Neutron Scattering Study Points The Way To Electrochemical For Carbon-Neutral Ammonia

Scientists from Stanford University and the Department of Energy's Oak Ridge National Laboratory are
turning air into fertilizer without leaving a carbon footprint. Their discovery could deliver a much-
needed solution to help meet worldwide carbon-neutral goals by 2050.
Published in the journal Energy & Environmental Science, the study describes a sustainable
electrochemical—rather than chemical—process for producing ammonia, a key ingredient for nitrogen
fertilizer.
In essence, the researchers used neutron scattering to understand how cycling an electric current during
the conversion of nitrogen to ammonia, also known as the nitrogen reduction reaction, increases the
amount of ammonia produced. This process has the potential to enable farmers to convert nitrogen, the
most abundant element in our atmosphere, into ammonia-based fertilizers without emitting carbon
dioxide.
"Ammonia is critical to food supplies for most of the world's population," said Sarah Blair, a former
doctoral student at Stanford's Center for Interface Science and Catalysis who now works at the National
Renewable Energy Laboratory in Colorado as a postdoctoral researcher. "As the world population
continues to grow, we need sustainable ways to produce fertilizers—especially as warming intensifies."
Industrial fertilizers allow farmers to grow more food on less land. Yet the primary method to create
industrial ammonia for more than a century, the Haber-Bosch process, accounts for nearly 2% of all
carbon dioxide emissions because of the fossil fuels it requires.
Two percent might not sound like a lot, but we are adding carbon dioxide to the atmosphere faster than
the planet can absorb it, making every effort count toward reducing that number. The Haber-Bosch
process produces about 500 million tons of carbon dioxide each year, which would require the
equivalent of almost all of the federal lands in the U.S. to absorb and store.
Insights from the study could also help scientists understand other processes for making carbon-neutral
ammonia for other applications. These could include recycling or recapturing fertilizer runoff before it
enters water streams and producing ammonia at seaports for fueling ships. Global shipping produces
another 3% of the world's carbon dioxide emissions, and fossil fuel combustion accounts for the largest
source of carbon dioxide from human activity.
"You can't improve the design of something if you don't know how it's already working," Blair said.
"Neutrons help science evolve by shedding light at the atomic level on certain systems that are
impossible to study otherwise."
Blair used a glovebox in the experiments, which required close collaboration and careful design by
Doucet so the project could make the most of limited beam time. Credit: Genevieve Martin/ORNL,
U.S. Dept. of Energy
Blair and Mat Doucet, a senior neutron scattering scientist at ORNL, conducted their neutron
experiments on the Liquids Reflectometer instrument at the Spallation Neutron Source. Their aim was
to understand the effect of cycling an electric current on the formation of the solid-electrolyte interface,
or SEI, in a nitrogen reduction reaction system that produces ammonia using lithium as a mediator.
Understanding SEI formation holds the key not only to unlock the science behind the electrochemical
production of ammonia but also to producing better batteries. The study also marks the first use of
neutron-based techniques to observe the formation of an SEI layer during this particular
electrochemical conversion.
In addition, a singular new neutron technique, time-resolved reflectometry, emerged from the study.
This technique allows scientists to slice neutron data into increments of a few seconds, capturing
greater detail, much like watching a movie frame by frame. Initially, Blair and Doucet thought the
electrochemical changes they observed happened gradually. However, thanks to the new technique,
they discovered changes happening in much smaller time increments.
"Processes that appear to be linear might not be linear at all when you look at them more closely,"
Doucet said. "Getting to that structure as a function of time is the hard part. The technique we
developed for this experiment allowed us to do just that."
Discoveries at SNS lay the foundations of knowledge for technological innovations that improve
people's daily lives. The technique Blair and Doucet developed opens new possibilities in
electrochemistry for SNS users.
Hanyu Wang, ORNL instrument scientist who also works closely with SNS users, said, "These time-
dependent experiments will draw scientists who study separation chemistries."
ORNL Neutron Reflectometry group leader Jim Browning added, "Their approach can answer a lot of
questions for separation chemistries, batteries, and an entire gamut of different areas of interest, like
energy production, energy storage, and conservation of energy."

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Scientists from Stanford University and the Department of Energy's Oak Ridge National Laboratory are

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