Xii-Board 3RD 33% Chemistry DRT - 2 - 20.11.2023

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VELAMMAL BODHI CAMPUS

“Velammal Knowledge Park”


THIRD 33% BOARD MODULE EXAM – 2023-24

Class : XII (DRT-2) Marks : 25


Date : 20.11.2023 CHEMISTRY Duration : 1 hour

I. ANSWER THE FOLLOWING QUESTIONS : 𝟓 × 𝟏 = 𝟓𝑴


1. Which of the following is most reactive in nucleophillic addition reactions?
a) HCHO b) CH3COCH3 c) CH3COC2H5 d) CH3CHO
2. What is the IUPAC name of the given compound
CH 3

CH 3  C  CH 2  CH 3

COOH
a) 2,2-Dimethylbutanoic acid b) 3-methylbutane carboxylic acid
c) 2-ethyl-2-methylpropanoic acid d) 3-methylbutane carboxyllic acid
3. Arrange the following acids in order of increasing acidity.
COOH COOH COOH COOH
NO2
(A) (B) (C) (D)

NO2 OH

a) A<B<C<D b) B<C<A<D c) C<D<B<A d) C<B<D<A


4. Assertion : Acetaldehyde undergoes aldol condensation with dil.NaOH.
Reason : Aldehydes which do not contains -hydrogen undergoes aldol
condensation.
a) Both ‘A’ and ‘R’ are correct statements, and ‘R’ is the correct explanation of the
‘A’
b) Both ‘A’ and ‘R’ are correct statements, but ‘R’ is not the correct explanation of
the ‘A’
c) ‘A’ is correct, but ‘R’ is incorrect statement
d) ‘A’ is incorrect, but ‘R’ is correct statement
5. Assertion : Aldehydes & ketones, both react with Tollen’s reagent to form silver
mirror.
Reason : Both aldehydes & ketones contain a carbonyl group.
a) Both ‘A’ and ‘R’ are correct statements, and ‘R’ is the correct explanation of the
‘A’
b) Both ‘A’ and ‘R’ are correct statements, but ‘R’ is not the correct explanation of
the ‘A’
c) ‘A’ is correct, but ‘R’ is incorrect statement
d) ‘A’ is incorrect, but ‘R’ is correct statement

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II. ANSWER THE FOLLOWING QUESTIONS : 𝟒 × 𝟐 = 𝟖𝑴
6. Write the products of the following reactions.
CHO
O
a) conc.NaOH b) + H2NNH – CO – NH2 𝐻⨁

CH2CH3
KMnO4
c)
KOH, heat

7. Give simple chemical tests to distinguish between the following pairs of


compounds.
a) Propanal and propanone b) Benzaldehyde & Acetophenone
c) Phenol & Benzoic acid
8. Describe the following :
a) Cross aldol condensation b) Cannizaro reaction
c) Decarboxylation
9. Give reasons for
a) Benzoic acid is a strong acid than acetic acid.
b) Presence of Alpha hydrogen in aldehydes & ketones is essential for aldol
condensation.

III. ANSWER THE FOLLOWING QUESTIONS : 𝟒 × 𝟑 = 𝟏𝟐𝑴


10. Explain :
(a) Etard reaction (b) Rosenmund reduction (c) Wolf-kishner reduction
11. Describe :
(a) Aldol condensation (b) Clemmensen reduction (c) HVZ-reaction
12. An organic compound with molecular formula C 9H10O forms 2, 4-DNP derivative,
reduces Tollens’ reagent and undergoes Canizzaro reaction. On vigorous
oxidation, it gives 1, 2-benzenedicarboxylic acid. Identify the compound and write
the reactions involved.
13. Complete each synthesis by giving starting material.
(a) C6 H 5CHO  CH 3CH 2CHO 
dil.NaOH


(b) Propanone 
dil. NaOH

(c) Write Gatterman-Koch reaction

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