Conforms to 91/155/EEC - 2001/58/EC - United Kingdom (UK)

SAFETY DATA SHEET

PRODUCT FORMULA No. 10
1. Identification of the substance/preparation and of the company/undertaking
Product name : PRODUCT FORMULA No. 10
Material Uses : Industrial applications: Cleaner for removal of vegetable or animal oil from
soiled surfaces.

Manufacturer / Supplier :
Drew Marine Drew Marine
Ashland Specialty Chemical Company Ashland Specialty Chemical Company
Malledijk 20 One Drew Plaza
3208 LA Spijkenisse Boonton, NJ 07005
Netherlands United States
Tel. No.: Tel. No.:
+31 181 457 070 +1 (973) 263 7600
Fax: Fax:
+31 181 625 792 +1 (973) 263 4491
Emergency telephone number
(Germany) : +49 621 60-43333
Fax:
(Germany) : +49 621 60-92664

2. Composition/information on ingredients
Substance/Preparation : Preparation

Chemical name* CAS No. % EC Number Classification

2-Butoxyethanol 111-76-2 10-20 203-905-0 Xn; R20/21/22
Xi; R36/38
2-Aminoethanol 141-43-5 10-20 205-483-3 Xn; R20
Xi; R36/37/38
Ethoxylated isononyl phenol 37205-87-1 1-5 Xi; R36/38
R53
See Section 16 for the full text of the R Phrases declared above

* Occupational Exposure Limit(s), if available, are listed in Section 8

3. Hazards identification
The preparation is classified as dangerous according to Directive 1999/45/EC and its amendments.
Classification : Harmful
R20- Harmful by inhalation.
R36/38- Irritating to eyes and skin.
Effects and symptoms
Inhalation : Inhalation causes headaches, dizziness, drowsiness, and nausea, and may
lead to unconsciousness.
Ingestion : Ingestion may cause gastrointestinal irritation and diarrhoea.
Skin contact : Slightly irritating to the skin. Skin inflammation is characterized by itching,
scaling, reddening, or, occasionally, blistering. Harmful if absorbed through
the skin. Severe over-exposure can result in death.
Eye Contact : Slightly hazardous in case of eye contact (irritant). Inflammation of the eye is
characterized by redness, watering and itching.

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Target Organs : Contains material which causes damage to the following organs: blood,
kidneys, liver, lymphatic system, upper respiratory tract, skin, central nervous
system (CNS), eye, lens or cornea.

4. First-aid measures
First-Aid measures
Inhalation : If inhaled, remove to fresh air. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen. Obtain medical attention.
Ingestion : Do NOT induce vomiting unless directed to do so by medical personnel.
Never give anything by mouth to an unconscious person. Loosen tight clothing
such as a collar, tie, belt or waistband. Get medical attention if symptoms
appear.
Skin contact : In case of contact, immediately flush skin copiously with water for at least 15
minutes while removing contaminated clothing and shoes. Cover the irritated
skin with an emollient. Cold water may be used. Wash clothing before reuse.
Clean shoes thoroughly before reuse. Obtain medical attention immediately.
Eye Contact : Check for and remove any contact lenses. In case of contact, immediately
flush eyes with a copious amount of water for at least 15 minutes. Cold water
may be used. Get medical attention if irritation occurs.

5. Fire-fighting measures
Extinguishing Media
Suitable : SMALL FIRE: Use dry chemical powder or CO2.
LARGE FIRE: Use water spray, fog or foam. Do not use water jet.
Unusual fire/explosion Hazards : Cool containing vessels with water jet in order to prevent pressure build-up,
autoignition or explosion.
Hazardous thermal (de)composition : These products are carbon oxides (CO, CO2) and water, nitrogen oxides (NO,
products NO2...).
Protection of fire-fighters : Fire fighters should wear self-contained positive pressure breathing apparatus
(SCBA) and full turnout gear.

6. Accidental release measures

Personal Precautions : Splash goggles. Full suit. Vapour respirator. Boots. Gloves. A self-contained
breathing apparatus should be used to avoid inhalation of the product.
Suggested protective clothing might not be sufficient; consult a specialist
BEFORE handling this product.
Environmental precautions and : Stop leak if without risk. Use water spray to reduce vapours. Prevent entry
cleanup methods into sewers, basements or confined areas; dike if needed. Eliminate all ignition
sources. Call for assistance on disposal. Neutralize the residue with a
dilute solution of acetic acid.
Note: See section 8 for personal protective equipment and section 13 for waste disposal.

7. Handling and storage

Handling : Keep away from heat. Keep away from sources of ignition. Ground all
equipment containing material. Do not breathe gas/fumes/vapour/spray.
Wear suitable protective clothing. If ingested, seek medical advice
immediately and show the container or the label. Keep away from
incompatibles such as oxidizing agents, acids.
Storage : Keep container tightly closed. Keep container in a cool, well-ventilated area.
Packaging materials
Recommended use : Use original container.

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8. Exposure controls/personal protection

Engineering measures : Provide exhaust ventilation or other engineering controls to keep the airborne
concentrations of vapours below their respective occupational exposure limits.
Ensure that eyewash stations and safety showers are close to the workstation
location.
Hygiene measures : Wash hands, forearms, and face thoroughly after handling compounds and
before eating, smoking, using lavatory, and at the end of day.
Occupational Exposure Limits

Ingredient Name Occupational Exposure Limits

2-Butoxyethanol EH40-OES (United Kingdom (UK), 2001). skin Notes:
OES
TWA: 123 mg/m3
TWA: 25 ppm
2-Aminoethanol EH40-OES (United Kingdom (UK), 2001). Notes: OES
STEL: 15 mg/m3
STEL: 6 ppm
TWA: 7.6 mg/m3
TWA: 3 ppm

Respiratory system : Wear appropriate respirator when ventilation is inadequate.

Skin and body : Overalls buttoned to the neck and wrist. Lab coat.
Hands : Impervious gloves.
Eyes : Safety glasses.

9. Physical and chemical properties

Physical state : Liquid.
Colour : Colourless.
Odour : Characteristic.
Odour threshold : The lowest known value is 2 ppm (2-Aminoethanol).
Boiling point : 100°C (212°F)
Melting point : -2°C (28°F)
Density : 1.02 g/cm3 (20°C / 68°F)
Vapour density : The highest known value is 4.07 (Air = 1) (2-Butoxyethanol).
Vapour pressure : 0.12 kPa (0.9 mmHg) (at 20°C)
Evaporation Rate : <1 compared to Ether (anhydrous).

Solubility : Easily soluble in cold water.

pH : 10.4 [Basic.]
Flash point : CLOSED CUP: >100°C (212°F).(Pensky-Martens.)
Autoignition temperature : 240°C (464°F)
Lower explosion limit : The greatest known range is LOWER: 2.5% UPPER: 13.1%
(2-Aminoethanol)

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10. Stability and reactivity

Stability : The product is stable.
Materials to avoid : Reactive with oxidizing agents, acids.
Hazardous decomposition products : These products are carbon oxides (CO, CO2) and water, nitrogen oxides (NO,
NO2...).
Remarks : Risks of Explosion : May form explosive mixtures with air. (> 60°C).

11. Toxicological information

Acute toxicity
Ingredient Name Test Result Route Species
2-Butoxyethanol LD50 470 mg/kg Oral Rat
LD50 300 mg/kg Oral Rabbit
LD50 1200 mg/kg Oral Guinea pig
LD50 220 mg/kg Dermal Rabbit
2-Aminoethanol LD50 1720 mg/kg Oral Rat
LD50 620 mg/kg Oral Guinea pig
LD50 700 mg/kg Oral Mouse
LD50 1020 mg/kg Dermal Rabbit
LDLo 1400 mg/kg Oral Mammal
Ethoxylated isononyl phenol LD50 5600 mg/kg Oral Rat
LD50 5800 mg/kg Oral Rat
LD50 4700 mg/kg Oral Mouse

Chronic toxicity : Repeated exposure to an highly toxic material may produce general
deterioration of health by an accumulation in one or many human organs.
Skin irritation : Hazardous in case of skin contact (irritant).
Eye irritation : Slightly hazardous in case of eye contact (irritant).
Carcinogenic effects : Not available.

Mutagenic Effects : Not available.

Reproduction toxicity : Not available.

12. Ecological information

Ecotoxicity Data
Ingredient Name Species Period Result
2-Aminoethanol Fish (LC50) 96 hours 314.2 mg/l
Ethoxylated isononyl phenol Fish (LC50) 96 hours 7.2 mg/l
Daphnia (EC50) 48 hours 15 mg/l
Algae (IC50) 72 hours 30 mg/l
Persistence/degradability : Not available.

13. Disposal considerations

Methods of disposal ; Waste of : Waste must be disposed of in accordance with federal, state and local
residues ; Contaminated packaging environmental control regulations.

European Waste Catalogue (EWC) : 16 05 03

Hazardous Waste : The classification of the product may meet the criteria for a hazardous waste.
Additional Information : 16 05 03 other waste containing organic chemicals, e.g. lab chemicals not
otherwise specified

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14. Transport information

International transport regulations
Land - Road/Railway
UN number : 2810
Proper shipping name : TOXIC LIQUID, ORGANIC, N.O.S. (2-Butoxyethanol)
ADR/RID Class : 6.1
Packing group : III
ADR/RID label :

Other information : Hazard identification number

60
Sea
UN number : 2810
Proper shipping name : TOXIC LIQUID, ORGANIC, N.O.S. (2-Butoxyethanol)
IMDG Class : 6.1
Packing group : III
IMDG label :

Other information : Emergency Schedules (EmS)

6.1-02

15. Regulatory information

EU Regulations
Hazard symbol(s) :

Harmful
Risk Phrases : R20- Harmful by inhalation.
R36/38- Irritating to eyes and skin.
Safety Phrases : S23- Do not breathe vapour/spray.
S37/39- Wear suitable gloves and eye/face protection.
Product Use : Classification and labelling have been performed according to EU directives
67/548/EEC, 88/379/EEC, including amendments and the intended use.
- Industrial applications.

16. Other information

Full text of R-Phrases with no. : R20- Harmful by inhalation.
appearing in Section 2 - United R20/21/22- Harmful by inhalation, in contact with skin and if swallowed.
Kingdom (UK) R36/37/38- Irritating to eyes, respiratory system and skin.
R36/38- Irritating to eyes and skin.
R53- May cause long-term adverse effects in the aquatic environment.
Text of classifications appearing in : Xn - Harmful
Section 2 - United Kingdom (UK) Xi - Irritant
HISTORY
Date of printing : 10/17/2002.

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Date of issue : 10/16/2002.

Version : 3
PRODUCT FORMULA No. 10 is a trademark of Ashland Inc.
Notice to Reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor
any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained
herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown
hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these
are the only hazards that exist.
Date of issue Version
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