TStsoln 3
TStsoln 3
Mock Test - 03
DURATION
DURATION ::180
90 Minutes
Minutes M.MARKS : 300
ANSWER KEY
[1]
Section-I (PHYSICS)
1. (1) 5. (4)
Value of g at equator g A g R2 C = NBiA sin 90°
Value of g at height h above the pole,
or 10 –6
–3
175 B 10 10
180
–4
2h
g B g.1
R B = 10–3T
As object is weighed equally at the equator and
poles, it means g is same at these places. 6. (4)
g A gB As, we know that an undamped oscillation can be
defined as the electrical oscillation whose
2h
g R2 g 1 amplitude remains constant with time or does not
R change with time.
2gh R 2 2 Here, we have a relation between spring
R2 = h
R 2g constant k, damping constant r, mass of the
2. (3) oscillator m with angular frequency as:
According to Doppler’s effect, k r2
v v0 m 4m 2
Apparent, Frequency f
f0
v vs
k r2
f vf 0 1
Now, f 0 v0 m 4mk
v vS v vS
r2
0 1 1 1%
So, slope = 0
f 8mk
v vs
Therefore, the correct option is (4) i.e the time
decreases by 1%
3. (2)
7. (1)
Inside sphere field varies linearly i.e. E r with
1
distance and outside varies according to E 2
r
Hence the variation is shown by curve (1)
8. (2)
T cos = mg
The focal length f of the equivalent mirror when
kq 2 lens is silvered,
T sin =
x2 1 2 1 2 1
kq 2 f f1 f m 15
tan
x 2 mg 15
f cm
x 2
tan sin
2l Since f has a positive value, the combination
x kq 2 behaves as a converging mirror.
2 15
2l x mg Here u = –20 cm, f – cm, v = ?
2
1/3
q 2l 1 1 1
x According to mirror formula
2 mg v u f
0
1 1 1
–
4. (2) v 20 15 / 2
Using formula, internal resistance, v = – 12 cm
l l 52 40 Negative sign indicates that the image is 12 cm in
r 1 2 s 5 1.5
l2 40 front or left of mirror.
[2]
9. (1) Current through the circuit,
Energy released in the given process = Binding
energy of product – Binding energy of reactants
= 7.6 × 4 – (1.1 × 2) × 2
= 30. 4 – 4.4 = 26 MeV
10. (4)
At maximum height, inclination with horizontal
becomes zero E
i
u sin gt r r2
so, t u= … (i)
g sin Potential difference through capacitor
Now, R = u cos × T R = u cos × 2t Q E
Vc E – ir E – r
R R sin C r r2
cos = cos = [From (i)]
2ut 2t.gt r2
2 2
Q CE
2gt 20t R r r2
tan = tan = cot
R R 20t 2
14. (2)
The contribution from the diode (1) is A,C. As
11. (3) shown in the fig. (a) during one half cycle the
For r R polarity of primary P and secondary S are
mv 2 GM opposite such that diode (1) is reversed biased
m 2 Where M is the total mass of
r r and hence non-conducting.
the spherical system.
15. (4)
1 4 3
v M R 0
r 3
For r < R
mv 2 GMr
m 3
r R
vr
i.e., v-r graph is a straight line passing through
origin. Distance, PQ = vP × t (Distance = Speed × time)
Distance, QR = v.t
12. (1) PQ 1 vp t v
cos60° = vP =
Electrostatic field at P is QR 2 v.t 2
16. (1)
From FBD shown, T = Mg – N
R = mg + N = ( + m)g – T
E p E1 E2 C1 P C2 P
3 0 3 0
30
C1P – C2 P
30
C1P PC2
30
C1C2
For no movement of block,
Statements c and d are true T R T [(M + m)g – T]
13. (1) M mg 0.5 5 4 10 45
In steady state, flow of current through capacitor T T
1 1 0.5 1.5
will be zero.
Tmax = 30N
[3]
1
17. (4) H 4
Or x r
Le t be the time taken by the particle to drop H h
from height h to collide with particle thrown
upward. 19. (3)
Δ temp Δ force
FL
(or) L ΔT
AY
FL F
2
AYT r YT
Coefficient of volume expression
3F
3
r 2YT
Using,
20. (1)
v2 u 2 2 gh v2 02 2 gh v 2 gh
Q2 TL
Downward distance travelled Coefficient of performance
W TH TL
1 2 1 h h
S1 gt g .
2 2 2g 4 dQ2
Distance of collision point from ground dt 263 263
h 3h dW 298 263 35
S2 h dt
4 4
Speed of (A) just before collision dQ2 263 dW 263
35
gh dt 35 dt 35
v1 gt
2 dQ2
And speed of (B) just before collision 263 watt
dt
gh
v2 2 gh
2
21. (4)
Using principle of conservation of linear
momentum mv1 + mv2 = 2mvf A hydrogen atom makes a transition from n = 2
gh gh to n = 1
2 gh m Then wavelength
2 2
vf m 0
2m 1 1 1
After collision, time taken (t1) for combined mass = Rcz 2 2 2 Rc(1)2 1
n1 n2 4
to reach the ground is
3h 1 2 3h 3
gt1 t1 Rc … (1)
4 2 2g 4
18. (1)
According to Bernoulli's Principle,
1 2 1
v1 gh v22 v12 2 gh v22
2 2
2 gH 2 gh v22 … (i)
a1v1 a2v2
r2 For ionized lithium
r 2 2 gh x 2 v2 v2 2
2 gh
x
2 1 1
Substituting the value of v2 in equation (i) Rc 3 2 Rc9 2
n n
r4
2 gH 2 gh 2 gh 3 1
x4 Rc Rc 9 2
4 n
[4]
3 9
4 n2
n = 12 2 3
The least quantum number must be 4.
22. (2)
dv
F ma qE m
dt
qEdt q sin1000 t
dv dt
m m
E sin103 t iˆ given 25. (9)
/
v q
0 dv
m sin1000t dt
0
T 2
max.speed is at 2 2 For heat flow from P to A
q cos1000t
/ dQ1 dm1 KA400
v= Lf … (i)
m 1000 0 dt dt x
For heat flow from P to B
1 cos1000t 0/ dQ2 dm KA300
= –3
Lvap 2 … (ii)
10 1000 dt dt 10 x – x
m 10 –3 kg , q 1C , E0 1NC –1 dm1 dm2
Given dt dt
and 103 rads –1 given
Dividing eq. (i) by (ii) and solving we get = 9
v – cos1000 – cos 0
1000
= – [ –1 – 1] = 2 ms –1 26. (11)
Hence maximum speed attained by the particle is Power, P = I2R
2 ms–1. 4.4 = 4×10–6 × R R=1.1 × 106
When supply of 11V is connected
23. (3)
Magnetic field in solenoid B = 0ni V 2 112
Power, P ' 106
B R 1.1
ni (where n = number of turns per unit = 11×10–5 W
0
length)
B Ni 27. (198)
0 L For obtaining secondary minima at a point, path
100i difference should be an integral multiple of
3×103 = wavelength
10 10–2
i = 3A n
d sin = n sin =
d
24. (2) For n to be maximum sin = 1
0 5 d 6 10 –5
2.0 n 100
2 – 1 2.5 6 10 –7
Total number of minima on one side = 99
Total number of minima = 198.
28. (4%)
[5]
E(t) = A2 e–t = A2e–0.2t 30. (3)
logeE = 2 loge A – 0.2t (CV) of two mixed gases is given as,
n1CV1 n2 CV2
On differentiating we get CV m i x
n1 n2
dE dA dt
2 – 0.2 t 3R 5R
E A t 1. 3. 2
2 2 9R R
As errors always add up
1 3 4 4
dE dA dt =3
100 2 100 0.2 t 100
E A t
dE
100 2 1.25% 0.2 5 1.5% 4%
E
29. (181)
Using parallel axes theorem, moment of interia
about ‘O’ l0 = Icm + md2
7 MR 2 55MR 2
2
2
6 M 2R
2
Again, moment of intertia about point P,
Ip = I0 + md 2
55MR 2 2 181
7 M 3R MR 2
2 2
Section-II (CHEMISTRY)
31. (4) S, Se, Te cannot undergo hydrogen bond formation
In oxides MO2 (M is lanthanoid metal) only four because of their larger size and lower
lanthanoids exhibit + 4 oxidation state. These electronegativity values.
lanthanoids are praseodymium (Pr, Z = 59),
neodymium (Nd, Z = 60) terbium (Tb, Z = 65) 34. (3)
dysprosium (Dy, Z = 66). In trigonal planar geometry, the hybridisation of
So, Yb (ytterbium) option (4) does not form MO2 metal M is sp2. The vector sum of two bonds,
type of oxide. dipole moment is equal and opposite to the dipole
moment of third bond.
32. (2)
Average atomic mass of Fe
54 5 56 90 57 5
= = 55.95
100
Hence option (2) is correct.
35. (2)
33. (1) N2O4 2NO2
(i) Hydrogen bonding increases the boiling point. Initial 1 mol 0
(ii) Hydrogen bonds are formed in compounds At eqn. (1 – 0.2)mol 0.4 mole
having F or O or N with hydrogen. = 0.8 mol
[6]
Total moles after dissociation, n2 = 0.8 + 0.4 = 1.2 Alkene undergoes electrophilic addition with HBr
Initial temperature = 300 K to give a major product by Markownikoff rule by
SN1mechanism.
P1V = n1 RT1 or 1 × V = 1 × R × 300 ……(i)
No. of moles after dissociation, n2 – 1.2
P2 × V = 1.2 × R × 600 ……(ii)
Dividing eqn (ii) by eqn (i)
2o carbocation undergoes methyl shift to form
1.2 600
P2 2.4atm more stable 3o carbocation
300
36. (2)
In general, the molar heat capacity for any process
is given by
R
C CV When PV constant
1
Attack of nucleophile on carbocation.
P
Here 1 , i.e. PV 1 constant 1
V
3R
For monoatomic gas, CV
2
3R R 3R R 4 R
C 2R
2 1 1 2 2 2
37. (4)
MX M X (where S is the solubility) 39. (3)
S S 3 5
Then Ksp = S or S =
2
K sp
Na 2 HAsO3 H3 AsO4 (oxidation) ……(i)
Change in O.N. = +2
For MX2 M2 2X NaBr O3 NaBr (reduction) …. (ii)
S 2S 5 1
Then, Ksp = (S) (2S)2 change in O.N. = –6
1/3 To balance the change in O.N., we will multiply
K sp first half reaction with 3 and add the second half
= 4S or S
3
4 reaction
3Na 2 HAsO 3 NaBrO 3 3H 3 AsO 4 NaBr
Similarly for M 3X 3M 3 X On balancing hydrogen:
3S S
1/4 3Na 2 HAsO3 NaBrO3 6H
3 K sp
K sp 3S S 27S or S
4
3H 3 AsO 4 NaBr
27
On balancing Cl and Na+
From the given values of Ksp for MX MX2, M3X,
3Na 2 HAsO3 NaBrO3 6H 6Cl
we can find the solubilities of these salts at
temperature, T. 3H 3AsO 4 NaBr 6Na 6Cl
Solubility of MX 4 108 2 104 Hence x = 3, y = 1 and z = 6.
1/3 40. (3)
3.2 10 14
Solubility of MX2 = or 2Ca 2 Na 2 Na 4 PO 3 6
4
1/3
4Na Na 2 Ca 2 PO3 6 water soluble
32 15 Polyphosphate makes a soluble complex with
4 10 or 2 10 5
Cationic species.
1/4
2.7 10 15 41. (4)
Solubility of M 3X
27 Hinsberg reagent (benzene sulphonyl chloride)
gives reaction product with 1° amine and it is
1/4 soluble in dil. NaOH.
1016 or 104
So, MX > M3X > MX2 42. (2)
Structure of borax
38. (4)
As we go down the group 1 from (Li to K), the
ionic radius increases, degree of solvation
decreases and hence effective size decreases
resulting in increase in ionic mobility. Hence,
equivalent conductance at infinite dilution
increases in the same order.
49. (2)
Correct formula of borax is During the extraction of copper, iron is present in
Na2[B4O5(OH)4].8H2O the ore as impurity (FeS).
Borax has tetra nuclear [B4O5(OH)4]2– unit. The ore together with a little coke and silica is
smelted. FeS present as impurity in the ore is
Only two ‘B’ atom lie in same plane.
oxidized to iron oxide, which then reacts with
Two boron are sp2 and two are sp3 hybridised. silica to form fusible ferrous silicate which is
One terminal hydroxide is present per boron removed as slag.
atom.
2FeS + 3O2 2FeO + 2SO2
43. (2) FeO + SiO2 FeSiO3 (slag)
LiNO3 behave differently from other alkali metal
nitrates. 50. (2)
Lithium nitrates decompose on heating producing
Phenol on reaction with Br2 in CS2/273 K
NO2. Whereas other alkali nitrates like NaNO3
undergoes at electrophilic substituion reaction by
produces nitrite and oxygen on decomposition..
Br+ (electrophile) in aprotic solven CS2 to give 4-
1 bromophenol as the major product.
2LiNO 3 Li 2O 2NO 2 O 2
2
1
NaNO3 NaNO 2 O 2
2
44. (1)
A straight chain alkane has a higher boiling point
than that of branched one.
45. (3)
Concentration of F– in drinking water above 2
ppm cause brown mottling of teeth.
46. (1)
3
For bcc structure atomic radius, r = a
4
51. (60)
3
4.3 1.86 Charge (Q) = It = 2 × 8 × 60 = 960C = 0.01F
4
Since, r = half the distance between two nearest Cr2O72 14H 6e 2Cr 3 7 H 2O
6F 2 Moles
neighbouring atoms.
The flow of charge in terms of
Shortest inter ionic distance = 2 × 1.86 = 3.72
1
q = 0.01 mole
3
47. (1)
Theoretical mass of Cr+3
Acccording to Henry’s Law
1 960
[P = KHX] = 52 0.173 g
3 96000
PN2 K H xN2
So, efficiency
0.8 × 5 = 1 × 105 × xN2 Wactual 0.104
= 100 100 60%
xN2 = 4 ×10–5; solubility in 10 moles Wtheoretical 0.173
= 4 × 10–4 52. (3)
The sum of mass number and atomic numbers of
48. (2) reactants = The sum of mass number and atomic
no. of products in a nuclear reaction. The given
nuclear fission reaction is 56. (6)
235
10 139 94 1 Structure of melamine as follows:
92 U n 54 Xe 38 Sr 30 n
53. (18)
Let the weight of acetic acid intially be w1 in 50
mL of 0.060 N solution.
w 1000
N1 1 Normality = 0.06 N
M.Wt. 50
w1 1000 Total no. of lone pairs of electron is ‘6’.
0.06 =
60 50
57. (4)
0.06 60 50 The number of water molecules directly bonded to
w1 0.18 g 180 mg
1000 the metal centre in CuSO4.5H2O is 4.
After an hour, the strength of acetic acid = 0.042
N
Let the weight of acetic acid w2.
w2 1000
N2
60 50 58. (1)
w 1000 Glucose being an aldose responds to Tollen’s test.
0.042 = 2 w2 = 0.126 g = 126 mg
3000 While fructose (an hydroxy ketone), although a
So amount of acetic acid adsorbed per g of ketone, undergoes rearrangement in presence of
charcoal basic medium (provided by Tollen’s reagent) to
54 form glucose, which then responds to Tollen’s test.
= 18 mg
3
54. (3) 59. (815)
Total number of stereoisomers are 3. After seen the given data.
H = [Energy of C—C Bond + Energy of H—H
55. (3) Bond] – [2 × Energy of C—H bond + Energy of
C C]
225 = (1410 + 330) – [(2 × 350) + Energy of C C]
So, Bond Energy of C C
= 815 kJ/mol
60. (1)
Anti addition of Br2 on trans alkene provides
meso compound.
*
Br
CH 3CH 2 CH CH 2
2 CH CH CH CH Br
3 2 2
Butene 1 |
Br
Function is continuous at x = 7
LHL = RHL
(7 – ) b +3 = (7 – ) a + 1
2 = (a – b) (7 – )
68. (4) 72. (3)
Let the equation of a plane parallel to the plane
x + y – 2z = 9 be x + y – 2z + k = 0
a 2b cos x a
2b cos y = 2a2 – 3b2
= (n + 1) (n + 1)! – n. n!
75. (3)
f (x) = 4x3 – 6x2 – 72x + 5 = [(n + 1)2 – n] n!
f ' (x) = 12x2 – 12x – 72 & f ''(x) = 24 x – 12 = (n2 + n + 1) n!
Now f '(x) = 0
12 (x2 – x – 6) = 0 78. (4)
(x – 3) (x + 2) = 0 log 2 ( x 5)
For domain of f (x) =
x = –2, 3 x2 5x 6
f '' (–2) = – 60 x2 + 5x + 6 0 and x + 5 > 0
x = – 2 is a point of local maximum x –2, – 3 and x > – 5
f '' (3) = 60 Domain of f (x) = (–5, ) – {–2, – 3}
x = 3 is a point of local minimum
Hence, (–2, 3) is the required ordered pair. 79. (1)
76. (2)
We know, the shortest distance between the lines
r a1 b1 & r a2 b2 is given by
( a2 a1 ) (b1 b2 )
d
b1 b2 Required area =
/3 /2
Here, a1 5iˆ 3 ˆj 2kˆ, a2 2iˆ 3 ˆj 4kˆ
sin 3 xdx sin 3x dx
b1 iˆ 2 ˆj 3kˆ, b2 2iˆ 4 ˆj 5kˆ /6 /3
/3 /2
Now, a2 a1 3iˆ 0 ˆj 2kˆ cos3 x cos3 x
3
3 /6 /3
iˆ ˆj kˆ
1 1
b1 b2 1 2 3 2iˆ jˆ 0kˆ [–1 – 0] [0 (1)]
3 3
2 4 5
2
= sq. units
a2 a1 b1 b2 (3iˆ 0 ˆj 2kˆ) . 3
(2iˆ ˆj 0kˆ) 6 and b1 b2 4 1 0 5 80. (1)
The given differential equation is
( a2 a1 ) (b1 b2 ) dy 1
Shortest distance, d (4 x 2 1) 8 xy 2
b1 b2 dx 4x 1
6 6 dy 8 xy 1
2
5 5 dx 4 x 1 (4 x 1)2
2
8x 1
Here, P = and Q
77. (4) 4x 1 2
(4 x 1)2
2
2
n n 1 n2 I.F. = e
8 x /(4 x 1) dx
elog(4 x
2
1)
4 x2 1
Let n! (n 1)! (n 2)!
Using y (I.F.) = Q( I .F .) dx C ,
1 1 1
1
y (4 x 2 1) 2
dx C
4x 1
1 2x 1 85. (4)
y (4 x 2 1) log C
4 2x 1 x 4
cos 1 sin 1
5 5 2
81. (27) x 4 1 1
63 r r x4 sin a cos a 2
a b 5 5
63
General term is Tr+1 = Cr 3
b
3
a
r 2r 21 86. (70)
21
63Cr a 2b 3 2
x2 y 2
Equation of ellipse is 1
Power of a = power of b 16 9
r 2 21 General equation of tangent to the ellipse of slope
21 r
2 3 2 m is
r = 27
y mx 16m2 9
2
n1 12 d12 n2 22 d 22 Let x be the length of side, V be the volume and S
be the surface area of the cube.
n1 n2
Then, V = x3 and S = 6x2, where x is a function of
100(9 144) 400(16 9) time t.
500
dV d dx
25300 12cm3 /s= ( x3 ) 3 x 2
= 50.6 dt dt dt
500
dx 4
dt x 2
83. (5)
dS d 4 48
5 (6 x 2 ) 12 x 2 x
lim x A dt dt x
x 0 x
dS
5 5 6cm2 /s
lim x A dt x 8cm
x 0 x x
5
lim 5 x A 88. (3)
x 0 x
Consider the line through (4, –1, 3) with DC's
5–0=A
1 2 2
A=5 , , is
3 3 3
x 4 y 1 z 3
84. (60) r
1/ 3 2 / 3 2 / 3
(6 1)! r 2r 2r
6 girls can stand in a circle by number of x 4 , y = –1+ , z 3
2! 3 3 3
ways, because in anticlockwise and clockwise It lies on the plane x + 3y – z = 3
order every person will have the same neighbours. r 6r 2r
(6 1)! 4 3 3 3
60 3 3 3
2! r=3
89. (0) 1 x x2 1 x x2
2
cos x ex 2 x cos 2 x / 2 1 y y 2 xyz 1 y y2
f ( x) x 2 sec x sin x x 3 1 z z2 1 z z2
1 2 x tan x
1 x x2
f (–x) = – f (x) f (x) is odd (1 xyz ) 1 y y2 0
f ' (x) is even f ''(x) is odd 1 z z2
Thus, f (x) + f '' (x) is odd function
1 + xyz = 0, since the determinant 0
Let (x) = (x2 + 1) {f (x) + f '' (x)}
(–x) = – (x)
i.e. (x) is odd
/2
( x)dx 0
/2
90. (1)
x x2 1 x3 x x2 1 x x2 x3
y y 2 1 y3 y y2 1 y y2 y3
z z2 1 z3 z z2 1 z z2 z3
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