Bme Notes
Bme Notes
UNIT-1
THERMODYNAMICS
Thermodynamics is the branch of science that deals with energy transfer and
its effect on the state or condition of the system.
Thermodynamics, basically entails four laws known as Zeroth, First, Second
and Third law of thermodynamics.
Zeroth law deals with thermal equilibrium, relates to the concept of
equality of temperature.
First law pertains to the conservation of energy and introduces the
concept of internal energy.
Second law relates the direction of flow of heat, dictates limits on the
conversion of heat into work and introduces the principle of increase of
entropy.
Third law defines the absolute zero of entropy
These laws are based on experimental observations and have No
Mathematical Proof.
All activities in nature involve some interaction between energy and matter;
thus, it is hard to imagine an area that does not relate to thermodynamics in
some manner.
Thermodynamics is commonly encountered in many engineering systems and
other aspects of life, and one does not need to go very far to see some
application areas of it. In fact, one does not need to go anywhere. The heart is
constantly pumping blood to all parts of the human body, various energy
conversions occur in trillions of body cells, and the body heat generated is
constantly rejected to the environment. The human comfort is closely tied to
the rate of this metabolic heat rejection. We try to control this heat transfer
rate by adjusting our clothing to the environmental conditions.
Some of the selected areas of application of engineering thermodynamics are:
Automobile engines
Turbines, Compressors & Pumps
Propulsion system for aircraft and rockets
Combustion systems
HVAC systems: Vapor compression & absorption refrigeration, Heat pumps
Cooling of electronic equipments
Power stations: Nuclear, Thermal, etc.
Alternative energy systems
Biomedical applications: Life-support systems, Artificial organs
System:
Suroundings:
Boundary:
The real or imaginary surfaces which separates the system and surroundings is called
boundary. The real or imaginary surfaces which separates the system and surroundings is
called boundary.
On the basis of mass and energy transfer the thermodynamic system is divided into three
types.
1. Closed system
2. Open system
3. Isolated system
Closed system: A system in which the transfer of energy but not mass can takes place across
the boundary is called closed system. The mass inside the closed system remains constant.
For example: Boiling of water in a closed vessel. Since the water is boiled in closed vessel so
the mass of water cannot escapes out of the boundary of the system but heat energy
continuously entering and leaving the boundary of the vessel. It is an example of closed
system.
Open system: A system in which the transfer of both mass and energy takes place is called
an open system. This system is also known as control volume
For example: Boiling of water in an open vessel is an example of open system because the
water and heat energy both enters and leaves the boundary of the vessel.
Isolated system: A system in which the transfer of mass and energy cannot takes place is
called an isolated system.
For example: Tea present in a thermos flask. In this the heat and the mass of the tea cannot cross
the boundary of the thermos flask. Hence the thermos flak is an isolated system.
Thermodynamic Equilibrium:
Property:
Process:
When the system undergoes change from one thermodynamic state to final state due change
in properties like temperature, pressure, volume etc, the system is said to have undergone
thermodynamic process.
Various types of thermodynamic processes are: isothermal process, adiabatic process,
isochoric process, isobaric process and reversible process.
Cycle:
Thermodynamic cycle refers to any closed system that undergoes various changes due to
temperature, pressure, and volume, however, its final and initial state are equal. This cycle is
important as it allows for the continuous process of a moving piston seen in heat engines and
the expansion/compression of the working fluid in refrigerators, for example. Without the
cyclical process, a car wouldn't be able to continuously move when fuel is added, or a
refrigerator would not be able to stay cold.
Visually, any thermodynamic cycle will appear as a closed loop on a pressure volume
diagram.
Examples: Otto cycle, Diesel Cycle, Brayton Cycle etc.
Reversibility:
Reversibility, in thermodynamics, a characteristic of certain processes (changes of a system
from an initial state to a final state spontaneously or as a result of interactions with other
systems) that can be reversed, and the system restored to its initial state, without leaving net
effects in any of the systems involved.
An example of a reversible process would be a single swing of a frictionless pendulum from
one of its extreme positions to the other. The swing of a real pendulum is irreversible because
a small amount of the mechanical energy of the pendulum would be expended in performing
work against frictional forces, and restoration of the pendulum to its exact starting position
would require the supply of an equivalent amount of energy from a second system, such as a
compressed spring in which an irreversible change of state would occur.
Irreversible Process:
The irreversible process is also called the natural process because all the processes occurring
in nature are irreversible processes. The natural process occurs due to the finite gradient
between the two states of the system. For instance, heat flow between two bodies occurs due
to the temperature gradient between the two bodies; this is in fact the natural flow of heat.
Similarly, water flows from high level to low level, current moves from high potential to low
potential, etc.
In the irreversible process the initial state of the system and surroundings cannot be
restored from the final state.
During the irreversible process the various states of the system on the path of change
from initial state to final state are not in equilibrium with each other.
During the irreversible process the entropy of the system increases decisively and it
cannot be reduced back to its initial value.
The phenomenon of a system undergoing irreversible process is called as
irreversibility.
Causes of Irreversibility:
Friction: Friction is invariably present in real systems. It causes irreversibility in the process
as work done does not show an equivalent rise in the kinetic or potential energy of the
system. The fraction of energy wasted due to frictional effects leads to deviation from
reversible states.
Free expansion: Free expansion refers to the expansion of unresisted type such as expansion
in a vacuum. During this unresisted expansion the work interaction is zero, and without the
expense of any work, it is not possible to restore initial states. Thus, free expansion is
irreversible.
Heat transfer through a finite temperature difference: Heat transfer occurs only when there
exist temperature difference between bodies undergoing heat transfer. During heat transfer, if
heat addition is carried out in a finite number of steps then after every step the new state shall
be a non-equilibrium state.
Nonequilibrium during the process: Irreversibilities are introduced due to lack of
thermodynamic equilibrium during the process. Non-equilibrium may be due to mechanical
inequilibrium, chemical inequilibrium, thermal inequilibrium, electrical inequilibrium, etc.
and irreversibility is called mechanical irreversibility, chemical irreversibility, thermal
irreversibility, electrical irreversibility respectively. Factors discussed above are also causing
non-equilibrium during the process and therefore make process irreversible.
Heat:
It is the energy in transition between the system and the surroundings by virtue of the
difference in temperature Heat is energy transferred from one system to another solely by
reason of a temperature difference between the systems. Heat exists only as it crosses the
boundary of a system and the direction of heat transfer is from higher temperature to lower
temperature. For thermodynamics sign convention, heat transferred to a system is positive;
Heat transferred from a system is negative.
Work:
Thermodynamic definition of work: Positive work is done by a system when the sole effect
external to the system could be reduced to the rise of a weight.
Work done BY the system is positive and work done ON the system is negative.
Path function depends on history of the system (or path by which system arrived at a
given state).
Examples for path functions are work and heat.
Path functions are not properties of the system, while point functions are properties
of the system.
Change in point function can be obtained by from the initial and final values of the
function, whereas path has to defined in order to evaluate path functions.
The Thermodynamics Zeroth Law states that if two systems are at the same time in thermal
equilibrium with a third system, they are in equilibrium with each other.
If an object with a higher temperature comes in contact with an object of lower temperature, it
will transfer heat to the lower temperature object. The objects will approach the same
temperature and in the absence of loss to other objects, they will maintain a single constant
temperature. Therefore, thermal equilibrium is attained.
If objects ‘A’ and ‘C’ are in thermal equilibrium with ‘B’, then object ‘A’ is in thermal
equilibrium with object ‘C’. Practically this means all three objects are at the same
temperature and it forms the basis for comparison of temperatures
Internal Energy
Through, Joule experiment what happen to energy between time it is added to water as work,
and time it is extracted to heat? Logic suggests that this energy contained in the water in
another form which called internal energy.
Internal energy refers to energy of molecules of substance which are ceaseless motion and
possess kinetics energy. The addition of heat to a substance increases this molecular activity,
and thus causes an increase in its internal energy. Work done on the substance can have the
same effect, as was shown by Joule. Internal energy cannot be directly measured; there are no
internal-energy meters. As a result, absolute values are unknown. However, this is not a
disadvantage in thermodynamic analysis, because only changes in internal energy are
required.
§(dQ – dW) = 0
§dQ = §dW
Corollary 1:
There exists property of closed system; the change in value of this property during the
process is given by the difference between heat supplied and work done.
dU = dQ - dW
Here E is property of system and is called as total energy that includes internal energy, kinetic
energy, potential energy, electrical energy, magnetic energy, chemical energy, etc.
Corollary 2:
For the isolated system, heat and work both interactions are absent (d Q = 0, d W = 0) and E =
constant. Energy can neither be created nor be destroyed; but, it can be converted from one
form to other.
Corollary 3:
Thermal Reservoir:
A thermal reservoir is a large system (very high mass x specific heat value) from which a
quantity of energy can be absorbed or added as heat without changing its temperature. The
atmosphere and sea are examples of thermal reservoirs. Any physical body whose thermal
energy capacity is large relative to the amount of energy it supplies or absorbs can be
modelled as a thermal reservoir. A reservoir that supplies energy in the form of heat is called
a source and one that absorbs energy in the form of heat is called a sink.
Heat Engine:
It is a cyclically operating device which absorbs energy as heat from a high temperature
reservoir, converts part of the energy into work and rejects the rest of the energy as heat to a
thermal reservoir at low temperature.
The working fluid is a substance, which absorbs energy as heat from a source, and rejects
energy as heat to a sink.
Schematic representation of Heat Engine
Heat pump:
A heat pump is a device that transfers heat energy from a source of heat to what is called a
heat sink. Heat pumps move thermal energy in the opposite direction of spontaneous heat
transfer, by absorbing heat from a cold space and releasing it to a warmer one. A heat pump
uses a small amount of external power to accomplish the work of transferring energy from the
heat source to the heat sink. The most common design of a heat pump involves four main
components – a condenser, an expansion valve, an evaporator and a compressor. The heat
transfer medium circulated through these components is called refrigerant.
The coefficient of performance, COP, of a refrigerator is defined as the heat removed from
the cold reservoir Qcold, (i.e. inside a refrigerator) divided by the work W done to remove the
heat (i.e. the work done by the compressor).
As can be seen, the better (more efficient) the refrigerator is when more heat Qcold can be
removed from the inside of the refrigerator for a given amount of work. Since the first law of
thermodynamics must be valid also in this case (Qcold + W = Qhot), we can rewrite the
above equation:
The COP for heating and cooling are thus different, because the heat reservoir of interest is
different. When one is interested in how well a machine cools, the COP is the ratio of the
heat removed from the cold reservoir to input work. However, for heating, the COP is the
ratio of the heat removed from the cold reservoir plus the input work to the input work:
medium to a high-temperature is called heat pump.
INTERNAL COMBUSTION ENGINES
An Engine is a device which transforms the chemical energy of a fuel into thermal energy and uses this
thermal energy to produce mechanical work. Engines normally convert thermal energy into mechanical work
and therefore they are called heat engines.
Heat engines can be broadly classified into :
i) External combustion engines ( E C Engines)
There are different types of IC engines that can be classified on the following basis.
Suction Stroke : During suction stroke, the piston is moved from the top dead centre to
the bottom dead centre by the crank shaft. The crank shaft is revolved either by the momentum of the flywheel
or by the electric starting motor. The inlet valve remains open and the exhaust valve is closed during this
stroke. The proportionate air-petrol
mixture is sucked into the cylinder due to the downward movement of the piston. This operation is represented
by the line AB on the P-V
V diagram. (Figure 3)
Compression Stroke: During compression stroke, the piston moves from bottom dead centre to the top dead
centre, thus compressing air petrol mixture. Due to compression, the pressure and temperature are increased
and is shown by the line BC on the P- V diagram. Just before the end ooff this stroke the spark - plug initiates a
spark, which ignites the mixture and combustion takes place at constant volume as shown by the line CD.
Both the inlet and exhaust valves remain closed during this stroke.
Working Stroke: The expansion of hot gase
gasess exerts a pressure on the piston. Due to this pressure, the piston
moves from top dead centre to bottom dead centre and thus the work is obtained in this stroke. Both the inlet
and exhaust valves remain closed during this stroke. The expansion of the gas is shown by the curve DE.
Exhaust Stroke: During this stroke, the inlet valve remains closed and the exhaust valve opens. The greater
part of the burnt gases escapes because of their own expansion. The drop in pressure at constant volume is
represented by the line EB. The piston moves from bottom dead centre to top dead centre and pushes the
remaining gases to the atmosphere. When the piston reaches the top dead centre the exhaust valve closes and
cycle is completed. This stroke is represented by the line BA on the P- V diagram. The operations are repeated
over and over again in running the engine. Thus a four stroke engine completes one working cycle, during this
the crank rotate by two revolutions.
Four Stroke Diesel Engine (Four Stroke Compression Ignition Engine
Engine— C.I.Engine)
The four stroke cycle diesel engine operates on diesel cycle or constant pressure cycle. Since ignition in these
engines is due to the temperature of the compressed air, they are also called comp
compression
ression ignition engines. The
construction and working of the four stroke diesel engine is shown in fig. 4, and fig. 5 shows a theoretical
diesel cycle. The four strokes are as follows:
Suction Stroke:: During suction stroke, the piston is moved from the to
topp dead centre to the bottom dead centre
by the crankshaft. The crankshaft is revolved either by the momentum of the flywheel or by the power
generated by the electric starting motor. The inlet valve remains open and the exhaust valve is closed during
this stroke. The air is sucked into the cylinder due to the downward movement of the piston. The line AB on
the P- V diagram represents this operation.
Compression Stroke: The air drawn at the atmospheric pressure during suction stroke is compressed to high
pressure
ssure and temperature as piston moves from the bottom dead centre to top dead centre. This operation is
represented by the curve BC on the P- V diagram. Just before the end of this stroke, a metered quantity of fuel
is injected into the hot compressed air in the form of fine sprays by means of fuel injector. The fuel starts
burning at constant pressure shown by the line CD. At point D, fuel supply is cut off, Both the inlet and
exhaust valves remain closed during this stroke
Working Stroke: The expansion of gases due to the heat of combustion exerts a pressure on the piston. Under
this impulse, the piston moves from top dead centre to the bottom dead centre and thus work is obtained in this
stroke. Both the inlet and exhaust valves remain closed during this stroke. The expansion of the gas is shown
by the curve DE.
Exhaust Stroke:: During this stroke, the inlet valve remains closed and the exhaust valve opens. The greater
part of the burnt gases escapes because of their own expansion. The vertical line EB represents the drop in
pressure at constant volume. The piston moves from bottom dead centre to top dead centre and pushes the
remaining gases to the atmosphere. When the piston reaches the top dead centre the exhaust valve closes and
the cycle is completed.
d. The line BA on the F
F- V diagram represents this stroke.
In two stroke cycle engines, the suction and exhaust strokes are eliminated. There are only two
remaining strokes i.e., the compression stroke and power stroke and thes
thesee are usually called upward
stroke and downward stroke respectively. Also, instead of valves, there are inlet and exhaust ports in
two stroke cycle engines. The burnt exhaust gases are forced out through the exhaust port by a fresh
charge which enters the cylinder nearly at the end of the working stroke through the inlet port. The
process of removing burnt exhaust gases from the engine cylinder is known as scavenging.
Upward Stroke : During the upward stroke, the piston moves from bottom dead centre to top dead centre,
compressing the air-petrol
petrol mixture in the cylinder. The cylinder is connected to a closed crank chamber. Due
to upward movement of the piston, a partial
vacuum is created in the crankcase, and a new charge is drawn into the crank case through the uncovered inlet
port. The exhaust port and transfer port are covered when the piston is at the top dead centre position as shown
in Figure 7 (b). The compressed charge is ignited in the combustion chamber by a spark provided by the spark
plug.
Downward Stroke: As soon as the charge is ignited, the hot gases force the piston to move downwards,
rotating the crankshaft, thus doing the useful work. During this stroke the inlet port is covered by the piston
and the new charge is compressed in the crank case as shown in the Figure 7(c) Further downward movement
of the piston uncovers first the exhaust port and then the transfer port as shown in Figure 7 (d). The burnt
gases escape through the exhaust port. As soon as the transfer port opens, the compressed charge from the
crankcase flows into the cylinder. The charge is deflected upwards by the hump provided on the head of the
piston and pushes out most of the exhaust gases. It may be noted that the incoming air-petrol mixture helps the
removal of burnt gases from the engine cylinder. If in case these exhaust gases do not leave the cylinder, the
fresh charge gets diluted and efficiency of the engine will decrease. The cycle of events is then repeated.
COMPARISON OF SI AND CI ENGINES
COMPARISON OF FOUR-STROKE AND TWO-STROKE ENGINES