CV1013 - Steel
CV1013 - Steel
CV1013 - Steel
1
Types of material
Asphalt concrete
Steel
Wood/Timber
Fiber–Reinforced Composites/Plastics
Masonry
Cement and Concrete
2
Introduction
Iron is the fourth most
abundant elements in the
earth’s crust.
It requires considerably less energy to extract from its ore than most of
the other engineering metals, for 1 kg of each metal:
iron (54 MJ),
aluminum (280 MJ),
copper (108 MJ),
magnesium (415 MJ),
titanium (550 MJ).
http://www.nea.gov.sg/energy-waste/waste-management/waste-statistics-and-overall-recycling 4
Max Planck Institute, 2012
Steel is everywhere
Eiffel Tower Brooklyn Bridge
5
http://my.whirlwindsteel.com/blog/bid/395563/The-Most-Famous-Steel-Structures-in-the-World
Steel is everywhere
Sky bridge/sky park Art Science Museum
Singapore flyer
Flower dome
6
http://www.makemytrip.com Wikimedia.org is.asia-city.com
Major applications of steel
Rolled sections
Plates
Fasteners
Reinforcing bars
Cables (Parallel wire & twisted wire)
7
Major applications of steel
Long span bridges
Skeleton steel
structure for high-rise
building
Locally precast
concrete is dominant
for high-rise building
Highly efficient/cost effective
Relatively labor intensive on
site
Environmental concerns
https://www.aisc.org/modernsteel/news/2015/july/steel-shots-grand- 8
vision/#.WHb-VlN95aQ
Major applications of steel
• Prefabricated Prefinished Volumetric Construction
(PPVC): a construction method whereby free-
standing volumetric modules (complete with
finishes for walls, floors and ceilings) are
manufactured in a factory and installed on site.
• Manufactured in factory means much higher
quality control;
• Onsite labour is greatly reduced;
• Less construction waste generated;
• Shipping cost may be higher.
Major applications of steel
10
Major applications of steel
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Major applications of steel
• Banyan Hall, Binjai Hall, Tanjong Hall (North Hill Cluster)
• About $200 million project
• Singapore's first major development using PPVC technology
• Not only save time but also labour, requiring about 40 per cent
less manpower to build the halls
• New method costs
about 10 to 15 % more
than traditional ones
• In long term, the
project expected to gain
cost effectiveness by
reducing maintenance
need
12
Overview of Steelmaking Process
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What is a Blast Furnace?
•The purpose of a blast
furnace is to reduce and
convert iron oxides into
liquid iron called "hot
metal".
•The blast furnace is a
huge, steel stack/kiln lined
with refractory brick.
•Iron ore, coke and
limestone are put into the
top, and preheated air is
blown into the kiln from
the bottom.
reactions take place before iron is produced
•Oxygen in the air reacts with coke to give
carbon dioxide:
C(s) + O2(g) CO2(g) (1)
https://www.youtube.com/watch?v=_Wem432xbWE
Steel – Outline
Crystal structure
Alloying
Cold-working alloyed, cold-worked & heat-treated steel
Heat-treatment
Engineering behavior and properties
Construction steel products
Welding
Corrosion
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Steel Structure at Nano-,
Micro- and Macro-level
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Body-Centered Cubic Crystal Structure
One atom on each corner and one in the centre of the cell volume
Atom
Unit Cell
(a) hard-ball model; (b) unit cell; and (c) single crystal with many unit cells.
Source: W. G. Moffatt, et al., The Structure and Properties of Materials, Vol. 1, John Wiley & Sons, 1976
20
Face-Centered Cubic Crystal Structure
One atom on each corner and one in the centre of each face
Atom
Unit Cell
(a) hard-ball model; (b) unit cell; and (c) single crystal with many unit cells.
Source: W. G. Moffatt, et al., The Structure and Properties of Materials, Vol. 1, John Wiley & Sons, 1976
21
3 Primary Metallic Crystal Structures
Phase: a liquid or solid state of a material with the same crystal structure, iron with
BCC and FCC structures are considered different phases
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Mamlouk and Zaniewski, Pearson Education (2011)
Theoretical Density of Metal
26
Mamlouk and Zaniewski, Pearson Education (2011)
Linear defects - dislocations
• Dislocations are areas where atoms are out of position in crystal structure.
• Movement of dislocations allows slip – plastic deformation to occur when a
stress is applied .
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Alloying
An alloy is a homogeneous mixture of two or more elements,
at least one of which is a metal
Most metals are alloyed with other elements to obtain better
mechanical properties
Alloying is actually not a modern technique
https://en.wikipedia.org/wiki/Iron_Age
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Alloying
Copper wire (soft) Ancient Chinese Bronze
Sword (strong)
www.datacabling.net ancientchinesewarfare.weebly.com
industrialsculpting.com www.tatasteeleurope.com
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Various Fe solutions & compounds
Solid solution: alloying elements are fully dissolvable in the base
metal (completely miscible system)
Intermediate compound: alloying elements are partially dissolvable
in the base metal (partially miscible system)
A1
Structural steel: < 0.3 %C
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Iron-Carbon Phase Diagram looks like Pikachu
34
http://9gag.com/gag/aj6gvgR/iron-carbon-phase-diagram-looks-like-pikachu
Fe-C diagram: from iron to steel
Ferrite + Cementite(Fe3C)
www.industrialheating.com 35
Various Fe solutions & compounds
Pearlite: A microstructure formed by the cooling of the austenite at the eutectoid.
It consists of an intimate lamellar mixture of α ferrite and cementite.
In the microstructure view: The ferrite appears white, and is laminated against
the cementite which appears grey
http://hsc.csu.edu.au/engineering_studies/
application/civil/1-1/answers.html
CV1013 - CEM
36
http://www.dierk-raabe.com/pearlitic-steels/
The evolution of the microstructure of hypo-eutectoid and
hyper-eutectoid steels during cooling in relationship to the Fe-C
phase diagram
Carbon (solid
solution in )
37
Fe-C diagram: from iron to steel
Ferrite + Cementite(Fe3C)
www.industrialheating.com 38
Rate of cooling on microstructure/strength
In general, strength depends on the nature, distribution,
and size of the phases and/or grains present
40
Hardness and strength versus the amount of carbon
41
Ductility and toughness versus the amount of carbon
Toughness, Joules
Source : Young et al (1998)
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Fraction of Each Phase of a Binary Phase Diagram
A3
A1
43
Lever Rule
where
a is the weight percentage of element B in the α phase
b is the weight percentage of element B in the β phase
c is the weight percentage of element B in the entire alloy
all at some fixed temperature. 44
Sample Problem 1
Calculate the fraction of each phases of steel composed of iron and 0.25%
carbon just above and below the eutectoid isotherm (727 deg C).
Solution:
At a temperature just above 727 degree, all the austenite will have a carbon
content of 0.8% and will transform to pearlite (also have carbon content 0.8%).
The ferrite will remain as primary ferrite.
45
Sample Problem 1
At a temperature just below 727 degree, all the austenite have been transformed
to pearlite (also have carbon content 0.8%). Hence the calculation results are the
same as before, except austenite should be replaced by pearlite.
However, if you are asked what are the factions of ferrite and iron carbide when
temperature is just below 727 degree, what would be your answer?
46
Sample Problem 1
Ferrite + Cementite(Fe3C)
47
Sample Problem 1
At a temperature just below 727 degree, the ferrite (0.025% Carbon) and iron
carbide fraction (6.7% Carbon):
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Cold working and heat treatment of steel
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Change in mechanical properties associated with cold
work or strain hardening
s2
s1’
s1
Percentage elongation
Tensile strength
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Strain hardening
Cold working
(rolling)
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Strengthening by grain boundaries
Dislocation pileups at grain boundaries indicate these boundaries are very strong
obstacles to dislocation motion
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Annealing
Objectives:
Refine the grain
Soften the steel
Remove internal stresses/gases
Increase ductility and toughness Cold rolling
Change electrical and magnetic properties
Full annealing
To put a hypoeutectoid steel into the softest possible condition (ductile).
Itinvolves heating the steel at about 50°C above the upper critical
temperature (followed by slow cooling within a furnace. This produces a coarse
pearlite structure).
54
Schematic representation of heat treatment process for
a hypoeutectoid steel
60°C
50°C
55
Changes in mechanical properties occurring during
annealing
Percentage elongation
Percentage elongation
Tensile strength
Annealing temperature
56
Normalising
Very similar to annealing, except slight difference in heating temp (higher)
and rate of cooling (faster).
This involves heating the steel at about 60°C above the upper critical
temperature followed by cooling in still air.
The faster rate of cooling gives a finer pearlite structure and the steel, while
relatively soft and ductile, is somewhat harder than full annealed material.
57
Quenching (Hardening)
A steel is hardened by rapidly quenching the steel, from a high temperature,
into water or oil. The very rapid cooling through the critical temperatures
causes the formation of martensite (very hard but brittle microstructure).
Tempering
Hardened steels may be tempered by heating within the range 200- 700°C.
This treatment will remove internal stresses created by quenching, reduce
the hardness, and increase the toughness and ductility of the steel.
The higher the tempering temperature, the greater will be the reduction in
hardness and the increase in toughness.
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Effects of tempering
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Engineering behaviour and properties
Tensile test
Failure mode
Toughness
Ductile-Brittle transition temperature
Hardness
Fatigue
60
Tensile Test
www.instron.com.br
https://www.mtu.edu/materials/k12/experiments/tensile/
61
Stress-strain curves for some metals
High-tensile steel
Tensile stress N/mm2
Copper
Lead
Strain percent
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Failure modes
Failure by yielding
Some metals are highly ductile with considerable plastic deformation
before failure.
Ductile yielding failure are always preferred in engineering
application as it will give adequate warning to the users before
catastrophic failure.
Failure by fracture
Most materials contain internal cracks and other defects, and these
can act as points of local stress concentration.
When a material is subject to a stress, any cracks within it can
propagate and may lead to catastrophic fracture before the yield
condition.
Even with ductile material like steel, low temperature can also
induce brittle fracture failure.
63
Toughness
64
Impact performance of brittle and ductile materials
Curve A
Brittle material
Stress Curve B
Ductile material
Stress
Strain
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Charpy V-notch impact test
Starting position
Hammer
Specimen
66
Plot of defect size against stress for a material
Applied stress
Failure by
yielding
Failure by fast fracture
Critical
size Defect size
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Fracture mechanics
Critical stress to cause crack propagation in brittle materials for plane
stress conditions is
1
s c KIC /(a) 2
Where
σ c is the critical stress for fracture,
a is one-half the crack length,
KIc is a fundamental property of a material and is termed fracture
toughness (also critical stress intensity factor).
68
The stresses at a crack tip were proportional to (a)-1/2. For an elliptical shaped flaw under plane stress
conditions in a plate of infinite size, the stress intensity factor (Dowling 1999),
KI = Ms (a)1/2
where M is a geometry factor to take account of varying flaw shapes and finite boundaries. Sudden fast
fracture will occur when KI reaches some critical value KIC. This critical stress intensity factor, KIC = (GCE)1/2,
is a constant of the material. It is also termed the fracture toughness of the material.
Note that there are three modes of cracking and mode I is the easiest
Ductile-brittle transition
69
Source : Jackson and Dhir 1996
Oil pipeline on fire
https://www.youtube.com/watch?v=zCy5WQ9S4c0
71
The Titanic Tragedy
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Effect of carbon and manganese content on the
ductile-brittle transition temperature of steel
Cv / J
Temperature 0C
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Hardness test
• Hardness is a measure of a material’s resistance to localized plastic deformation, such as
a dent or scratch on the surface of the material;
• All tests are very similar, either by measuring area or depth of indenter (penetrator) and
then related to a hardness index number;
• Hard material small impressions high hardness number;
• A relative number, needed to be converted between different methods via tables;
• Can be used to approximate the tensile strength of the material;
• A certain hardness is required for many machine parts and tools.
http://www.qualitydigest.com/april04/articles/01_article.shtml 74
Effects of carbon content on the hardness of the various
steel microstructure
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Source : Dowling 1988
Fatigue
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Types of stress-cycles
Repeating
Alternating
Fluctuating
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Operations and importance of container quay crane
https://www.youtube.com/watch?v=UuvkrEg
t0TM&hl=en-GB&gl=SG
78
S-N curves (alternating)
(i) metal showing fatigue limit e.g. steel
(ii) metal showing no fatigue limit e.g. aluminium
Stress s
80
Cyclic Loading
R = -1: complete reversal of load
samp
R = 0: zero to full tensile load
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S-N Curve
1ksi = 6.9MPa
82
Fracture Mechanics Approach
83
Fatigue-Crack Propagation
af
Crack Length, a
ai
Number of Cycles
84
Fatigue Crack Growth Influencing Factors
86
Paris’ Law for Fatigue Crack Propagation
Experimental Data suggests
da
ln C n ln ( K
dN
da
C ( K
n
(The formula was introduced
dN by P. C. Paris in 1961)
C and n are material constants
units:
acr
da a: one-half crack length,
N
ao
C ( K ) n
metre
KI: stress intensity factor,
MPa√m
87
Designing Against Fatigue Fracture
Based on inspection results, assume a
maximum flaw size ao
With calibrated KI, and known KIC, compute
critical crack length acr
With known load range s, obtain expression
for K using calibrated KI
Determine C and n for given material from
fatigue test (or look up material property
database)
Integrate crack growth equation to obtain
fatigue life
88
Design Example 1
Assume following conditions
A514 high strength steel, sys=690 MPa; KIC = 165
MPa√m; C = 1.35x 10-10 m/(MPa√m)n per cycle;
n=2.25
ao=7.6mm, edge crack in tension (M=1.12)
smax = 310 MPa; smin = 172 MPa; s = 138 MPa
KI = 1.12 s√(a); KI = 1.12 s√(a)
2
K IC
acr 2.8in = 71.9mm
0.0719m
1.12 s
max
Nf = 87,470 cycles using Eq. for N (two pages
back)
89
Design Example 2
Assume following conditions
A large steel crankshaft, KIC = 45 MPa√m; C =
1.5x 10-12 m/(MPa√m)n per cycle; n=2.5
ao=2.5 mm, assume M=1.0 (Centre crack)
smax = 225 MPa (tensile); smin = 60 MPa (comp);
s = 225 MPa (??)
KI = 1.0 s√(a); KI = 1.0 s√(a)
2
K IC
acr 2.8in = 12.7mm
0.0127m
1.12
1.0 s max
Nf = 1,253,768 (~1.25x106) cycles using Eq. for
N (three pages back)
90
Design Example continue
Can compute a vs N curve
a a
da
N
ao
C ( K ) n
Nf N
Can compute S-N curve
S = s –>KI 2
K IC
S-N curve smax –>acr acr
M s max
1.12
acr
da
Nf
ao
C (K ) n S
N
91
Alternative approach to calculate a-N relation
1. Begin with initial crack length; N = 0 cycle;
2. Assume crack length increment a (e.g. 1% increase)
(m);
3. Calculate K (MPa√m) for given s (MPa);
4. Calculate da/dN using Paris Law (m/cycle);
5. Calculate N (cycles)
6. Update N = N + N (cycles);
7. Update crack length a = a + a (m);
8. Calculate new Kmax (at smax) (MPa√m)
9. Check if Kmax = KIC; If so, N = Nf, stop. Otherwise,
10. Continue iteration by incrementing crack length (step 2)
to obtain a-N relation.
92
Approaches to Extend Service Life
93
Construction steel products
In civil and structural engineering the vast majority of the steels used are
plain carbon steels, or slightly modified plain carbon steels.
Plain carbon steels are those alloys with compositions up to 2% by weight
of carbon. They are cheap compared to alloy steel.
Low carbon steels, which contain up to 0.3% carbon, are generally used in
the normalised, cold worked, or cold worked and annealed conditions.
Low carbon steels are also weldable and this makes them extremely useful
for large structures such as ships and bridges.
Medium carbon steels are those which contain between 0.3 and
0.6% carbon, and these may be hardened and tempered.
High carbon steels (or tool steels) contain more than 0.6% carbon, and are
always used in the hardened and tempered condition.
94
Some properties for weldable structural steels other than hollow section (BS EN 10025-2)
95
Notes on structural steel
96
Factors on selection of structural steel
the tensile & yield strength required;
the toughness, ductility and other properties
required;
the availability and cost; and
arbitrary local conditions as may be imposed by
specifications and codes of practice.
97
Steel stress-strain curves at high temperatures
Strength/stiffness reduction
factors for elastic modulus and
yield strength (2% strain).
https://www.youtube.com/watch?v=PK_iBYSqEsc
98
Welding - Some types of welds
99
Heat affected zone (HAZ)
This changes the properties of parent metal in the vicinity of the weld, the
so-called heat-affected-zone (HAZ).
The micro structural changes in this region can be considerable and are
generally accompanied by a deterioration of its mechanical properties.
These changes depend on
(1) the composition of the parent metal,
(2) its original condition, and, possibly,
(3) the cooling rate after the weld.
100
Variation of structure and properties across a weld in a
low carbon steel
Fine ferrite +
Very fine
pearlite Normalised
ferrite + pearlite
structure
101
Weldability
The value of CE should not exceed about 0.25 for heavy structural steels; if
not, controlled cooling of the weld is necessary to avoid risks of
embrittlement.
102
Welding defects
(a) good weld (b) incomplete fusion, lack of penetration (c) excess
penetration and overlap (d) gas porosity and inclusions (e) undercut
Lack of penetration
(a) (b)
Overlap Porosity
Porosityor inclusions
or inclusions
Loss of
section
103