust respirator.
Skin and body : Lab coat.

Hands : PVC gloves.
Eyes : Safety glasses.
9. Physical and chemical properties

Physical state : Solid. (Powdered solid.)
Colour : Brown / Green
Odour : Not available.
Melting point : >400°C (752°F)
Density : 1.16 to 1.31 g/cm3
Solubility : Soluble in cold water.
pH : 4.5 [Acidic.]
Flash point : Not applicable.
10. Stability and reactivity

Stability : The product is stable.
Hazardous decomposition products : These products are carbon oxides (CO, CO2) and water, sulphur oxides (SO2,
SO3, etc.). Some metallic oxides.
Remarks : Emits toxic fumes when heated to decomposition. Hazardous Decomposition
Products sulphur oxides (SO2, SO3, etc.)
11. Toxicological information

Acute toxicity
Ingredient Name Test Result Route Species
Ferrous sulphate, heptahydrate LD50 1520 mg/kg Oral Mouse
LD50 600 to 1400 Oral Rat
mg/kg
LDLo 1389 mg/kg Oral Rat
LDLo 2778 mg/kg Oral Rabbit
Chronic toxicity : Repeated or prolonged exposure is not known to aggravate medical condition.
Skin irritation : Slightly hazardous in case of skin contact (irritant).
Eye irritation : Slightly hazardous in case of eye contact (irritant).
Carcinogenic effects : Not available.
Mutagenic Effects : Not available.

Reproduction toxicity : Not available.
12. Ecological information
Persistence/degradability : Not available.

FERROFILM
13. Disposal considerations

Methods of disposal ; Waste of : Waste must be disposed of in accordance with federal, state and local
residues ; Contaminated packaging environmental control regulations.
European Waste Catalogue (EWC) : 06 03 03

Hazardous Waste : To present knowledge of the supplier, this product is not regarded as
hazardous waste as defined by EU Directive 91/689/EC.
Additional Information : 06 03 03 solid salts containing sulphates, sulphites or sulphides
14. Transport information

International transport regulations
Land - Road/Railway
UN number : Not regulated.
Proper shipping name : -
ADR/RID Class : -
Other information : Remarks
Not controlled under ADR (Europe).
Sea
UN number : Not regulated.
Proper shipping name : -
IMDG Class : -
Other information : Remarks
Not controlled under IMDG.
15. Regulatory information

EU Regulations
Hazard symbol(s) :
Harmful
Risk Phrases : R22- Harmful if swallowed.
Safety Phrases : Not applicable.
Contains : Ferrous sulphate, heptahydrate
Product Use : Classification and labelling have been performed according to EU directives
67/548/EEC, 88/379/EEC, including amendments and the intended use.
- Industrial applications.
16. Other information

Full text of R-Phrases with no. : R22- Harmful if swallowed.
appearing in Section 2 - United
Kingdom (UK)
Text of classifications appearing in : Xn - Harmful
Section 2 - United Kingdom (UK)
HISTORY
Date of printing : 10/17/2002.
Date of issue : 10/16/2002.
Version : 3
FERROFILM™ is a trademark of Ashland Inc.

FERROFILM
Notice to Reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor
any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained
herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown
hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these
are the only hazards that exist.
Date of issue Version
10/16/2002. 3 Page: 5/5

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Conforms to 91/155/EEC - 2001/58/EC - United Kingdom (UK)

SAFETY DATA SHEET

Chemical name* CAS No. % EC Number Classification

* Occupational Exposure Limit(s), if available, are listed in Section 8

Date of issue : 10/16/2002. Page: 1/5

6. Accidental release measures

7. Handling and storage

8. Exposure controls/personal protection

Date of issue : 10/16/2002. Page: 2/5

Respiratory system : Dust respirator.

Skin and body : Lab coat.

9. Physical and chemical properties

10. Stability and reactivity

11. Toxicological information

Mutagenic Effects : Not available.

12. Ecological information

Persistence/degradability : Not available.

Date of issue : 10/16/2002. Page: 3/5

13. Disposal considerations

European Waste Catalogue (EWC) : 06 03 03

14. Transport information

15. Regulatory information

16. Other information

Date of issue : 10/16/2002. Page: 4/5

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