H$moS> Z§.

Code No. 56/1/1

amob Z§. narjmWu H$moS >H$mo CÎma-nwpñVH$m Ho$ _wI-n¥ð
Roll No. >na Adí` {bIo§ &
Candidates must write the Code on the
title page of the answer-book.

ZmoQ> NOTE
(I) H¥$n`m Om±M H$a b| {H$ Bg àíZ-nÌ _o§ _w{ÐV (I) Please check that this question
n¥ð> 19 h¢ & paper contains 19 printed pages.

(II) àíZ-nÌ _| Xm{hZo hmW H$s Amoa {XE JE H$moS (II) Code number given on the right
>Zå~a H$mo N>mÌ CÎma-nwpñVH$m Ho$ _wI-n¥ð> na hand side of the question paper
{bI| & should be written on the title page of
the answer-book by the candidate.
(III) H¥$n`m Om±M H$a b| {H$ Bg àíZ-nÌ _| (III) Please check that this question
>37 àíZ h¢ & paper contains 37 questions.
(IV) H¥$n`m àíZ H$m CÎma {bIZm ewê$ H$aZo go (IV) Please write down the Serial
nhbo, CÎma-nwpñVH$m _| àíZ H$m H«$_m§H$ Number of the question in the
Adí` {bI| & answer-book before attempting it.
(V) Bg àíZ-nÌ H$mo n‹T>Zo Ho$ {bE 15 {_ZQ >H$m (V) 15 minute time has been allotted to
g_` {X`m J`m h¡ & àíZ-nÌ H$m {dVaU read this question paper. The
nydm©• _| 10.15 ~Oo {H$`m OmEJm & question paper will be distributed
10.15 ~Oo go 10.30 ~Oo VH$ N>mÌ Ho$db at 10.15 a.m. From 10.15 a.m. to
10.30 a.m., the students will
àíZ-nÌ H$mo n‹T>|Jo Am¡a Bg Ad{Y Ho$ Xm¡amZ read the question paper only and
do CÎma-nwpñVH$m na H$moB© CÎma Zht {bI|Jo & will not write any answer on the
answer-book during this period.

agm`Z {dkmZ (g¡ÕmpÝVH$)

CHEMISTRY (Theory)

{ZYm©[aV g_` : 3 KÊQ>o A{YH$V_ A§H$ : 70

Time allowed : 3 hours Maximum Marks : 70

.56/1/1 1 P.T.O.
gm_mÝ` {ZX}e :
{ZåZ{b{IV {ZX}em| H$mo ~hþV gmdYmZr go n{‹T>E Am¡a CZH$m g™Vr go nmbZ H$s{OE :
(i) `h àíZ-nÌ Mma IÊS>m| _| {d^m{OV {H$`m J`m h¡ – H$, I, J Ed§ K & Bg àíZ-nÌ _|
37 àíZ h¢ & g^r àíZ A{Zdm`© h¢ &
(ii) IÊS> H$ _| àíZ g§»`m 1 go 20 VH$ A{V bKw-CÎmar` àH$ma Ho$ àíZ h¢, àË`oH$ àíZ 1 A§H$ H$m
h¡ & àË`oH$ àíZ H$m CÎma EH$ eãX `m EH$ dmŠ` _| Xr{OE &
(iii) IÊS> I _| àíZ g§»`m 21 go 27 VH$ bKw-CÎmar` àH$ma Ho$ àíZ h¢, àË`oH$ àíZ 2 A§H$m| H$m
h¡ &
(iv) IÊS> J _| àíZ g§»`m 28 go 34 VH$ XrK©-CÎmar` àH$ma-I Ho$ àíZ h¢, àË`oH$ àíZ 3 A§H$m| H$m
h¡ &
(v) IÊS> K _| àíZ g§»`m 35 go 37 VH$ XrK©-CÎmar` àH$ma-II Ho$ àíZ h¢, àË`oH$ àíZ 5 A§H$m| H$m
h¡ &
(vi) àíZ-nÌ _| H$moB© g_J« {dH$ën Zht h¡ & VWm{n, Xmo-Xmo A§H$m| Ho$ Xmo àíZm| _|, VrZ-VrZ A§H$m| Hoo$
Xmo àíZm| _| VWm nm±M-nm±M A§H$m| Ho$ VrZm| àíZm| _| AmÝV[aH$ {dH$ën {X`m J`m h¡ & Eogo àíZm| _|
go Ho$db EH$ hr {dH$ën H$m CÎma Xr{OE &
(vii) BgHo$ A{V[aº$, Amdí`H$VmZwgma, àË`oH$ IÊS> Am¡a àíZ Ho$ gmW `Wmo{MV {ZX}e {XE JE h¢ &
(viii) Ho$ëHw$boQ>a AWdm bm°J Q>o~b Ho$ à`moJ H$s AZw_{V Zht h¡ &

IÊS> H$
{XE JE AZwÀN>oX H$mo n{‹T>E VWm àíZ g§»`m 1 go 5 Ho$ CÎma Xr{OE : 15=5

EopëH$b h¡bmBS>m| H$s à{VñWmnZ A{^{H«$`m _w»`V`m SN1 AWdm SN2 {H«$`m{d{Y Ûmam
hmoVr h¡ & à{VñWmnZ A{^{H«$`mE± hmoZo Ho$ {bE EopëH$b h¡bmBS> {H$gr ^r {H«$`m{d{Y H$mo
AnZmE±, CZHo$ {bE H$m~©Z h¡bmoOZ Am~ÝY H$s Y«wdUVm hr CÎmaXm`r hmoVr h¡ & SN1
A{^{H«$`mAm| H$m doJ H$m~m}H¡$Q>m`Z Ho$ ñWm{`Ëd na {Z^©a H$aVm h¡ O~{H$ SN2
A{^{H«$`mAm| H$m {Ì{d_{dÝ`mg H$maH$ na & `{X Amapå^H$ nXmW© {H$aob `m¡{JH$ hmo, Vmo
CËnmX `m Vmo à{Vbmo{_V hmoJm AWdm ao{g{_H$ {_lU, Omo EopëH$b h¡bmBS>m| Ûmam AnZmB© JB©
{H«$`m{d{Y Ho$ àH$ma na {Z^©a H$aVm h¡ & B©Wam| H$m HI go {dXbZ ^r {Ì{d_{dÝ`mg H$maH$
Am¡a H$m~m}H¡$Q>m`Z Ho$ ñWm{`Ëd go {Z`pÝÌV hmoVm h¡, Omo Bg ~mV H$m ÚmoVH$ h¡ {H$ H$m~©{ZH$
agm`Z _| `hr Xmo à_wI H$maH$ h¢ Omo h_| ghm`Vm H$aVo h¢ {H$ CËnmX {H$g àH$ma H$m
~ZoJm ?
.56/1/1 2
General Instructions :
Read the following instructions very carefully and strictly follow them :
(i) This question paper comprises four Sections – A, B, C and D. There are
37 questions in the question paper. All questions are compulsory.
(ii) Section A – Questions no. 1 to 20 are very short answer type questions,
carrying 1 mark each. Answer these questions in one word or one sentence.
(iii) Section B – Questions no. 21 to 27 are short answer type questions, carrying
2 marks each.
(iv) Section C – Questions no. 28 to 34 are long answer type-I questions, carrying
3 marks each.
(v) Section D – Questions no. 35 to 37 are long answer type-II questions, carrying
5 marks each.
(vi) There is no overall choice in the question paper. However, an internal choice
has been provided in 2 questions of two marks, 2 questions of three marks and
all the 3 questions of five marks. You have to attempt only one of the choices in
such questions.
(vii) In addition to this, separate instructions are given with each section and
question, wherever necessary.
(viii) Use of calculators and log tables is not permitted.

SECTION A

Read the given passage and answer the questions number 1 to 5 that follow : 15=5

The substitution reaction of alkyl halide mainly occurs by SN1 or SN2

mechanism. Whatever mechanism alkyl halides follow for the
substitution reaction to occur, the polarity of the carbon halogen bond is
responsible for these substitution reactions. The rate of SN1 reactions are
governed by the stability of carbocation whereas for SN2 reactions steric
factor is the deciding factor. If the starting material is a chiral compound,
we may end up with an inverted product or racemic mixture depending
upon the type of mechanism followed by alkyl halide. Cleavage of ethers
with HI is also governed by steric factor and stability of carbocation,
which indicates that in organic chemistry, these two major factors help
us in deciding the kind of product formed.

.56/1/1 3 P.T.O.
1. ~ZZo dmbo CËnmX H$s {Ì{d_agm`Z H$s àmJw{º$ H$s{OE `{X H$moB© Y«wdU KyU©H$ (àH$meV:
g{H«$`) EopëH$b h¡bmBS> SN1 {H«$`m{d{Y go à{VñWmnZ A{^{H«$`m gånÞ H$aVm h¡ &

2. Cg `§Ì H$m Zm_ ~VmBE Omo Cg H$moU Ho$ _mnZ Ho$ {bE à`wº$ hmoVm h¡ {Og na g_Vb
Y«w{dV àH$me Ky{U©V hmo OmVm h¡ &
3. _w»` CËnmX H$s àmJw{º$ H$s{OE O~ 2-~«mo_monoÝQ>oZ, EoëH$mohm°br KOH Ho$ gmW A{^{H«$`m
H$aVm h¡ &
4. CHI3 H$m EH$ Cn`moJ Xr{OE &
5. CZ CËnmXm| H$s g§aMZmE± {b{IE O~ Eo{Zgmob H$mo HI Ho$ gmW A{^{H«${`V {H$`m OmVm h¡ &

àíZ g§»`m 6 go 10 EH$ eãX CÎmar¶ h¢ : 15=5

6. `{X Ðd A Am¡a B Ho$ ŠdWZm§H$ H«$_e: 140C Am¡a 180C h¢, Vmo Cg Ðd H$s nhMmZ
H$s{OE {OgH$m 90C na dmîn Xm~ CƒVa hmoJm &
7. bmoho H$s dñVwAm| H$mo gwa{jV aIZo Ho$ {bE qµOH$ VWm {Q>Z _| go {H$gH$s H$moqQ>J ~ohVa h¡ ?

8. Š`m {H$gr A{^{H«$`m H$m doJ pñWam§H$ T na {Z^©a H$aoJm `{X A{^{H«$`m H$s Eact (g{H«$`U
D$Om©) eyÝ` hmo ?
9. PVC Ho$ EH$bH$ H$s g§aMZm Xr{OE &
10. {H$gr An_mO©H$ _| CnpñWV H$m¡Z-gr g§aMZmË_H$ BH$mB© CgH$mo AO¡d{ZåZrH$aUr` ~Zm XoVr
h¡ ?
àíZ g§»`m 11 go 15 ~hþ{dH$ënr¶ àíZ h¢ : 15=5

11. Obr` {db`Z _| {ZåZ{b{IV _| go à~bV_ jma h¡

(A) _o{WbEo_rZ
(B) S>mB_o{WbEo_rZ
(C) Q´>mB_o{WbEo_rZ
(D) Eo{ZbrZ

.56/1/1 4
1. Predict the stereochemistry of the product formed if an optically active
alkyl halide undergoes substitution reaction by SN1 mechanism.

2. Name the instrument used for measuring the angle by which the plane
polarised light is rotated.

3. Predict the major product formed when 2-Bromopentane reacts with

alcoholic KOH.

4. Give one use of CHI3.

5. Write the structures of the products formed when anisole is treated with
HI.

Questions number 6 to 10 are one word answers : 15=5

6. Identify which liquid will have a higher vapour pressure at 90C if the
boiling points of two liquids A and B are 140C and 180C, respectively.

7. Out of zinc and tin, whose coating is better to protect iron objects ?

8. Will the rate constant of the reaction depend upon T if the Eact
(activation energy) of the reaction is zero ?

9. Give the structure of the monomer of PVC.

10. Which structural unit present in a detergent makes it non-biodegradable ?

Questions number 11 to 15 are multiple choice questions : 15=5

11. Out of the following, the strongest base in aqueous solution is

(A) Methylamine

(B) Dimethylamine

(C) Trimethylamine

(D) Aniline

.56/1/1 5 P.T.O.
12. {ZåZ{b{IV _| go {H$gHo$ Ûmam Am`moS>mo\$m°_© narjU Zht {X`m OmVm h¡ ?

(A) EWoZm°b
(B) EWoZ¡b
(C) noÝQ>oZ-2-AmoZ
(D) noÝQ>oZ-3-AmoZ

13. {ZåZ{b{IV g§H«$_U VÎdm| _| go {H$gHo$ Ûmam A{YH$V_ Am°ŠgrH$aU AdñWmE± àX{e©V H$s
OmVr h¢ ?
(A) Sc (Z = 21)
(B) Cr (Z = 24)
(C) Mn (Z = 25)
(D) Fe (Z = 26)

14. M_© g§ñH$aU CÚmoJ _| M_© H$m H$R>moa hmoZm {Z^©a H$aVm h¡
(A) d¡ÚwV H$U-g§MbZ na
(B) {dÚwV²-namgaU na
(C) nmañn[aH$ ñH§$XZ na
(D) {Q>ÝS>b à^md na

15. {XE JE `m¡{JH$ H$m ghr AmB©.`y.nr.E.gr. Zm_ Š`m h¡ ?

(A) 2,2-S>mB_o{Wbã`yQ>oZm°BH$ Aåb

(B) 2-H$m~m}pŠgb-2-_o{Wbã`yQ>Z
o
(C) 2-Eo{Wb-2-_o{WbàmonoZm°BH$ Aåb
(D) 3-_o{Wbã`yQ>oZ H$m~m}pŠg{bH$ Aåb
.56/1/1 6
12. Iodoform test is not given by
(A) Ethanol
(B) Ethanal
(C) Pentan-2-one
(D) Pentan-3-one

13. Out of the following transition elements, the maximum number of

oxidation states are shown by
(A) Sc (Z = 21)
(B) Cr (Z = 24)
(C) Mn (Z = 25)
(D) Fe (Z = 26)

14. Hardening of leather in tanning industry is based on

(A) Electrophoresis
(B) Electro-osmosis
(C) Mutual coagulation
(D) Tyndall effect

15. What is the correct IUPAC name of the given compound ?

(A) 2,2-Dimethylbutanoic acid

(B) 2-Carboxyl-2-methylbutane
(C) 2-Ethyl-2-methylpropanoic acid
(D) 3-Methylbutane carboxylic acid

.56/1/1 7 P.T.O.
àíZ g§»`m 16 go 20 Ho$ {bE, Xmo H$WZ {XE JE h¢ {OZ_| EH$ H$mo A{^H$WZ (A) VWm Xÿgao
H$mo H$maU (R) Ûmam A§{H$V {H$`m J`m h¡ & BZ àíZm| Ho$ ghr CÎma ZrMo {XE JE H$mo S>m| (i),
(ii), (iii) Am¡a (iv) _| go MwZH$a Xr{OE : 15=5
(i) A{^H$WZ (A) Am¡a H$maU (R) XmoZm| ghr H$WZ h¢ Am¡a H$maU (R), A{^H$WZ (A)
H$s ghr ì¶m»¶m h¡ &
(ii) A{^H$WZ (A) Am¡a H$maU (R) XmoZm| ghr H$WZ h¢, naÝVw H$maU (R),
A{^H$WZ (A) H$s ghr ì¶m»¶m Zht h¡ &
(iii) A{^H$WZ (A) ghr h¡, naÝVw H$maU (R) µJbV H$WZ h¡ &
(iv) A{^H$WZ (A) µJbV h¡, naÝVw H$maU (R) ghr H$WZ h¡ &

16. A{^H$WZ (A) : Au Am¡a Ag H$m {ZîH$f©U CZHo$ A`ñH$m| Ho$ NaCN Ho$ VZw {db`Z Ûmam
{ZjmbZ go {H$`m OmVm h¡ &
H$maU (R) : BZ A`ñH$m| go g§~Õ Aew{Õ`m± NaCN _| Kwb OmVr h¢ &
17. A{^H$WZ (A) : F2 AUw _| F – F Am~ÝY Xþ~©b hmoVm h¡ &
H$maU (R) : F na_mUw H$m AmH$ma N>moQ>m hmoVm h¡ &

18. A{^H$WZ (A) : Cnghg§`moOZ `m¡{JH$m| _| C^`X§Vr g§b½Zr Ho$ H$maU ~ÝYZr g_md`dVm
CËnÞ hmoVr h¡ &
H$maU (R) : C^`X§Vr g§b½Zr O¡go NO2 _| Xmo {^Þ XmVm na_mUw N Am¡a O hmoVo h¢ &
19. A{^H$WZ (A) : gyH«$mog EH$ AZnM`r eH©$am h¡ &
H$maU (R) : gyH«$mog _| ½bmBH$mo{g{S>H$ ~§Y hmoVm h¡ &
20. A{^H$WZ (A) : A{^{H«$`m H2 + Br2  2HBr _| AmpÊdH$Vm 2 àVrV hmoVr h¡ &
H$maU (R) : Xr hþB© àmW{_H$ A{^{H«$`m _| A{^H$maH$m| Ho$ Xmo AUw ^mJ boVo h¢ &

IÊS> I
21. {ZåZ{b{IV nXm| H$s n[a^mfm {b{IE : 12=2
(a) àem§VH$
(b) ny{VamoYr
AWdm
gm~wZm| H$s emoYZ {H«$`m g_PmBE & 2

.56/1/1 8
For questions number 16 to 20, two statements are given  one labelled
Assertion (A) and the other labelled Reason (R). Select the correct
answer to these questions from the codes (i), (ii), (iii) and (iv) as given
below : 15=5
(i) Both Assertion (A) and Reason (R) are correct statements, and
Reason (R) is the correct explanation of the Assertion (A).
(ii) Both Assertion (A) and Reason (R) are correct statements, but
Reason (R) is not the correct explanation of the Assertion (A).
(iii) Assertion (A) is correct, but Reason (R) is incorrect statement.
(iv) Assertion (A) is incorrect, but Reason (R) is correct statement.

16. Assertion (A) : Au and Ag are extracted by leaching their ores with a dil.
solution of NaCN.
Reason (R) : Impurities associated with these ores dissolve in NaCN.

17. Assertion (A) : F – F bond in F2 molecule is weak.

Reason (R) : F atom is small in size.

18. Assertion (A) : Linkage isomerism arises in coordination compounds

because of ambidentate ligand.
Reason (R) : Ambidentate ligand like NO2 has two different donor
atoms i.e., N and O.

19. Assertion (A) : Sucrose is a non-reducing sugar.

Reason (R) : Sucrose has glycosidic linkage.

20. Assertion (A) : The molecularity of the reaction H2 + Br2  2HBr

appears to be 2.
Reason (R) : Two molecules of the reactants are involved in the given
elementary reaction.

SECTION B
21. Define the following terms : 12=2
(a) Tranquilizers
(b) Antiseptic
OR
Explain the cleansing action of soaps. 2
.56/1/1 9 P.T.O.
22. 300 K na `y[a`m (‘moba Ð춑mZ = 60 g/mol) Ho$ 5% {db`Z H$m namgaU Xm~
n[aH${bV H$s{OE & [R = 0·0821 L atm K–1 mol–1] 2

AWdm
{dem Zo Xmo Obr` {db`Z, EH$ _| 100 g Ob _| `y[a`m (‘moba Ð춑mZ = 60 g/mol) Ho$
7·5 g Am¡a Xÿgao _| {H$gr nXmW© Z Ho$ 42·75 g, 100 g Ob _| {bE & `h ào{jV {H$`m
J`m {H$ XmoZm| {db`Z EH$g_mZ Vmn na {h_r^yV hþE & Z H$m _moba Ðì`_mZ n[aH${bV
H$s{OE & 2

23. A{^H$maH$ H$s gmÝÐVm Am¡a g_` Ho$ ~rM {XE JE J«m\$ H$m {díbofU H$s{OE & 12=2

(a) A{^{H«$`m H$s H$mo{Q> H$s àmJw{º$ H$s{OE &>

(b) g¡ÕmpÝVH$ Ñ{ï> go Š`m AZ§VH$mb Ho$ ~mX {H$gr A{^H$maH$ H$s gmÝÐVm KQ>H$a eyÝ`
hmo gH$Vr h¡ ? ì`m»`m H$s{OE &

24. {ZåZ{b{IV AUwAmo§ H$s AmH¥${V It{ME : 12=2

(a) XeOF4

(b) BrF3

.56/1/1 10
22. For a 5% solution of urea (Molar mass = 60 g/mol), calculate the osmotic
pressure at 300 K. [R = 0·0821 L atm K–1 mol–1] 2
OR
Visha took two aqueous solutions — one containing 7·5 g of urea (Molar
mass = 60 g/mol) and the other containing 42·75 g of substance Z in
100 g of water, respectively. It was observed that both the solutions froze
at the same temperature. Calculate the molar mass of Z. 2

23. Analyse the given graph, drawn between concentration of reactant vs.
time. 12=2

(a) Predict the order of reaction.

(b) Theoretically, can the concentration of the reactant reduce to zero

after infinite time ? Explain.

24. Draw the shape of the following molecules : 12=2

(a) XeOF4

(b) BrF3

.56/1/1 11 P.T.O.
25. {ZåZ{b{IV `m¡{JH$m| Ho$ gyÌ Xr{OE : 12=2

(a) nmoQ>¡{e`_ Q>oQ´>mhmBS´>mopŠgS>mo{µO§Ho$Q> (II)

(b) hoŠgmEoå_rZßb¡{Q>Z_ (IV) ŠbmoamBS>

26. Š`m hmoVm h¡ O~

(a) àmonoZmoZ H$mo _o{Wb_¡½Zr{e`_ Am`moS>mBS> Ho$ gmW A{^{H«${`V H$aHo$ Ob-AnK{Q>V
{H$`m OmVm h¡, Am¡a >
(b) ~oݵOrZ H$mo {ZO©b AlCl3 H$s CnpñW{V _| CH3COCl Ho$ gmW A{^{H«${`V {H$`m
OmVm h¡ & 12=2

27. {ZåZ{b{IV ~hþbH$m| _| EH$bH$m| Ho$ Zm_ Am¡a g§aMZmE± {b{IE : 12=2

(a) ~¡Ho$bmBQ>
(b) {ZAmoàrZ
IÊS> J
1
28. {ZåZ{b{IV A{^{H«$`mAm| Ho$ AZwH«$_ _| A Am¡a B H$s g§aMZmE± Xr{OE : 6=3
2
NH3 NaOBr
(a) CH3COOH  
 A   B


Fe / HCl NaNO  HCl

(b) C6H5NO2  A  2  B
0 –5C

+ CuCN H O / H
(c) C6H5N2Cl  A 2 
    B

AWdm
(a) {ZåZ{b{IV `wJbm| Ho$ `m¡{JH$m| Ho$ ~rM Amn {d^oX H¡$go H$a|Jo : 12=2

(i) Eo{ZbrZ Am¡a EWoZo_rZ

(ii) Eo{ZbrZ Am¡a N-_o{WbEo{ZbrZ
(b) {ZåZ{b{IV `m¡{JH$m| H$mo CZHo$ ŠdWZm§H$ Ho$ KQ>Vo hþE H«$_ _| ì`dpñWV H$s{OE : 1
ã`yQ>oZm°b, ã`yQ>oZo_rZ, ã`yQ>oZ
.56/1/1 12
25. Give the formulae of the following compounds : 12=2
(a) Potassium tetrahydroxidozincate (II)
(b) Hexaammineplatinum (IV) chloride

26. What happens when

(a) Propanone is treated with methylmagnesium iodide and then

hydrolysed, and
(b) Benzene is treated with CH3COCl in presence of anhydrous
AlCl3 ? 12=2

27. Write the names and structures of monomers in the following polymers :
12=2
(a) Bakelite
(b) Neoprene

SECTION C

1
28. Give the structures of A and B in the following sequence of reactions : 6=3
2
NH3 NaOBr
(a) CH3COOH   A  B

Fe / HCl NaNO  HCl
(b) C6H5NO2  A  2  B
0 –5C

+ CuCN H O / H
(c) C6H5N2Cl  A 2 
    B

OR
(a) How will you distinguish between the following pairs of
compounds : 12=2
(i) Aniline and Ethanamine
(ii) Aniline and N-methylaniline

(b) Arrange the following compounds in decreasing order of their

boiling points : 1
Butanol, Butanamine, Butane
.56/1/1 13 P.T.O.
29. {ZåZ{b{IV Ho$ {bE {dídgZr` ñnîQ>rH$aU Xr{OE : 13=3
(a) ½byH$mog 2,4-S>r.EZ.nr. narjU Zht XoVm &
(b) DNA Ho$ Xmo aÁOwH$ g_mZ Zht hmoVo, naÝVw EH$-Xÿgao Ho$ nyaH$ hmoVo h¢ &
(c) ñQ>mM© Am¡a gobwbmog XmoZm| _| EH$bH$m| Ho$ ê$n _| ½byH$mog BH$mB© hmoVr h¡ , {\$a ^r do
g§aMZmË_H$ Ñ{îQ> go {^Þ h¢ &
30. {ZåZ{b{IV Ho$ H$maU Xr{OE : 13=3
(a) gëâ`yag Aåb EH$ AnMm`H$ h¡ &
(b) âbwAmoarZ Ho$db EH$ Am°ŠgmoAåb ~ZmVr h¡ &
(c) CËH¥$îQ> J¡gm| Ho$ ŠdWZm§H$ He go Rn VH$ ~‹T>Vo h¢ &>
AWdm
{ZåZ{b{IV amgm`{ZH$ A{^{H«$`mAm| H$mo nyU© H$s{OE : 13=3

(a) MnO2 + 4 HCl 

(b) XeF6 + KF 
(c) I – (aq) + H+ (aq) + O2 (g) 

31. {ZåZ{b{IV H$s ^y{_H$m H$s ì`m»`m H$s{OE : 13=3

(a) ZnS Am¡a PbS H$mo n¥WH²$ H$aZo _| NaCN H$s &
(b) Aew{Õ Ho$ ê$n _| bm¡h`wº$ Cu Ho$ YmVwH$_© _| SiO2 H$s &
(c) Ti Ho$ n[aîH$aU _| Am`moS>rZ H$s &
32. ^m¡{VH$ A{YemofU Am¡a agmodemofU _| {d^oX Ho$ VrZ {~ÝXþ Xr{OE & 3

33. A{^{H«$¶m H$m doJ {H$g àH$ma à^m{dV hmoJm O~

(a) A{^H$maH$ H$m n¥îR>r` joÌ\$b H$_ H$a {X`m OmE,
(b) CËH«$_Ur` A{^{H«$`m _| CËàoaH$ {_bm {X`m OmE, Am¡a
(c) A{^{H«$`m H$m Vmn ~‹T>m {X`m OmE ? 13=3

34. 75 g Eogr{Q>H$Aåb _| Kmobo OmZo dmbr EoñH$m°{~©H$ Aåb

(‘moba Ð춑mZ = 176 g mol–1) H$s _mÌm (Ðì`_mZ) n[aH${bV H$s{OE {Oggo BgH$m
{h_m§H$ 1·5C H$_ hmo OmE & (Kf = 3·9 K kg mol–1) 3

.56/1/1 14
29. Give the plausible explanation for the following : 13=3
(a) Glucose doesn’t give 2,4-DNP test.
(b) The two strands in DNA are not identical but are complementary.
(c) Starch and cellulose both contain glucose unit as monomer, yet
they are structurally different.

30. Account for the following : 13=3

(a) Sulphurous acid is a reducing agent.
(b) Fluorine forms only one oxoacid.
(c) Boiling point of noble gases increases from He to Rn.
OR
Complete the following chemical reactions : 13=3

(a) MnO2 + 4 HCl 

(b) XeF6 + KF 

(c) I – (aq) + H+ (aq) + O2 (g) 

31. Explain the role of the following : 13=3

(a) NaCN in the separation of ZnS and PbS.

(b) SiO2 in the metallurgy of Cu containing Fe as impurity.
(c) Iodine in the refining of Ti.

32. Give three points of difference between physisorption and chemisorption. 3

33. How will the rate of the reaction be affected when

(a) Surface area of the reactant is reduced,
(b) Catalyst is added in a reversible reaction, and
(c) Temperature of the reaction is increased ? 13=3

34. Calculate the mass of ascorbic acid (Molar mass = 176 g mol–1) to be
dissolved in 75 g of acetic acid, to lower its freezing point by 1·5C.
(Kf = 3·9 K kg mol–1) 3

.56/1/1 15 P.T.O.
 IÊS> K
35. (a) A{^{H«$¶m
Zn (s) + Cu2+ (aq)  Zn2+ (aq) + Cu (s)
Ho$ {bE G n[aH${bV H$s{OE & 3
{X`m J`m h¡ : Zn2+/Zn Ho$ {bE E = – 0·76 V
Cu2+/Cu Ho$ {bE E = + 0·34 V
R = 8·314 JK–1 mol–1
F = 96500 C mol–1.
(b) BªYZ gobm| Ho$ Xmo bm^ Xr{OE & 2
AWdm
(a) {ZåZ{b{IV `wJbm| _| go, H$maU g{hV Cg EH$ H$s àmJw{º$ H$s{OE Omo {dÚwV² Ymam
H$s A{YH$ _mÌm Ho$ MmbZ H$s AZw_{V XoVm h¡ : 13=3
(i) 30C na Mm±Xr H$m Vma AWdm 60C na Mm±Xr H$m Vma &
(ii) 0·1 M CH3COOH {db`Z AWdm 1 M CH3COOH {db`Z &
(iii) 20C na KCl {db`Z AWdm 50C na KCl {db`Z &

(b) {dÚwV²-amgm`{ZH$ gob Am¡a {dÚwV²-AnKQ>Zr gob Ho$ _Ü` A§Va Ho$ Xmo {~ÝXþ Xr{OE & 2

36. (a) {ZåZ{b{IV Ho$ H$maU {b{IE : 13=3

(i) H$m°na (I) `m¡{JH$ g\o$X hmoVo h¢ O~{H$ H$m°na (II) `m¡{JH$ a§JrZ hmoVo h¢ &
(ii) H«$mo_oQ> AnZm a§J Aåbr` {db`Z _| n[ad{V©V H$a XoVo h¢ &
(iii) Zn, Cd, Hg d-ãbm°H$ VÎd Vmo _mZo OmVo h¢ naÝVw g§H«$_U VÎd Zht &

(b) Co Am¡a Co2+ Ho$ BboŠQ´>m°{ZH$ {dÝ`mg {bIH$a Co2+ (Z = 27) Ho$ {bE
àMH«$U-_mÌ AmKyU© n[aH${bV H$s{OE & 2

AWdm
(a) b¡ÝWoZm°`S>m| Am¡a EopŠQ>Zm°`S>m| Ho$ _Ü` A§Va Ho$ VrZ {~ÝXþ Xr{OE & 3

(b) H$maU XoVo hþE EH$ na_mUw/Am`Z N>m±{Q>E Omo nyN>m J`m JwUY_© Xem©Vm hmo : 12=2
(i) Sc3+ AWdm Cr3+ (à{VMwå~H$s` ì`dhma Xem©Vm h¡)
(ii) Cr AWdm Cu (Cƒ JbZm§H$ Am¡a ŠdWZm§H$)

.56/1/1 16
 SECTION D
35. (a) Calculate G for the reaction

Zn (s) + Cu2+ (aq)  Zn2+ (aq) + Cu (s). 3

Given : E for Zn2+/Zn = – 0·76 V and
E for Cu2+/Cu = + 0·34 V
R = 8·314 JK–1 mol–1
F = 96500 C mol–1.

(b) Give two advantages of fuel cells. 2

OR
(a) Out of the following pairs, predict with reason which pair will
allow greater conduction of electricity : 13=3
(i) Silver wire at 30C or silver wire at 60C.
(ii) 0·1 M CH3COOH solution or 1 M CH3COOH solution.
(iii) KCl solution at 20C or KCl solution at 50C.

(b) Give two points of differences between electrochemical and

electrolytic cells. 2

36. (a) Account for the following : 13=3

(i) Copper (I) compounds are white whereas Copper (II)
compounds are coloured.
(ii) Chromates change their colour when kept in an acidic
solution.
(iii) Zn, Cd, Hg are considered as d-block elements but not as
transition elements.
(b) Calculate the spin-only moment of Co2+ (Z = 27) by writing the
electronic configuration of Co and Co2+. 2
OR
(a) Give three points of difference between lanthanoids and actinoids. 3

(b) Give reason and select one atom/ion which will exhibit asked
property : 12=2
(i) Sc3+ or Cr3+ (Exhibit diamagnetic behaviour)
(ii) Cr or Cu (High melting and boiling point)
.56/1/1 17 P.T.O.
37. (a) t-ã`y{Q>b EoëH$mohm°b Am¡a n-ã`yQ>oZm°b _| go H$m¡Z-gm Aåb CËào[aV {ZO©bZ Vrd«Vm go
XoJm Am¡a Š`m| ? 2

(b) {ZåZ{b{IV ê$nmÝVaU gånÞ H$s{OE : 13=3

(i) µ\$sZm°b go g¡{b{gbEopëS>hmBS>

(ii) t-ã`y{Q>bŠbmoamBS> go t-ã`y{Q>b E{Wb B©Wa
(iii) àmonrZ go àmonoZm°b
AWdm
(a) EWrZ go EWoZm°b ~ZZo H$s {H«$`m{d{Y Xr{OE & 2

(b) {ZåZ{b{IV ê$nm§VaU gånÞ H$aZo Ho$ {bE A{^H$_©H$ H$s àmJw{º$ H$s{OE : 13=3

(i) µ\$sZm°b go ~oݵOmo{ŠdZmoZ

(ii) Eo{Zgmob go p-~«mo_moEo{Zgmob
(iii) µ\$sZm°b go 2,4,6-Q´>mB~«mo_moµ\$sZm°b

.56/1/1 18
37. (a) Out of t-butyl alcohol and n-butanol, which one will undergo acid
catalyzed dehydration faster and why ? 2

(b) Carry out the following conversions : 13=3

(i) Phenol to Salicylaldehyde
(ii) t-butylchloride to t-butyl ethyl ether
(iii) Propene to Propanol

OR

(a) Give the mechanism for the formation of ethanol from ethene. 2

(b) Predict the reagent for carrying out the following conversions : 13=3
(i) Phenol to benzoquinone
(ii) Anisole to p-bromoanisole
(iii) Phenol to 2,4,6-tribromophenol

.56/1/1 19 P.T.O.
 Strictly Confidential: (For Internal and Restricted use only)
Senior School Certificate Examination-2020
Marking Scheme – CHEMISTRY
(SUBJECT CODE -043) (PAPER CODE – 56/1/1,2,3)
General Instructions: -

1. You are aware that evaluation is the most important process in the actual and correct
assessment of the candidates. A small mistake in evaluation may lead to serious problems
which may affect the future of the candidates, education system and teaching profession. To
avoid mistakes, it is requested that before starting evaluation, you must read and understand
the spot evaluation guidelines carefully. Evaluation is a 10-12 days mission for all of us.
Hence, it is necessary that you put in your best efforts in this process.
2. Evaluation is to be done as per instructions provided in the Marking Scheme. It should not be
done according to one’s own interpretation or any other consideration. Marking Scheme
should be strictly adhered to and religiously followed. However, while evaluating, answers
which are based on latest information or knowledge and/or are innovative, they may
be assessed for their correctness otherwise and marks be awarded to them.
3. The Head-Examiner must go through the first five answer books evaluated by each evaluator
on the first day, to ensure that evaluation has been carried out as per the instructions given
in the Marking Scheme. The remaining answer books meant for evaluation shall be given
only after ensuring that there is no significant variation in the marking of individual evaluators.
4. Evaluators will mark( √ ) wherever answer is correct. For wrong answer ‘X”be marked.
Evaluators will not put right kind of mark while evaluating which gives an impression that
answer is correct and no marks are awarded. This is most common mistake which
evaluators are committing.
5. If a question has parts, please award marks on the right-hand side for each part. Marks
awarded for different parts of the question should then be totaled up and written in the left-
hand margin and encircled. This may be followed strictly.
6. If a question does not have any parts, marks must be awarded in the left-hand margin and
encircled. This may also be followed strictly.
7. If a student has attempted an extra question, answer of the question deserving more marks
should be retained and the other answer scored out.
8. No marks to be deducted for the cumulative effect of an error. It should be penalized only
once.
9. A full scale of marks 0-70 has to be used. Please do not hesitate to award full marks if the
answer deserves it.
10. Every examiner has to necessarily do evaluation work for full working hours i.e. 8 hours
every day and evaluate 20 answer books per day in main subjects and 25 answer books per
day in other subjects (Details are given in Spot Guidelines).
11. Ensure that you do not make the following common types of errors committed by the
Examiner in the past:-
 Leaving answer or part thereof unassessed in an answer book.
 Giving more marks for an answer than assigned to it.
 Wrong totaling of marks awarded on a reply.
 Wrong transfer of marks from the inside pages of the answer book to the title page.
 Wrong question wise totaling on the title page.
 Wrong totaling of marks of the two columns on the title page.
 Wrong grand total.
 Marks in words and figures not tallying.
 Wrong transfer of marks from the answer book to online award list.
 Answers marked as correct, but marks not awarded. (Ensure that the right tick mark is
correctly and clearly indicated. It should merely be a line. Same is with the X for incorrect
answer.)
 Half or a part of answer marked correct and the rest as wrong, but no marks awarded.
 12. While evaluating the answer books if the answer is found to be totally incorrect, it should be
marked as cross (X) and awarded zero (0)Marks.

13. Any unassessed portion, non-carrying over of marks to the title page, or totaling error
detected by the candidate shall damage the prestige of all the personnel engaged in the
evaluation work as also of the Board. Hence, in order to uphold the prestige of all concerned,
it is again reiterated that the instructions be followed meticulously and judiciously.

14. The Examiners should acquaint themselves with the guidelines given in the Guidelines for
spot Evaluation before starting the actual evaluation.

15. Every Examiner shall also ensure that all the answers are evaluated, marks carried over to
the title page, correctly totaled and written in figures and words.

16. The Board permits candidates to obtain photocopy of the Answer Book on request in an RTI
application and also separately as a part of the re-evaluation process on payment of the
processing charges.

56/1/1 – Set
MARKING SCHEME
Sr. SECONDARY SCHOOL EXAMINATION, 2020
Subject: CHEMISTRY
Distribut
Q.No. Expected Answer / Value Points ion of
Marks
SECTION - A
1. Racemic Mixture 1
2. Polarimeter 1
3. Pent-2-ene / CH3CH=CHCH2CH3 1
4. Antiseptic 1
5. CH3I + C6H5OH 1
6. A 1
7. Zn 1
8. No 1
9. CH2=CH-Cl 1
10. Branched hydrocarbon part 1
11. B 1
12. D 1
13. C 1
14. C 1
15. A 1
16. iii 1
17. ii 1
18. i 1
19. ii 1
20. i 1
 SECTION – B
21. (a) The drugs which are used to control stress / anxiety / tension / mild or severe 1
mental diseases
(b) The drugs which are used to kill or to prevent the growth of micro-organism, 1
applied externally on living tissues.
OR
21 Soap molecules form micelle around the oil droplet or dirt in such a way that 2
hydrophobic part interacts with the oil droplet and hydrophilic part projects out.
Micelles can be washed away on rinsing with water. Thus soap helps in
emulsification and washing away of oil and fats.
22.  = CRT (Volume of solution = 100 mL) ½

 = RT
½
=
1
 = 20.5 atm. (½ mark may be deducted for no or incorrect unit)

OR

22. Tf (urea) = Tf (Z) ½

(or by any other correct method) 1

(½ mark may be deducted for no or incorrect unit)
23. (a) 1st order 1
(b) No, due to exponential relation / the curve never touches the x-axis.
½+½
24. a) 1

b)
1

25. (a) K2[Zn(OH)4] 1

1
(b) [Pt(NH3)6]Cl4
26. a) (CH3)3C-OH / tertiary butyl alcohol is formed. 1
 b) C6H5COCH3 / acetophenone is formed 1
(or correct chemical equation)
27. a) C6H5OH + HCHO , Phenol + formaldehyde ½+½
b) CH2= C(Cl) – CH=CH2, Chloroprene ½+½
SECTION - C
28. (a) (A)  CH3CONH2 (B)  CH3NH2 ½+½
(b) (A)  C6H5NH2 (B)  C6H5N2Cl ½+½
(c) (A)  C6H5CN (B)  C6H5COOH ½+½

OR
28 a) (i) Add Ice cold (NaNO2 + HCl) followed by phenol or β-Naphthol to both the 1
compounds.
Aniline forms orange red dye while ethylamine doesn’t.
ii) Add CHCl3 and KOH (alc.) to both the compounds. 1
Aniline gives foul smelling isocyanide while N-Methylaniline doesn’t.
(or any other suitable chemical test)
b) Butanol > Butanmine > Butane 1

29. (a) Because the – CHO group in glucose is involved in hemiacetal formation 1
and thus is not free / due to cyclic structure of glucose -CHO group is not
free.
(b) Because the hydrogen bonds are formed between specific pairs of bases. 1
(c) Starch is a polymer of  - glucose while cellulose is a polymer of  - 1
glucose.

30. (a) Because sulphur readily gets oxidized itself to more stable +6 state. 1
(b) Because of absence of d-orbital in Fluorine.
1
(c) Because size increases from Helium to Radon. / dispersion or van der Waal
forces increase from Helium to Radon. 1
OR
(a) MnO2+ 4HCl  MnCl2 + Cl2 + 2H2O
30 1
(b) XeF6 + KF  K+[XeF7]-
(c) 4I-(aq.) + 4H+(aq.) + O2(g)  2I2(s) + 2H2O(l) 1

1
31. (a) NaCN act as a depressant. 1
(b) SiO2 act as a flux. / used to remove FeO as slag 1
(c) I2 is used to convert Ti into volatile compound (TiI4). 1
32. 1x3

(or any other correct differences)

33. (a) Decreases. 1
(b) Increases 1
(c) Increases 1

34. Tf = Kf m 1

1.5 = 1
Mass of ascorbic acid = 5.08 g. 1
SECTION – D
35 (a) E0cell = EoC – EoA ½
= 0.34 – (-0.76)
= 1.10V ½
Go = -nFEo ½
= -2  1.10  96500 ½
= -212300 J/mol or -212.3 kJ/mol 1
(b) (i) Pollution free 1
(ii) High efficiency. 1
OR
o
35. (a) (i) Silver wire at 30 C because as temperature decreases, resistance 1
decreases so conduction increases.
(ii) 0.1 M CH3COOH, because on dilution degree of ionization increases 1
hence conduction increases.
(iii) KCl solution at 50oC, because at high temperature mobility of ions 1
increases and hence conductance increases
(b)
Electrochemical Electrolytic
(1) Anode -ve Anode +ve
1
Cathode +ve Cathode -ve
(2) Convert chemical Convert electrical 1
Energy to electrical energy Energy to chemical energy
(or any other correct differences)
36. (a) (i) Cu+1(3d10) compounds are white because of absence of unpaired 1
electrons while Cu+2 (3d9) compounds are coloured due to unpaired e- / shows d-
d transition.
(ii) chromate (CrO42-) changes to dichromate (Cr2O72-) ion in acidic medium. 1

(iii) due to completely filled d-orbitals in their ground state as well as in 1

oxidized state.
(b) Co = [Ar]4s23d7 , Co+2 =[Ar] 3d7
½+½
½
½
OR
36. (a)
Lanthanoids Actinoids 1x3
(1) most of them are not radioactive All are radioactive
(2) don’t show a wide range of Show a wide range of oxidation
oxidation state states
(3) Most of their ions are colourless Most of their ions are coloured
(or any other correct differences)

(b) (i) Sc+3, because of absence of unpaired electron. ½+½

(ii) Cr, because of presence of strong intermetallic bonding than Cu. ½+½
37. (a) Tert-butyl alcohol, 1
because it forms more stable 3o carbocation than 1o carbocation. 1
(b) i)

Na
ii) (CH3)3CCl +NaOH(aq.) (CH3)3COH (CH3)3CONa 1
.
C2H5Cl

(CH3)3COC2H5
i) B2H6
iii) CH3CH=CH2 CH3CH2CH2OH 1
ii) H2O2/OH-
(or by any other suitable method)

OR
37. a)

b) i) K2Cr2O7 + H2SO4 / Na2Cr2O7 + H2SO4 1

ii) Br2 in CH3COOH 1
iii) Br2 aq. / Bromine water 1