An example of a testing system that provides the capabili- The only way to truly understand the downstream

ties to simulate the complex pressure profile of the filling performance characteristics of PET carbonated beverage
operation is the Agr PPT3000™. The PPT3000 accurately containers is by reproducing the abrupt, non-linear pres-
represents the counter-pressure filling simulation by provid- surization that a container experiences during the filling
ing a precise pressure profile that simulates a true filling process. Routine pressure testing that follows the pressure
environment. This pressure profile has been dubbed the profiles applied by the filling machine, in combination with
“Fill Ramp”, where the container is subjected to an abrupt, the monitoring of material properties, form the basis for a
~500 millisecond non-linear pressurization, up to the test sound testing program that will ensure optimal container
pressure hold level (60–100psi). It is held at that test pres- performance, both in the production/filler environment as
sure for 13 seconds, and then subjected to a pressure ramp well as throughout the commercial lifecycle.
increase of 10 psi/sec, leading to the identification of the
yield pressure and ultimate burst pressure. The “Fill Ramp” The Agr PPT3000 is the only pressure testing system cur-
pressure profile (figure 4.0) shows the change in pressure vs. rently available that truly simulates the filling process and,
time for the test and how the different segments of the test ultimately, the downstream conditions.
correlate with the filling cycle.

CONCLUSION
With the trend toward high-speed, combined blow-fill
Real World
operations and the propagation of ultra-lightweight PET
containers, it has become increasingly imperative to identify Pressure Testing
of PET Containers
and correct blowmolding problems before loss-of-pressure
failures occur downstream in the filler, in the warehouse or
through retail channels.

OVERVIEW

Copyright Agr International 2017

Agr International, Inc.

Butler, PA, USA
updated 01/2017
PURPOSE container will experience an unrecoverable yield or deforma-
Figure 1.0: Bottle Pressurization Figure 3.0: Fill Cycle Diagram
Proper pressure testing of PET containers is an essential tion. The natural frequency and potential impact of these
During CSD Filling Process
part of a smooth filling process and favorable downstream End of fill cycle. processing changes drive the need to regularly pressure test
performance of carbonated soft drinks (CSD) and other Understanding volume expansion at this containers to determine how a given production run will
pressure products. Whether we realize it or not, all PET con- CO2 Pressure P point is critical perform under filling and down-stream conditions.
tainers used for pressure products are being pressure tested,
both as they are filled in high-speed counter-pressure filling PRESSURE TESTING
product
machines and in the distribution channels as they experience For over 25 years, PET containers have been pressure tested
varying ambient temperature conditions. Relying on the with the intent of understanding how well a container will
filling equipment and downstream events of a container’s Valve Vent tube perform under real-world filling, storage, transportation,
life cycle to verify container performance can be very costly ~13 second hold shelf-life and consumer-use conditions.
and have undesirable implications on brand confidence. For under pressure
this reason, state-of-the-art container manufacturers have When PET, as a material, is tested using a tensile tester, a
CO2 Pressure P
adopted pressure testing protocols that simulate all of the stretching force is applied to determine the amount of force
conditions experienced by the container during the filling Settle time required to reach the yield point (where material is perma-
process and beyond. This paper will discuss the pressurized nently deformed) and is continued until failure (point where
environments that a PET carbonated beverage is subjected the material stops stretching and breaks). With a container,
to and the test methods used to ensure that commercial Typical counter this can be equated to the application of internal pressure
pressure used: Container
quality containers are produced. expanding the container volume and stretching the material
• Cold product filling to the point where the PET yields, and then a continuation
Pressure P=60–80 psi
CONTAINER FILLING of pressurization to container failure (burst). Yield and burst
• Ambient product
The typical filling process for a PET carbonated beverage filling
are the two key material failure modes experienced by a PET
container uses a counter-pressure technique. When the Pressure P=80–100 psi bottle. This simple ramp approach is acceptable for use only
Bottles in Bottles out
empty container is presented to the filling station, it is after the 13 second hold spoken of earlier.
sealed and quickly charged with CO2. The CO2 located <500 milliseconds Bottles lowered
above the carbonated product in a holding bowl as well counter pressure charge from filling valve To simulate actual conditions, a complex test is warranted
Figure 2.0: Pressure Testing:
as in the container are pressurized higher than the desired that subjects the container to the same abrupt, non-linear
non-linear vs linear pressure profiles
product carbonation level to prevent the dissolved CO2 in VOLUME EXPANSION pressure dynamic (counter-pressures) seen in the filling pro-
the product from coming out of solution during filling. A container that survives the initial rapid pressurization cess, then held at actual filling pressures for the appropriate
140
Typical counter pressures range from 60–100 psi for cold still may not provide acceptable performance. After the filling time, and then subjected to a continuously increasing
or ambient filling conditions. Gravity is used to transfer the counter-pressure has been applied, the container is subjected pressure ramp to identify the container yield point and
120
carbonated product from the bowl into the container, and to a pressure hold for approximately 13 seconds (figure 3.0). ultimate failure. Testing PET containers in this manner
after the filling process is complete, pressure is relieved from Understanding volume expansion behavior of the container provides the manufacturer with the information required to
PRESSURE (PSI)

the container. A schematic of this technique can be seen in 100 during this hold time provides an important data point understand how the containers will perform in the filling
Figure 1.0. about how the container will react throughout the com- operation and throughout the commercial lifecycle.
80 mercial lifecycle. A container with a weak overall structure
INITIAL PRESSURIZATION or lower levels of material orientation may expand beyond
Figure 4.0: Fill Ramp Test
Of particular note in the filling process is the speed of initial 60 acceptable levels, causing thinning of the wall thickness,
pressurization of the PET container, by far the most im- faster loss of carbonation and a higher risk for sidewall FILLING MATERIALS
portant step as it relates to the ongoing performance of the 40 failures. To ensure that the filled container will ultimately TEST
CONTAINER
container. The initial pressurization found in normal filling LINEAR
perform for the consumer, a quality pressure testing method COUNTER CONTAINER BURST
PRESSURE YIELD
machines occurs in approximately 500 milliseconds, as the NON-LINEAR must include the pressure hold at a value that simulates the CHARGE
20
ambient air in the container is replaced with CO2. 0 0.2 0.4 0.6 0.8 1.0 real-world experience of the bottle.
I D
PS ON
10 EC
BRITTLE FAILURES TIME (SECONDS) PROCESSING HISTORY ON INHERENT S
P ER

This rapid, non-linear pressurization in PET containers can MATERIAL PROPERTIES

trigger brittle failures, especially in the base. Excess amor- early failures occur well below the pressure level used in the The ultimate material properties of a finished PET container 100 psi
phous material that remains in the base of the container after counter-pressure filling process. Conversely, pressure testing are the cumulative result of multiple factors including the VOLUME
EXPANSION
the blowing process creates a region, with high concentra- containers with slow initial pressurization characteristics is time and temperature profiles for heating the preform, along
tions of stress, between the oriented and amorphous mate- not sufficient to identify when the blowing process is mak- with the stretching and blowing profiles in the formation
rial. The material in this region is brittle and can fracture ing containers that will not survive this first step of the filling of the container itself. A change in any of these variables 0 .5 13
easily when the container is pressurized. Many of these process (figure 2.0). will affect many factors, including the pressure at which the SECONDS
PURPOSE container will experience an unrecoverable yield or deforma-
Figure 1.0: Bottle Pressurization Figure 3.0: Fill Cycle Diagram
Proper pressure testing of PET containers is an essential tion. The natural frequency and potential impact of these
During CSD Filling Process
part of a smooth filling process and favorable downstream End of fill cycle. processing changes drive the need to regularly pressure test
performance of carbonated soft drinks (CSD) and other Understanding volume expansion at this containers to determine how a given production run will
pressure products. Whether we realize it or not, all PET con- CO2 Pressure P point is critical perform under filling and down-stream conditions.
tainers used for pressure products are being pressure tested,
both as they are filled in high-speed counter-pressure filling PRESSURE TESTING
product
machines and in the distribution channels as they experience For over 25 years, PET containers have been pressure tested
varying ambient temperature conditions. Relying on the with the intent of understanding how well a container will
filling equipment and downstream events of a container’s Valve Vent tube perform under real-world filling, storage, transportation,
life cycle to verify container performance can be very costly ~13 second hold shelf-life and consumer-use conditions.
and have undesirable implications on brand confidence. For under pressure
this reason, state-of-the-art container manufacturers have When PET, as a material, is tested using a tensile tester, a
CO2 Pressure P
adopted pressure testing protocols that simulate all of the stretching force is applied to determine the amount of force
conditions experienced by the container during the filling Settle time required to reach the yield point (where material is perma-
process and beyond. This paper will discuss the pressurized nently deformed) and is continued until failure (point where
environments that a PET carbonated beverage is subjected the material stops stretching and breaks). With a container,
to and the test methods used to ensure that commercial Typical counter this can be equated to the application of internal pressure
pressure used: Container
quality containers are produced. expanding the container volume and stretching the material
• Cold product filling to the point where the PET yields, and then a continuation
Pressure P=60–80 psi
CONTAINER FILLING of pressurization to container failure (burst). Yield and burst
• Ambient product
The typical filling process for a PET carbonated beverage filling
are the two key material failure modes experienced by a PET
container uses a counter-pressure technique. When the Pressure P=80–100 psi bottle. This simple ramp approach is acceptable for use only
Bottles in Bottles out
empty container is presented to the filling station, it is after the 13 second hold spoken of earlier.
sealed and quickly charged with CO2. The CO2 located <500 milliseconds Bottles lowered
above the carbonated product in a holding bowl as well counter pressure charge from filling valve To simulate actual conditions, a complex test is warranted
Figure 2.0: Pressure Testing:
as in the container are pressurized higher than the desired that subjects the container to the same abrupt, non-linear
non-linear vs linear pressure profiles
product carbonation level to prevent the dissolved CO2 in VOLUME EXPANSION pressure dynamic (counter-pressures) seen in the filling pro-
the product from coming out of solution during filling. A container that survives the initial rapid pressurization cess, then held at actual filling pressures for the appropriate
140
Typical counter pressures range from 60–100 psi for cold still may not provide acceptable performance. After the filling time, and then subjected to a continuously increasing
or ambient filling conditions. Gravity is used to transfer the counter-pressure has been applied, the container is subjected pressure ramp to identify the container yield point and
120
carbonated product from the bowl into the container, and to a pressure hold for approximately 13 seconds (figure 3.0). ultimate failure. Testing PET containers in this manner
after the filling process is complete, pressure is relieved from Understanding volume expansion behavior of the container provides the manufacturer with the information required to
PRESSURE (PSI)

the container. A schematic of this technique can be seen in 100 during this hold time provides an important data point understand how the containers will perform in the filling
Figure 1.0. about how the container will react throughout the com- operation and throughout the commercial lifecycle.
80 mercial lifecycle. A container with a weak overall structure
INITIAL PRESSURIZATION or lower levels of material orientation may expand beyond
Figure 4.0: Fill Ramp Test
Of particular note in the filling process is the speed of initial 60 acceptable levels, causing thinning of the wall thickness,
pressurization of the PET container, by far the most im- faster loss of carbonation and a higher risk for sidewall FILLING MATERIALS
portant step as it relates to the ongoing performance of the 40 failures. To ensure that the filled container will ultimately TEST
CONTAINER
container. The initial pressurization found in normal filling LINEAR
perform for the consumer, a quality pressure testing method COUNTER CONTAINER BURST
PRESSURE YIELD
machines occurs in approximately 500 milliseconds, as the NON-LINEAR must include the pressure hold at a value that simulates the CHARGE
20
ambient air in the container is replaced with CO2. 0 0.2 0.4 0.6 0.8 1.0 real-world experience of the bottle.
I D
PS ON
10 EC
BRITTLE FAILURES TIME (SECONDS) PROCESSING HISTORY ON INHERENT S
P ER

This rapid, non-linear pressurization in PET containers can MATERIAL PROPERTIES

trigger brittle failures, especially in the base. Excess amor- early failures occur well below the pressure level used in the The ultimate material properties of a finished PET container 100 psi
phous material that remains in the base of the container after counter-pressure filling process. Conversely, pressure testing are the cumulative result of multiple factors including the VOLUME
EXPANSION
the blowing process creates a region, with high concentra- containers with slow initial pressurization characteristics is time and temperature profiles for heating the preform, along
tions of stress, between the oriented and amorphous mate- not sufficient to identify when the blowing process is mak- with the stretching and blowing profiles in the formation
rial. The material in this region is brittle and can fracture ing containers that will not survive this first step of the filling of the container itself. A change in any of these variables 0 .5 13
easily when the container is pressurized. Many of these process (figure 2.0). will affect many factors, including the pressure at which the SECONDS
An example of a testing system that provides the capabili- The only way to truly understand the downstream
ties to simulate the complex pressure profile of the filling performance characteristics of PET carbonated beverage
operation is the Agr PPT3000™. The PPT3000 accurately containers is by reproducing the abrupt, non-linear pres-
represents the counter-pressure filling simulation by provid- surization that a container experiences during the filling
ing a precise pressure profile that simulates a true filling process. Routine pressure testing that follows the pressure
environment. This pressure profile has been dubbed the profiles applied by the filling machine, in combination with
“Fill Ramp”, where the container is subjected to an abrupt, the monitoring of material properties, form the basis for a
~500 millisecond non-linear pressurization, up to the test sound testing program that will ensure optimal container
pressure hold level (60–100psi). It is held at that test pres- performance, both in the production/filler environment as
sure for 13 seconds, and then subjected to a pressure ramp well as throughout the commercial lifecycle.
increase of 10 psi/sec, leading to the identification of the
yield pressure and ultimate burst pressure. The “Fill Ramp” The Agr PPT3000 is the only pressure testing system cur-
pressure profile (figure 4.0) shows the change in pressure vs. rently available that truly simulates the filling process and,
time for the test and how the different segments of the test ultimately, the downstream conditions.
correlate with the filling cycle.

CONCLUSION
With the trend toward high-speed, combined blow-fill
Real World
operations and the propagation of ultra-lightweight PET
containers, it has become increasingly imperative to identify Pressure Testing
of PET Containers
and correct blowmolding problems before loss-of-pressure
failures occur downstream in the filler, in the warehouse or
through retail channels.

OVERVIEW

Copyright Agr International 2017

Agr International, Inc.

Butler, PA, USA
updated 01/2017