Sulfur Hexafluoride sf6 Safety Data Sheet Sds p4657

Sulfur hexafluoride
Safety Data Sheet P-4657

This SDS conforms to U.S. Code of Federal Regulations 29 CFR 1910.1200, Hazard Communication.
Issue date: 01/01/1979 Revision date: 11/10/2022 Supersedes: 05/24/2022 Version: 1.2
SECTION: 1. Product and company identification

1.1. Product identifier
Product form : Substance
Substance name : Sulfur hexafluoride
Chemical name : Sulfur hexafluoride
CAS-No. : 2551-62-4
Formula : SF6
1.2. Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture : Industrial use; Use as directed.
1.3. Details of the supplier of the safety data sheet
Linde Inc.
10 Riverview Drive
Danbury, CT 06810-6268, USA
www.lindeus.com
Linde Inc. 1-844-44LINDE (1-844-445-4633)

1.4. Emergency telephone number
Emergency number : Onsite Emergency: 1-800-645-4633
CHEMTREC, 24hr/day 7days/week

— Within USA: 1-800-424-9300, Outside USA: 001-703-527-3887
(collect calls accepted, Contract 17729)
SECTION 2: Hazard identification

2.1. Classification of the substance or mixture
GHS US classification
Simple asphyxiant SIAS
Press. Gas (Liq.) H280
2.2. Label elements

GHS US labeling
Hazard pictograms (GHS US) :
GHS04
Signal word (GHS US) : Warning
Hazard statements (GHS US) : H280 - CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF HEATED
OSHA-H01 - MAY DISPLACE OXYGEN AND CAUSE RAPID SUFFOCATION.
CGA-HG01 - MAY CAUSE FROSTBITE.
Precautionary statements (GHS US) : P202 - Do not handle until all safety precautions have been read and understood.
P262 - Do not get in eyes, on skin, or on clothing.
P271+P403 - Use and store only outdoors or in a well-ventilated place.
P280 - Wear protective gloves/protective clothing/eye protection/face protection.
P304, P340, P313 - IF INHALED: Remove person to fresh air and keep comfortable for
breathing. Get medical advice/attention.
P302, P336, P315 - IF ON SKIN: Thaw frosted parts with lukewarm water. Do not rub affected
area.. Get immediate medical advice/attention.
CGA-PG05 - Use a back flow preventive device in the piping.
CGA-PG10 - Use only with equipment rated for cylinder pressure.
CGA-PG12 - Do not open valve until connected to equipment prepared for use.
EN (English US) SDS ID: P-4657 1/9
This document is only controlled while on the Linde US website and a copy of this controlled version is available for download. Linde cannot assure the integrity or
accuracy of any version of this document after it has been downloaded or removed from our website.
Sulfur hexafluoride
CGA-PG06 - Close valve after each use and when empty.

CGA-PG02 - Protect from sunlight when ambient temperature exceeds 52°C (125°F).
2.3. Other hazards

No additional information available
2.4. Unknown acute toxicity (GHS US)
Not applicable
SECTION 3: Composition/Information on ingredients

3.1. Substances
Name : Sulfur hexafluoride
CAS-No. : 2551-62-4
Name Product identifier %
Sulfur hexafluoride (CAS-No.) 2551-62-4 99.5 – 100
3.2. Mixtures
Not applicable
SECTION 4: First aid measures

4.1. Description of first aid measures
First-aid measures after inhalation : Remove to fresh air and keep at rest in a position comfortable for breathing. If not breathing,
give artificial respiration. If breathing is difficult, trained personnel should give oxygen. Call a
physician.
First-aid measures after skin contact : The liquid may cause frostbite. For exposure to liquid, immediately warm frostbite area with
warm water not to exceed 105°F (41°C). Water temperature should be tolerable to normal
skin. Maintain skin warming for at least 15 minutes or until normal coloring and sensation have
returned to the affected area. In case of massive exposure, remove clothing while showering
with warm water. Seek medical evaluation and treatment as soon as possible.
First-aid measures after eye contact : The liquid may cause frostbite. Immediately flush eyes thoroughly with water for at least 15
minutes. Hold the eyelids open and away from the eyeballs to ensure that all surfaces are
flushed thoroughly. Contact an ophthalmologist immediately.
First-aid measures after ingestion : Ingestion is not considered a potential route of exposure.
4.2. Most important symptoms and effects, both acute and delayed
4.3. Indication of any immediate medical attention and special treatment needed
None.
SECTION 5: Firefighting measures

5.1. Extinguishing media
Suitable extinguishing media : Use extinguishing media appropriate for surrounding fire.
5.2. Special hazards arising from the substance or mixture
Reactivity : No reactivity hazard other than the effects described in sub-sections below.
5.3. Advice for firefighters
Firefighting instructions : Evacuate all personnel from the danger area. Use self-contained breathing apparatus (SCBA)
and protective clothing. Immediately cool containers with water from maximum distance. Stop
flow of gas if safe to do so, while continuing cooling water spray. Remove ignition sources if
safe to do so. Remove containers from area of fire if safe to do so. On-site fire brigades must
comply with OSHA 29 CFR 1910.156 and applicable standards under 29 CFR 1910 Subpart
L—Fire Protection.
Protection during firefighting : Compressed gas: asphyxiant. Suffocation hazard by lack of oxygen.
Special protective equipment for fire fighters : Use self-contained breathing apparatus. Standard protective clothing and equipment (Self
Contained Breathing Apparatus) for fire fighters.
This document is only controlled while on the Linde US website and a copy of this controlled version is available for download. Linde cannot assure the integrity or accuracy
of any version of this document after it has been downloaded or removed from our website.
Sulfur hexafluoride
Specific methods : Use fire control measures appropriate for the surrounding fire. Exposure to fire and heat
radiation may cause gas containers to rupture. Cool endangered containers with water spray jet
from a protected position. Prevent water used in emergency cases from entering sewers and
drainage systems.
Stop flow of product if safe to do so.
Use water spray or fog to knock down fire fumes if possible.
SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures
General measures : Evacuate area. Ensure adequate air ventilation. Prevent from entering sewers, basements and
workpits, or any place where its accumulation can be dangerous. Monitor concentration of
released product. Try to stop release.
6.1.1. For non-emergency personnel

6.1.2. For emergency responders
6.2. Environmental precautions
Try to stop release. Prevent waste from contaminating the surrounding environment. Prevent soil
and water pollution. Dispose of contents/container in accordance with container supplier/owner
instructions.
6.3. Methods and material for containment and cleaning up
6.4. Reference to other sections
See also sections 8 and 13.
SECTION 7: Handling and storage

7.1. Precautions for safe handling
Precautions for safe handling : Wear leather safety gloves and safety shoes when handling cylinders. Protect cylinders from
physical damage; do not drag, roll, slide or drop. While moving cylinder, always keep in place
removable valve cover. Never attempt to lift a cylinder by its cap; the cap is intended solely to
protect the valve. When moving cylinders, even for short distances, use a cart (trolley, hand
truck, etc.) designed to transport cylinders. Never insert an object (e.g, wrench, screwdriver,
pry bar) into cap openings; doing so may damage the valve and cause a leak. Use an
adjustable strap wrench to remove over-tight or rusted caps. Slowly open the valve. If the
valve is hard to open, discontinue use and contact your supplier. Close the container valve
after each use; keep closed even when empty. Never apply flame or localized heat directly to
any part of the container. High temperatures may damage the container and could cause the
pressure relief device to fail prematurely, venting the container contents. For other precautions
in using this product, see section 16.
7.2. Conditions for safe storage, including any incompatibilities
Storage conditions : Store in a cool, well-ventilated place. Store and use with adequate ventilation. Store only where
temperature will not exceed 125°F (52°C). Firmly secure containers upright to keep them from
falling or being knocked over. Install valve protection cap firmly in place by hand. Store full and
empty containers separately. Use a first-in, first-out inventory system to prevent storing full
containers for long periods.
OTHER PRECAUTIONS FOR HANDLING, STORAGE, AND USE: When handling product
under pressure, use piping and equipment adequately designed to withstand the pressures to
be encountered. Never work on a pressurized system. Use a back flow preventive device in the
piping. Gases can cause rapid suffocation because of oxygen deficiency; store and use with
adequate ventilation. If a leak occurs, close the container valve and blow down the system in a
safe and environmentally correct manner in compliance with all international, federal/national,
state/provincial, and local laws; then repair the leak. Never place a container where it may
become part of an electrical circuit.
Sulfur hexafluoride
7.3. Specific end use(s)

None.
SECTION 8: Exposure controls/personal protection

8.1. Control parameters
Sulfur hexafluoride (2551-62-4)
ACGIH ACGIH OEL TWA [ppm] 1000 ppm
USA OSHA OSHA PEL TWA [1] 6000 mg/m³
USA OSHA OSHA PEL TWA [2] 1000 ppm

ACGIH ACGIH OEL TWA [ppm] 1000 ppm
USA OSHA OSHA PEL TWA [1] 6000 mg/m³
USA OSHA OSHA PEL TWA [2] 1000 ppm
8.2. Exposure controls

Appropriate engineering controls : Use a local exhaust system with sufficient flow velocity to maintain an adequate supply of air in
the worker's breathing zone. Mechanical (general): General exhaust ventilation may be
acceptable if it can maintain an adequate supply of air.
Hand protection : Wear working gloves when handling gas containers. Select hand protection in accordance with
OSHA 29 CFR 1910.138.
Eye protection : Wear safety glasses with side shields or goggles when transfilling or breaking transfer
connections. Wear safety glasses with side shields. Select eye protection in accordance with
OSHA 29 CFR 1910.133.
Respiratory protection : When workplace conditions warrant respirator use, follow a respiratory protection program that
meets OSHA 29 CFR 1910.134, ANSI Z88.2, or MSHA 30 CFR 72.710 (where applicable).
Use an air-supplied or air-purifying cartridge if the action level is exceeded. Ensure that the
respirator has the appropriate protection factor for the exposure level. If cartridge type
respirators are used, the cartridge must be appropriate for the chemical exposure. For
emergencies or instances with unknown exposure levels, use a self-contained breathing
apparatus (SCBA).
Thermal hazard protection : Wear cold insulating gloves when transfilling or breaking transfer connections.
SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties
Physical state : Gas
Appearance : Colorless gas.
Molecular mass : 146 g/mol
Color : Colorless.
Odor : Irritating choking
Odor threshold : No data available
pH : Not applicable.
Relative evaporation rate (butyl acetate=1) : No data available
Relative evaporation rate (ether=1) : Not applicable.
Melting point : -50.8 °C
Freezing point : No data available
Boiling point : -63.8 °C
Flash point : Not applicable.
Critical temperature : 45.5 °C
Auto-ignition temperature : No data available
Decomposition temperature : No data available
Flammability (solid, gas) : No data available
Vapor pressure : 23.07 bar (334.6 psia) (@20°C)
Sulfur hexafluoride
Critical pressure : 37.6 bar (545.3 psia)

Relative vapor density at 20 °C : No data available
Relative density : 1.4
Relative density of saturated gas/air mixture : 5.04
Density : 0.0061 g/cm³ (at 20 °C)
Relative gas density : 5
Solubility : Water: 41 mg/l
Partition coefficient n-octanol/water (Log Pow) : 1.68
Partition coefficient n-octanol/water (Log Kow) : Not applicable.
Viscosity, kinematic : Not applicable.
Viscosity, dynamic : Not applicable.
Explosive properties : Not applicable.
Oxidizing properties : None.
Explosion limits : Non flammable.
9.2. Other information
Sublimation point : -63.9 °C
Gas group : Press. Gas (Liq.)
Additional information : Gas/vapor heavier than air. May accumulate in confined spaces, particularly at or below ground
level.
SECTION 10: Stability and reactivity

10.1. Reactivity
No reactivity hazard other than the effects described in sub-sections below.
10.2. Chemical stability
Stable under normal conditions.
10.3. Possibility of hazardous reactions
May occur.
10.4. Conditions to avoid
Avoid temperature above 800°C (1472°F).
10.5. Incompatible materials
Explodes violently in contact with disilane.
10.6. Hazardous decomposition products
Under normal conditions of storage and use, hazardous decomposition products should not be
produced. Thermal decomposition may produce : Fluorides. Sulfur dioxide.
SECTION 11: Toxicological information
11.1. Information on toxicological effects

Acute toxicity (oral) : Not classified
Acute toxicity (dermal) : Not classified
Acute toxicity (inhalation) : Not classified
Skin corrosion/irritation : Not classified

pH: Not applicable.
Serious eye damage/irritation : Not classified
pH: Not applicable.
Sulfur hexafluoride
Respiratory or skin sensitization : Not classified

Germ cell mutagenicity : Not classified
Carcinogenicity : Not classified
Reproductive toxicity : Not classified
STOT-single exposure : Not classified
STOT-repeated exposure : Not classified
Aspiration hazard : Not classified
SECTION 12: Ecological information

12.1. Toxicity
Ecology - general : No ecological damage caused by this product.
12.2. Persistence and degradability

Persistence and degradability Not applicable for inorganic gases.
Persistence and degradability Not applicable for inorganic gases.
12.3. Bioaccumulative potential
Partition coefficient n-octanol/water (Log Pow) 1.68
Partition coefficient n-octanol/water (Log Kow) Not applicable.
Bioaccumulative potential No data available.
Partition coefficient n-octanol/water (Log Pow) 1.68
Bioaccumulative potential No data available.
12.4. Mobility in soil
Mobility in soil No data available.
Ecology - soil Because of its high volatility, the product is unlikely to cause ground or water pollution.
Ecology - soil Because of its high volatility, the product is unlikely to cause ground or water pollution.
12.5. Other adverse effects

Effect on ozone layer : None.
Global warming potential [CO2=1] : 22200
Effect on the global warming : Contains Fluorinated greenhouse gases covered by the Kyoto protocol.
SECTION 13: Disposal considerations

13.1. Waste treatment methods
Product/Packaging disposal recommendations : Dispose of contents/container in accordance with local/regional/national/international
regulations. Contact supplier for any special requirements.
SECTION 14: Transport information

In accordance with DOT
Transport document description (DOT) : UN1080 Sulfur hexafluoride, 2.2
UN-No.(DOT) : UN1080
Proper Shipping Name (DOT) : Sulfur hexafluoride
Class (DOT) : 2.2 - Class 2.2 - Non-flammable compressed gas 49 CFR 173.115
Sulfur hexafluoride
Hazard labels (DOT) : 2.2 - Non-flammable gas
Additional information
Emergency Response Guide (ERG) Number : 126
Other information : No supplementary information available.

Special transport precautions : Avoid transport on vehicles where the load space is not separated from the driver's
compartment. Ensure vehicle driver is aware of the potential hazards of the load and knows
what to do in the event of an accident or an emergency. Before transporting product containers:
- Ensure there is adequate ventilation. - Ensure that containers are firmly secured. - Ensure
cylinder valve is closed and not leaking. - Ensure valve outlet cap nut or plug (where provided)
is correctly fitted. - Ensure valve protection device (where provided) is correctly fitted.
Transport by sea
UN-No. (IMDG) : 1080
Proper Shipping Name (IMDG) : SULPHUR HEXAFLUORIDE
Class (IMDG) : 2 - Gases
Division (IMDG) : 2.2 - Non-flammable, non-toxic gases
MFAG-No : 126
Air transport
UN-No. (IATA) : 1080
Proper Shipping Name (IATA) : Sulphur hexafluoride
Class (IATA) : 2 - Gases
Civil Aeronautics Law : Gases under pressure/Gases nonflammable nontoxic under pressure
SECTION 15: Regulatory information

15.1. US Federal regulations
Listed on the United States TSCA (Toxic Substances Control Act) inventory
All components of this product are listed on the Toxic Substances Control Act
(TSCA) inventory.
15.2. International regulations

CANADA

Listed on the Canadian DSL (Domestic Substances List)
Listed on the Canadian DSL (Domestic Substances List)
EU-Regulations

Listed on the EEC inventory EINECS (European Inventory of Existing Commercial Chemical Substances)
Sulfur hexafluoride
15.2.2. National regulations

Listed introduction on Australian Industrial Chemicals Introduction Scheme (AICIS Inventory)
Listed on IECSC (Inventory of Existing Chemical Substances Produced or Imported in China)
Listed on the Japanese ENCS (Existing New Chemical Substances) inventory
Listed on the Japanese ISHL (Industrial Safety and Health Law)
Listed on KECL/KECI (Korean Existing Chemicals Inventory)
Listed on NZIoC (New Zealand Inventory of Chemicals)
Listed on PICCS (Philippines Inventory of Chemicals and Chemical Substances)
Listed on the Canadian IDL (Ingredient Disclosure List)
Listed on INSQ (Mexican National Inventory of Chemical Substances)
Listed on the TCSI (Taiwan Chemical Substance Inventory)
15.3. US State regulations

Sulfur hexafluoride(2551-62-4)
U.S. - California - Proposition 65 - Carcinogens List No
U.S. - California - Proposition 65 - Developmental No
Toxicity
U.S. - California - Proposition 65 - Reproductive No
Toxicity - Female
U.S. - California - Proposition 65 - Reproductive No
Toxicity - Male
State or local regulations U.S. - Massachusetts - Right To Know List
U.S. - New Jersey - Right to Know Hazardous Substance List
U.S. - Pennsylvania - RTK (Right to Know) List

U.S. - California - U.S. - California - U.S. - California - U.S. - California - No significant risk level
Proposition 65 - Proposition 65 - Proposition 65 - Proposition 65 - (NSRL)
Carcinogens List Developmental Toxicity Reproductive Toxicity - Reproductive Toxicity - Male
Female
No No No No

U.S. - Massachusetts - Right To Know List
U.S. - New Jersey - Right to Know Hazardous Substance List
U.S. - Pennsylvania - RTK (Right to Know) List
Sulfur hexafluoride
SECTION 16: Other information

Other information : When you mix two or more chemicals, you can create additional, unexpected hazards. Obtain
and evaluate the safety information for each component before you produce the mixture.
Consult an industrial hygienist or other trained person when you evaluate the end product.
Before using any plastics, confirm their compatibility with this product.
Linde asks users of this product to study this SDS and become aware of the product hazards
and safety information. To promote safe use of this product, a user should (1) notify
employees, agents, and contractors of the information in this SDS and of any other known
product hazards and safety information, (2) furnish this information to each purchaser of the
product, and (3) ask each purchaser to notify its employees and customers of the product
hazards and safety information.
The opinions expressed herein are those of qualified experts within Linde Inc. We believe that
the information contained herein is current as of the date of this Safety Data Sheet. Since the
use of this information and the conditions of use are not within the control of Linde Inc, it is the
user's obligation to determine the conditions of safe use of the product.
Linde SDSs are furnished on sale or delivery by Linde or the independent distributors and
suppliers who package and sell our products. To obtain current SDSs for these products,
contact your sales representative, local distributor, or supplier, or download from
www.lindeus.com. If you have questions regarding Linde SDSs, would like the document
number and date of the latest SDS, or would like the names of the Linde suppliers in your area,
phone or write the Linde Call Center (Phone: 1-844-44-Linde (1-844-445-4633); Address: Linde
Call Center, Linde Inc, P.O. Box 44, Tonawanda, NY 14151-0044).
Linde and the Linde wordmark are trademarks or registered trademarks of Linde plc or its
affiliates. The information contained herein is offered for use by technically qualified personnel
at their discretion and risk without warranty of any kind.
Copyright © 2022, Linde Inc.

Revision date : 11/10/2022
NFPA health hazard : 2 - Materials that, under emergency conditions, can cause
temporary incapacitation or residual injury.
NFPA fire hazard : 0 - Materials that will not burn under typical fire conditions,
including intrinsically noncombustible materials such as
concrete, stone, and sand.
NFPA instability : 0 - Material that in themselves are normally stable, even
under fire conditions.
SDS US (GHS HazCom 2012) - Linde 2022
This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as
guaranteeing any specific property of the product.

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Sulfur hexafluoride

Safety Data Sheet P-4657

SECTION: 1. Product and company identification

Linde Inc. 1-844-44LINDE (1-844-445-4633)

CHEMTREC, 24hr/day 7days/week

SECTION 2: Hazard identification

2.2. Label elements

EN (English US) SDS ID: P-4657 1/9

CGA-PG06 - Close valve after each use and when empty.

2.3. Other hazards

SECTION 3: Composition/Information on ingredients

SECTION 4: First aid measures

SECTION 5: Firefighting measures

EN (English US) SDS ID: P-4657 2/9

Stop flow of product if safe to do so.

Use water spray or fog to knock down fire fumes if possible.

SECTION 6: Accidental release measures

6.1.1. For non-emergency personnel

SECTION 7: Handling and storage

EN (English US) SDS ID: P-4657 3/9

7.3. Specific end use(s)

SECTION 8: Exposure controls/personal protection

Sulfur hexafluoride (2551-62-4)

8.2. Exposure controls

SECTION 9: Physical and chemical properties

EN (English US) SDS ID: P-4657 4/9

Critical pressure : 37.6 bar (545.3 psia)

SECTION 10: Stability and reactivity

SECTION 11: Toxicological information

11.1. Information on toxicological effects

Skin corrosion/irritation : Not classified

Respiratory or skin sensitization : Not classified

SECTION 12: Ecological information

12.2. Persistence and degradability

12.5. Other adverse effects

SECTION 13: Disposal considerations

SECTION 14: Transport information

EN (English US) SDS ID: P-4657 6/9

Hazard labels (DOT) : 2.2 - Non-flammable gas

Other information : No supplementary information available.

SECTION 15: Regulatory information

15.2. International regulations

Sulfur hexafluoride (2551-62-4)

Sulfur hexafluoride (2551-62-4)

EN (English US) SDS ID: P-4657 7/9

15.2.2. National regulations

15.3. US State regulations

Sulfur hexafluoride (2551-62-4)

Sulfur hexafluoride (2551-62-4)

EN (English US) SDS ID: P-4657 8/9

SECTION 16: Other information

Copyright © 2022, Linde Inc.

SDS US (GHS HazCom 2012) - Linde 2022

EN (English US) SDS ID: P-4657 9/9

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