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Conforms to 91/155/EEC - 2001/58/EC - United Kingdom (UK)
SAFETY DATA SHEET

AMERFROST A407c
1. Identification of the substance/preparation and of the company/undertaking
Product name : AMERFROST A407c
Material Uses : Industrial applications: Refrigerant.
Manufacturer / Supplier :
Drew Marine Drew Marine
Ashland Specialty Chemical Company Ashland Specialty Chemical Company
Malledijk 20 One Drew Plaza
3208 LA Spijkenisse Boonton, NJ 07005
Netherlands United States
Tel. No.: Tel. No.:
+31 181 457 070 +1 (973) 263 7600
Fax: Fax:
+31 181 625 792 +1 (973) 263 4491
Emergency telephone number
(Germany) : +49 621 60-43333
Fax:
(Germany) : +49 621 60-92664
2. Composition/information on ingredients
Substance/Preparation : Preparation
Chemical characterization : Halogenated hydrocarbon (blend)
Chemical name* CAS No. % EC Number Classification

1,1,1,2-Tetrafluoroethane 811-97-2 50-60 212-377-0
See Section 16 for the full text of the R Phrases declared above
* Occupational Exposure Limit(s), if available, are listed in Section 8
3. Hazards identification
The preparation is not classified as dangerous according to Directive 1999/45/EC and its amendments.
Classification :
This product is not classified according to the EU regulations.
Effects and symptoms
Skin contact : Dermal contact with a rapidly evaporating liquid could result in frosting of the
tissues or frostbite.
Other Adverse Effects : Narcotic in high concentrations. Gas reduces oxygen available for breathing.
Severe over-exposure can result in death.
4. First-aid measures
First-Aid measures
Inhalation : If inhaled, remove to fresh air. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen. Get medical attention if symptoms appear.
Ingestion : Since the product is a gas and it is mostly probable that it will be inhaled more
than ingested, in case of inhalation please consider looking first at preventative
measures.
Date of issue : 10/16/2002. Page: 1/5

AMERFROST A407c
Skin contact : In case of contact, immediately flush skin with plenty of water. Remove
contaminated clothing and shoes. Wash clothing before reuse. Clean shoes
thoroughly before reuse. Obtain medical attention.
Eye Contact : Check for and remove any contact lenses. In case of contact, immediately
flush eyes with a copious amount of water for at least 15 minutes. Cold water
may be used. Obtain medical attention.
5. Fire-fighting measures
Extinguishing Media
Suitable : Not applicable.
Hazardous thermal (de)composition : These products are carbon oxides (CO, CO2) and water, halogenated
products compounds.
Protection of fire-fighters : Fire fighters should wear self-contained positive pressure breathing apparatus
(SCBA) and full turnout gear.
6. Accidental release measures

Personal Precautions : Splash goggles. Full suit. Boots. Gloves.
Environmental precautions and : Not available.
cleanup methods
Note: See section 8 for personal protective equipment and section 13 for waste disposal.
7. Handling and storage

Handling : Keep away from heat. In case of insufficient ventilation, wear suitable
respiratory equipment. If you feel unwell, seek medical attention and show the
label when possible. Keep container tightly closed and in a well-ventilated
place. Keep away from incompatibles such as oxidizing agents.
Storage : Keep container in a cool, well-ventilated area. Keep container tightly closed
and sealed until ready for use. Do not store below 50°C (122°F).
Packaging materials
Recommended use : Use original container.
8. Exposure controls/personal protection

Engineering measures : No special ventilation requirements.
Hygiene measures : Wash hands after handling compounds and before eating, smoking, using
lavatory, and at the end of day.
Occupational Exposure Limits
Ingredient Name Occupational Exposure Limits

1,1,1,2-Tetrafluoroethane EH40-OES (United Kingdom (UK), 2001). Notes: OES
TWA: 4240 mg/m3
TWA: 1000 ppm
Respiratory system : In case of insufficient ventilation, wear suitable respiratory equipment.

Self-contained breathing apparatus.
Skin and body : Lab coat.

Hands : Insulated gloves suitable for low temperatures
Eyes : Splash goggles.

AMERFROST A407c
9. Physical and chemical properties

Physical state : Gas. (Compressed Gas (liquid))
Colour : Colourless.
Odour : Ethereal. (Slight.)
Boiling point : -44°C (-47°F)
Melting point : -101°C (-150°F) based on data for: 1,1,1,2-Tetrafluoroethane.
Density : 1.136 g/cm3 (25°C / 77°F)
Evaporation Rate : >1 compared to Tetrachloromethane
Solubility : Very slightly soluble in cold water.

pH : Not available.
Flash point : Not applicable.
10. Stability and reactivity

Stability : The product is stable.
Materials to avoid : Reactive with oxidizing agents.
Incompatible with finely-powdered metals. ( Aluminium , Zinc , Magnesium
powder )
Hazardous decomposition products : These products are carbon oxides (CO, CO2) and water, halogenated
compounds.
Remarks : In a fire, the following can be released: Hydrogen Fluoride (HF) , Carbonyl
fluoride
11. Toxicological information

Acute toxicity
Ingredient Name Test Result Route Species
1,1,1,2-Tetrafluoroethane LC50 1.5e+006 Inhalation Rat
mg/m3 (4
hours)
Difluoromethane LC50 >520000 Inhalation Rat
ppm (4
hours)
Chronic toxicity : Repeated or prolonged exposure is not known to aggravate medical condition.
Carcinogenic effects : Not available.
Mutagenic Effects : Not available.

Reproduction toxicity : Not available.
12. Ecological information

Ecotoxicity Data
Ingredient Name Species Period Result
1,1,1,2-Tetrafluoroethane Fish (LC50) 96 hours 450 mg/l
Daphnia (EC50) 48 hours 980 mg/l
Persistence/degradability : Not available.

AMERFROST A407c
13. Disposal considerations

Methods of disposal ; Waste of : Waste must be disposed of in accordance with federal, state and local
residues ; Contaminated packaging environmental control regulations.
European Waste Catalogue (EWC) : 14 05 01

Hazardous Waste : The classification of the product may meet the criteria for a hazardous waste.
Additional Information : 14 05 01 chlorofluorocarbons
14. Transport information

International transport regulations
Land - Road/Railway
UN number : 3340
Proper shipping name : REFRIGERANT GAS R 407C
ADR/RID Class : 2
ADR/RID label :
Other information : Hazard identification number

20
Sea
UN number : 3340
Proper shipping name : REFRIGERANT GAS R 407C
IMDG Class : 2.2
IMDG label :
Other information : Emergency Schedules (EmS)

2-09
15. Regulatory information

EU Regulations
Risk Phrases : This product is not classified according to the EU regulations.
Safety Phrases : S9- Keep container in a well-ventilated place.
S23- Do not breathe gas.
Product Use : Classification and labelling have been performed according to EU directives
67/548/EEC, 88/379/EEC, including amendments and the intended use.
- Industrial applications.
16. Other information

Full text of R-Phrases with no. :
appearing in Section 2 - United
Kingdom (UK)
HISTORY
Date of printing : 10/17/2002.
Date of issue : 10/16/2002.
Version : 3
AMERFROST® is a registered trademark of Ashland Inc.

AMERFROST A407c
Notice to Reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor
any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained
herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown
hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these
are the only hazards that exist.
Date of issue Version
10/16/2002. 3 Page: 5/5

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Conforms to 91/155/EEC - 2001/58/EC - United Kingdom (UK)

SAFETY DATA SHEET

Chemical name* CAS No. % EC Number Classification

* Occupational Exposure Limit(s), if available, are listed in Section 8

Date of issue : 10/16/2002. Page: 1/5

6. Accidental release measures

7. Handling and storage

8. Exposure controls/personal protection

Ingredient Name Occupational Exposure Limits

Respiratory system : In case of insufficient ventilation, wear suitable respiratory equipment.

Skin and body : Lab coat.

Date of issue : 10/16/2002. Page: 2/5

9. Physical and chemical properties

Solubility : Very slightly soluble in cold water.

10. Stability and reactivity

11. Toxicological information

Mutagenic Effects : Not available.

12. Ecological information

Date of issue : 10/16/2002. Page: 3/5

13. Disposal considerations

European Waste Catalogue (EWC) : 14 05 01

14. Transport information

Other information : Hazard identification number

Other information : Emergency Schedules (EmS)

15. Regulatory information

16. Other information

Date of issue : 10/16/2002. Page: 4/5

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