Project
Project
CLASS – XIth A
ROLL NO. – 01
SUBJECT – CHEMISTRY
PROJECT ON:-
Study of Methods for Purification of Water
LAXMI
INTERNATIONAL
SCHOOL
SESSION – 2013-2014
CERTIFI
ACKNOWLEGEMENT
Contents
1 Sources of water
2 Treatment
o 2.1 Pre-treatment
2.1.1 pH adjustment
o 2.2 Sedimentation
substances
o 2.7 Disinfection
INTRODUCTION
Water purification is the process of removing
undesirable chemicals, biological contaminants,
suspended solids and gases from contaminated water.
The goal is to produce water fit for a specific purpose.
Most water is purified for human consumption (drinking
water), but water purification may also be designed for a
variety of other purposes, including meeting the
requirements of medical, pharmacological, chemical and
industrial applications. In general the methods used
include physical processes such
as filtration, sedimentation, and distillation, biological
processes such as filters or biologically active carbon,
chemical processes such
as flocculation and chlorination and the use of
electromagnetic radiation such as ultraviolet light.
The purification process of water may reduce the
concentration of particulate matter
including suspended particles, parasites, bacteria, algae
, viruses,fungi; and a range of dissolved and particulate
material derived from the surfaces that water may have
made contact with after falling as rain.
The standards for drinking water quality are typically set
by governments or by international standards. These
standards will typically set minimum and maximum
concentrations of contaminants for the use that is to be
made of the water.
It is not possible to tell whether water is of an
appropriate quality by visual examination. Simple
procedures such as boiling or the use of a household
activated filter are not sufficient for treating all the
possible contaminants that may be present in water from
an unknown source. Even natural spring – considered
safe for all practical purposes in the 19th century – must
now be tested before determining what kind of
treatment, if any, is
needed. Chemical and microbiological analysis, while
expensive, are the only way to obtain the information
necessary for deciding on the appropriate method of
purification.
According to a 2007 World Health Organization (WHO)
report, 1.1 billion people lack access to an improved
drinking water supply, 88 percent of the 4 billion annual
cases of diarrheal disease are attributed to unsafe water
and inadequate sanitation and hygiene, and 1.8 million
people die from diarrheal diseases each year. The WHO
estimates that 94 percent of these diarrheal cases are
preventable through modifications to the environment,
including access to safe water. Simple techniques for
treating water at home, such as chlorination, filters, and
solar disinfection, and storing it in safe containers could
save a huge number of lives each year. Reducing
deaths from waterborne diseases is a major public
health goal in developing countries.
PRESENTATION
Sources of water
pH adjustment
Pure water has a pH close to 7
(neither alkaline nor acidic). Sea water can have pH values that
range from 7.5 to 8.4 (moderately alkaline). Fresh water can
have widely ranging pH values depending on the geology of
the drainage basin or aquifer and the influence of contaminant
inputs (acid rain). If the water is acidic (lower than
7), lime, soda ash, or sodium hydroxide can be added to raise
the pH during water purification processes. Lime addition
increases the calcium ion concentration, thus raising the water
hardness. For highly acidic waters, forced draft degasifierscan
be an effective way to raise the pH, by stripping dissolved
carbon dioxide from the water. Making the water alkaline
helps coagulation and flocculation processes work effectively
and also helps to minimize the risk of lead being dissolved from
lead pipes and from lead solder in pipe fittings. Sufficient
alkalinity also reduces the corrosiveness of water to iron pipes.
Acid (carbonic acid, hydrochloric acid or sulphuric acid) may be
added to alkaline waters in some circumstances to lower the
pH. Alkaline water (above pH 7.0) does not necessarily mean
that lead or copper from the plumbing system will not be
dissolved into the water. The ability of water to precipitate
calcium carbonate to protect metal surfaces and reduce the
likelihood of toxic metals being dissolved in water is a function
of pH, mineral content, temperature, alkalinity and calcium
concentration.
Sedimentation
Waters exiting the flocculation basin may enter
the sedimentation basin, also called a clarifier or settling basin.
It is a large tank with low water velocities, allowing floc to settle
to the bottom. The sedimentation basin is best located close to
the flocculation basin so the transit between the two processes
does not permit settlement or floc break up. Sedimentation
basins may be rectangular, where water flows from end to end,
or circular where flow is from the centre outward.
Sedimentation basin outflow is typically over a weir so only a
thin top layer of water—that furthest from the sludge—exits.
In 1904, Allen Hazen showed that the efficiency of a
sedimentation process was a function of the particle settling
velocity, the flow through the tank and the surface area of tank.
Sedimentation tanks are typically designed within a range of
overflow rates of 0.5 to 1.0 gallons per minute per square foot
(or 1.25 to 2.5 meters per hour). In general, sedimentation
basin efficiency is not a function of detention time or depth of
the basin. Although, basin depth must be sufficient so that
water currents do not disturb the sludge and settled particle
interactions are promoted. As particle concentrations in the
settled water increase near the sludge surface on the bottom of
the tank, settling velocities can increase due to collisions and
agglomeration of particles. Typical detention times for
sedimentation vary from 1.5 to 4 hours and basin depths vary
from 10 to 15 feet (3 to 4.5 meters).
Inclined flat plates or tubes can be added to traditional
sedimentation basins to improve particle removal performance.
Inclined plates and tubes drastically increase the surface area
available for particles to be removed in concert with Hazen’s
original theory. The amount of ground surface area occupied by
a sedimentation basin with inclined plates or tubes can be far
smaller than a conventional sedimentation basin.
Sludge storage and removal
As particles settle to the bottom of a sedimentation basin, a
layer of sludge is formed on the floor of the tank. This layer of
sludge must be removed and treated. The amount of sludge
that is generated is significant, often 3 to 5 percent of the total
volume of water that is treated. The cost of treating and
disposing of the sludge can be a significant part of the
operating cost of a water treatment plant. The sedimentation
tank may be equipped with mechanical cleaning devices that
continually clean the bottom of the tank or the tank can be
periodically taken out of service and cleaned manually.
Dissolved air flotation
When particles to be removed do not settle out of solution
easily, dissolved air flotation (DAF) is often used. Water
supplies that are particularly vulnerable to unicellular algae
blooms and supplies with low turbidity and high colour often
employ DAF. After coagulation and flocculation processes,
water flows to DAF tanks where air diffusers on the tank bottom
create fine bubbles that attach to floc resulting in a floating
mass of concentrated floc. The floating floc blanket is removed
from the surface and clarified water is withdrawn from the
bottom of the DAF tank.
Filtration
After separating most floc, the water is filtered as the final step
to remove remaining suspended particles and unsettled floc.
Rapid sand filters
Filters out much smaller particles than paper and sand filters
can.
Filters out virtually all particles larger than their specified
pore sizes.
They are quite thin and so liquids flow through them fairly
rapidly.
They are reasonably strong and so can withstand pressure
differences across them of typically 2–5 atmospheres.
They can be cleaned (back flushed) and reused.
Membrane filtration
Membrane filters are widely used for filtering both drinking
water and sewage. For drinking water, membrane filters can
remove virtually all particles larger than
0.2 um—including giardia and cryptosporidium. Membrane
filters are an effective form of tertiary treatment when it is
desired to reuse the water for industry, for limited domestic
purposes, or before discharging the water into a river that is
used by towns further downstream. They are widely used in
industry, particularly for beverage preparation (including bottled
water). However no filtration can remove substances that are
actually dissolved in the water such
as phosphorus, nitrates and heavy metal ions.
Removal of ions and other dissolved
substances
Ultra filtration membranes use polymer membranes with
chemically formed microscopic pores that can be used to filter
out dissolved substances avoiding the use of coagulants. The
type of membrane media determines how much pressure is
needed to drive the water through and what sizes of micro-
organisms can be filtered out.
Ion exchange: Ion exchange systems use ion exchange resin-
or zeolite-packed columns to replace unwanted ions. The most
common case is water softening consisting of removal
of Ca2+and Mg2+ ions replacing them with benign (soap
friendly) Na+ or K+ ions. Ion exchange resins are also used to
remove toxic ions such as
nitrate, nitrite, lead, mercury, arsenic and many others.
Precipitate softening: Water rich
in hardness (calcium and magnesium ions) is treated with lime
(calcium oxide) and/or soda-ash (sodium carbonate) to
precipitate calcium carbonate out of solution utilizing
the common-ion effect.
Electro deionization: Water is passed between a
positive electrode and a negative electrode. Ion
exchange membranes allow only positive ions to migrate from
the treated water toward the negative electrode and only
negative ions toward the positive electrode. High purity
deionised water is produced with a little worse degree of
purification in comparison with ion exchange treatment.
Complete removal of ions from water is regarded as electro
dialysis. The water is often pre-treated with a reverse
osmosis unit to remove non-ionic organic contaminants.
Disinfection
Disinfection is accomplished both by filtering out harmful micro-
organisms and also by adding disinfectant chemicals. Water is
disinfected to kill any pathogens which pass through the filters
and to provide a residual dose of disinfectant to kill or inactivate
potentially harmful micro-organisms in the storage and
distribution systems. Possible pathogens
include viruses, bacteria, including
Salmonella, Cholera, Campylobacter and Shigella,
and protozoa, including Giardia lamblia and
other cryptosporidium. Following the introduction of any
chemical disinfecting agent, the water is usually held in
temporary storage – often called a contact tank or clear well to
allow the disinfecting action to complete.
Chlorine disinfection
The most common disinfection method involves some form
of chlorine or its compounds such as chloramines or chlorine
dioxide. Chlorine is a strong oxidant that rapidly kills many
harmful micro-organisms. Because chlorine is a toxic gas, there
is a danger of a release associated with its use. This problem is
avoided by the use of sodium hypochlorite, which is a relatively
inexpensive solution that releases free chlorine when dissolved
in water. Chlorine solutions can be generated on site by
electrolyzing common salt solutions. A solid form, calcium
hypochlorite, releases chlorine on contact with water. Handling
the solid, however, requires greater routine human contact
through opening bags and pouring than the use of gas
cylinders or bleach which are more easily automated. The
generation of liquid sodium hypochlorite is both inexpensive
and safer than the use of gas or solid chlorine.
All forms of chlorine are widely used, despite their respective
drawbacks. One drawback is that chlorine from any source
reacts with natural organic compounds in the water to form
potentially harmful chemical by-products. These by-
products, trihalomethanes (THMs) and halo acetic
acids (HAAs), are both carcinogenic in large quantities and are
regulated by the United States Environmental Protection
Agency (EPA) and the Drinking Water Inspectorate in the UK.
The formation of THMs and halo acetic acids may be minimized
by effective removal of as many organics from the water as
possible prior to chlorine addition. Although chlorine is effective
in killing bacteria, it has limited effectiveness against protozoa
that form cysts in water (Giardia lamblia and Cryptosporidium,
both of which are pathogenic).
Chlorine dioxide disinfection
Chlorine dioxide is a faster-acting disinfectant than elemental
chlorine. It is relatively rarely used, because in some
circumstances it may create excessive amounts of chlorite,
which is a by-product regulated to low allowable levels in the
United States. Chlorine dioxide is supplied as an aqueous
solution and added to water to avoid gas handling problems;
chlorine dioxide gas accumulations may spontaneously
detonate.
Ozone disinfection
Ozone is an unstable molecule which readily gives up one atom
of oxygen providing a powerful oxidizing agent which is toxic to
most waterborne organisms. It is a very strong, broad spectrum
disinfectant that is widely used in Europe. It is an effective
method to inactivate harmful protozoa that form cysts. It also
works well against almost all other pathogens. Ozone is made
by passing oxygen through ultraviolet light or a "cold" electrical
discharge. To use ozone as a disinfectant, it must be created
on-site and added to the water by bubble contact. Some of the
advantages of ozone include the production of fewer dangerous
by-products and the absence of taste and odour problems (in
comparison to chlorination) . Although fewer by-products are
formed by ozonation, it has been discovered that ozone reacts
with bromide ions in water to produce concentrations of the
suspected carcinogen bromated. Bromide can be found in fresh
water supplies in sufficient concentrations to produce (after
ozonation) more than 10 ppb of bromate — the maximum
contaminant level established by the USEPA. Another
advantage of ozone is that it leaves no residual disinfectant in
the water. Ozone has been used in drinking water plants since
1906 where the first industrial ozonation plant was built in Nice,
France. The U.S. Food and Drug Administration has accepted
ozone as being safe; and it is applied as an anti-microbiological
agent for the treatment, storage, and processing of foods.
Ultraviolet disinfection
Ultraviolet light (UV) is very effective at inactivating cysts, in low
turbidity water. UV light's disinfection effectiveness decreases
as turbidity increases, a result of the absorption, scattering, and
shadowing caused by the suspended solids. The main
disadvantage to the use of UV radiation is that, like ozone
treatment, it leaves no residual disinfectant in the water;
therefore, it is sometimes necessary to add a residual
disinfectant after the primary disinfection process. This is often
done through the addition of chloramines, discussed above as
a primary disinfectant. When used in this manner, chloramines
provide an effective residual disinfectant with very few of the
negative effects of chlorination.
Solar water disinfection
One low-cost method of disinfecting water that can often be
implemented with locally available materials is solar
disinfection (SODIS). Unlike methods that rely on firewood, it
has low impact on the environment.
One recent study has found that the wild Salmonella which
would reproduce quickly during subsequent dark storage of
solar-disinfected water could be controlled by the addition of
just 10 parts per million of hydrogen peroxide.
Other popular methods for purifying water, especially for local private
supplies are listed below. In some countries some of these methods are
also used for large scale municipal supplies. Particularly important are
distillation (de-salination of seawater) and reverse osmosis.
UV-LIGHT TREATMENT
In this method, a UV lamp is used to produce UV light.
Contaminated water is then exposed to this light for treatment. A
dominant type of UV called UV-C or ‘germicidal UV’ is used in this
process. It is an efficient and trusted method of water purification.
It destroys 99.99% of disease-causing microorganisms. These
include E. coli, Giardia, and Cryptosporidium. When UV-Crays
are exposed to the micro-organisms contained in the water, the
DNA of the micro –organisms absorbs the rays. After absorption,
these rays alter the DNA of the pathogens is such a way that they
can no longer produce, and they permanently die. This process of
altering their DNA is called inactivation. The threat of water- borne
diseases is eliminated, and water made safe for drinking
purposes.
CONCLUSION
BIBLIOGRAPHY