MSDS-Hydrazine 80%

Conforms to Regulation (EC) No.
1907/2006 (REACH), Annex II, as amended by Regulation (EU)

No. 453/2010 - Europe
SAFETY DATA SHEET

HYDRAZINE HYDRATE 80%
05528771
SECTION 1: Identification of the substance/mixture and of
the company/undertaking
1.1 Product identifier
Product name : HYDRAZINE HYDRATE 80%
Hazardous ingredients : Contains: Hydrazine
1.2 Relevant identified uses of the substance or mixture and uses advised against
Suitable uses : Chemical for synthesis
Reducing agent. (Corrosion inhibitor)
Identified uses Sector of Use Chemical Process Article Environmental
Product Category Category Release
Category Category
Hydrazine.Use as SU03 PC19 PROC01 ERC06a
intermediate in closed SU08 PC32 PROC03 ERC06c
systems. Use as SU09 PROC08b
monomer in closed SU10 PROC09
systems. (Industrial)
Hydrazine.Use as SU23 PC37 PROC01 ERC07
corrosion inhibitor in PROC08b
steam generating and PROC09
heating systems
(Industrial)
Hydrazine.Use as SU03 PC0 PROC01 ERC06b
reducing agent to SU08 PROC08b
remove nitrosyl kations SU09 PROC09
contained in sulphuric
acid (Industrial)
Hydrazine.Use as SU03 PC0 PROC01 ERC06b
stabilising reagent in SU08 PC0 PROC08b
aromatic amines to be SU09 PROC09
further used in synthesis
of dyestuffs (Industrial)
Hydrazine. Use as a SU09 PC21 PROC15 ERC06a
laboratory chemical. SU08 ERC06b
(Industrial) SU10
SU12
SU14
SU23
SU24
Hydrazine .Distribution, SU03 PROC01 ERC02
formulation and (re) PROC03
packing of substances PROC08b
and mixtures (Industrial) PROC09
Hydrazine .Use as SU03 PC0 PROC01 ERC04
reducing agent for metal- SU14 PROC03 ERC06b
based chemicals in PROC08b
closed industrial
systems under
controlled conditions
(Industrial)
1.3 Details of the supplier of the safety data sheet

Supplier : LANXESS Distribution GmbH
D-51369 Leverkusen
Telephone: +49 214 30 65109 Fax: +49 214 30 55787
E-mail: [email protected]
1.4 Emergency telephone : +49 214 30 99300 (Sicherheitszentrale CHEMPARK Leverkusen)
number
Date of issue : 2016-03-03 Page: 1/42

HYDRAZINE HYDRATE 80% 05528771 / 6.01
SECTION 2: Hazards identification

2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP/GHS]
Classification : Acute Tox. 3, H301
Acute Tox. 3, H311
Acute Tox. 2, H330
Skin Corr. 1B, H314
Skin Sens. 1, H317
Carc. 1B, H350
Aquatic Acute 1, H400
Aquatic Chronic 1, H410
Classification according to Directive 1999/45/EC [DPD]
Classification : Carc. Cat. 2; R45
T; R23/24/25
C; R34
R43
N; R50/53
Human health hazards : May cause cancer. Also toxic by inhalation, in contact with skin and
if swallowed. Causes burns. May cause sensitisation by skin
contact.
Environmental hazards : Very toxic to aquatic organisms, may cause long-term adverse
effects in the aquatic environment.
2.2 Label elements
Hazard pictograms :
Signal word : Danger

Contains: Hydrazine
Hazard statements : H330 - Fatal if inhaled.
H301 + H311 - Toxic if swallowed or in contact with skin.
H314 - Causes severe skin burns and eye damage.
H317 - May cause an allergic skin reaction.
H350 - May cause cancer.
H410 - Very toxic to aquatic life with long lasting effects.
Additional warning phrases : Not applicable.
Precautionary statements
Prevention : Obtain special instructions before use. Wear protective gloves/
clothing and eye/face protection. Avoid release to the environment.
Do not breathe vapour.
Response : IF INHALED: Remove person to fresh air and keep comfortable for
breathing. Immediately call a POISON CENTER or physician. IF
SWALLOWED: Immediately call a POISON CENTER or physician.
Do NOT induce vomiting. IF ON SKIN (or hair): Take off
immediately all contaminated clothing. Rinse skin with water or
shower. Immediately call a POISON CENTER or physician. IF IN
EYES: Immediately call a POISON CENTER or physician.
Storage : Store locked up.
Disposal : Dispose of contents and container in accordance with all local,
regional, national and international regulations.
2.3 Other hazards
Substance meets the : No.
criteria for PBT according
to Regulation (EC) No.
1907/2006, Annex XIII
2.3 Other hazards

Substance meets the : No.
criteria for vPvB according
to Regulation (EC) No.
1907/2006, Annex XIII
Other hazards which do : Causes digestive tract burns.
not result in classification
SECTION 3: Composition/information on ingredients

Product definition (REACH) : Mixture
hydrazine solution
contains 80 % hydrazine hydrate, corresponds to 51 % Hydrazine
(aqueous solution)
Classification
Product/ingredient Identifiers % 67/548/EEC Regulation (EC) Type
name No. 1272/2008
[CLP]
Hydrazine REACH #: 51 R10 Flam. Liq. 3, H226 [1]
01-2119492624-31 Carc. Cat. 2; R45 Acute Tox. 3, H301
EC: 206-114-9 T; R23/24/25 Acute Tox. 3, H311
CAS: 302-01-2 C; R34 Acute Tox. 2, H330
Index: 007-008-00-3 R43 Skin Corr. 1B, H314
N; R50/53 Skin Sens. 1A,
H317
Carc. 1B, H350
Aquatic Acute 1,
H400
Aquatic Chronic 1,
H410
See Section 16 for See Section 16
the full text of the for the full text of
R-phrases the H statements
declared above. declared above.
Occupational exposure limits, if available, are listed in Section 8.

Type
[1] Substance classified with a health or environmental hazard
[2] Substance with a workplace exposure limit
[3] Substance meets the criteria for PBT according to Regulation (EC) No. 1907/2006, Annex XIII
[4] Substance meets the criteria for vPvB according to Regulation (EC) No. 1907/2006, Annex XIII
[5] Substance of equivalent concern
SECTION 4: First aid measures

4.1 Description of first aid measures

Inhalation : Get medical attention immediately. Move exposed person to fresh

air. If it is suspected that fumes are still present, the rescuer should
wear an appropriate mask or self-contained breathing apparatus.
Keep person warm and at rest. If not breathing, if breathing is
irregular or if respiratory arrest occurs, provide artificial respiration or
oxygen by trained personnel. It may be dangerous to the person
providing aid to give mouth-to-mouth resuscitation. If unconscious,
place in recovery position and get medical attention immediately.
Maintain an open airway. Loosen tight clothing such as a collar, tie,
belt or waistband. In case of inhalation of decomposition products
in a fire, symptoms may be delayed. The exposed person may need
to be kept under medical surveillance for 48 hours.
Ingestion : Get medical attention immediately. Wash out mouth with water.
Move exposed person to fresh air. Keep person warm and at rest.
If material has been swallowed and the exposed person is
conscious, give small quantities of water to drink. Stop if the
exposed person feels sick as vomiting may be dangerous. Do not
induce vomiting unless directed to do so by medical personnel. If
vomiting occurs, the head should be kept low so that vomit does not
enter the lungs. Chemical burns must be treated promptly by a
physician. Never give anything by mouth to an unconscious person.
If unconscious, place in recovery position and get medical attention
immediately. Maintain an open airway. Loosen tight clothing such
as a collar, tie, belt or waistband.
Skin contact : Get medical attention immediately. Flush contaminated skin with
plenty of water. Remove contaminated clothing and shoes.
Continue to rinse for at least 10 minutes. Chemical burns must be
treated promptly by a physician. In the event of any complaints or
symptoms, avoid further exposure. Wash clothing before reuse.
Clean shoes thoroughly before reuse.
Eye contact : Get medical attention immediately. Immediately flush eyes with
plenty of water, occasionally lifting the upper and lower eyelids.
Check for and remove any contact lenses. Continue to rinse for at
least 10 minutes. Chemical burns must be treated promptly by a
physician.
4.2 Most important symptoms and effects, both acute and delayed
See Section 11 for more detailed information on health effects and symptoms.
4.3 Indication of any immediate medical attention and special treatment needed
Notes to physician : No special measures required.
See Section 11 for more detailed information on health effects and symptoms.
SECTION 5: Firefighting measures

5.1 Extinguishing media
Suitable extinguishing : Use dry chemical, CO₂, water spray (fog) or foam.
media
Unsuitable extinguishing : Do not use water jet.
media
5.2 Special hazards arising from the substance or mixture
Hazards from the : Combustible liquid. In a fire or if heated, a pressure increase will
substance or mixture occur and the container may burst, with the risk of a subsequent
explosion.
Hazardous combustion : Decomposition products may include the following materials:
products nitrogen oxides
5.3 Advice for firefighters

Special precautions for : Promptly isolate the scene by removing all persons from the vicinity
fire-fighters of the incident if there is a fire. No action shall be taken involving
any personal risk or without suitable training. Move containers from
fire area if this can be done without risk. Use water spray to keep
fire-exposed containers cool. This material is very toxic to aquatic
organisms. Fire water contaminated with this material must be
contained and prevented from being discharged to any waterway,
sewer or drain.
Special protective : Fire-fighters should wear appropriate protective equipment and self-
equipment for fire-fighters contained breathing apparatus (SCBA) with a full face-piece
operated in positive pressure mode.
SECTION 6: Accidental release measures

6.1 Personal precautions, : Avoid exposure - obtain special instructions before use. No action
protective equipment and shall be taken involving any personal risk or without suitable training.
emergency procedures Evacuate surrounding areas. Keep unnecessary and unprotected
personnel from entering. Do not touch or walk through spilt material.
Shut off all ignition sources. No flares, smoking or flames in hazard
area. Avoid breathing vapour or mist. Provide adequate ventilation.
Put on appropriate personal protective equipment (see Section 8).
6.2 Environmental : Avoid dispersal of spilt material and runoff and contact with soil,
precautions waterways, drains and sewers. Inform the relevant authorities if the
product has caused environmental pollution (sewers, waterways, soil
or air). Very toxic to aquatic organisms, may cause long-term
adverse effects in the aquatic environment.
6.3 Methods and material for containment and cleaning up
Small spill : Stop leak if without risk. Move containers from spill area. Dilute
with water and mop up if water-soluble or absorb with an inert dry
material and place in an appropriate waste disposal container. Use
spark-proof tools and explosion-proof equipment. Dispose of via a
licensed waste disposal contractor.
Large spill : Stop leak if without risk. Move containers from spill area. Prevent
entry into sewers, water courses, basements or confined areas.
Contain and collect spillage with non-combustible, absorbent
material e.g. sand, earth, vermiculite or diatomaceous earth and
place in container for disposal according to local regulations (see
Section 13). Use spark-proof tools and explosion-proof equipment.
Dispose of via a licensed waste disposal contractor. Note: see
Section 1 for emergency contact information and Section 13 for
waste disposal. Contaminated absorbent material may pose the
same hazard as the spilt product.
6.4 Reference to other : See Section 1 for emergency contact information.

sections See Section 8 for information on appropriate personal protective
equipment.
See Section 13 for additional waste treatment information.
SECTION 7: Handling and storage

The information in this section contains generic advice and guidance. The list of Identified Uses in
Section 1 should be consulted for any available use-specific information provided in the Exposure
Scenario(s).

7.1 Precautions for safe : Avoid exposure - obtain special instructions before use. Put on
handling appropriate personal protective equipment (see Section 8). Eating,
drinking and smoking should be prohibited in areas where this
material is handled, stored and processed. Workers should wash
hands and face before eating, drinking and smoking. Persons with a
history of skin sensitization problems should not be employed in any
process in which this product is used. Do not get in eyes or on skin
or clothing. Do not breathe vapour or mist. Do not ingest. Avoid
release to the environment. Use only with adequate ventilation. Wear
appropriate respirator when ventilation is inadequate. Do not enter
storage areas and confined spaces unless adequately ventilated.
Keep in the original container or an approved alternative made from
a compatible material, kept tightly closed when not in use. Store and
use away from heat, sparks, open flame or any other ignition source.
Use explosion-proof electrical (ventilating, lighting and material
handling) equipment. Use non-sparking tools. Take precautionary
measures against electrostatic discharges. To avoid fire or explosion,
dissipate static electricity during transfer by earthing and bonding
containers and equipment before transferring material. Keep away
from acids. Empty containers retain product residue and can be
hazardous.
7.2 Conditions for safe : Store in accordance with local regulations. Store in a segregated
storage, including any and approved area. Store in original container protected from direct
incompatibilities sunlight in a dry, cool and well-ventilated area, away from
incompatible materials (see Section 10) and food and drink. Store
locked up. Eliminate all ignition sources. Separate from acids.
Separate from oxidizing materials. Keep container tightly closed and
sealed until ready for use. Containers that have been opened must
be carefully resealed and kept upright to prevent leakage. Do not
store in unlabelled containers. Use appropriate containment to avoid
environmental contamination.
Seveso III Directive - Reporting thresholds (in tonnes)
Named substances
Name Notification and Safety report
MAPP threshold threshold
Hydrazine 0,5 2
Danger criteria
Category Notification and Safety report
MAPP threshold threshold
H2: Acute toxicity 2 any route of entry or Acute 50 200
toxicity 3 Inhalation route of entry
E1: Hazardous to the aquatic environment - Acute 1 100 200
or Chronic 1
C2: Toxic 50 200
C9i: Very toxic for the environment 100 200
7.3 Specific end use(s)
Recommendations : Not available.
Industrial sector specific : Not available.
solutions
Remarks : Transfer and handle product only in a closed system.

SECTION 8: Exposure controls/personal protection

Scenario(s).
8.1 Control parameters
Exposure limit values : Not available.
Derived effect levels

Ingredient name Type Exposure Value Population Effects Remarks
Hydrazine DNEL Short term 0,133 mg/ Workers Systemic -
Inhalation m³
DNEL Short term 0,133 mg/ Workers Local -
Inhalation m³
DNEL Long term Inhalation 0,013 mg/ Workers Systemic -
m³
DNEL Long term Inhalation 0,013 mg/ Workers Local -
m³
DNEL Long term Dermal 0,006 mg/ Workers Systemic -
kg bw/day
Conclusion/Summary : Not available.
Predicted No Effect Concentration (PNEC)

Ingredient name Compartment Value Method Detail Remarks
Detail
Hydrazine Sewage Treatment 0,055 mg/l Assessment Factors -
Plant
Marine 0,06 μg/l Assessment Factors -
Fresh water 0,6 μg/l Assessment Factors -
Recommended monitoring : If this product contains ingredients with exposure limits, personal,
procedures workplace atmosphere or biological monitoring may be required to
determine the effectiveness of the ventilation or other control
measures and/or the necessity to use respiratory protective
equipment. Reference should be made to monitoring standards,
such as the following: European Standard EN 689 (Workplace
atmospheres - Guidance for the assessment of exposure by
inhalation to chemical agents for comparison with limit values and
measurement strategy) European Standard EN 14042 (Workplace
atmospheres - Guide for the application and use of procedures for
the assessment of exposure to chemical and biological agents)
European Standard EN 482 (Workplace atmospheres - General
requirements for the performance of procedures for the
measurement of chemical agents) Reference to national guidance
documents for methods for the determination of hazardous
substances will also be required.
8.2 Exposure controls
Risk management measures
Occupational exposure controls
Technical measures : Use only with adequate ventilation. Use process enclosures, local
exhaust ventilation or other engineering controls to keep worker
exposure to airborne contaminants below any recommended or
statutory limits. The engineering controls also need to keep gas,
vapour or dust concentrations below any lower explosive limits. Use
explosion-proof ventilation equipment.
Personal protection measures

Respiratory protection : Use a properly fitted, air-purifying or air-fed respirator complying with
an approved standard if a risk assessment indicates this is
necessary. Respirator selection must be based on known or
anticipated exposure levels, the hazards of the product and the safe
working limits of the selected respirator.
Recommended: Vapour respirator, ammonia filter (Type K)
Hand protection : Chemical-resistant, impervious gloves complying with an approved
standard should be worn at all times when handling chemical
products if a risk assessment indicates this is necessary. After
contamination with product change the gloves immediately and
dispose of them according to relevant national and local regulations
Recommended: (< 1 hour) Polyvinyl chloride - PVC
Eye protection : Safety eyewear complying with an approved standard should be
used when a risk assessment indicates this is necessary to avoid
exposure to liquid splashes, mists, gases or dusts.
Recommended: Tightly fitting safety goggles.
Skin protection : Personal protective equipment for the body should be selected
based on the task being performed and the risks involved and
should be approved by a specialist before handling this product.
Recommended: Wear protective clothing.
Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical
products, before eating, smoking and using the lavatory and at the
end of the working period. Appropriate techniques should be used
to remove potentially contaminated clothing. Wash contaminated
clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Environmental exposure controls
Technical measures : Emissions from ventilation or work process equipment should be
checked to ensure they comply with the requirements of
environmental protection legislation. In some cases, fume
scrubbers, filters or engineering modifications to the process
equipment will be necessary to reduce emissions to acceptable
levels.
SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties
General information
Appearance
Physical state : Liquid.
Colour : Colourless.
Odour : Ammoniacal.
Important health, safety and environmental information
pH : >12 [Conc. (% w/w): 51%]
Boiling point : 117,2 °C (1013 hPa)
Melting point : -57°C (-70,6°F)
Flash point : Closed cup: 91°C (195,8°F) [DIN 51758]
Explosion limits : Lower: 4,8%
Upper: 100%
Vapour pressure : 13 hPa (20℃)
Density : 1,028 kg/L (20℃)
Solubility : Miscible in water.
Viscosity : Dynamic: 1,33 mPa·s
Ignition temperature : 310°C

Decomposition : Not available.

temperature
9.2 Other information
No additional information.
SECTION 10: Stability and reactivity

10.1 Reactivity : No specific test data related to reactivity available for this product or
its ingredients.
10.2 Chemical stability : The product is stable.
10.3 Possibility of : Under normal conditions of storage and use, hazardous reactions
hazardous reactions will not occur.
10.4 Conditions to avoid : Contact with strong oxidising agents may cause hazardous reactions.
Keep away from oxidising and acid substances and from heavy
metal compounds. Contact with cellulose or cotton textiles,
especially at elevated temperatures, may result in ignition.
10.5 Incompatible materials : Reactive or incompatible with the following materials:

acids
10.6 Hazardous : Under normal conditions of storage and use, hazardous
decomposition products decomposition products should not be produced.
SECTION 11: Toxicological information

11.1 Information on toxicological effects
Potential acute health effects
Inhalation : Fatal if inhaled. May give off gas, vapour or dust that is very
irritating or corrosive to the respiratory system.
Ingestion : Toxic if swallowed. Corrosive to the digestive tract. Causes burns.
Skin contact : Causes severe burns. Toxic in contact with skin. May cause an
allergic skin reaction.
Eye contact : Causes serious eye damage.
Acute toxicity
Product/ingredient Result Species Dose Exposure Test

name
Hydrazine LD50 Oral - Rat - Male 173 mg/kg - -
LD50 Oral - Rat - 108 to 141 - -
Female mg/kg
Hydrazine LC50 - Rat 759 mg/m³ 4 hours -
Inhalation
Vapour
Acute toxicity estimates
Route ATE value (Acute Toxicity Estimates)
Oral 212 mg/kg
Dermal 588,8 mg/kg
Inhalation (gases) 1373,8 ppm
Inhalation (vapours) 1,49 mg/l
Inhalation (dusts and mists) 0,9813 mg/l
Irritation/Corrosion
Product/ingredient Result Species Score Exposure Test Reversibility
name

HYDRAZINE Skin - Rabbit - 4 hours * Not

HYDRATE 80% Visible reversible
necrosis
Skin : Corrosive. * Test results for a product at higher concentration
Eyes : Risk of serious damage to eyes.
Sensitiser
Product/ingredient Route of Species Result Test description
name exposure
Hydrazine skin Human Sensitising -
Potential chronic health effects

Chronic toxicity
Product/ingredient name Result Species Dose Exposure
Hydrazine Sub-acute NOAEL Rat 1,92 mg/kg 28 days; 7
Oral per day days per week
Carcinogenicity
Conclusion/Summary : Hydrazine:In long−term animal tests and mutagenicity
investigations carried out with several hydrazid compounds
indications of a mutagenic/carcinogenic potential of this substance
group were noted.
Mutagenicity
Product/ingredient name Test Experiment Result
Hydrazine OECD 471 Bacterial Experiment: In vitro Positive
Reverse Mutation Test;
with metabolic activation
and without metabolic
activation
Subject: Bacteria
OECD 473 In vitro Experiment: In vitro Positive
Mammalian
Chromosomal
Aberration Test
Subject:
Mammalian-Animal
Cell: Somatic
OECD 476 In vitro Experiment: In vitro Positive
Mammalian Cell Gene
Mutation Test
Subject:
Mammalian-Animal
Cell: Somatic
Carcinogenicity : May cause cancer. Risk of cancer depends on duration and level of
exposure.
SECTION 12: Ecological information

12.1 Toxicity
Product/ingredient Test Result Species Exposure
name
Hydrazine OECD 209 Acute EC0 5,5 mg/l Bacteria 3 hours
Activated
Sludge,
Respiration
Inhibition Test
- Acute EC50 0,175 mg/l Daphnia - 48 hours
Daphnia pulex

Product/ingredient Test Result Species Exposure

name
OECD EU C. Acute IC50 0,017 mg/l Algae - 72 hours
3 Desmodesmus
subspicatus
- Acute LC50 0,61 mg/l Fish - 96 hours
Lebistes
reticulatus
OECD 211 Chronic NOEC 0,01 mg/l Daphnia - 21 days
Daphnia Daphnia
Magna magna
Reproduction
Test
OECD EU C. Chronic NOEC 0,006 mg/l Algae - 48 hours
3 Desmodesmus
subspicatus
12.2 Persistence and degradability
Product/ingredient name Aquatic half-life Photolysis Biodegradability
Hydrazine Fresh water <1 days, pH - -
8,2, 21°C
Product/ingredient name Rate of Period (days) Test
degradation/
elimination (%)
Hydrazine 88 % 0,25 days OECD 302B Inherent
Biodegradability: Zahn-Wellens/
EMPA Test
12.3 Bioaccumulative potential
Bioaccumulative potential
Product/ingredient name LogPow BCF Potential
Hydrazine -0,16 - low
12.4 Mobility in soil
Soil/water partition : Not available.
coefficient (KOC)
Mobility : Not available.
12.5 Results of PBT and vPvB assessment
PBT : No.
vPvB : No.
12.6 Other adverse effects
Other adverse effects : Not available.
AOX : The product does not contain organically bound halogens which
could lead to an AOX value in waste water.

SECTION 13: Disposal considerations

Scenario(s).
13.1 Waste treatment methods
Product
Methods of disposal : Examine possibilities for re-utilisation. Product residues and
uncleaned empty containers should be packaged, sealed, labelled,
and disposed of or recycled according to relevant national and local
regulations. Where large quantities are concerned, consult the
supplier. When uncleaned empty containers are passed on, the
recipient must be warned of any possible hazard that may be caused
by residues. For disposal within the EC, the appropriate code
according to the European Waste List (EWL) should be used. It is
among the tasks of the polluter to assign the waste to waste codes
specific to industrial sectors and processes according to the
European Waste List (EWL).
Hazardous waste : The classification of the product may meet the criteria for a
hazardous waste.
Packaging
Methods of disposal : The generation of waste should be avoided or minimised wherever
possible. Waste packaging should be recycled. Incineration or
landfill should only be considered when recycling is not feasible.
Special precautions : This material and its container must be disposed of in a safe way.
Care should be taken when handling emptied containers that have
not been cleaned or rinsed out. Empty containers or liners may
retain some product residues. Avoid dispersal of spilt material and
runoff and contact with soil, waterways, drains and sewers.
SECTION 14: Transport information

ADR/RID ADN IMDG IATA
14.1 UN number UN2030 UN2030 UN2030 UN2030
14.2 UN proper HYDRAZINE, HYDRAZINE HYDRAZINE, HYDRAZINE,

shipping name AQUEOUS AQUEOUS AQUEOUS AQUEOUS
SOLUTION SOLUTION SOLUTION SOLUTION
14.3 Transport 8 (6.1) 8 (6.1) 8 (6.1) 8 (6.1)
hazard class(es)/
Marks
14.4 Packing II II II II
group
14.5 Yes. Yes. Yes Yes
Environmental
hazards

14.6 Special Hazard Hazard Emergency Passenger

precautions for identification identification schedules (EmS) aircraft
user/Additional number number F-A, S-B Forbidden
information 86 86
Cargo aircraft
855: 30 L
14.7 Transport in bulk according to Annex : Not available.

II of MARPOL 73/78 and the IBC Code
Hazard notes:
Corrosive.
Toxic.
Combustible.
Flash point (Closed cup): 91°C (DIN 51758)
Environmentally hazardous substance.
Keep away from acids and oxidizing agents.
Keep separated from foodstuffs.
SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or
mixture
EU Regulation (EC) No. 1907/2006 (REACH)
Annex XIV - List of substances subject to authorisation
Annex XIV
None of the components are listed.
Substances of very high concern
Ingredient name Intrinsic property Status Reference Date of
number revision
Hydrazine Carcinogen Candidate ED/31/2011 30.06.
2011
Annex XVII - Restrictions on the manufacture, placing on the market and use of certain dangerous
substances, mixtures and articles
Product/ingredient name EC number CAS no. Restriction
Hydrazine 206-114-9 302-01-2 28
Other EU regulations
Seveso III Directive
This product is controlled under the Seveso III Directive.
Named substances
Name
Hydrazine
Danger criteria
Category
H2: Acute toxicity 2 any route of entry or Acute toxicity 3 Inhalation route of entry
E1: Hazardous to the aquatic environment - Acute 1 or Chronic 1
C2: Toxic
C9i: Very toxic for the environment

15.2 Chemical Safety : Complete.

Assessment
SECTION 16: Other information

Abbreviations and acronyms : ATE = Acute Toxicity Estimate
CLP = Classification, Labelling and Packaging Regulation [Regulation (EC) No.
1272/2008]
DNEL = Derived No Effect Level
EUH statement = CLP-specific Hazard statement
PBT = Persistent, Bioaccumulative and Toxic
PNEC = Predicted No Effect Concentration
RRN = REACH Registration Number
vPvB = Very Persistent and Very Bioaccumulative
Procedure used to derive the classification according to Regulation (EC) No. 1272/2008 [CLP/
GHS]
Classification Justification
Acute Tox. 3, H301 Calculation method
Skin Corr. 1B, H314 Calculation method
Skin Sens. 1, H317 Calculation method
Carc. 1B, H350 Calculation method
Aquatic Acute 1, H400 Calculation method
Aquatic Chronic 1, H410 Calculation method
Full text of abbreviated H : H226 Flammable liquid and vapour.
statements H301 Toxic if swallowed.
H301 (oral) Toxic if swallowed.
H311 Toxic in contact with skin.
H311 (dermal) Toxic in contact with skin.
H314 Causes severe skin burns and eye damage.
H317 May cause an allergic skin reaction.
H330 Fatal if inhaled.
H330 (inhalation) Fatal if inhaled.
H350 May cause cancer.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.
Full text of classifications : Acute Tox. 2, ACUTE TOXICITY (inhalation) - Category 2
[CLP/GHS] H330
Acute Tox. 3, ACUTE TOXICITY (oral) - Category 3
H301
Acute Tox. 3, ACUTE TOXICITY (dermal) - Category 3
H311
Aquatic Acute 1, ACUTE AQUATIC HAZARD - Category 1
H400
Aquatic Chronic 1, LONG-TERM AQUATIC HAZARD - Category 1
H410
Carc. 1B, H350 CARCINOGENICITY - Category 1B
Flam. Liq. 3, H226 FLAMMABLE LIQUIDS - Category 3
Skin Corr. 1B, SKIN CORROSION/IRRITATION - Category 1B
H314
Skin Sens. 1, SKIN SENSITIZATION - Category 1
H317
Skin Sens. 1A, SKIN SENSITIZATION - Category 1A
H317

Full text of R-phrases : R10- Flammable.

referred to in sections 2 and R45- May cause cancer.
3 R23/24/25- Also toxic by inhalation, in contact with skin and if
swallowed.
R34- Causes burns.
R43- May cause sensitisation by skin contact.
R50/53- Very toxic to aquatic organisms, may cause long-term
adverse effects in the aquatic environment.
Wording of the instructions : ERC02 Formulation of preparations
ERC04 Industrial use of processing aids in processes and
for use according to Use
products, not becoming part of articles
Descriptor System, to which ERC06a Industrial use resulting in manufacture of another
reference is made in substance (use of intermediates)
paragraph 1: ERC06b Industrial use of reactive processing aids
ERC06c Industrial use of monomers for manufacture of
thermoplastics
ERC07 Industrial use of substances in closed systems
PC0 UCN R0500/R05100 (reduction agents)
PC19 Intermediate
PC21 Laboratory chemicals
PC32 Polymer preparations and compounds
PC37 Water treatment chemicals
PROC01 Use in closed process, no likelihood of exposure
PROC03 Use in closed batch process (synthesis or formulation)
PROC08b Transfer of substance or preparation (charging/
discharging) from/to vessels/large containers at
dedicated facilities
PROC09 Transfer of substance or preparation into small
containers (dedicated filling line, including weighing)
PROC15 Use a laboratory reagent
SU03 Industrial uses
SU08 Manufacture of bulk, large scale chemicals (including
petroleum products)
SU09 Manufacture of fine chemicals
SU10 Formulation [mixing] of preparations and/or re-
packaging (excluding alloys)
SU12 Manufacture of plastics products, including
compounding and conversion
SU14 Manufacture of basic metals, including alloys
SU23 Electricity, steam, gas water supply and sewage
treatment
SU24 Scientific research and development
History
Date of issue : 2016-03-03
Date of previous issue : 2014-12-08
Version : 6.01
Indicates information that has changed from previously issued version.
Notice to reader
The data given here is based on current knowledge and experience. The purpose of this
Safety Data Sheet and its Annex [if required according to Regulation (EC) 1907/2006 (REACh)]
is to describe the products in terms of their safety requirements. The given details do not
imply any guarantee concerning the composition, properties or performance.
Annex to the extended Safety Data Sheet
(eSDS)
Identification of the substance or mixture
Product definition : Mixture
Code : 05528771
Section 1 - Title
Short title/List of use : Identified use name: Hydrazine.Use as intermediate in closed
descriptors systems. Use as monomer in closed systems. (Industrial)
Process Category: PROC01, PROC03, PROC08b, PROC09
Substance supplied to that use in form of: As such
Sector of end use: SU03, SU08, SU09, SU10
Subsequent service life relevant for that use: No.
Environmental Release Category: ERC06a, ERC06c
Market sector by type of chemical product: PC19, PC32
Name of contributing : -ERC06a, ERC06c
environmental scenario
and corresponding ERC
List of names of : -PROC01, PROC03, PROC08b, PROC09
contributing worker
scenarios and
corresponding PROCs
Additional information : PROCs and ERCs for communication purpose only. Risk
assessment based on Expert judgement.
Section 2 - Exposure controls

Contributing scenario controlling environmental exposure for : -ERC06a, ERC06c
Product characteristics : Liquid.

Vapour pressure: 19.2 hPa (25 °C) (hydrazine hydrate 100%)
Concentration of substance : ≤ 64% (referring to pure hydrazine)
in mixture or article
Amounts used : Annual site tonnage (t/a): Not applicable.
Risk from exposure via the aquatic environment is driven by effluent
discharge to freshwater. Emissions are limited by the daily waste
water independent of the tonnage applied.
Frequency and duration of : Continuous release (d/a) : 300
use
Environment factors not : Local freshwater dilution factor: 10
influenced by risk If receiving surface water flow is (m³/d): 18 000
management Local marine water dilution factor 100
Other given operational : The substance shall be rigorously contained by technical means
conditions affecting during handling and use.
environmental exposure
Technical conditions and : waste water (kg/d) ≤ 0.02(referring to pure hydrazine)
measures at process level Deviating from the STP size and water body size daily emissions
(source) to prevent release have to be adjusted.
Based on the applied operational conditions, emission in the air and
soil compartment are negligible.
16/42
HYDRAZINE HYDRATE 80% hydrazine. Use as intermediate in closed
systems. Use as monomer in closed
Technical on-site conditions : The waste water has to be directed to a dedicated sewage
and measures to reduce or treatment plant or treated by other suitable techniques.
limit discharges, air Waste air should be scrubbed or filtered. (efficiency %): > 95
emissions and releases to Floor should be impervious and resistant to liquid.
soil
Organisational measures to : Only properly trained and authorised personnel shall handle the
prevent/limit release from substance.
site Substance-handling procedures shall be well documented and
supervised.
Conditions and measures : Size of sewage treatment plant (m³/d): 2 000
related to municipal sewage (efficiency %): > 45
treatment plant Sewage sludge has not to be disposed on agricultural soil.
Conditions and measures : General information on waste disposal see section 13.
related to external treatment
of waste for disposal
Conditions and measures : No special measures required.
related to external recovery
of waste
Contributing scenario controlling worker exposure for : -PROC01, PROC03, PROC08b,

PROC09
Product characteristics : Vapour pressure: 19.2 hPa (25 °C) (hydrazine hydrate 100%)
Concentration of : ≤ 64% (referring to pure hydrazine)
substance in mixture or
article
Physical state : Liquid
Amounts used : Not applicable.
Frequency and duration of : Exposure frequency(d/a) : 230
use Exposure duration per day:
PROC01, PROC03 :
8 h (full shift).
PROC08b, PROC09: ≤ 1 hours

Sampling: ≤ 0.25 hours
Human factors not : Respiratory volume (m³/d): 10 (light activity)
influenced by risk
management
Other given operational : Indoor setting
conditions affecting Outdoor setting
workers exposure
Technical conditions and : Product is handled under closed conditions.
measures at process level
(source) to prevent release
Technical conditions and : Local exhaust ventilation required.(efficiency %): > 90 %
measures to control Sample via a closed loop or other system to avoid exposure.
dispersion from source Use of closed transfers of liquids from storage to production
towards the worker equipment (e.g. metered piped or pumped additions).
Use vapour recovery system.
Clear transfer lines prior to de-coupling.
Provide extract ventilation to points where emissions occur.
17/42
prevent/limit releases, substance.
dispersion and exposure Substance-handling procedures shall be well documented and
supervised.
Ensure intensive management supervision controls.
Drain down systems and clear transfer lines prior to breaking
containment.
Clean/flush equipment, where possible, prior to maintenance.
Clear up spills immediately.
Regularly inspect, test and maintain all control measures.
Consider the need for risk based health surveillance.
Organize regular exposure monitoring to check that exposure
levels of operators stay beyond the exposure limits (exposure
limits: see Section 8)
Conditions and measures related to personal protection and hygiene
Personal protection : Wear protective clothing as described in section 8.
Wear gloves as described in section 8.
Wear safety goggles as described in section 8.
Sampling:
If the efficiency of the local exhaust ventilation cannot be ensured
or the installation of a LEV is not possible, wear respiratory
protective equipment (efficiency %): 95
During (Dis)connection steps:

Wear respiratory protection as described in section 8. (efficiency
%): 95
(Dis)Connection of non-closed (?) dosing units: Wear coverall
according to section 8.
Section 3 - Exposure estimation and reference to its source

Website: : Not available.
Exposure estimation and reference to its source - Environment: -ERC06a, ERC06c
Exposure assessment : Manual calculated.

(environment):
Exposure estimation : The calculated individual exposure figures are below the PNECs
(RCR ratios < 1).
Exposure estimation and reference to its source - Workers: -PROC01, PROC03, PROC08b,
PROC09
Exposure assessment : Qualitative Assessment.

(human):
Exposure estimation : Applying the stipulated Risk Management Measures and
operational conditions, hydrazine will be highly contained.
Based on these measures, no risk for workers is concluded.
Section 4 - Guidance to DU to evaluate whether he works inside the

boundaries set by the ES
18/42
Environment : Under the above listed conditions the process is deemed safe.
Other conditions should only be considered when measurements or
suitable calculations show that the RCR is < 1.
Health : Under the above listed conditions the process is deemed safe.
Additional good practice advice beyond the REACH CSA

Environment : Not applicable.
Health : Not applicable.
19/42
(eSDS)
Code : 05528771
Section 1 - Title
Short title/List of use : Identified use name: Hydrazine.Use as corrosion inhibitor in steam
descriptors generating and heating systems (Industrial)
Process Category: PROC01, PROC08b, PROC09
Substance supplied to that use in form of: In a mixture
Sector of end use: SU23
Environmental Release Category: ERC07
Market sector by type of chemical product: PC37
Name of contributing : -ERC07
environmental scenario -ERC07
List of names of : -PROC01, PROC08b, PROC09
contributing worker
scenarios and
corresponding PROCs

Contributing scenario controlling environmental exposure for : -ERC07

use
Environment factors not : Local freshwater dilution factor 10
influenced by risk Local marine water dilution factor 100
management
Other given operational : Direct emission of blow-off water into fresh/ marine water.
conditions affecting Concentration in the blow off-water (mg/L): ≤ 5.47*10-3 (pure
environmental exposure hydrazine)
Deviating from the dilution factors, daily emissions have to be
adjusted.
20/42
HYDRAZINE HYDRATE 80% hydrazine. Use as corrosion inhibitor in
steam generating and heating systems
(Industrial)
Technical conditions and : The substance shall be rigorously contained by technical means
measures at process level during handling and use.
Technical on-site conditions : Waste air should be scrubbed or filtered. (efficiency %): > 95
and measures to reduce or Floor should be impervious and resistant to liquid.
limit discharges, air
emissions and releases to
soil
supervised.
Conditions and measures : Not required
related to municipal sewage
treatment plant
of waste

use
management Local marine water dilution factor: 100
Other given operational : waste water (kg/day) : ≤ 0.02 (referring to pure hydrazine)
conditions affecting Deviating from the dilution factors, daily emissions have to be
environmental exposure adjusted.
Technical conditions and : The substance shall be rigorously contained by technical means
measures at process level during handling and use.
limit discharges, air Waste air should be scrubbed or filtered. (efficiency %): > 95
soil
supervised.
21/42
(Industrial)
related to municipal sewage (efficiency %): ≥ 45
treatment plant
Sewage sludge shall not be disposed on agricultural soil.
of waste
Contributing scenario controlling worker exposure for : -PROC01, PROC08b, PROC09
Concentration of : ≥ 15 % to ≤ 64 % (referring to pure hydrazine)
article
PROC01: 8 hours
PROC08b, PROC09 :≤ 1 h
Sampling: ≤ 0.25
influenced by risk
management
workers exposure
Technical conditions and : Process fully enclosed.
Technical conditions and : Sample via a closed loop or other system to avoid exposure.
measures to control Use of closed transfers of liquids from storage to production
dispersion from source equipment (e.g. metered piped or pumped additions).
towards the worker Use vapour recovery system.
supervised.
containment.
22/42
(Industrial)
Wear gloves as described in section 8. (efficiency %): 90
Sampling:

%): 95

Exposure estimation and reference to its source - Environment: -ERC07

(environment):
(RCR ratios < 1).

(environment):
(RCR ratios < 1).
Exposure estimation and reference to its source - Workers: -PROC01, PROC08b, PROC09

(human):


23/42
(eSDS)
Code : 05528771
Section 1 - Title
Short title/List of use : Identified use name: Hydrazine.Use as reducing agent to remove
descriptors nitrosyl kations contained in sulphuric acid (Industrial)
Sector of end use: SU03, SU08, SU09
Environmental Release Category: ERC06b
Name of contributing : -ERC06b
contributing worker
scenarios and
corresponding PROCs

Contributing scenario controlling environmental exposure for : -ERC06b

Concentration of substance : 40 % (25.6 % hydrazine pure)
use
Other given operational : Percentage release to waste water: 0
conditions affecting Based on the applied operational conditions, emission in the air and
environmental exposure soil compartment are negligible.
Technical conditions and : The generation of waste should be avoided or minimised wherever
measures at process level possible.
24/42
HYDRAZINE HYDRATE 80% hydrazine. Use as reducing agent to
remove nitrosyl kations contained in
sulphuric acid (Industrial)
Technical on-site conditions : Waste air should be scrubbed or filtered. (efficiency %):> 95
soil
supervised.
Conditions and measures : Not applicable as there is no release to wastewater.
treatment plant
of waste
Concentration of : 40 % (25.6 % hydrazine pure)
article
PROC01: 8 hours
PROC08b, PROC09≤ 1 hours
Sampling: ≤ 0.25
influenced by risk
management
workers exposure
Technical conditions and : Process fully enclosed.
measures at process level Product is handled under closed conditions.
25/42
supervised.
containment.
Sampling:
protective equipment (efficiency %): 95 %

Wear respiratory protection as described in section 8.

Exposure estimation and reference to its source - Environment: -ERC06b
Exposure assessment : Qualitative Assessment

(environment):

(human):

26/42

27/42
(eSDS)
Code : 05528771
Section 1 - Title
Short title/List of use : Identified use name: Hydrazine.Use as stabilising reagent in
descriptors aromatic amines to be further used in synthesis of dyestuffs
(Industrial)
Sector of end use: SU03, SU08, SU09
Environmental Release Category: ERC06b
Market sector by type of chemical product: PC0, PC0
Name of contributing : -ERC06b
contributing worker
scenarios and
corresponding PROCs

Contributing scenario controlling environmental exposure for : -ERC06b

Vapour pressure: 19.2 2hPa (25 °C) (hydrazine hydrate 100%)
Concentration of substance : ≤ 64 %(referring to pure hydrazine)
use
Other given operational : Percentage release to waste water: 0
conditions affecting Based on the applied operational conditions, emission in the air and
environmental exposure soil compartment are negligible.
Technical conditions and : The generation of waste should be avoided or minimised wherever
measures at process level possible.
28/42
HYDRAZINE HYDRATE 80% hydrazine. Use as stabilising reagent in
aromatic amines to be further used in
synthesis of dyestuffs (Industrial)
Technical on-site conditions : Waste air should be scrubbed or filtered. (efficiency %): > 95
soil
supervised.
Conditions and measures : Not applicable as there is no release to wastewater.
treatment plant
of waste
Concentration of : ≤ 64 %(referring to pure hydrazine)
article
PROC01 : 8 hours
PROC08b, PROC09 :≤ 1 hours
Sampling: ≤ 0.25
Human factors not : Respiratory volume (m³/d): 10(light activity)
influenced by risk
management
workers exposure
Technical conditions and : Product is handled under closed conditions.
29/42
dispersion and exposure
Substance-handling procedures shall be well documented and
supervised.

containment.

Sampling:

Wear respiratory protection as described in section 8.

Exposure estimation and reference to its source - Environment: -ERC06b

(environment):

(human):

30/42

31/42
(eSDS)
Code : 05528771
Section 1 - Title
Short title/List of use : Identified use name: Hydrazine. Use as a laboratory chemical.
descriptors (Industrial)
Process Category: PROC15
Sector of end use: SU09, SU08, SU10, SU12, SU14, SU23, SU24
Environmental Release Category: ERC06a, ERC06b
Name of contributing : -ERC06a, ERC06b
List of names of : -PROC15
contributing worker
scenarios and
corresponding PROCs

Contributing scenario controlling environmental exposure for : -ERC06a, ERC06b

Concentration of substance : ≤ 64 % (referring to pure hydrazine)
Amounts used : ≤ 0.5 L/day
Frequency and duration of : Not applicable.
use
Other given operational : Avoid release to the environment.
conditions affecting In case of incidental aqueous waste, the water has to pre-treated to
environmental exposure reduce hydrazine concentrations prior to emission.
limit discharges, air Waste air should be scrubbed or filtered.(efficiency %): > 95
soil
32/42
HYDRAZINE HYDRATE 80% hydrazine. Laboratory reagent (Industrial)
supervised.
related to municipal sewage (efficiency %): 45
treatment plant
of waste
Contributing scenario controlling worker exposure for : -PROC15
Concentration of : ≤ 64 % (referring to pure hydrazine)
article
Amounts used : 0.5 L/day
Frequency and duration of : Covers exposure up to: 8 hours
use Exposure frequency (d/a) : 230
influenced by risk
management
conditions affecting
workers exposure
Technical conditions and : Handle in a fume cupboard or under extract ventilation.
measures to control
dispersion from source
towards the worker
dispersion and exposure
Substance-handling procedures shall be well documented and
supervised.

Wear gloves as described in section 8. (efficiency %): 90
33/42
HYDRAZINE HYDRATE 80% hydrazine. Laboratory reagent (Industrial)

Exposure estimation and reference to its source - Environment: -ERC06a, ERC06b

(environment):
Exposure estimation and reference to its source - Workers: -PROC15

(human):


34/42
(eSDS)
Code : 05528771
Section 1 - Title
Short title/List of use : Identified use name: Hydrazine .Distribution, formulation and (re)
descriptors packing of substances and mixtures (Industrial)
Process Category: PROC01, PROC03, PROC08b, PROC09
Sector of end use: SU03
Environmental Release Category: ERC02
Name of contributing : -ERC02
List of names of : -PROC01, PROC03, PROC08b, PROC09
contributing worker
scenarios and
corresponding PROCs
Additional information : ERC only for communication purposes. Risk assessment based on
Expert judgement


Concentration of substance : ≤ 64 %. (referring to pure hydrazine)
use
management Local marine water dilution factor: 100
Technical conditions and : Maximum load to waste water (kg/d): ≤ 0.02 (referring to pure
measures at process level hydrazine)
(source) to prevent release Deviating from the STP size and water body size daily emissions
have to be adjusted. Based on the applied operational conditions,
emission in the air and soil compartment are negligible.
35/42
HYDRAZINE HYDRATE 80% hydrazine. Distribution, formulation and (re)
packing of substances and mixtures
(Industrial)
emissions and releases to Waste air has to be cleaned by a waste gas scrubber or or a
soil combustion unit or treated by other suitable techniques. (efficiency
%): > 95
Floor should be impervious and resistant to liquid.

supervised.
Conditions and measures : Size of sewage treatment plant (m³/d): 2 000(Removal rate %): ≥ 45
of waste
Contributing scenario controlling worker exposure for : -PROC01, PROC03, PROC08b,

PROC09
Product characteristics : Vapour pressure: 19.2 hPa. (25 °C) (hydrazine hydrate 100 %.)
Concentration of : ≤ 64 %. (referring to pure hydrazine)
article
Frequency and duration of : Exposure frequency (d/a) : 230.
use
Exposure duration (h/d):
PROC01, PROC03: 8 h (full shift).
PROC08b, PROC09 :≤1.
Sampling : ≤ 0.25.
Other given operational : Indoor setting / Outdoor setting
workers exposure
Technical conditions and : The substance shall be contained by technical means during
measures at process level handling and use.
Technical conditions and : Local exhaust ventilation required. (efficiency %): 90
measures to control
dispersion from source Sample via a closed loop or other system to avoid exposure.
towards the worker Use of closed transfers of liquids from storage to production
equipment (e.g. metered piped or pumped additions).
36/42
(Industrial)
supervised.
containment.

Sampling :

%): 95
(Dis)Connection of non-closed (?) dosing units:

Wear coverall according to section 8.

Exposure assessment : Calculation method

(environment):
(RCR ratios < 1).
Exposure estimation and reference to its source - Workers: -PROC01, PROC03, PROC08b,
PROC09
Exposure assessment : Qualitative assessment

(human):

37/42
(Industrial)

38/42
(eSDS)
Code : 05528771
Section 1 - Title
Short title/List of use : Identified use name: Hydrazine .Use as reducing agent for metal-
descriptors based chemicals in closed industrial systems under controlled
conditions (Industrial)
Process Category: PROC01, PROC03, PROC08b
Sector of end use: SU03, SU14
Environmental Release Category: ERC04, ERC06b
Name of contributing : -ERC04, ERC06b
List of names of : -PROC01, PROC03, PROC08b
contributing worker
scenarios and
corresponding PROCs
Additional information : ERC only for communication purposes. Risk assessment based on
Expert judgement

Contributing scenario controlling environmental exposure for : -ERC04, ERC06b

Concentration of substance : ≤ 64 %. (referring to pure hydrazine)
use
39/42
HYDRAZINE HYDRATE 80% hydrazine. Use as reducing agent for metal-
based chemicals in closed industrial
systems under controlled conditions
(Industrial)
Technical conditions and : Maximum load to waste water (kg/d): ≤ 0.02(referring to pure
measures at process level hydrazine)
(source) to prevent release Deviating from the STP size and water body size daily emissions
have to be adjusted. Based on the applied operational conditions,
emission in the air and soil compartment are negligible.
emissions and releases to Waste air has to be cleaned by a waste gas scrubber or or a
soil combustion unit or treated by other suitable techniques. (efficiency
%): > 95
Floor should be impervious and resistant to liquid.

supervised.
Conditions and measures : Size of sewage treatment plant (m³/d): 2 000(Removal rate %): ≥ 45
of waste
Contributing scenario controlling worker exposure for : -PROC01, PROC03, PROC08b
Product characteristics : Vapour pressure: 19 . 2 hPa (25 °C) (hydrazine hydrate 100%)
Concentration of : ≤ 64 % (referring to pure hydrazine)
article
Frequency and duration of : Exposure frequency 230 days per year
use
Exposure duration (h/d):
PROC01, PROC03 :8 h (full shift).
PROC08b: ≤ 1
Sampling : ≤ 0.25
Other given operational : Indoor setting/Outdoor setting
workers exposure
Technical conditions and : The substance shall be contained by technical means during
measures at process level handling and use.
40/42
(Industrial)
Technical conditions and : Local exhaust ventilation required.
measures to control
dispersion from source Ventilation rate (h-1): 3-5
towards the worker
Ensure samples are obtained under containment or extract
ventilation.
Sample via a closed loop or other system to avoid exposure.
Use of closed transfers of liquids from storage to production
equipment (e.g. metered piped or pumped additions).
supervised.
containment.

Sampling :

%): 95

Exposure estimation and reference to its source - Environment: -ERC04, ERC06b
Exposure assessment : Calculation method

(environment):
(RCR ratios < 1).
41/42
(Industrial)
Exposure estimation and reference to its source - Workers: -PROC01, PROC03, PROC08b
Exposure assessment : Qualitative assessment

(human):


42/42

MSDS-Hydrazine 80%

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Conforms to Regulation (EC) No.

1907/2006 (REACH), Annex II, as amended by Regulation (EU)

SAFETY DATA SHEET

1.3 Details of the supplier of the safety data sheet

Date of issue : 2016-03-03 Page: 1/42

SECTION 2: Hazards identification

Signal word : Danger

2.3 Other hazards

SECTION 3: Composition/information on ingredients

Occupational exposure limits, if available, are listed in Section 8.

SECTION 4: First aid measures

Date of issue : 2016-03-03 Page: 3/42

Inhalation : Get medical attention immediately. Move exposed person to fresh

SECTION 5: Firefighting measures

Date of issue : 2016-03-03 Page: 4/42

SECTION 6: Accidental release measures

6.4 Reference to other : See Section 1 for emergency contact information.

SECTION 7: Handling and storage

Date of issue : 2016-03-03 Page: 5/42

Date of issue : 2016-03-03 Page: 6/42

SECTION 8: Exposure controls/personal protection

Derived effect levels

Predicted No Effect Concentration (PNEC)

Date of issue : 2016-03-03 Page: 7/42

SECTION 9: Physical and chemical properties

Date of issue : 2016-03-03 Page: 8/42

Decomposition : Not available.

SECTION 10: Stability and reactivity

10.5 Incompatible materials : Reactive or incompatible with the following materials:

SECTION 11: Toxicological information

Product/ingredient Result Species Dose Exposure Test

Date of issue : 2016-03-03 Page: 9/42

HYDRAZINE Skin - Rabbit - 4 hours * Not

Potential chronic health effects

SECTION 12: Ecological information

Date of issue : 2016-03-03 Page: 10/42

Product/ingredient Test Result Species Exposure

Date of issue : 2016-03-03 Page: 11/42

SECTION 13: Disposal considerations

SECTION 14: Transport information

14.2 UN proper HYDRAZINE, HYDRAZINE HYDRAZINE, HYDRAZINE,

Date of issue : 2016-03-03 Page: 12/42

14.6 Special Hazard Hazard Emergency Passenger

14.7 Transport in bulk according to Annex : Not available.

SECTION 15: Regulatory information

Date of issue : 2016-03-03 Page: 13/42

15.2 Chemical Safety : Complete.

SECTION 16: Other information

Date of issue : 2016-03-03 Page: 14/42

Full text of R-phrases : R10- Flammable.

Section 2 - Exposure controls

Product characteristics : Liquid.

Contributing scenario controlling worker exposure for : -PROC01, PROC03, PROC08b,

PROC08b, PROC09: ≤ 1 hours

During (Dis)connection steps:

Section 3 - Exposure estimation and reference to its source

Exposure estimation and reference to its source - Environment: -ERC06a, ERC06c

Exposure assessment : Manual calculated.

Exposure assessment : Qualitative Assessment.

Section 4 - Guidance to DU to evaluate whether he works inside the