BECRC - Hydrogen Powering of Vessels - Phase I Report - A4 - E20112023
BECRC - Hydrogen Powering of Vessels - Phase I Report - A4 - E20112023
BECRC - Hydrogen Powering of Vessels - Phase I Report - A4 - E20112023
PHASE I REPORT
A REVIEW OF THE FEASIBILITY OF
UTILISING HYDROGEN AS A MARINE FUEL
IN AUSTRALIA | NOVEMBER 2023
The Blue Economy CRC is funded in part under the Australian Government’s CRC Program, administered by the Department of
Industry, Science, Energy and Resources. The CRC Program supports industry-led collaborations between industry, researchers and
the community.
AUTHORS
ACKNOWLEDGEMENT
PARTICIPANTS
Department of Treasury
and Finance, Tasmania
CONFIDENTIAL REPORT
This report has been prepared solely for the use of the Blue Economy CRC-Co and
the Project Parties. This report is not intended for any other purpose, and shall not
be provided to any other Blue Economy CRC Participant or non-Participant without
the prior approval of the Blue Economy CRC CEO.
The Blue Economy CRC-Co acknowledges that it is, and will continue to be, solely
responsible for making any decisions based on the information contained in this
report, or when implementing any advice or recommendations in this report.
Figure 14. Schematic of a PEM fuel cell. 18 Table 2. Comparison of hydrogen storage 23
types.
Figure 15. Schematic of the fuel cell 18
power system. Table 3. Classification societies’ rules or 31
guidelines.
Figure 16. A simplified FC powertrain for 19
a vessel. Table 4. Selected international hydrogen 32
standards.
Figure 17. Hydrogen storage methods. 20
Table 5. Professional organisations’ 32
Figure 18. Type I-V compressed hydrogen 21 guidelines.
tanks.
Table 6. Hydrogen safety hazards and 35
Figure 19. Compressed hydrogen 24 preventions.
bunkering station
FAME Fatty Acid Methyl Ester PEMFC Proton exchange membrane fuel cell
FC Fuel cell
PIMs Polymers of intrinsic microporosity
GHG Greenhouse gas
SGMF The Society for Gas as a Marine Fuel
HT- High-temperature PEMFC
PEMFC
SOFC Solid oxide fuel cell
HVO Hydrotreated Vegetable Oil
SOLAS The International Convention for the
H2 Hydrogen Safety of Life at Sea
The existing hydrogen-powered vessels worldwide, which are mainly of smaller size,
serve as valuable examples for the adoption of hydrogen technology in Australian waters.
Australia has announced to achieve net zero greenhouse gas (GHG) emissions by 2050, and cut
emissions by 43% from 2005 levels by 2030 (Australian government, 2022; Reese, 2021). Therefore, the
emission reduction timeline for Australia’s domestic vessels should align with this overarching goal.
Based on the data submitted by the Australian Government to the United Nations Framework
Convention on Climate Change (Australian government, 2023), Figure 1 illustrates Australia’s domestic
maritime navigation carbon dioxide equivalent (CO2-e) emissions from 2005 to 2021. In recent years,
domestic maritime emissions have consistently hovered around 2 million tonnes per year, constituting
approximately 0.4% of the nation’s total annual emissions. To achieve the decarbonisation targets, these
emissions should be reduced by 43% from 2005 levels, reaching 1.31 million tonnes annually by 2030,
and ultimately reach zero emissions by 2050.
(0.40%) (0.40%)
(0.37%) 2.5351 2.4384 (0.41%)
Carbon dioxide equivalent (CO2-e)/
2005 2006 2007 2008 2009 2010 2011 2012 2013 2014 2015 2016 2017 2018 2019 2020 2021
» Hydrogen serves as an excellent carrier of renewable energies such as wind, solar, and hydropower,
which can be released as heat through combustion or as electricity through fuel cells (FCs), and the only
additional input required is oxygen, and the sole by-product produced is water. Not only GHG emissions
but also air pollutants, such as sulphur oxides, nitrogen oxides, and particulate matter, could be well
addressed using hydrogen as a fuel.
» Current hydrogen solutions are better suited for small vessels.
Voyage
optimisation Speed reducing
Autonomous shipping
hull coatings
Air lubrication
Propeller ducts
Pre-swirl stators
Towing kites
Sails
Solar panels
Technical Alternative
options Low emission fuels LNG
fuels/energy
Zero/near zero emissions fuels/energy
Bio-LNG
Carbon tax
Market E-fuels Hydrogen
mechanism
E-Ammonia
Subsides
E-Methanol
E-LNG
Since then, the maritime industry has witnessed a growing number of hydrogen-powered ships being
constructed or retrofitted to explore their feasibility and demonstrate their potential. Currently, more
and more hydrogen-powered vessels are under construction, on order, or under development. This
section provides an overview of these hydrogen-powered vessels and discusses the prospects of future
advancements in this field.
41
As of June 2023, a total of 41 hydrogen-powered vessels have
undergone testing and most of them are currently operational.
The information of these vessels can be found in Appendix Table A1. Figure 3 shows the number
of vessels categorised by their respective delivery year. As the maritime industry prioritises the
decarbonisation of its operations, the emergence of hydrogen-powered vessels has been on the
rise since 2021, and 19 out of the existing ships (46%) were delivered after 2021. Figure 4 presents a
breakdown of the number of ships based on the countries. It is evident that a considerable proportion
of these vessels are in Europe, while the United States (US), East Asian countries such as China, Japan,
and South Korea, as well as New Zealand, have also some hydrogen-powered vessels.
9
Number of Vessels
4
3 3
2 2 2 2 2
1 1 1 1 1 1
Delivery Year
8
7
7
Number of Vessels
6
5
5
4 4
4
3 3 3 3
3
2 2
2
1 1 1 1 1 1
1
Country
The fleet of existing hydrogen-powered vessels comprises a diverse range of ship types,
encompassing passenger ships, cargo ships, tugboats, sailing boats, and race boats.
The distribution of these ship types is presented in Figure 5, highlighting the versatility and feasibility
of utilising hydrogen across various vessel categories. Figure 6 shows that most of these vessels use
hydrogen as main power source.
Figure 7 shows photos of the selected vessels. Most the existing hydrogen-powered vessels are
classified as small-sized vessels, as illustrated in Figure 8. A significant majority of these vessels,
specifically 34 (83%) out of the total have a length of less than 50 meters. This indicates that the
existing cases of small-sized vessels utilising hydrogen can be crucial references for achieving the zero-
emission target for Australia’s domestic maritime sector.
2023, Inland cargo barge, “Antonie”, 2023, Inland container barge, “H2 Barge 1”,
The Netherlands The Netherlands
2023, Tugboat, “Hydrotug 1”, 2023, Passenger ship, “San Xia Qing Zhou 1”,
Belgium China
2022, Race boat, “Chase Zero”, 2022, Offshore crew transfer vessel (CTV),
New Zealand “Hydrocat 48”, The UK
2021, Passenger ship, “Hydro BINGO”, 2021, Inland pusher tug, “Elektra”,
Japan Germany
Number of Vessels 28
6
3 3 1
Length
Retrofitting existing vessels, on the other hand, presents some complexities, as it involves replacing
diesel systems with hydrogen systems and complying with safety requirements outlined in class rules.
Figure 9 provides an overview of the distribution of new build vessels and retrofitted vessels, illustrating
the efforts in adopting hydrogen technologies in both newbuilding and retrofitting sectors.
A variety of technologies have been explored Figure 12 and Figure 13 present the distributions
and tested on the vessels. Among the existing of the power of individual FC modules and the
vessels, 36 of them utilise hydrogen as their total FC power per ship respectively, providing
primary power source, while 5 vessels employ insights into the power capacities of these
hydrogen as an auxiliary power source. vessels.
19
Number of Vessels
10
1
0 0
With the maturing of hydrogen-related technologies, the maritime industry is venturing into the
exploration of larger and more advanced hydrogen-powered vessels.
Several countries have set ambitious targets in this regard. Notably, the California Air Resources Board
in the US has established a goal to ensure that at least 25% of ships operating in California waters will
be powered by hydrogen FCs by 2045 (Mandra, 2022).
According to the currently available information, by 2030, at least 35 hydrogen-powered vessels are
expected to be delivered around the world. Most of these vessels will utilise PEMFCs as their primary
propulsion power source. Among them, certain vessels will have FC power ranging 2-6 MW, with the
largest vessel reaching a maximum power of 23 MW, which is equivalent to the maximum power levels
of existing fossil fuel powered ships. Detailed information about the future hydrogen-powered vessels
can be found in Appendix Table A2.
3. TECHNOLOGIES
The core technologies for utilising hydrogen as an energy source in maritime applications
include energy conversion technologies (FCs or ICEs), hydrogen storage technologies, and
hydrogen bunkering technologies. This section discusses the characteristics and maturity
levels of the technologies.
The technologies of using hydrogen as a power source on vessels can be primarily divided into two
types: using hydrogen as a feedstock to generate electricity in FCs and using hydrogen as a fuel in ICEs,
where it reacts directly with oxygen to produce thermal energy.
Hydrogen FCs facilitate the direct conversion into Low-Temperature PEMFC (typically
of chemical energy inherent in the fuel into represented as PEMFC) and High-Temperature
electrical energy via chemical reactions. PEMFC (HT-PEMFC). The comparison of these
technologies can be found in the literature
These electrochemical devices can serve as a (ENERGY.GOV, 2023).
reliable power source for vessels. Comprising
positive and negative electrodes and an It appears that there is a preference for PEMFC
electrolyte, FCs operate through oxidation and when regarding maritime applications due to its
reduction reactions that transpire on opposing high technology readiness level. PEMFC operates
sides of the electrolyte membrane. As the at relatively low temperatures, which enhances
liberated electrons move through an external its flexibility, safety, and quick start-up.
circuit, they generate a continuous flow of
electrical energy. By sustaining a steady inflow of Figure 14 shows a schematic of a typical PEMFC.
fuel and oxidant, FCs maintain an uninterrupted It consists of anode and cathode, sandwiched
generation of electrical energy. around a PEM. Hydrogen is fed to the anode, and
air is fed to the cathode. A catalyst separates
Hydrogen FCs can be classified into various hydrogen atoms into protons and electrons,
types based on the type of electrolyte they which take different paths to the cathode.
employ, including Alkaline Fuel Cell (AFC),
Proton Exchange Membrane Fuel Cell (PEMFC), The electrons go through an external circuit,
Phosphoric Acid Fuel Cell (PAFC), Molten creating a flow of electricity. The protons migrate
Carbonate Fuel Cell (MCFC), and Solid Oxide Fuel through the electrolyte to the cathode, where
Cell (SOFC). PEMFC can be further subdivided they reunite with oxygen and the electrons to
produce water and heat.
The PEMFC system comprises the FC stack and its balance-of-plant (BoP) systems including hydrogen
supply system, air supply system, and cooling system, as shown in Figure 15.
As FCs do not deliver mechanical energy as needed for propulsion, they must be combined with electric
motors. Figure 16 presents a simplified powertrain of a vessel.
As hydrogen FCs produce direct current (DC) electricity, vessels typically employ a DC distribution
system. The FC system is connected to the DC bus via a DC-DC converter, which stabilises the variable
amplitude DC electricity generated by the FC system. The DC bus is then connected to an inverter,
converting the DC electricity on the bus into alternating current (AC) electricity to power propulsion
motors and the onboard electrical grid for daily loads. The motors drive the rotation of the main
propulsion propeller or azimuth thrusters.
However, FCs typically require several minutes for the hybrid propulsion systems. This ensures
to adjust to sudden changes in operating the stability, reliability, and safety of ship
conditions, which may not meet the load operations.
demands of a vessel. Therefore, FC systems are
often integrated with energy storage devices Currently, there are some commercialised
such as batteries and supercapacitors, to form maritime PEMFC systems in the market. Table
hybrid propulsion systems, as depicted in Figure 1 presents selected maritime PEMFC suppliers
16. Energy storage devices come into service in and their product parameters, where the
load variations. maximum nominal rated output power is 600
kW. To achieve higher power output, individual
When the ship requires low power and the FC FC modules can be connected in series and/or
system generates excess electricity, it can be parallel to form a FC stack assembly to meet the
used to charge the energy storage device via power demands of vessels.
the DC bus. On the other hand, from the Safe
Return to Port (SrtP) perspective, the energy Nevertheless, the primary limitations of these
storage device such as battery is necessary and maritime PEMFC products lie in their substantial
its capacity should be sufficient, particularly for weight and size. The most compact design
passenger ships. It is crucial to employ energy currently available is 4.7 kg/kW and occupies
management coordination and control systems 0.0072 m3/kW, making it considerably heavier
to regulate the flow of different energy sources and larger than traditional maritime ICEs.
NOMINAL POWER OF
MAKER COUNTRY REF.
SINGLE MODULE (KW)
(Nedstack, 2023a,
Nedstack The Netherlands 120-600
2023b)
The predominant propulsion systems utilised on ships at present are centred around ICEs.
The adoption of hydrogen as a fuel provides the possibility to modify existing engine
concepts to accommodate hydrogen, while also facilitating the development of dedicated
engine designs for hydrogen fuel.
The structure and working principles of hydrogen ICEs are similar to conventional ones. It can operate
with lower-grade hydrogen which is handy for specific use cases. Nevertheless, achieving optimal
performance in a hydrogen ICE poses a significant challenge. Due to hydrogen’s low ignition energy, hot
gases and hot spots on the cylinder can act as potential ignition sources, leading to issues such as
premature ignition and flashback. Additionally, the broad flammability range of hydrogen implies that a
hot spot can ignite nearly any mixture it encounters.
Therefore, hydrogen ICE has not yet been used commercially on a large scale. Some engine
manufacturers, for instance, Cummins, Toyota, and Yamaha, have been testing hydrogen engines
to mitigate the risks associated with hydrogen (Cummins, 2022; Frangoul, 2022). To mitigate risks,
hydrogen-diesel dual fuel engines are under development or tested (Ghazal, 2019; Schwartz, 2022). The
world’s first hydrogen-fuelled tugboat uses a hydrogen-diesel dual fuel ICE (MarineLink, 2022). However,
utilising dual-fuel engines cannot achieve zero-emission target, and it is essential to ensure that NOx
emissions comply with the international and flag regulations.
The density of hydrogen gas at standard atmosphere is 0.084 kg/m3. Hydrogen’s boiling point is -252.77
°C, its melting point is -259.1 °C, and its critical point is -240 °C at 1.32 MPa. Therefore, Hydrogen
storage onboard is challenging. As shown in Figure 17, hydrogen can be stored using physical-based
methods, such as compressed hydrogen, cryogenic liquid hydrogen, and cryogenic compressed liquid
hydrogen, and material-based methods, including using liquid chemical hydrogen carriers, metal
hydrides, and adsorbents.
Compressed hydrogen
Absorption
Compressed hydrogen storage refers to the storage of hydrogen gas under high pressure, and the
required pressure level depends on specific applications.
For maritime applications, the volume of hydrogen is a critical factor for vessel designs, so
higher pressures are necessary. Higher pressure means more hydrogen can be stored, allowing
for longer distances to be travelled, but it also requires additional safety precautions.
As a result, two typical pressure levels, 350 While cryogenic liquid hydrogen technologies
and 700 bar, are currently used in the maritime have been utilised in the aerospace industry for
sector. Some demonstration projects use lower several decades in the US and China (Ustolin et
pressure, for instances 200 and 300 bar, to al., 2022), they are prohibitively expensive for
reduce the risk of hydrogen release. civilian applications. Currently, there is only one
known hydrogen-powered vessel named “MF
Compressed hydrogen gas storage tanks are Hydra” in Norway that utilises cryogenic liquid
categorised into Type I, II, III, IV, and V (Figure hydrogen for storing hydrogen (Ivan Østvik, 2021).
18) based on their construction and operational
characteristics (Langmi et al., 2022). (3) Cryogenic compressed hydrogen
Type I tanks are made of metal and are heavy, Cryogenic compressed hydrogen storage involves
suitable for low-pressure storage. Type II tanks storing hydrogen at cryogenic temperatures
are also made of metal but have an additional in a pressurised vessel (for example, at 300
layer for increased pressure resistance. Type III bar). This method differs from conventional
tanks’ liners are made of metal and their wrap cryogenic storage, which stores liquid
layers are made of composite materials, such as hydrogen at near-ambient pressures. Cryogenic
carbon fibre reinforced polymer, offering higher compressed hydrogen storage can encompass
strength and reduced weight. Type IV tanks are liquid hydrogen, cold compressed hydrogen,
entirely composite, utilising composite materials or hydrogen in a two-phase region (saturated
and a plastic liner, providing excellent strength- liquid and vapour) (Langmi et al., 2022). It
to-weight ratios and high-pressure capabilities. offers the potential for even higher densities
Type V tanks do not have an internal liner so the compared to cryogenic liquid hydrogen. However,
composite acts as both the gas barrier and load achieving these densities requires specific design
bearing structure for further weight reduction considerations, including effective thermal
and increased capacity (Air et al., 2023). insulation and the incorporation of a high-
pressure accumulator. Consequently, cryogenic
The choice of tank type depends on the specific compressed hydrogen storage systems often
application’s requirements regarding pressure, have thicker walls and increased weight.
weight, storage capacity, and cost. Type III and IV
tanks have been used on the existing hydrogen- While this storage method shows promise in
powered vessels (Figure 10). meeting volumetric capacity requirements in
the maritime industry, it suffers from high
(2) Cryogenic liquid hydrogen manufacturing, operating, and maintenance
costs.
The storage of hydrogen in a liquefied state
offers the highest storage density, making it a
preferred option for minimising storage size.
Liquid hydrogen storage has the added benefit Figure 18. Type I-V compressed hydrogen tanks.
of being able to be stored at a low pressure
of approximately 4 bar. However, the major
disadvantage is that hydrogen becomes liquid
at an extreme low temperature of -253°C (at
atmospheric pressure), requiring specialised
cryogenic tanks with reliable thermal insulation
to reduce vapourisation caused by heating.
Additionally, the current industrial capacity to
produce liquid hydrogen is relatively low, which Source: AFP (2022)
poses a challenge for the widespread adoption of
this storage method.
(1) Liquid chemical hydrogen carrier advantages of metal hydrides for hydrogen
storage is their high volumetric storage
Numerous chemical compounds can react capacities. This characteristic enables a safer
with hydrogen and act as chemical storage. and more compact storage solution compared to
The promising chemical compounding forms conventional methods such as compressed and
are liquid ammonia, methanol, or liquid cryogenic storage (Gray, 2007; Hirscher et al.,
organic hydrogen carriers (LOHCs) such as 2020). Metal hydrides can be classified into three
methylcyclohexane (MCH) and dibenzyl toluene groups: intermetallic hydrides, binary hydrides,
(DBT) (Hydrogen Council, 2021; Meca et al., 2022). and complex metal hydrides (Langmi et al.,
2022).
Ammonia is a compound of hydrogen and
nitrogen in the form of NH3 synthesised via the More than 50 metallic elements of the periodic
Haber-Bosch process (MacFarlane et al., 2020). table can absorb hydrogen in good quantities;
Methanol is a hydrogen carrier in the form of hence, the possible choices of hydride materials
CH3OH. The reaction of H2 with CO2 to form are enormous. But only some of them are
methanol and water (IRENA, 2021). LOHCs are suitable for hydrogen storage at moderate
emerging hydrogen carriers, where hydrogen temperatures and pressures. For example,
is stored inside a LOHC molecule (exothermic LaNi5, FeTi, and Mg2Ni. In practical applications,
hydrogenation) and released (endothermic containers for hydrogen storage are filled with
dehydrogenation) at the point of consumption. metal powders that can absorb and release
Then, the dehydrogenated LOHC returns to hydrogen as required. When hydrogen is
the hydrogenation point to start a new cycle absorbed by a metal hydride, heat is released. To
(Niermann et al., 2021). release the stored hydrogen, the hydride needs
to be heated. However, the utilisation of metal
These chemical compounding forms can be
hydrides for maritime applications is limited
stored under relatively easy conditions compared
due to the complexity of hydrogenation and
to compressed hydrogen and liquid hydrogen.
dehydrogenation processes onboard.
Liquid ammonia can be stored at minus 33 °C
under atmospheric pressure or at 0.8−1.0 MPa (3) Adsorption storage
under atmospheric temperature (Al-Aboosi et
al., 2021; Fan et al., 2022; Valera-Medina et al., In the adsorption storage of hydrogen, hydrogen
2021). Methanol and LOHCs can be stored in molecules are bound to the surface of the pores
liquid forms at normal temperature and pressure of the materials through physical interaction
(McKinlay et al., 2021; Raab et al., 2021). However, (physisorption), which involves weak van
the use of liquid chemical hydrogen carriers der Waals forces. Numerous materials have
can be constrained by reversibility issues, as been extensively studied for their potential in
not all compounds can efficiently regenerate hydrogen storage via adsorption. These materials
pure hydrogen during the release process. range from traditional options like zeolites and
Additionally, the onboard dehydrogenation activated carbon to advanced ones such as
processes consume a significant amount of carbon nanotubes, fullerenes, zeolite-templated
energy, rendering them uncompetitive for carbons, as well as more recent categories like
maritime applications. metal-organic frameworks (MOFs), covalent
organic frameworks (COFs), and polymers of
(2) Metal hydride intrinsic microporosity (PIMs) (Langmi et al.,
2022). However, the practical implementation of
Hydrogen interacts with various metals and
hydrogen storage management using adsorption
alloys at various temperatures and pressures
is complex and not yet fully developed for
to form metal hydrides. One of the significant
maritime applications.
Table 4 provides an overview of various storage technologies (Andersson & Grönkvist, 2019;
Andersson et al., 2020; B.Gupta, 2009; Langmi et al., 2022; Niermann et al., 2019; Sekine & Higo,
2021; Toyota, 2023; Züttel, 2003).
Notably, the list is not exhaustive, as new methods are continuously being developed, and
extensive research is underway to improve the technologies (Hirscher et al., 2020).
Volumetric Storage
H2 density (kg/ Relative
Storage type State energy density density
m3) 1 density
(MJ/m3) 2 (wt%) 3
Standard
Gas 0.084 10.08 1 /
hydrogen
274
5.5;7.7
Compressed 23 (350bar); 2760 (350bar); (350bar);
Gas (Type IV
hydrogen 42 (700 bar) 5040 (700 bar) 500 (700
tank)
bar)
Cryogenic
88 (-253 °C, 10,560 (-253 °C, 1048 (-253
compressed Liquid 9
300bar) 300bar) °C, 300bar)
hydrogen
Methanol
Liquid 99 11,880 1179 12.1
(Chemical carrier)
MCH (Chemical
Liquid 47.3 5676 563 6.16
carrier)
DBT (Chemical
Liquid 56.4 6768 671 6.21
carrier)
Mg2FeH6 (Metal
Solid 150 18,000 1786 5.6
hydride)
LaNi5H6 (Metal
Solid 117 14,040 1393 1.3
hydride)
FeTiH1.7 (Metal
Solid 113 13,560 1345 1.7
hydride)
MgH2 (Metal
Solid 109 13,080 1298 7.7
hydride)
LiBH4 (Metal
Solid 121 14,520 1440 18
hydride)
Note: 1 If not specified, the data is based on Normal Temperature and Pressure; 2 The lower heating value (LHV) is 120 MJ/kg;
3 Weight percentage (wt%) defines the net usable specific energy from the standpoint of the total onboard storage system,
not just the storage medium.
Both compressed hydrogen and liquid hydrogen tanks have lifespans that align with the
operational lifespan of vessels. As a result, in the short term, these two methods of hydrogen
storage are poised to become the mainstream approaches in the maritime industry.
Looking towards the future, material-based storage methods hold potential for maritime use.
Specifically, metal hydrides are well-suited for maritime applications due to their safety advantages and
high hydrogen storage efficiency. However, technological advancements are necessary to ensure that
fuel supply matches the real-time fluctuating characteristics of FCs or engine fuel demands.
On the other hand, the potential of liquid chemical hydrogen carriers is limited due to the complexity
and high energy consumption involved in the dehydrogenation process. It is important to note that this
conclusion is specific to hydrogen-powered vessels. Ammonia and methanol can be directly used as
fuels for ship ICEs, although the advantages in this aspect are beyond the scope of this research.
It is worth noting that compared to traditional marine fossil fuels such as diesel and LNG, hydrogen has
a relatively high lower heating value (LHV), 120 MJ/kg, which is 2.8 times that of diesel (42.7 MJ/kg) and
2.2 times that of LNG (53.6 MJ/kg). However, due to hydrogen’s low density, its volumetric energy density
is much lower than that of fossil fuels. For example, the volumetric energy density of hydrogen at 350
bar pressure (2760 MJ/m3) and cryogenic liquid hydrogen (8520 MJ/m3) is only 0.07 times and 0.23
times that of diesel (37,363 MJ/m3), respectively, and 0.11 times and 0.35 times that of LNG (24,120 MJ/
m3), respectively. Even with high-efficiency solid-state hydrogen storage, its volumetric energy density
still lags significantly behind fossil fuels. This presents challenges for vessel designs.
The TCO of a hydrogen-powered vessel can be evaluated from three aspects: capital expenditure
(CAPEX), operational expenditure (OPEX), and carbon benefits. CAPEX primarily includes the initial
investment in the hydrogen fuel system, while OPEX mainly consists of fuel costs, ship maintenance
costs, parts replacement costs (FC system and battery replacement), and carbon taxes. This section
introduces the fundamental data pertaining to CAPEX and OPEX. In terms of energy conversion, this
section only considers commercially available hydrogen FC systems due to ICE technologies being in the
research and development stage.
The primary initial investment for hydrogen FC-powered ships comprises hydrogen storage equipment,
FC systems (including FC stacks and associated BoP systems), and batteries. The cost estimation is
based on land-based equipment or systems. However, it is important to note that the investment cost
of marine equipment and systems is considerably higher than similar products used on land. This is
primarily due to the necessity of meeting stringent maritime environmental standards (such as vibration
resistance and withstanding high-salinity environments) and obtaining certification from classification
societies.
Among the feasible maritime hydrogen fuel storage methods, only compressed high-pressure gaseous
hydrogen storage that have reached the commercial application stage. Therefore, this report only
provides the estimated investment costs for high-pressure hydrogen tanks. Currently, hydrogen tanks
for land-based vehicles have reached a certain market size. This report considers the cost of marine
hydrogen tanks by multiplying the cost of automotive hydrogen tanks by 1.5 as the investment cost for
marine hydrogen tanks.
In 2021, the US Department of Energy (DOE) evaluated the cost of 700 bar Type IV hydrogen tanks for
long haul trucks, which included integrated valves and regulators. Based on higher end of the cost range
in DOE’s report (Houchins et al., 2021), this study estimated the 2022 constant cost of Type IV tank
system for maritime use, as shown in Figure 23. The estimated cost range for 700 bar Type IV tanks for
maritime use is AUD1490-2210 per kg of hydrogen; the estimated cost range for 350 bar Type IV tanks for
maritime use is AUD1192-1768 per kg of hydrogen.
Figure 23. Estimated cost of Type IV tank system for maritime use.
2210
1619
350 bar Type IV
1473 1490
tank for ships
1295 1192
1079 700 bar Type IV
993 tank for trucks
PEM FC systems for automotive applications have reached commercial scale in the market. However, the
power range of FC systems used in vehicles is smaller compared to those used in marine applications.
Therefore, evaluating the cost of marine PEMFC systems based on automotive FC system costs would
be inaccurate.
The US DOE evaluated the costs of 100 kW and 250 kW PEMFCs for land-based applications (Battelle
Memorial Institute, 2016). This power range is close to the power range of small-scale vessels. Hence,
this report relies on the conclusions drawn by the US DOE to assess the cost of marine PEMFC systems.
Figure 24 provide the estimated 2022 constant costs of PEMFC systems and FC stacks. For PEMFC
systems with a power output of 100-250 kW, the cost range is projected to be between AUD3486 and
7499 per kW, depending on the scale of production. As for PEMFC stacks, the cost range is estimated to
be between AUD504 and 812 per kW, depending on the production scale.
Figure 24. Estimated costs of PEMFC systems and PEMFC stacks for maritime use.
7399
6292
AUD IN 2022 (/kW)
Production capaxcity:
1000 systems/year
4807
Production capaxcity:
1000 systems/year
3486
100 kW 250 kW
Production capaxcity:
812
1000 systems/year
AUD IN 2022 (/kW)
Production capaxcity:
1000 systems/year
670
Note: The analysis does not account
for fluctuations in raw material
549
prices; the currency exchange rate
504 in 2016 was 1 USD = 1.3457 AUD; a
factor of 1.5 is applied to estimate
the cost for maritime applications;
the inflation rate between 2016 and
2022 was 16.7% (RBA, 2023).
100 kW 250 kW
Lithium-ion batteries have reached a mature and well-commercialized state in the vehicle industry, and
this study considers them as the energy storage device. According to the US DOE, the cost of an electric
vehicle lithium-ion battery pack has seen a significant decline of 89% between 2008 and 2022 (using
2022 constant dollars) (DOE, 2023).
In 2022, the estimated cost was USD 153/kWh on a usable-energy basis for production at a scale of at
least 100,000 units per year. This represents a considerable reduction compared to the cost of USD1355/
kWh in 2008. The decline in cost can be attributed to advancements in battery technologies and
chemistries, as well as increased manufacturing volume. Consequently, the estimated 2022 constant
cost of a lithium-ion battery for maritime use 2022 is 331 AUD/kWh, as illustrated in Figure 25.
331
Note: The currency exchange rate in 2022 was 1 USD = 1.4421 AUD; a factor of 1.5 is applied to estimate the cost for
maritime applications; a factor of 1.5 is applied to estimate the cost for maritime applications.
The OPEX primarily come from fuel prices and the costs of system replacement and maintenance.
When determining the price of hydrogen fuel for ships, it is essential to consider various cost factors
such as production, storage, transport, and bunkering operations.
Projections indicate that the costs of hydrogen production from renewable sources are
expected to decrease, primarily driven by the declining costs of wind and solar power, as well
as advancements in water electrolysers.
Figure 29. Status and progress of the regulatory framework for hydrogen-powered vessels.
IGF Code;
SOLAS regulation II-1/55;
IMO
MSC.1/Circ.1647: Interim guidelines for the safety of ships using fuel cell power
installations;
MSC.1/Circ.1212/Rev.1 and MSC.1/Circ.1455: Alternative design and arrangement Flag
regulations
AMSA: Novel vessel policy statement 2022
Classification
ABS: Hydrogen as marine fuel; BV:NR 547: Fuel cell power systems
Societies’ rules
on board ships; CCS: Guidelines Classification Societies’ rules for
Ships Using Alternative Fuels; DNV: Part 6 Chapter 2 Section 3
Fuel Cell Installations- FC; KR: Guidance for Fuel Cell Systems on ISO, IEC
Board of Ships LR: Appendix LR3- Requirements for Ships Using
Hydrogen as Fuel
National Standards...
Guidelines issued by
IEC 62282 series: Fuel cell technologies; IS014687;
profesional guidelines
Hydrogen fuel quality— Product specification; ISO/
TR 15916: Gaseous hydrogen- cylinders and tubes for
stationary storage; ISO 26142: Hydrogen detection
apparatus; ISO/TS 19880-1: Gaseous hydrogen — Fuelling
stations; Standards Australia: ME-093.
SGMF: Hydrogen as a marine fuel an introduction; ABS: Sustainability whitepaper: Hydrogen as marine fuel;
DNV: Handbook for hydrogen-fuelled vessels
Using hydrogen on ships falls within the purview of the IMO International Code of Safety for Ships Using
Gases or Other Low-flashpoint Fuels (IGF Code). Following the 5th session of the IMO Sub-Committee
on Carriage of Cargoes and Containers in 2018, the correspondence group of the IGF Code initiated the
drafting of the guidelines of utilising FC power installations on ships. In 2022, the IMO issued the Interim
Guidelines for the Safety of Ships Using FC Power Installations (MSC.1/Circ.1647), which outlined safety
design requirements for ships equipped with FC installations.
However, these guidelines did not address hydrogen storage and bunkering procedures on ships.
Currently, the IGF Code correspondence group is drafting the full requirements for hydrogen FC
powered vessels, which are expected to be finalised until 2025-26. Thus, at the moment, alternative
design method should be used according to IGF Code Part A: 2.3, where state “The equivalence of the
alternative design shall be demonstrated as specified in SOLAS (International Convention for the Safety
of Life at Sea) regulation II-1/55 and approved by the Administration.”
During implementing SOLAS regulation II-1/55, the documents, MSC.1/Circ.1212 Guidelines on alternative
design and arrangements for SOLAS chapters II-1 and III and MSC.1/Circ.1455 Guidelines for the approval
of alternatives and equivalents as provided for in various IMO instruments, shall be referred.
The AMSA issued the Novel Vessel Policy Statement in June 2022 (AMSA, 2022). It clarified the novel
vessel certification pathway, stating that “a novel vessel must be constructed and maintained in
accordance with the class rules of a recognised organisation.” Where a recognised organisation’s rules
do not extend to a novel vessel, then risk assessment-based method can be accepted.
Classification societies have created their rules or guidelines for the use of hydrogen as a marine
fuel, as listed in Table 3. In cases where a classification society has established a comprehensive set
of rules for adopting hydrogen on vessels, which address specific requirements not covered by the
IMO’s regulations, the flag administration, AMSA, may accept the application of these rules to facilitate
alternative design approaches. Furthermore, the rules developed by classification societies can serve as
a foundation for the development of future IMO regulations.
The International Electrotechnical Commission (IEC) and the International Organization for
Standardization (ISO) have established hydrogen standards that primarily focus on safety and testing
requirements for road vehicles. These standards, listed in Table 4, are widely adopted as regulatory
components in several countries including Australia. However, there is currently an inadequate set of
standards to comprehensively address hydrogen applications on ships.
Storage ISO/TR 15916 Basic considerations for the safety of hydrogen systems
Professional organisations are actively taking part in bridging the knowledge and expertise gaps related
to hydrogen-powered vessels. The Society for Gas as a Marine Fuel (SGMF) has released an introductory
book that focuses on the utilisation of hydrogen as a marine fuel. Classification societies like ABS and
DNV have also published whitepapers and handbooks to provide guidance to the industry on the use of
hydrogen. Table 5 summarises these publications.
The training should encompass ship crew members as well as bunkering workers. This section provides
an overview of the essential steps and actions required for effective training.
The inclusion of crew training requirements The hydrogen fuel bunkering requires qualified
for hydrogen-powered ships in the IMO personnel to perform the operation. Due to
International Convention on Standards of limited practical experience with hydrogen
Training, Certification and Watchkeeping for bunkering in the world, there are challenges
Seafarers (STCW convention) is still pending. in providing practical training for hydrogen
Additionally, AMSA has yet to establish crew bunkering. Some countries have set up hydrogen
training requirements specifically for hydrogen- education systems (Beasy et al., 2023; Nowotny
powered vessels. Drawing from the crew training et al., 2014; Reijalt, 2010). In Australia, a National
requirements for LNG-powered ships outlined in Hydrogen Skills and Training Analysis has been
the STCW convention, it is advisable that crew conducted in 2022 to identify and plan for the
training for hydrogen-powered ships incorporates future skills and training needs of Australians
both theoretical and practical components. The working with hydrogen (PWC, 2021). However,
training concept can be divided into various these efforts did not specifically address
methods as follows: the training needs for hydrogen bunkering
operations.
» Courses: These can be conducted in a
classroom setting or through e-learning modules To address the challenge of insufficient training
to provide theoretical knowledge on hydrogen preparation for hydrogen bunkering, this research
systems. provides the following solutions:
» Training with simulation programs: Utilising » Developing practical training programs specific
simulation programs, crew members can gain to hydrogen bunkering operations, which cover
practical knowledge and experience in the safe handling procedures, emergency response
handling of hydrogen systems. protocols, and maintenance practices.
» Trainings/Demonstrations: This stage involves » Engaging professional hydrogen experts from the
practical applications and can take place on land transport and aerospace industries who
an actual ship or within a real hydrogen facility. can provide practical knowledge and hands-on
These sessions aim to deepen and consolidate training exercises to enhance the skill set of
the practical knowledge that has already been port professionals in the hydrogen bunkering
acquired. sector.
By incorporating these training methods, crew » Establishing continuous professional
members can acquire the necessary skills and development programs to keep personnel
expertise to operate hydrogen-powered ships updated with the latest technologies and safety
safely and effectively. practices in hydrogen bunkering field.
Taking these factors into consideration, in the initial stages, feasible hydrogen-powered ships should
primarily target small vessels operating on fixed routes. This approach ensures both the practicality of
fuel bunkering and the availability of hydrogen power system. It is crucial to prioritise the development
of a robust supply chain and scalable FCs for large vessels before gradually expanding the application of
hydrogen to larger ships.
Currently, ferries, port working vessels (dredger, floating crane, pilot boat, tugboat, etc), aquaculture
support vessels, and offshore wind farm support vessels are considered suitable for using hydrogen for
they often operate on fixed routes with predetermined schedules, making them well-suited for hydrogen
bunkering infrastructure planning. With proper infrastructure in place, these vessels can be bunkered
during scheduled stops or overnight, ensuring continuous operation without disruptions.
8. SAFETY
Safety is of paramount importance for adopting hydrogen on vessels. This section identifies hydrogen’s
safety hazards and preventions and proposes a safe design process for hydrogen powered vessels.
Hydrogen bunkering, storage, and utilisation present potential safety hazards that can be categorised
as physical hazards (related to phase changes, component failures, and embrittlement) and chemical
hazards (such as ignition and burning). Many historical incidents and accidents involve a combination of
both physical and chemical hazards.
The most significant hazard associated with hydrogen is the inadvertent creation of a flammable or
detonable mixture, which can result in fires or explosions. Enhancing safety requires ship designers and
crew to have a thorough understanding of the specific hazards associated with hydrogen handling. Table
6 lists the hydrogen safety hazards and preventions (NASA, 1997).
Dispersion Gaseous hydrogen is lighter than air, Monitoring and detection systems
making the cloud positively buoyant. The should be in place to capture
dispersion of the cloud is affected by wind flammable hydrogen cloud.
speed and direction and can be influenced
by atmospheric turbulence and nearby
structures.
Ignition Fires and explosions could occur due There shall be no ignition
to various ignition sources, including sources, such as from open
mechanical sparks from rapidly closing flames, electrical equipment,
valves, electrostatic discharges in or heating equipment in rooms
ungrounded particulate filters, sparks from containing hydrogen systems.
electrical equipment, welding and cutting
operations, catalyst particles, and lightning
strikes near the vent stack.
Vent and Vent and exhaust system accidents are Backflow of air can be prevented
exhaust attributed to inadequate ventilation and the with suitable vent stack designs,
system inadvertent entry of air into the vent. provision of makeup air (or
accident adequate supply of inert gas as
the situation demands), check
valves, or molecular seals.
The causes represented on the left side of the diagram include ship structure, fuel containment,
detection and control, and ignition source control. The consequences depicted on the right side of
the diagram encompass fire and explosion protection, communication, evacuation, and rescue. Safety
barriers are suggested based on the protective measures identified in Table 6.
Figure 27. Bow-tie diagram model for the safety design of a hydrogen-powered vessel.
Given the lack of specific IMO and flag state regulations for hydrogen-powered vessels, this study
proposes a safe design process outlined in Figure 28. The design process incorporates both the
regulatory established design method and an alternative risk-based design method. For ship stability
and load line, ship structural strength, and non-hydrogen mechanical and electrical installations, the
established regulations and rules can be followed. However, for hydrogen-related systems and safety
measures, the alternative risk-based methods should be employed.
The safety goals for a hydrogen-powered vessel are defined in existing regulations and rules,
but the specific means to achieve those goals should be determined through comprehensive
risk assessments that cover ship layout, gas detection and alarm systems, firefighting
systems, and emergency response plans.
It is recommended to seek an Approval in Principle (AIP) from classification societies before proceeding
with preliminary, contract, and detailed designs. Statutory and class documents will be developed for
approval, after which the construction phase can commence.
Requirements Requirements
» IGF Code » IMO regulations
» SOLAS II-1/55 » Flag state’s regulations
» Class rules and guidelines » Class rules
Construction
Additionally, the study proposes potential ship types suitable for hydrogen use and outlines safe design
processes. The key findings and recommendations of the study are summarised in this section.
9.1. FINDINGS
» Australia’s domestic maritime fleet is 2210 per kgH2, while for 350 bar Type IV tanks,
predominantly composed of small vessels, and the estimated 2022 constant cost range is
at present, hydrogen energy solutions are better AUD1192-1768 per kg of hydrogen. For PEMFC
suited for these smaller vessels. This aligns well systems with a power output of 100-250 kW, the
with the need for Australia’s domestic maritime projected 2022 constant cost range is between
sector to achieve net zero emissions by 2050. AUD3486 and 7499 per kW, depending on the
production scale. The estimated 2022 constant
» Existing hydrogen-powered vessels worldwide,
cost range for PEMFC stacks is between AUD504
predominantly small-sized vessels, serve as
and 812 per kW, depending on the production
valuable references for adopting hydrogen
scale. The 2022 constant cost of a lithium-ion
technology in Australian waters.
battery pack for maritime use is estimated to
» Hydrogen FC systems, well-established in the be AUD331/kWh. The estimated levelised cost
automotive sector, can be utilised on ships of hydrogen dispensed by refuelling stations in
considering the marine environment. However, Australia could range from AUD6.78-15.60/kg.
hydrogen ICEs for ships are still in the research The FC stack and battery are anticipated to be
stage. replaced several times throughout the ship’s
lifespan.
» Compressed hydrogen and cryogenic liquid
hydrogen storage methods are feasible in » The regulatory, normative, and standard
the short term. Metal hydrides offer safety framework for hydrogen-powered ships is
advantages and high storage efficiency, making steadily taking shape, with obstacles in this
them suitable for maritime applications in the regard gradually being overcome.
future. The potential of liquid chemical hydrogen
» Training programmes related to hydrogen-
carriers is limited due to the complexity and
powered vessels have not yet been built and
high energy consumption associated with the
conducted in Australia. It is imperative to
dehydrogenation process.
promptly initiate training programs for the
» Hydrogen bunkering operations have been operation and bunkering of hydrogen-powered
carried out around the world. The high-pressure ships.
refuelling technologies in the automotive
» In the initial stages, the implementation of
industry provide valuable references for vessel
feasible hydrogen-powered ships should
bunkering. Similar to LNG, cryogenic liquid
primarily target small-sized vessels operating
hydrogen bunkering can be conducted through
on fixed routes. This approach ensures the
shore-based station-to-ship, truck-to-ship, or
practicality of fuel bunkering and the availability
ship-to-ship modes. For small-sized vessels,
of hydrogen power systems.
the portable tank swap mode using ISO tank
containers can be a convenient option for both » The design process of a hydrogen-powered
compressed and liquid hydrogen. vessel incorporates both the regulatory
established design method and the alternative
» The CAPEX and OPEX of a hydrogen FC-powered
risk-based design methods, considering the
vessel can be evaluated using available data.
safety risks associated with hydrogen and
The estimated 2022 constant cost range for 700
the current insufficiency of regulations and
bar Type IV tanks for maritime use is AUD1490-
standards.
The
7 2009 Nemo H2 Passenger ship (S Chakraborty, 2013)
Netherlands
Passenger ship
9 2010 MF Vågen Norway (Stensvold, 2010)
(Ferry)
13 2016 Gold Green HYGEN South Korea Passenger ship (Choi et al., 2016)
Passenger ship
14 2016 Cheetah The UK (Cheetah Marine, 2016)
(Yacht)
Passenger ship
15 2016 Race For Water Switzerland (Race For Water, 2016)
(Sailing boat)
(The Maritime
17 2017 Hydroville Belgium Passenger ship
Executive, 2017)
The
21 2019 MV Emeli Bulk (MARIKO GmbH, 2019)
Netherlands
Passenger ship
28 2021 Yanmar Japan (Vella, 2021)
(Fishing cruiser)
Passenger ship
32 2022 Hydrocat 48 The UK (Offshore crew (CMB.TECH, 2022)
transfer vessel)
Passenger ship
33 2022 Viking Neptune Norway (FincaNTIERI, 2022b)
(Cruise)
Passenger ship
34 2022 Chase Zero New Zealand (Baird Maritime, 2022)
(Race boat)
Passenger ship
35 2022 Hydrogenia South Korea (Danfoss, 2022)
(Yacht)
36 2023 San Xia Qing Zhou 1 China Passenger ship (Guan et al., 2023)
The
39 2023 Antonie Inland cargo barge (NPRC, 2023)
Netherlands
EXPECTED
NO. DELIVERY COUNTRY SHIP TYPE AMOUNT PROPONENTS REF.
YEAR
(The Maritime
5 2024 Norway Ferry (Ro-Ro) 2 Topeka
Executive, 2021)
(FuelcellsWorks,
6 2024 France Dredger 1 The ports of Occitania
2022)
Cochin Shipyard
Limited (CSL), KPTI
7 2024 India Passenger ship 1 Technologies, and Indian (Bahtić, 2023b)
Registry of Shipping
(IRS)
H2Ships, Port of
Amsterdam, TU Delft
The (Davemart,
8 2024 Passenger ship 1 Fuel, MARIN, Wijk Yacht
Netherlands 2023)
Vision, Lloyd’s Register,
and Baumuller
Hydrogen Innovation
– Future Innovation &
9 2024 The UK Test vessel 1 Vessel Evaluation and (h2-view, 2023)
Demonstration (HI-
FIVED) consortium
Ferry (ROPAX,
Torghatten Nord,
11 2025 Norway 599 passengers 2 (Howard, 2023)
PowerCell, SEAM
and 120 cars)
Ferry (high-
Teco, Umoe Mandal,
12 2025 Norway speed 35 knots, 1 (Hampel, 2022)
Blom Maritime
300 passengers)
Containership (Chambers,
The
13 2025 (500TEU, 2+2 Samskip, Ocean Infinity 2023; Zasiadko,
Netherlands
Rotterdam-Oslo) 2022)
Offshore
commissioning
The (Durakovic,
14 2025 service 2 Windcat Offshore
Netherlands 2022)
operation
vessels (CSOVs)
multi-purpose (TransGlory,
15 2025 France 1 Energy Observer
cargo ship 2022)
Cargo ship
(20TEU, high- Boundary Layer (Chambers,
17 2025 The US 1
speed 40 knots, Technologies 2022)
hydrofoil)
Research vessel
Bangor University, OS
19 2025 The UK (Prince Madog, 1 (BBC, 2023)
Energy
retrofit)
Northern Xplorer, AS
Norwegian Hydrogen AS,
(Hydrogen
20 2025/2026 Norway Cruise 1 HYON AS, Multi Maritime
Central, 2023)
AS, Hexagon Purus
Maritime AS.
2026/2027/
21 Italy Cruise 4 FINCANTIERI, Viking Line (Prevljak, 2022)
2028
Ferry
DFDS, Ørsted, ABB, (Kobie, 2021;
22 2027 Denmark (Copenhagen- 1
Ballard Morgan, 2020)
Oslo)
(FINCANTIERI,
23 2027/2028 Italy Cruise 2 FINCANTIERI, MSC
2022a)
(at least
25% of The California Air
24 2045 The US / ships in (Mandra, 2022)
California Resources Board
waters)
Ferry (200
25 Unknown Australia 1 SeaLink Gladstone (CSIRO, 2022)
passengers)
Norwegian Electrical
(Radowitz,
27 Unknown Norway Cruise 1 Systems (NES), Havyard
2020)
Design, Havila
The University of
California San Diego’s
29 Unknown The US Research ship 1 (Bahtić, 2023a)
Scripps Institution of
Oceanography
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