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    COOH

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    tanvip16
    The document contains multiple choice questions about organic chemistry reactions and compounds. It tests knowledge of reaction mechanisms, products of substitutions, additions, eliminations, hydrolysis, and other common organic reactions. The questions cover topics like relative rates of nucleophilic substitution, order of acid derivative hydrolysis, carbonyl compound reactions, amide and ester synthesis, reductions, and identification of structures from reaction steps.

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    © All Rights Reserved
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    COOH

    Uploaded by

    tanvip16
    9 views4 pages
    The document contains multiple choice questions about organic chemistry reactions and compounds. It tests knowledge of reaction mechanisms, products of substitutions, additions, eliminations, hydrolysis, and other common organic reactions. The questions cover topics like relative rates of nucleophilic substitution, order of acid derivative hydrolysis, carbonyl compound reactions, amide and ester synthesis, reductions, and identification of structures from reaction steps.

    Original Title

    -COOH

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    The document contains multiple choice questions about organic chemistry reactions and compounds. It tests knowledge of reaction mechanisms, products of substitutions, additions, eliminations, hydrolysis, and other common organic reactions. The questions cover topics like relative rates of nucleophilic substitution, order of acid derivative hydrolysis, carbonyl compound reactions, amide and ester synthesis, reductions, and identification of structures from reaction steps.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    9 views4 pages

    COOH

    Uploaded by

    tanvip16
    The document contains multiple choice questions about organic chemistry reactions and compounds. It tests knowledge of reaction mechanisms, products of substitutions, additions, eliminations, hydrolysis, and other common organic reactions. The questions cover topics like relative rates of nucleophilic substitution, order of acid derivative hydrolysis, carbonyl compound reactions, amide and ester synthesis, reductions, and identification of structures from reaction steps.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    of 4

    Single Answer Type :

    O O
    - -
    1. Rate of the reaction R - C - Z + Nu R - C - Nu + Z is fastest when Z is
    (A) OC2H5 (D) NH2 (C) Cl (D) NH2

    2. The correct order of ease of hydrolysis of acid derivatives is


    (A) ester>amide>acid chloride (B) amide>ester>acid chloride
    (C) amide>acid chloride>ester (D) acid chloride>ester>amide

    3. The carbon atom of COCl group in CH3COCl use the following type of orbitals for forming
     bonds
    (A) sp3 (B) sp2 (C) sp (D) p

    4. The product X of the following reaction is CH3COCl  H2 


    Pd
    X
    (A) CH3CHO (B) CH3CH2OH (C) CH3Cl (D) CH3CH2Cl

    5. Sodium ethoxide has reacted with ethanoyl chloride. The compound that is produced in
    the above reaction is
    (A) 2-butanone (B) ethyl chloride (C) ethyl ethanoate (D) diethl ether

    anhydrous AlCl3 H2O


    6. In C6H6  COCl2   x   Y, the X and Y will be respectively
    (A) C6H5COOH and C6H5COCl (B) C6H5COCl and C6H5COOH
    (C) C6H5OH and C6H5COCl (D) C6H5COCl and C6H5CHO

    7. On strong heating ammonium acetate gives


    (A) acetamide (B) formamide
    (C) ammonium syanate (D) urea

    8. Acetamide is treated with the following reagents. Which one of these would give methyl
    amine
    (A) PCl5 (B) soda lime (C) NaOH  Br2 (D) hot cone. H2SO4

    9. An organic compound A upon reacting with NH3 gives B. On heating, B gives C. C in


    presence of KOH reacts with Br2 to give CH3CH2NH2. A is
    (A) CH3COOH (B) CH3CH2CH2COOH
    (C) CH3  CH  CH3   COOH (D) CH3CH2COOH

    10. In a set of reactions propionic acid yielded a compound D.


    CH3CH2COOH  SOCl2
     B 
    NH3
     C 
    KOH
     D The structure of D would be
    Br 2
    (A) CH3CH2NH2 (B) CH3CH2CH2NH2 (C) CH3CH2CONH2 (D) CH3CH2NHCH3

    11. Which of the following sets of ractions would not yield benzamide

    (A) C6H5COOH  NH3  (B) C6H5COOH  NH3  Pr oduct 

    (C) C6H5COONH4  (D) C6H5COCl  NH3 

    12. Acid hydrolysis of which of the following compounds yields two different organic
    compounds
    (A) CH3COOH (B) CH3CONH2 (C) CH3COOC2H5 (D)  CH3CO2 O

    1
    13. Alkaline hydrolysis of ester is called
    (A) neutralization (B) esterification (C) polymerization (D) saponification

    14. What will be formed on reduction of CH3COOC2H5 with LiAlH4


    (A) 2 molecules of C2H5OH (B) 3 molecules of C2H5OH
    (C) 2 molecules of CH3OH (D) 3 molecules of CH3OH

    15. A keto lactone is reduced by different reagents to give A and B, A and B are
    O

    LiAlH4 O NaBH4
    [B] [A]
    CH3OH

    O
    O OH O
    (A) O
    (B) OH
    O O OH
    and and

    O OH OH OH
    O OH OH

    (C) O O (D) O OH
    OH
    and and

    OH OH OH OH

    16. Give the structure of the compound P formed in the following reaction.
    O
    OCH3
    (i) CH3CH2MgI
    P
    O (ii) H3O+
    O
    OH
    CH3CH2 CH3
    (A) (B) CH3
    O O

    (C) CH3 (D)


    CH3CH2 O O CH3CH2 O O

    17. In the reaction


    O
    (1) NaOH/Br2
    CH3 C T The structure of the product T is:
    O
    HN2 (2) C
    Cl

    2
    O (B)
    (A) NH
    C O C CH3
    O C O

    (C)
    H3C NH (D) O
    C CH3 C O
    O NH C

    18. The following sequence of reactions give final product is


    CH2CONH2
    1.Br2 / NaOH

    COOCH3 2. heat
    O O

    O NH

    (A) O (B) O
    O

    NH

    (C) O (D) O

    19. Which of the following esters can not undergo self Claisen condensation
    (A) CH3CH2CH2COOC2H5 (B) C6H5COOC2H5
    (C) C3H5CH2COOC2H5 (D) C6H11CH2COOC2H5

    Multiple Type :

    20. The reagent (s) which can transform


    O

    C N
    NH2

    (A) P2O5 (B) SOCl2 (C) POCl3 (D) PCl5

    21. Which of the following will undergo acetylation?


    (A) CH3CH2NH2 (B) CH3CHO (C) CH3CH2CH2OH (D) CH3COCH3

    3
    22. Compound A is obtained by following reaction.
    (i) C2H5ONa
    CH3COOC2H5 [A]
    +
    (ii) H3O
    (iii) heat
    Which of the following statement (s) is (are) true about A?
    (A) It gives red colour with blue litmus solution.
    (B) It decomposes NaHCO3 solution and evolves CO2 gas.
    (C) It gives yellow ppt with NaOI
    (D) It reacts with 2,4-dinitropheny1-hydrazine

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