Experiment No. 3
Experiment No. 3
Aim
a) To observe the action of Zn, Fe, Cu and Al metals on the
following salt solutions:
ZnSO4 (aq)
FeSO4 (aq)
CuSO4 (aq)
Al2(SO4)3 (aq)
b) Arrange Zn, Fe, Cu and Al metals in the decreasing order of
reactivity based on the above result.
Apparatus and Chemicals
Test tubes
Test tube stand
Distilled water
Four metals (Fe, Cu, Al, and Zn)
FeSO4 solution
CuSO4 solution
Al2(SO4) solution
ZnSO4 solution
Sand paper
Principle
A more reactive metals displaces a less reactive metal from its salt solution. The
reactivity of these four metals is in the order Al > Zn > Fe > Cu. As such aluminium
will displace Zinc, iron and copper.
Zinc will displaces iron and copper from their solutions. But it will not displaces
aluminium from its salt solution.
Zn + Al2(SO4)3 → No reaction
Zn + FeSO4 → ZnSO4 + Fe
Zn + CuSO4 → ZnSO4 + Cu
Fe + CuSO4 → FeSO4 + Cu
Procedure
Clean the metals with sand paper and cut into small pieces.
Take 10 mL each of ZnSO4, FeSO4, and CuSO4 solutions in three test tubes. Add 1-2 small
pieces of aluminium to each test tube. Record your observation in the table.
Take 10 mL each of Al2(SO4)3, FeSO4 and CuSO4 solutions in three test tubes. Add 1-2 small
pieces of Zinc to each test tube. Record your observations in the table.
Take 10 mL each of Al2(SO4)3, FeSO4 and CuSO4 solutions in three test tubes. Add 1-2 small
pieces of iron to each test tube. Record your observations in the table.
Take 10 mL each of Al2(SO4)3, FeSO4 and FeSO4 solutions in three test tubes. Add 1-2 small
pieces of copper to each test tube. Record your observations in the table.
Observations
Metal
Al2(SO4)3 sol. ZnSO4 sol. FeSO4 sol. CuSO4 sol.
added
Zn is Fe is Cu is
Aluminium —–
displaced displaced displaced
Fe is Cu is
Zinc No reaction —–
displaced displaced
Cu is
Iron No reaction No reaction —–
displaced
No
Copper No reaction No reaction —–
reaction
Inference : The order of reactivity of these four metals is ; Al > Zn > Fe > Cu
Precautions
Use only distilled water for the experiment.
Add 1-2 drops of conc. H2SO4 to clear the solutions of metals salts (if needed).
Thoroughly clean the apparatus before the experiment.
Clean the metals pieces with sand paper before experiment