Revision date: 23/06/2020 Revision: 10 Supersedes date: 29/04/2020

SAFETY DATA SHEET

3000000122 PFPL DARK GREEN PIGMENT
According to Regulation (EC) No 1907/2006, Annex II, as amended by Regulation (EU) No 453/2010

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

Product name 3000000122 PFPL DARK GREEN PIGMENT

Product number WS34594APF

1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses COLOURING OF FLEXIBLE PVC & PU COMPOUNDS

1.3. Details of the supplier of the safety data sheet

Supplier WEST AND SENIOR LIMITED.
MILLTOWN STREET
RADCLIFFE
MANCHESTER. M26 1WE.
TEL + 44 01617247131
FAX + 44 01617249519
[email protected]

1.4. Emergency telephone number

Emergency telephone 24 HOUR EMERGENCY TELEPHONE NUMBER : + 44 (0) 7930 595916

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture

Classification (EC 1272/2008)
Physical hazards Not Classified

Health hazards Skin Sens. 1 - H317

Environmental hazards Not Classified

Environmental The product is not expected to be hazardous to the environment.

2.2. Label elements

Hazard pictograms

Signal word Warning

Hazard statements H317 May cause an allergic skin reaction.

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Precautionary statements P261 Avoid breathing vapour/ spray.

P272 Contaminated work clothing should not be allowed out of the workplace.
P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.
P302+P352 IF ON SKIN: Wash with plenty of water.
P321 Specific treatment (see medical advice on this label).
P333+P313 If skin irritation or rash occurs: Get medical advice/ attention.
P362+P364 Take off contaminated clothing and wash it before reuse.
P501 Dispose of contents/ container in accordance with national regulations.

Contains Poly(oxy-1,2-ethandiyl),.alpha.-[(2Z)-3-carboxy-1-oxo-2-propenyl]-.omega.-hydroxy-, C9-11-

alkyl, maleic anhydride

2.3. Other hazards

This product does not contain any substances classified as PBT or vPvB.

SECTION 3: Composition/information on ingredients

3.2. Mixtures

TITANIUM DIOXIDE 1-5%

CAS number: 13463-67-7 EC number: 236-675-5 REACH registration number: 01-
2119489379-17-0000

Classification
Not Classified

Poly(oxy-1,2-ethandiyl),.alpha.-[(2Z)-3-carboxy-1-oxo-2- <1%
propenyl]-.omega.-hydroxy-, C9-11-alkyl
CAS number: 709014-50-6

Classification
Skin Sens. 1 - H317

maleic anhydride <0.01%

CAS number: 108-31-6 EC number: 203-571-6 REACH registration number: 01-
2119472428-31-0000

Classification
Acute Tox. 4 - H302
Skin Corr. 1B - H314
Eye Dam. 1 - H318
Resp. Sens. 1 - H334
Skin Sens. 1A - H317

The full text for all hazard statements is displayed in Section 16.
Composition comments No other disclosure required under the latest EC Directives

SECTION 4: First aid measures

4.1. Description of first aid measures

General information No specific recommendations. If in doubt, get medical attention promptly.

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Inhalation Move affected person to fresh air at once. Get medical attention if any discomfort continues.
When breathing is difficult, properly trained personnel may assist affected person by
administering oxygen. If breathing stops, provide artificial respiration.

Ingestion Never give anything by mouth to an unconscious person. Do not induce vomiting. Rinse
mouth thoroughly with water. Give plenty of water to drink. Get medical attention if any
discomfort continues.

Skin contact Remove affected person from source of contamination. Get medical attention if irritation
persists after washing. Wash skin thoroughly with soap and water.

Eye contact Remove any contact lenses and open eyelids wide apart. Continue to rinse for at least 15
minutes. Continue to rinse for at least 15 minutes. Get medical attention if any discomfort
continues.

4.2. Most important symptoms and effects, both acute and delayed
General information Not applicable.

4.3. Indication of any immediate medical attention and special treatment needed
Notes for the doctor No specific recommendations.

SECTION 5: Firefighting measures

5.1. Extinguishing media

Suitable extinguishing media Extinguish with the following media: Water spray, foam, dry powder or carbon dioxide.

Unsuitable extinguishing High volume water jet.

media

5.2. Special hazards arising from the substance or mixture

Hazardous combustion Oxides of: Carbon. Sulphur.
products

5.3. Advice for firefighters

Protective actions during Cool containers exposed to heat with water spray and remove them from the fire area if it can
firefighting be done without risk.

Special protective equipment Wear positive-pressure self-contained breathing apparatus (SCBA) and appropriate protective
for firefighters clothing.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

Personal precautions Wear protective clothing as described in Section 8 of this safety data sheet. Avoid contact with
skin and eyes. Provide adequate ventilation. Do not breathe vapour. In case of spills, beware
of slippery floors and surfaces.

6.2. Environmental precautions

Environmental precautions Do not discharge into drains or watercourses or onto the ground. Spillages or uncontrolled
discharges into watercourses must be reported immediately to the Environmental Agency or
other appropriate regulatory body.

6.3. Methods and material for containment and cleaning up

Methods for cleaning up Stop leak if possible without risk. Absorb in vermiculite, dry sand or earth and place into
containers. Avoid the spillage or runoff entering drains, sewers or watercourses. For waste
disposal, see Section 13.

6.4. Reference to other sections

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Reference to other sections For personal protection, see Section 8. For waste disposal, see section 13.

SECTION 7: Handling and storage

7.1. Precautions for safe handling

Usage precautions Wear suitable protective equipment for prolonged exposure and/or high concentrations of
vapours, spray or mist. Good personal hygiene procedures should be implemented. Wash
hands and any other contaminated areas of the body with soap and water before leaving the
work site. Avoid inhalation of vapours and spray/mists.

7.2. Conditions for safe storage, including any incompatibilities

Storage precautions Store in tightly-closed, original container in a dry, cool and well-ventilated place. Keep only in
the original container. Keep separate from food, feedstuffs, fertilisers and other sensitive
material.

7.3. Specific end use(s)

Specific end use(s) The identified uses for this product are detailed in Section 1.2.

SECTION 8: Exposure controls/Personal protection

8.1. Control parameters

Occupational exposure limits
TITANIUM DIOXIDE
EH40 WEL, Time Weighted Average (TWA):, Inhalable dust. 10 mg/m3, 8 h
EH40 WEL, Time Weighted Average (TWA):, Respirable dust. 4 mg/m3, 8 h
maleic anhydride
Long-term exposure limit (8-hour TWA): WEL 1 mg/m³
Short-term exposure limit (15-minute): WEL 3 mg/m³
Sen
WEL = Workplace Exposure Limit.
Sen = Capable of causing occupational asthma.

Ingredient comments No exposure limits known for ingredient(s).

C.I. PIGMENT BLACK 11 (CAS: 1317-61-9)

Ingredient comments No exposure limits known for ingredient(s).

TITANIUM DIOXIDE (CAS: 13463-67-7)

DNEL Workers - Inhalation; Long term local effects: 10 mg/m³

Professional - Inhalation; Long term local effects: 10 mg/m³
Consumer - Oral; Long term systemic effects: 700 mg/kg/day

PNEC marine water; 0.0184 mg/l

Fresh water; 0.184 mg/l
Intermittent release; 0.193 mg/l
STP; 100 mg/l
Sediment, marine water; 100 mg/kg
Sediment, Fresh water; 1000 mg/kg
Soil; 100 mg/kg

Trimethylolpropane (CAS: 77-99-6)

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DNEL Workers - Inhalation; Long term systemic effects: 3.3 mg/m³

Workers - Dermal; Long term systemic effects: 0.94 mg/kg
Consumer - Inhalation; Long term systemic effects: 0.58 mg/m³
Consumer - Dermal; Long term systemic effects: 0.34 mg/kg
Consumer - Oral; Long term systemic effects: 0.34 mg/kg

8.2. Exposure controls

Protective equipment

Appropriate engineering No specific ventilation requirements.

controls

Eye/face protection Eyewear complying with an approved standard should be worn if a risk assessment indicates
eye contact is possible. The following protection should be worn: Chemical splash goggles or
face shield.

Hand protection Chemical-resistant, impervious gloves complying with an approved standard should be worn if
a risk assessment indicates skin contact is possible.

Other skin and body Wear appropriate clothing to prevent any possibility of skin contact.
protection

Hygiene measures Do not smoke in work area. Wash at the end of each work shift and before eating, smoking
and using the toilet. Wash promptly if skin becomes contaminated. Promptly remove any
clothing that becomes contaminated. Use appropriate skin cream to prevent drying of skin.
When using do not eat, drink or smoke.

Respiratory protection Respiratory protection must be used if the airborne contamination exceeds the recommended
occupational exposure limit. If ventilation is inadequate, suitable respiratory protection must
be worn. Wear a respirator fitted with the following cartridge: Gas filter, type A2.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

Appearance Coloured paste. or Coloured liquid.

Colour Various colours.

Odour Odourless.

Odour threshold No information available.

pH No information available.

Melting point No information available.

Initial boiling point and range >300°C

Flash point >200C°C Closed cup.

Evaporation rate No information available.

Evaporation factor No information available.

Flammability (solid, gas) No information available.

Upper/lower flammability or No information available.

explosive limits

Other flammability No information available.

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Vapour pressure No information available.

Vapour density No information available.

Relative density No information available.

Bulk density No information available.

Solubility(ies) Insoluble in water.

Partition coefficient No information available.

Auto-ignition temperature No information available.

Decomposition Temperature No information available.

Viscosity Varying @ °C

Explosive properties None.

Explosive under the influence No

of a flame

Oxidising properties Not applicable.

Comments No information available.

9.2. Other information

Other information Not relevant.

SECTION 10: Stability and reactivity

10.1. Reactivity
Reactivity There are no known reactivity hazards associated with this product.

10.2. Chemical stability

Stability Stable at normal ambient temperatures.

10.3. Possibility of hazardous reactions

Possibility of hazardous No potentially hazardous reactions known.
reactions

10.4. Conditions to avoid

Conditions to avoid Avoid excessive heat for prolonged periods of time. When heated, vapours/gases hazardous
to health may be formed. Sulphur dioxide.

10.5. Incompatible materials

Materials to avoid No specific material or group of materials is likely to react with the product to produce a
hazardous situation.

10.6. Hazardous decomposition products

Hazardous decomposition Does not decompose when used and stored as recommended. Fire creates: Sulphur dioxide.
products Phenol

SECTION 11: Toxicological information

11.1. Information on toxicological effects

Acute and chronic health No specific health hazards known.

hazards

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Toxicological information on ingredients.

maleic anhydride

Acute toxicity - oral

ATE oral (mg/kg) 500.0

Skin corrosion/irritation

Animal data Corrosive to skin. Rabbit

Serious eye damage/irritation

Serious eye Corrosive. to Eyes Rabbit

damage/irritation

Skin sensitisation

Skin sensitisation Sensitising. Guinea pig

SECTION 12: Ecological information

Ecotoxicity Not regarded as dangerous for the environment.

12.1. Toxicity
Toxicity Not considered toxic to fish.

Acute aquatic toxicity

Acute toxicity - fish LC₅₀, 96 hours: >2 mg/l, Fish

Acute toxicity - aquatic EC₅₀, 48 hours: >100 mg/l, Daphnia magna

invertebrates

Acute toxicity - aquatic plants IC₅₀, 72 hours: >2 mg/l, Algae

Ecological information on ingredients.

maleic anhydride

Acute aquatic toxicity

Acute toxicity - fish LC₅₀, 96 hours: 75 mg/l, Oncorhynchus mykiss (Rainbow trout)

Acute toxicity - aquatic EC₅₀, 48 hours: 42.81 mg/l, Daphnia magna

invertebrates

Acute toxicity - aquatic ErC50, 72 hours: 74.35 mg/l, Pseudokirchneriella subcapitata

plants

Chronic aquatic toxicity

Chronic toxicity - aquatic NOEC, 21 days: 10 mg/l, Daphnia magna

invertebrates

12.2. Persistence and degradability

Persistence and degradability No data available.

Ecological information on ingredients.

maleic anhydride

Biodegradation The product is readily biodegradable.

12.3. Bioaccumulative potential

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Bioaccumulative potential The product is not bioaccumulating.

Partition coefficient No information available.

Ecological information on ingredients.

maleic anhydride

Partition coefficient log Pow: ~ 2.61 (19.8°C)

12.4. Mobility in soil

Mobility The product contains substances which may accumulate in sediment.

12.5. Results of PBT and vPvB assessment

Results of PBT and vPvB This substance is not classified as PBT or vPvB according to current EU criteria.
assessment

12.6. Other adverse effects

Other adverse effects Not relevant.

SECTION 13: Disposal considerations

13.1. Waste treatment methods

Disposal methods Dispose of waste to licensed waste disposal site in accordance with the requirements of the
local Waste Disposal Authority. EWC NUMBER : Allocation of a waste code number in
accordance with the European Waste Catalogue, should be carried out in agreement with an
EA authorised waste disposal company. Waste material and any included combustible
absorbent and containers should be suitable for incineration at an approved facility.

SECTION 14: Transport information

General The product is not covered by international regulations on the transport of dangerous goods
(IMDG, IATA, ADR/RID).

14.1. UN number
Not applicable.

14.2. UN proper shipping name

Not applicable.

14.3. Transport hazard class(es)

Not applicable.

14.4. Packing group

Not applicable.

14.5. Environmental hazards

Environmentally hazardous substance/marine pollutant

No.

14.6. Special precautions for user

Not applicable.

14.7. Transport in bulk according to Annex II of MARPOL and the IBC Code

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Transport in bulk according to Not applicable.

Annex II of MARPOL 73/78
and the IBC Code

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
National regulations Control of Substances Hazardous to Health Regulations 2002 (as amended).

EU legislation Commission Regulation (EU) 2015/830 of 28 May 2015 amending Regulation (EC) No
1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning
the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH),
establishing a European Chemicals Agency, amending Directive 1999/45/EC and repealing
Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as
Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC,
93/105/EC and 2000/21/EC, including amendments. Regulation (EC) No 1272/2008 of the
European Parliament and of the Council of 16 December 2008 on classification, labelling and
packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and
1999/45/EC, and amending Regulation (EC) No 1907/2006 with amendments.

Guidance A guide to local exhaust ventilation (LEV) HSG258 (as ammended)

Workplace Exposure Limits EH40.

15.2. Chemical safety assessment

No chemical safety assessment has been carried out.

SECTION 16: Other information

Revision date 23/06/2020

Revision 10

Supersedes date 29/04/2020

Hazard statements in full H302 Harmful if swallowed.

H314 Causes severe skin burns and eye damage.
H317 May cause an allergic skin reaction.
H318 Causes serious eye damage.
H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.

The information contained within this document is presented in good faith and is believed to be correct. West and Senior
Limited makes no representation as to the accuracy and/or completeness of this information. This information is issued on
the condition that the user will determine the safety and suitability of products for their purposes prior to use. All technical
details and values presented are deemed typical and do not constitute a delivery specification.

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