4 Bonding P1

Download as pdf or txt
Download as pdf or txt
You are on page 1of 19

IB Chemistry SL Classified Paper_1 Chapter_4

47 4 – Chemical Bonding Mostafa Barakat (0100 165 44 62)


IB Chemistry SL Classified Paper_1 Chapter_4

SPECIMEN 2016 Q (9, 10, 11, 12)


1) 9. Which is the best description of ionic bonding?
A. Electrostatic attraction between oppositely charged ions
B. Electrostatic attraction between positive ions and electrons
C. Electrostatic attraction of nuclei towards shared electrons in the bond
between the nuclei
D. Electrostatic attraction between nuclei
2) 10. Which has bonds with the greatest covalent character?
A. SrCl2
B. SiCl4
C. SnCl2
D. Sn
3)11. Which bond is the least polar?
A. C=O in CO2
B. C–H in CH4
C. C–Cl in CCl4
D. N–H in CH3NH2
4) 12. Which substance has a high melting point and does not conduct
electricity in any state?
A. PbBr2
B. Fe
C. NaCl
D. SiO2
May 2016 TZ0 Q (9, 10, 11, 12)
5) 9. Which molecule is non-polar?
A. OF2
B. NH3
C. BF3
D. SO2
6) 10. Which compound contains both ionic and covalent bonds?
A. SiH4
B. NaNO3
C. H2CO
D. Na2S

48 4 – Chemical Bonding Mostafa Barakat (0100 165 44 62)


IB Chemistry SL Classified Paper_1 Chapter_4

7) 11. Which compound has resonance structures?


A. C6H12
B. CH3CHO
C. NaBr
D. Na2CO3
8) 12. Which of the following are van der Waals’ forces?
I. Dipole-dipole forces
II. Hydrogen bonds
III. London (dispersion) forces
A. I and II only
B. I and III only
C. II and III only
D. I, II and III
Nov 2016 TZ0 Q (9, 10, 11, 12)
9) 9. Which pair of molecules has the same bond angles?
A. PCl3 and BCl3
B. SO2 and CO2
C. H2O and NH3
D. CCl4 and SiH4
10) 10. The C=N bond has a bond length of 130 pm and an average bond
enthalpy of 615 kJ mol–1. Which values would be most likely for the C–N
bond?

11) 11. Between which pair of molecules can hydrogen bonding occur?
A. CH4 and H2O
B. CH3OCH3 and CF4
C. CH4 and HF
D. CH3OH and H2O

49 4 – Chemical Bonding Mostafa Barakat (0100 165 44 62)


IB Chemistry SL Classified Paper_1 Chapter_4

12) 12. Which substance has a giant covalent structure?

May 2017 TZ1 Q (9, 10, 11, 12)


13) 9. A substance has the following properties:

What is the most probable structure of this substance?


A. Network covalent
B. Polar covalent molecule
C. Ionic lattice
D. Metallic lattice
14) 10.Which two atoms form the most polar bond?
A.C and F
B.C and Cl
C.Si and F
D.Si and Cl
15) 11.Which combination describes the sulfate(IV) ion, SO32– (also known
as sulfite ion)?

50 4 – Chemical Bonding Mostafa Barakat (0100 165 44 62)


IB Chemistry SL Classified Paper_1 Chapter_4

16) 12.Which correctly states the strongest intermolecular forces in the


compounds below?

May 2017 TZ2 Q (9, 10, 11, 12)


17) 9. How many bonding electrons are there in the urea molecule?

A. 8
B. 16
C. 20
D. 24
18) 10. Which bonds cause the boiling point of water to be significantly
greater than that of hydrogen sulfide?
A. London (dispersion)
B. Covalent
C. Ionic
D. Hydrogen
19) 11. What are the approximate bond angles and structure of crystalline
SiO2?

51 4 – Chemical Bonding Mostafa Barakat (0100 165 44 62)


IB Chemistry SL Classified Paper_1 Chapter_4

20) 12. Which metal has the strongest metallic bond?


A. Li
B. Na
C. K
D. Rb
Nov 2017 TZ0 Q (9, 10, 11, 12)
21) 9. The electronegativity values of four elements are given.

C N O F
2.6 3.0 3.4 4.0
What is the order of increasing polarity of the bonds in the following
compounds?
A. CO < OF2 < NO < CF4
B. CF4 < CO < OF2 < NO
C. NO < OF2 < CO < CF4
D. CF4 < NO < OF2 < CO
22) 10. Which compound has the shortest C–N bond?
A. CH3NH2
B. (CH3)3CNH2
C. CH3CN
D. CH3CHNH
23) 11. Which of the following series shows increasing hydrogen bonding with
water?
A. Propane < propanal < propanol < propanoic acid
B. Propane < propanol < propanal < propanoic acid
C. Propanal < propane < propanoic acid < propanol
D. Propanoic acid < propanol < propanal < propane
24) 12. Which statements are correct for metals?
I. They conduct electricity because they have free moving ions.
II. They consist of a close-packed lattice of positive ions with delocalized
electrons.
III. They are malleable because the layers of positive ions can slide over
each other.
A. I and II only
B. I and III only
C. II and III only
D. I, II and III

52 4 – Chemical Bonding Mostafa Barakat (0100 165 44 62)


IB Chemistry SL Classified Paper_1 Chapter_4

May 2018 TZ1 Q (7, 9, 10, 11, 12)


25) 7. Which describes the oxide of sodium, Na2O?

26) 9. What is the formula of ammonium phosphate?


A. (NH3)3PO4
B. (NH4)3PO4
C. (NH4)2PO4
D. (NH3)2PO3
27) 10. Which form of carbon is the poorest electrical conductor?
A. Graphite
B. Graphene
C. Diamond
D. Carbon nanotube
28) 11. What is the molecular geometry and bond angle in the molecular ion
NO3−?

29) 12. What are the strongest intermolecular forces between molecules of
propanone, CH3COCH3, in the liquid phase?
A. London (dispersion) forces
B. Covalent bonding
C. Hydrogen bonding
D. Dipole–dipole forces
53 4 – Chemical Bonding Mostafa Barakat (0100 165 44 62)
IB Chemistry SL Classified Paper_1 Chapter_4

May 2018 TZ2 Q (9, 10, 11, 12)


30) 9. What is the formula of magnesium nitride?
A. MgN
B. Mg2N3
C. Mg3N
D. Mg3N2
31) 10. Which species has the longest carbon to oxygen bond length?
A. CO
B. CH3OH
C. CH3CO2−
D. H2CO
32) 11. What are the predicted electron domain geometries around the carbon
and both nitrogen atoms in urea, (NH2)2CO, applying VSEPR theory?

33) 12. The compounds shown below have similar relative molecular masses.
What is the correct order of increasing boiling point?
A. CH3COOH < (CH3)2CO < (CH3)2CHOH
B. CH3COOH < (CH3)2CHOH < (CH3)2CO
C. (CH3)2CO < CH3COOH < (CH3)2CHOH
D. (CH3)2CO < (CH3)2CHOH < CH3COOH
Nov 2018 TZ0 Q (9, 10, 11, 12)
34) 9. Which species has the same molecular geometry as SO32−?
A. BF3
B. SO3
C. PF3
D. CO32−

54 4 – Chemical Bonding Mostafa Barakat (0100 165 44 62)


IB Chemistry SL Classified Paper_1 Chapter_4

35) 10. How many lone pairs and bonding pairs of electrons surround the
central chlorine atom in ClF2+?

36) 11. Which compound has the highest boiling point?


A. CH3CHO
B. CH3CH2F
C. CH3OCH3
D. CH3CH2NH2
37) 12. Which molecule is polar?
A. BeCl2
B. BCl3
C. NCl3
D. CCl4
May 2019 TZ1 Q (9, 10, 11, 12)
38) 9. What is the order of increasing boiling point?

39) 10. Which species does not have resonance structures?

55 4 – Chemical Bonding Mostafa Barakat (0100 165 44 62)


IB Chemistry SL Classified Paper_1 Chapter_4

40) 11. Which describes an ionic compound?

41) 12. Which combination corresponds to a strong metallic bond?

May 2019 TZ2 Q (9, 10, 11, 12)


42) 9. How does a lithium atom form the most stable ion?
A. The atom gains a proton to form a positive ion.
B. The atom loses a proton to form a negative ion.
C. The atom loses an electron to form a positive ion.
D. The atom gains an electron to form a negative ion.
43) 10. Which combination causes the strength of metallic bonding to
increase?

56 4 – Chemical Bonding Mostafa Barakat (0100 165 44 62)


IB Chemistry SL Classified Paper_1 Chapter_4

44) 11. Which molecule contains an incomplete octet of electrons?


A. NF3
B. BF3
C. BrF
D. SF2
45) 12. Which compound has hydrogen bonds between its molecules?
A. CH4
B. CH4O
C. CH3Cl
D. CH2O
Nov 2019 TZ0 Q (9, 10, 11, 12)
46) 9. Which is correct for all solid ionic compounds?
A. High volatility
B. Poor electrical conductivity
C. Low melting point
D. Good solubility in water
47) 10. Which compound has the shortest C to O bond?
A. CH3CHO
B. CO
C. CO2
D. C2H5OC2H5
48) 11. Which describes a resonance structure?
A. Double bond can be drawn in alternative positions.
B. Bonds vibrate by absorbing IR radiation.
C. A double and a single bond in the molecule
D. A Lewis structure
49) 12. What is the structure and bonding in SiO2(s)?

57 4 – Chemical Bonding Mostafa Barakat (0100 165 44 62)


IB Chemistry SL Classified Paper_1 Chapter_4

Nov 2020 TZ0 Q (9, 10, 11, 12)


50) 9. Which formula is correct?
A. NH4PO4
B. (NH4)2PO4
C. (NH4)3PO4
D. (NH4)3(PO4)2
51) 10. Which molecule is most polar?
A. CHF3
B. CF4
C. CClF3
D. CCl4
52) 11. Which combination correctly describes the geometry of the carbonate
ion, CO32−?

53) 12. Which series shows the correct order of metallic bond strength from
strongest to weakest?
A. Na > K > Rb > Mg
B. Mg > Rb > K > Na
C. Rb > K > Na > Mg
D. Mg > Na > K > Rb
May 2021 TZ1 Q (9, 10, 11, 12)
54) 9. The Lewis structure of methylamine is shown.

What is the molecular geometry around N?


A. Square planar
B. Tetrahedral
C. Trigonal planar
D. Trigonal pyramidal
58 4 – Chemical Bonding Mostafa Barakat (0100 165 44 62)
IB Chemistry SL Classified Paper_1 Chapter_4

55) 10. Which compound contains both ionic and covalent bonds?
A. MgO
B. CH2Cl2
C. CH3COOH
D. NaOH
56) 11. Which substance is most likely to be ionic?

57) 12. Along which series is the bond angle increasing?


A. NH3 H2O CH4
B. CH4 NH3 H2O
C. H2O NH3 CH4
D. H2O CH4 NH3
May 2021 TZ2 Q (9, 10, 11, 12)
58) 9. Which compound has the greatest volatility under the same conditions?
A. SO2
B. SiO2
C. SnO2
D. SrO
59) 10. Which compound has the shortest C to N bond?
A. HCN
B. CH3CH2NH2
C. CH3CHNH
D. (CH3)2NH
60) 11. What is the formula of the compound formed from Ca2+ and PO43–?
A. CaPO4
B. Ca3(PO4)2
C. Ca2(PO4)3
D. Ca(PO4)2

59 4 – Chemical Bonding Mostafa Barakat (0100 165 44 62)


IB Chemistry SL Classified Paper_1 Chapter_4

61) 12. Which is the correct order based on increasing strength?


A. covalent bonds < hydrogen bonds < dipole-dipole forces < dispersion
forces
B. dipole-dipole forces < dispersion forces < hydrogen bonds < covalent
bonds
C. dispersion forces < dipole-dipole forces < hydrogen bonds < covalent
bonds
D. dispersion forces < dipole-dipole forces < covalent bonds < hydrogen
bonds
Nov 2021 TZ0 Q (9, 10, 11, 12, 13)
62) 9. Which molecule has the weakest nitrogen to nitrogen bond?
A. N2
B. N2H2
C. N2H4

63) 10. Which combination would create the strongest ionic bond?

64) 11. Which compound contains both ionic and covalent bonds?
A. CH3COONa
B. CH3COOH
C. K2O
D. CaCl2
65) 12. The following compounds have similar relative molecular masses.
What is the order of increasing boiling point?
A. CH3CH2CH2OH < CH3CH2CHO < CH3COOH
B. CH3CH2CHO < CH3CH2CH2OH < CH3COOH
C. CH3CH2CHO < CH3COOH < CH3CH2CH2OH
D. CH3COOH < CH3CH2CHO < CH3CH2CH2OH

60 4 – Chemical Bonding Mostafa Barakat (0100 165 44 62)


IB Chemistry SL Classified Paper_1 Chapter_4

66) 13. Which alcohol is least soluble in water?


A. CH3OH
B. CH3CH2OH
C. CH3CH2CH2OH
D. CH3CH2CH2CH2OH
May 2022 TZ1 Q (9, 10, 11, 12)
67) 9. A compound consists of the ions Ca2+ and PO43–. What are the name
and formula of the compound?

68) 10. What is the explanation for the high melting point of sodium chloride?
A. The covalent bond between sodium and chlorine atoms is strong.
B. Electrostatic attraction between sodium and chloride ions is strong.
C. Intermolecular forces in sodium chloride are strong.
D. Delocalized electrons cause strong bonding in sodium chloride.
69) 11. Which molecule is most polar?
A. CF4
B. CCl4
C. CHF3
D. CClF3
70) 12. For which species can resonance structures be drawn?
A. HCOOH
B. HCOO–
C. CH3OH
D. H2CO3

61 4 – Chemical Bonding Mostafa Barakat (0100 165 44 62)


IB Chemistry SL Classified Paper_1 Chapter_4

May 2022 TZ2 Q (9, 10, 11, 12)


71) 9. Which statement best describes the intramolecular bonding in HCN(l)?
A. Electrostatic attractions between H+ and CN– ions
B. Hydrogen bonding
C. Van der Waals forces and hydrogen bonding
D. Electrostatic attractions between pairs of electrons and positively charged
nuclei
72) 10. What is the type of bonding in a compound that has high boiling and
melting points, poor electrical conductivity, and low solubility in water?
A. Ionic
B. Molecular covalent
C. Metallic
D. Giant covalent
73) 11. What is the name of the compound with formula Ti3(PO4)2?
A. Titanium phosphate
B. Titanium(ll) phosphate
C. Titanium(lll) phosphate
D. Titanium(IV) phosphate
74) 12. What is the main interaction between liquid CH4 molecules?
A. London (dispersion) forces
B. Dipole-dipole forces
C. Hydrogen bonding
D. Covalent bonding
Nov 2022 TZ0 Q (9, 10, 11, 12, 13)
75) 9. Which molecule can be represented by resonance structures?
A. H2S
B. HNO3
C. H2O2
D. HClO
76) 10. Which molecule is polar?
A. BeH2
B. AlH3
C. PH3
D. SiH4

62 4 – Chemical Bonding Mostafa Barakat (0100 165 44 62)


IB Chemistry SL Classified Paper_1 Chapter_4

77) 11. Which structure of CF2Cl2 is shown with correct bond and molecular
dipoles?

78) 12. Alloying a metal with a metal of smaller atomic radius can disrupt the
lattice and make it more difficult for atoms to slide over each other. Which
property will increase as a result?
A. Electrical conductivity
B. Ductility
C. Malleability
D. Strength

63 4 – Chemical Bonding Mostafa Barakat (0100 165 44 62)


IB Chemistry SL Classified Paper_1 Chapter_4

79) 13. Chlorofluorocarbons (CFCs) contain bonds of the following lengths:


C–C = 1.54 × 10−10 m
C–F = 1.38 × 10−10 m
C–Cl = 1.77 × 10−10 m
What is the order of increasing bond strength in the CFC molecule?

May 2023 TZ1 Q (9, 10, 11, 12, 13)


80) 9. How many electrons will be gained or lost when the element with
electron configuration 1s2 2s2 2p3 forms an ionic bond?
A. Two electrons lost
B. Two electrons gained
C. Three electrons lost
D. Three electrons gained
81) 10. Which substance is likely to have an ionic lattice structure at 298 K
and 100 kPa?

82) 11. Why does the melting point of the elements decrease down group 1?
A. Atomic mass increases
B. Number of electrons increases
C. Radius of metal ion increases
D. First ionization energy decreases
83) 12. In which molecule does the central atom have an incomplete octet of
electrons?
A. H2Se
B. PH3
C. OF2
D. BF3
64 4 – Chemical Bonding Mostafa Barakat (0100 165 44 62)
IB Chemistry SL Classified Paper_1 Chapter_4

84) 13. Which allotrope, oxygen or ozone, has the stronger bond between O
atoms, and which absorbs higher frequency UV radiation in the
atmosphere?

May 2023 TZ2 Q (9, 10, 11, 12)


85) 9. Which compound is both volatile and soluble in water?
A. NaCl
B. CH3CH2CH3
C. CH3OH
D. C12O22H11
86) 10. Which are the correct sequences of increasing bond strengths and
bond lengths between two carbon atoms?

87) 11. What is the electron domain geometry of sulfur dioxide, SO2?
A. bent
B. linear
C. tetrahedral
D. trigonal planar
88) 12. What is the correct comparison of H–N–H bond angles in NH2–, NH3,
and NH4+?
A. NH2– < NH3 < NH4+
B. NH4+ < NH3 < NH2–
C. NH3 < NH2– < NH4+
D. NH3 < NH4+ < NH2–

65 4 – Chemical Bonding Mostafa Barakat (0100 165 44 62)

You might also like