Conforms to UN GHS (Rev.

7) (2017)

SAFETY DATA SHEET

Barrier 80 Comp A
Section 1. Identification
Product name : Barrier 80 Comp A
Product code : 7680
Product description : Paint.
Product type : Liquid.
Other means of : Not available.
identification

Relevant identified uses of the substance or mixture and uses advised against
Use in coatings - Industrial use
Use in coatings - Professional use
Supplier's details : Jotun India Pvt. Ltd.
Fulcrum, A wing – 601(II) / 602,
Next to Hyatt Regency,
Sahar Road, Andheri – East, Mumbai – 99
India

Manufacturing site address:

Jotun India Pvt. Ltd.

Plot No. D-280, Ranjangaon MIDC,
Village - Karegaon, Taluka - Shirur,
Dist- Pune, PIN: 412220
India

[email protected]

Emergency telephone : Jotun India Pvt Ltd +91 2138 671300

number
7461;7680 1,2 7680
^(ValidationDate) 1

Section 2. Hazards identification

Classification of the : FLAMMABLE LIQUIDS - Category 3
substance or mixture SKIN CORROSION/IRRITATION - Category 2
SERIOUS EYE DAMAGE/EYE IRRITATION - Category 2A
SKIN SENSITISATION - Category 1
SHORT-TERM (ACUTE) AQUATIC HAZARD - Category 1
LONG-TERM (CHRONIC) AQUATIC HAZARD - Category 1

GHS label elements

Hazard pictograms :

Signal word : Warning.

Hazard statements : H226 - Flammable liquid and vapour.
H315 - Causes skin irritation.
H317 - May cause an allergic skin reaction.
H319 - Causes serious eye irritation.
H410 - Very toxic to aquatic life with long lasting effects.

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Section 2. Hazards identification

Precautionary statements
Prevention : P280 - Wear protective gloves. Wear eye or face protection.
P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition
sources. No smoking.
P273 - Avoid release to the environment.
P261 - Avoid breathing vapour.
Response : P391 - Collect spillage.
P362 + P364 - Take off contaminated clothing and wash it before reuse.
P302 + P352 - IF ON SKIN: Wash with plenty of water.
P333 + P313 - If skin irritation or rash occurs: Get medical advice or attention.
P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing.
P337 + P313 - If eye irritation persists: Get medical advice or attention.
Storage : Not applicable.
Disposal : P501 - Dispose of contents and container in accordance with all local, regional,
national and international regulations.

Other hazards which do not : None known.

result in classification

Section 3. Composition/information on ingredients

Substance/mixture : Mixture
Other means of : Not available.
identification

CAS number/other identifiers

CAS number : Not applicable.
EC number : Mixture.
Product code : 7680
Ingredient name % CAS number
zinc ≥50 - ≤75 7440-66-6
epoxy resin (MW 700-1200) ≤10 25036-25-3
xylene ≤10 1330-20-7
1-methoxy-2-propanol ≤3 107-98-2
ethylbenzene ≤3 100-41-4
zinc oxide ≤3 1314-13-2
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require
reporting in this section.
Occupational exposure limits, if available, are listed in Section 8.

Section 4. First aid measures

Description of necessary first aid measures
Eye contact : Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10
minutes. Get medical attention.
Inhalation : Remove victim to fresh air and keep at rest in a position comfortable for breathing.
If not breathing, if breathing is irregular or if respiratory arrest occurs, provide
artificial respiration or oxygen by trained personnel. It may be dangerous to the
person providing aid to give mouth-to-mouth resuscitation. Get medical attention if
adverse health effects persist or are severe. If unconscious, place in recovery
position and get medical attention immediately. Maintain an open airway. Loosen
tight clothing such as a collar, tie, belt or waistband.

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Section 4. First aid measures

Skin contact : Wash with plenty of soap and water. Remove contaminated clothing and shoes.
Wash contaminated clothing thoroughly with water before removing it, or wear
gloves. Continue to rinse for at least 10 minutes. Get medical attention. In the
event of any complaints or symptoms, avoid further exposure. Wash clothing before
reuse. Clean shoes thoroughly before reuse.
Ingestion : Wash out mouth with water. Remove dentures if any. If material has been
swallowed and the exposed person is conscious, give small quantities of water to
drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not
induce vomiting unless directed to do so by medical personnel. If vomiting occurs,
the head should be kept low so that vomit does not enter the lungs. Get medical
attention if adverse health effects persist or are severe. Never give anything by
mouth to an unconscious person. If unconscious, place in recovery position and get
medical attention immediately. Maintain an open airway. Loosen tight clothing such
as a collar, tie, belt or waistband.

Most important symptoms/effects, acute and delayed

Potential acute health effects
Eye contact : Causes serious eye irritation.
Inhalation : No known significant effects or critical hazards.
Skin contact : Causes skin irritation. May cause an allergic skin reaction.
Ingestion : No known significant effects or critical hazards.
Over-exposure signs/symptoms
Eye contact : Adverse symptoms may include the following:
pain or irritation
watering
redness
Inhalation : No specific data.
Skin contact : Adverse symptoms may include the following:
irritation
redness
Ingestion : No specific data.

Indication of immediate medical attention and special treatment needed, if necessary

Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if large
quantities have been ingested or inhaled.
Specific treatments : No specific treatment.
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. It
may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.
Wash contaminated clothing thoroughly with water before removing it, or wear
gloves.

See toxicological information (Section 11)

Section 5. Firefighting measures

Extinguishing media
Suitable extinguishing : Use dry chemical, CO₂, water spray (fog) or foam.
media
Unsuitable extinguishing : Do not use water jet.
media

Specific hazards arising : Flammable liquid and vapour. Runoff to sewer may create fire or explosion hazard.
from the chemical In a fire or if heated, a pressure increase will occur and the container may burst, with
the risk of a subsequent explosion. This material is very toxic to aquatic life with
long lasting effects. Fire water contaminated with this material must be contained
and prevented from being discharged to any waterway, sewer or drain.

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Section 5. Firefighting measures

Hazardous thermal : Decomposition products may include the following materials:
decomposition products carbon dioxide
carbon monoxide
halogenated compounds
metal oxide/oxides

Special protective actions : Promptly isolate the scene by removing all persons from the vicinity of the incident if
for fire-fighters there is a fire. No action shall be taken involving any personal risk or without
suitable training. Move containers from fire area if this can be done without risk.
Use water spray to keep fire-exposed containers cool.
Special protective : Fire-fighters should wear appropriate protective equipment and self-contained
equipment for fire-fighters breathing apparatus (SCBA) with a full face-piece operated in positive pressure
mode.

Section 6. Accidental release measures

Personal precautions, protective equipment and emergency procedures
For non-emergency : No action shall be taken involving any personal risk or without suitable training.
personnel Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilt material. Shut off all ignition sources.
No flares, smoking or flames in hazard area. Avoid breathing vapour or mist.
Provide adequate ventilation. Wear appropriate respirator when ventilation is
inadequate. Put on appropriate personal protective equipment.
For emergency responders : If specialised clothing is required to deal with the spillage, take note of any
information in Section 8 on suitable and unsuitable materials. See also the
information in "For non-emergency personnel".

Environmental precautions : Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air). Water polluting material. May be harmful
to the environment if released in large quantities. Collect spillage.

Methods and material for containment and cleaning up

Small spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Dilute with water and mop up if water-soluble.
Alternatively, or if water-insoluble, absorb with an inert dry material and place in an
appropriate waste disposal container. Dispose of via a licensed waste disposal
contractor.
Large spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Approach the release from upwind. Prevent entry into
sewers, water courses, basements or confined areas. Wash spillages into an
effluent treatment plant or proceed as follows. Contain and collect spillage with non-
combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth
and place in container for disposal according to local regulations (see Section 13).
Dispose of via a licensed waste disposal contractor. Contaminated absorbent
material may pose the same hazard as the spilt product. Note: see Section 1 for
emergency contact information and Section 13 for waste disposal.

Section 7. Handling and storage

Precautions for safe handling
Protective measures : Put on appropriate personal protective equipment (see Section 8). Persons with a
history of skin sensitization problems should not be employed in any process in
which this product is used. Do not get in eyes or on skin or clothing. Do not ingest.
Avoid breathing vapour or mist. Avoid release to the environment. Use only with
adequate ventilation. Wear appropriate respirator when ventilation is inadequate.
Do not enter storage areas and confined spaces unless adequately ventilated. Keep
in the original container or an approved alternative made from a compatible material,
kept tightly closed when not in use. Store and use away from heat, sparks, open
flame or any other ignition source. Use explosion-proof electrical (ventilating,
lighting and material handling) equipment. Use only non-sparking tools. Take
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Barrier 80 Comp A

Section 7. Handling and storage

precautionary measures against electrostatic discharges. Empty containers retain
product residue and can be hazardous. Do not reuse container.
Advice on general : Eating, drinking and smoking should be prohibited in areas where this material is
occupational hygiene handled, stored and processed. Workers should wash hands and face before
eating, drinking and smoking. Remove contaminated clothing and protective
equipment before entering eating areas. See also Section 8 for additional
information on hygiene measures.

Conditions for safe storage, : Store in accordance with local regulations. Store in a segregated and approved
including any area. Store in original container protected from direct sunlight in a dry, cool and well-
incompatibilities ventilated area, away from incompatible materials (see Section 10) and food and
drink. Eliminate all ignition sources. Separate from oxidising materials. Keep
container tightly closed and sealed until ready for use. Containers that have been
opened must be carefully resealed and kept upright to prevent leakage. Do not
store in unlabelled containers. Use appropriate containment to avoid environmental
contamination. See Section 10 for incompatible materials before handling or use.

Section 8. Exposure controls/personal protection

Control parameters
Occupational exposure limits
None.

Appropriate engineering : Use only with adequate ventilation. Use process enclosures, local exhaust
controls ventilation or other engineering controls to keep worker exposure to airborne
contaminants below any recommended or statutory limits. The engineering controls
also need to keep gas, vapour or dust concentrations below any lower explosive
limits. Use explosion-proof ventilation equipment.
Environmental exposure : Emissions from ventilation or work process equipment should be checked to ensure
controls they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process
equipment will be necessary to reduce emissions to acceptable levels.

Individual protection measures

Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Contaminated work clothing should not be allowed out of the workplace. Wash
contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Eye/face protection : Safety eyewear complying to ISO 16321-1:2022 should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn,
unless the assessment indicates a higher degree of protection: chemical splash
goggles.
Skin protection
Hand protection : There is no one glove material or combination of materials that will give unlimited
resistance to any individual or combination of chemicals.
The breakthrough time must be greater than the end use time of the product.
The instructions and information provided by the glove manufacturer on use,
storage, maintenance and replacement must be followed.
Gloves should be replaced regularly and if there is any sign of damage to the glove
material.
Always ensure that gloves are free from defects and that they are stored and used
correctly.
The performance or effectiveness of the glove may be reduced by physical/chemical
damage and poor maintenance.
Barrier creams may help to protect the exposed areas of the skin but should not be
applied once exposure has occurred.

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Section 8. Exposure controls/personal protection

Wear suitable gloves tested to ISO 374-1:2016.
Not recommended, gloves(breakthrough time) < 1 hour: neoprene (> 0.35 mm),
butyl rubber (> 0.4 mm)
May be used, gloves(breakthrough time) 4 - 8 hours: PVC (> 0.5 mm)
Recommended, gloves(breakthrough time) > 8 hours: nitrile rubber (> 0.4 mm), 4H/
Silver Shield® (> 0.07 mm), Teflon (> 0.35 mm), polyvinyl alcohol (PVA) (> 0.3 mm)

Body protection : Personal protective equipment for the body should be selected based on the task
being performed and the risks involved and should be approved by a specialist
before handling this product. When there is a risk of ignition from static electricity,
wear anti-static protective clothing. For the greatest protection from static
discharges, clothing should include anti-static overalls, boots and gloves.
Other skin protection : Appropriate footwear and any additional skin protection measures should be
selected based on the task being performed and the risks involved and should be
approved by a specialist before handling this product.
Respiratory protection : If workers are exposed to concentrations above the exposure limit, they must use a
respirator according to EN 140. Use respiratory mask with charcoal and dust filter
when spraying this product, according to EN 14387(as filter combination A2-P2). In
confined spaces, use compressed-air or fresh-air respiratory equipment. When use
of roller or brush, consider use of charcoalfilter.

Section 9. Physical and chemical properties

Appearance
Physical state : Liquid.
Colour : Grey
Odour : Characteristic.
Odour threshold : Not applicable.
pH : Not applicable.
Melting point : Not applicable.
Boiling point : Lowest known value: 120.17°C (248.3°F) (1-methoxy-2-propanol). Weighted
average: 132.36°C (270.2°F)
Flash point : Closed cup: 27°C (80.6°F)
Evaporation rate : Highest known value: 0.84 (ethylbenzene) Weighted average: 0.79compared with
butyl acetate
Flammability (solid, gas) : Not applicable.
Lower and upper explosive : 0.8 - 13.74%
(flammable) limits
Vapour pressure : Highest known value: 1.2 kPa (9.3 mm Hg) (at 20°C) (ethylbenzene). Weighted
average: 1 kPa (7.5 mm Hg) (at 20°C)
Vapour density : Highest known value: 3.7 (Air = 1) (xylene). Weighted average: 3.56 (Air = 1)
Density : 3.025 g/cm³ @ 20 °C
Solubility : Insoluble in the following materials: cold water and hot water.
Partition coefficient: n- : Not available.
octanol/water
Auto-ignition temperature : Lowest known value: 270°C (518°F) (1-methoxy-2-propanol).
Decomposition temperature : Not available.
Viscosity : Kinematic (40°C): >20.5 mm2/s (>20.5 cSt)

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Section 10. Stability and reactivity

Reactivity : No specific test data related to reactivity available for this product or its ingredients.
Chemical stability : The product is stable.
Possibility of hazardous : Under normal conditions of storage and use, hazardous reactions will not occur.
reactions
Conditions to avoid : Avoid all possible sources of ignition (spark or flame). Do not pressurise, cut, weld,
braze, solder, drill, grind or expose containers to heat or sources of ignition.
Incompatible materials : Reactive or incompatible with the following materials:
oxidising materials
Hazardous decomposition : Under normal conditions of storage and use, hazardous decomposition products
products should not be produced.

Section 11. Toxicological information

Information on toxicological effects
Acute toxicity
Product/ingredient name Result Species Dose Exposure
xylene LC50 Inhalation Vapour Rat 20 mg/l 4 hours
LD50 Oral Rat 4300 mg/kg -
TDLo Dermal Rabbit 4300 mg/kg -
1-methoxy-2-propanol LD50 Dermal Rabbit 13 g/kg -
LD50 Oral Rat 6600 mg/kg -
ethylbenzene LC50 Inhalation Vapour Rat - Male 17.8 mg/l 4 hours
LD50 Dermal Rabbit >5000 mg/kg -
LD50 Oral Rat 3500 mg/kg -
Irritation/Corrosion
Product/ingredient name Result Species Score Exposure Observation
zinc Skin - Mild irritant Human - 72 hours 300 -
Micrograms
Intermittent
epoxy resin (MW 700-1200) Eyes - Mild irritant Mammal - - - -
species
unspecified
Skin - Mild irritant Mammal - - - -
species
unspecified
xylene Eyes - Mild irritant Rabbit - 87 milligrams -
Skin - Mild irritant Rat - 8 hours 60 -
microliters
1-methoxy-2-propanol Eyes - Mild irritant Rabbit - 24 hours 500 -
mg
Skin - Mild irritant Rabbit - 500 mg -
zinc oxide Eyes - Mild irritant Rabbit - 24 hours 500 -
mg
Skin - Mild irritant Rabbit - 24 hours 500 -
mg
Sensitisation
Product/ingredient name Route of Species Result
exposure
epoxy resin (MW 700-1200) skin Mammal - species Sensitising
unspecified
Mutagenicity
Not available.
Carcinogenicity
Not available.

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Section 11. Toxicological information

Reproductive toxicity
Not available.
Teratogenicity
Not available.
Specific target organ toxicity (single exposure)
Name Category Route of Target organs
exposure
xylene Category 3 - Respiratory tract
irritation
1-methoxy-2-propanol Category 3 - Narcotic effects
Specific target organ toxicity (repeated exposure)
Name Category Route of Target organs
exposure
ethylbenzene Category 2 - hearing organs
Aspiration hazard
Name Result
xylene ASPIRATION HAZARD - Category 1
ethylbenzene ASPIRATION HAZARD - Category 1

Information on likely routes : Not available.

of exposure
Potential acute health effects
Eye contact : Causes serious eye irritation.
Inhalation : No known significant effects or critical hazards.
Skin contact : Causes skin irritation. May cause an allergic skin reaction.
Ingestion : No known significant effects or critical hazards.

Symptoms related to the physical, chemical and toxicological characteristics

Eye contact : Adverse symptoms may include the following:
pain or irritation
watering
redness
Inhalation : No specific data.
Skin contact : Adverse symptoms may include the following:
irritation
redness
Ingestion : No specific data.

Delayed and immediate effects as well as chronic effects from short and long-term exposure
Short term exposure
Potential immediate : Not available.
effects
Potential delayed effects : Not available.
Long term exposure
Potential immediate : Not available.
effects
Potential delayed effects : Not available.
Potential chronic health effects
Not available.

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Section 11. Toxicological information

General : Once sensitized, a severe allergic reaction may occur when subsequently exposed
to very low levels.
Carcinogenicity : No known significant effects or critical hazards.
Mutagenicity : No known significant effects or critical hazards.
Teratogenicity : No known significant effects or critical hazards.
Developmental effects : No known significant effects or critical hazards.
Fertility effects : No known significant effects or critical hazards.

Numerical measures of toxicity

Acute toxicity estimates
Route ATE value
Dermal 15986.19 mg/kg
Inhalation (vapours) 211.46 mg/l

Section 12. Ecological information

Toxicity
Product/ingredient name Result Species Exposure
zinc Acute LC50 330 μg/l Fresh water Daphnia - Daphnia magna 48 hours
Acute LC50 0.78 mg/l Fresh water Fish 96 hours
xylene Acute LC50 8500 μg/l Marine water Crustaceans - Palaemonetes 48 hours
pugio
Acute LC50 13400 μg/l Fresh water Fish - Pimephales promelas 96 hours
ethylbenzene Acute EC50 7700 μg/l Marine water Algae - Skeletonema costatum 96 hours
Acute EC50 2.93 mg/l Daphnia 48 hours
Acute LC50 4.2 mg/l Fish 96 hours
zinc oxide Acute LC50 1.1 ppm Fresh water Fish - Oncorhynchus mykiss 96 hours
Chronic NOEC 0.02 mg/l Fresh water Algae - Pseudokirchneriella 72 hours
subcapitata - Exponential
growth phase

Persistence and degradability

Product/ingredient name Aquatic half-life Photolysis Biodegradability
zinc - - Not readily
xylene - - Readily
ethylbenzene - - Readily
zinc oxide - - Not readily

Bioaccumulative potential
Product/ingredient name LogPow BCF Potential
xylene 3.12 8.1 to 25.9 low
1-methoxy-2-propanol <1 - low
ethylbenzene 3.6 - low
zinc oxide - 28960 high

Mobility in soil
Soil/water partition : Not available.
coefficient (KOC)

Other adverse effects : No known significant effects or critical hazards.

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Section 13. Disposal considerations

Disposal methods : The generation of waste should be avoided or minimised wherever possible.
Disposal of this product, solutions and any by-products should at all times comply
with the requirements of environmental protection and waste disposal legislation and
any regional local authority requirements. Dispose of surplus and non-recyclable
products via a licensed waste disposal contractor. Waste should not be disposed of
untreated to the sewer unless fully compliant with the requirements of all authorities
with jurisdiction. Waste packaging should be recycled. Incineration or landfill
should only be considered when recycling is not feasible. This material and its
container must be disposed of in a safe way. Care should be taken when handling
emptied containers that have not been cleaned or rinsed out. Empty containers or
liners may retain some product residues. Vapour from product residues may create
a highly flammable or explosive atmosphere inside the container. Do not cut, weld
or grind used containers unless they have been cleaned thoroughly internally. Avoid
dispersal of spilt material and runoff and contact with soil, waterways, drains and
sewers.

Section 14. Transport information

ADR/RID IMDG IATA
UN number UN1263 UN1263 UN1263

UN proper Paint Paint. Marine pollutant (zinc) Paint

shipping name
Transport hazard 3 3 3
class(es)

Packing group III III III

Environmental Yes. Yes. Yes. The environmentally
hazards hazardous substance mark is
not required.
Additional - The marine pollutant mark is The environmentally
information not required when transported hazardous substance mark
in sizes of ≤5 L or ≤5 kg. may appear if required by
Emergency schedules F-E, other transportation
S-E regulations.

Additional information
ADR/RID : The environmentally hazardous substance mark is not required when transported in
sizes of ≤5 L or ≤5 kg.
Hazard identification number 30
Tunnel code (D/E)
IMDG : The marine pollutant mark is not required when transported in sizes of ≤5 L or ≤5 kg.
Emergency schedules F-E, S-E
IATA : The environmentally hazardous substance mark may appear if required by other
transportation regulations.
Special precautions for user : Transport within user’s premises: always transport in closed containers that are
upright and secure. Ensure that persons transporting the product know what to do in
the event of an accident or spillage.

Transport in bulk according : Not available.

to IMO instruments

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Section 15. Regulatory information

Safety, health and : No known specific national and/or regional regulations applicable to this product
environmental regulations (including its ingredients).
specific for the product
International regulations
Chemical Weapon Convention List Schedules I, II & III Chemicals
Not listed.
Montreal Protocol
Not listed.

Stockholm Convention on Persistent Organic Pollutants

Not listed.

UNECE Aarhus Protocol on POPs and Heavy Metals

Not listed.

Section 16. Other information

History
Date of printing : 08.05.2023
Date of issue/Date of : 08.05.2023
revision
Date of previous issue : 08.05.2023
Version : 2.03
Key to abbreviations : ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships,
1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution)
UN = United Nations
References : Not available.
Indicates information that has changed from previously issued version.
Notice to reader
The information in this document is given to the best of Jotun's knowledge, based on laboratory testing and
practical experience. Jotun's products are considered as semi-finished goods and as such, products are
often used under conditions beyond Jotun's control. Jotun cannot guarantee anything but the quality of the
product itself. Minor product variations may be implemented in order to comply with local requirements.
Jotun reserves the right to change the given data without further notice.

Users should always consult Jotun for specific guidance on the general suitability of this product for their
needs and specific application practices.

If there is any inconsistency between different language issues of this document, the English (United
Kingdom) version will prevail.

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