UT-4A_Paper-2 (Code-B) JEE (Advanced) CoE (XII)-2022-23

20. A proton and an alpha particle are projected inside a uniform and transverse magnetic field with same
kinetic energy. A new term K is defined as ratio of radius and time period of revolution. Kp and K defines
2
 Kp 
the new term for proton and alpha respectively then value of   is ____
 K 

PART – II: CHEMISTRY

SECTION -1
Only One Option Correct Type
This section contains 6 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) out of
which ONLY ONE is correct.

21. Consider the following reaction

K 4 Fe  CN6   H2SO4  H2O 


K2SO4  FeSO4  NH4 2 SO4  gas 
 Conc 

Identify the correct statement with respect to the above reaction for 1 mole of K4[Fe(CN)6] reacted
(A) 5 moles of a gas is produced which turns lime water milky
(B) 6 moles of a gas is produced which has bond order of 3
(C) 5 moles of a gas is produced which is acidic in nature

(D) 6 moles of gas is produced having bond order 2

22. Identify the correct statement.

(A) Order of bond angles in Cl2O < OF2 < ClO2 < H2O

(B) Pb3O4 on reaction with conc. HNO3 acid forms Pb(NO3)2, PbO2 and H2O
(C) PCl3, SO2 and S2Cl2 are side products when P4 reacts with SO2Cl2

(D) CrO3, CrO, BeO are amphoteric oxides

23. Which of the following statement is correct?
(A) XeF6 is never kept in glass bottles because of formation of XeO3 which is explosive
(B) XeF6 on complete hydrolysis give XeOF4
(C) XeF4 forms pentagonal bipyramidal structure
(D) XeF4 reacts with SbF5 forming [XeF4]+ [SbF5]–
24. Incorrect statement regarding oxide of chlorine is
(A) Cl2O7 > Cl2O6 > ClO2 > Cl2O decreasing order of acidic strength
(B) Cl2O5 is anhydride of HClO3
(C) ClO2 is a mixed anhydride of HClO3 + HClO2
(D) F2 , Cl2 and Br2 each with water gives hydrohalic acid and hypohalous acid
25. Which of the following interhalogen compound does not exist?
(A) ClF
(B) ICl5
(C) BrF3
(D) FCl3

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26. For profitable extraction, which of the calcined ores can be reduced by carbon?
(A) Haematite
(B) Copper pyrite
(C) Sphalerite
(D) Argentite

SECTION – 2
One or More Options Correct Type
This section contains 5 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) out of
which ONE OR MORE is/are correct.

27. Which of the following statement(s) is/are correct about bleaching powder?
(A) The composition of bleaching power is Ca(OCl)2. CaCl2. Ca(OH)2.2H2O

(B) Bleaching powder reacts with CO2 and gives chlorine which accounts for its oxidizing and bleaching
action.

(C) With dilute acids it decomposes and gives chlorine which is known as available chlorine
(D) Oxidation state of chlorine in bleaching powder is +1 and –1

28. Select the incorrect statement(s) among the following

(A) BCl3 and PCl3 give similar type of reaction on hydrolysis

(B) BiCl3 and PCl3 give similar type of reaction on hydrolysis

(C) NCl3 and PCl3 give similar type of reaction on hydrolysis

(D) NF3 and PCl3 give similar type of reaction on hydrolysis

29. The correct statement about interhalogen compounds is/are
(A) ICl3 is an interhalogen compound which decomposes to ICl and Cl2 in gas phase
(B) Liquid ICl3 conducts electricity
(C) Hydrolysis of interhalogen compound gives oxyacid of more electronegative atom
(D) IF > BrF > ClF > ICl is order of thermal stability
30. Free energies of formation fG MgO(s) and CO(s) at 1273 K and 2273 K are given below

f G MgO  s   941 kJ/mol at 1273 K ....(i)

f G MgO  s   314 kJ/mol at 2273 K ....(ii)

f G  CO  s   439 kJ/mol at 1273 K ....(iii)

f G  CO  g   628 kJ/mol at 2273 K ....(iv)

On the basis of above data mark the correct options.

(A) Redox equation for reduction of MgO to Mg by C can be obtained by subtracting eq.(i) from eq.(iii)
(B) Reduction of MgO by C at 1273 K is not feasible as rG of reaction is positive
(C) Redox equation for reduction of MgO to Mg by C can be obtained by subtracting eq. (ii) from eq(iv)
(D) Reduction of MgO by C at 1273 K is not feasible as rG of reaction is negative

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UT-4A_Paper-2 (Code-B) JEE (Advanced) CoE (XII)-2022-23

31. Conc. HNO3 is added to the following test tubes labelled (i) to (iv)

Identify the correct statements about the elements present in test tubes.
(A) Fe and Zn are the only metals which produce H2 gas in (i)
(B) In (ii) active metals like Fe, Zn, Sn react to give NO2 gas
(C) In (iv) there can be a protein as Nitric acid with proteins gives yellow compound
(D) The oxidation state of metal in brown complex in test tube (iii) is (+1)

SECTION - 3
Paragraph Based Questions
This section contains 2 paragraphs. Each describing theory, experiment, data etc. Four questions relate to
two paragraphs with two questions on each paragraph. Each question of a paragraph has only one correct
answer among the four choices (A), (B), (C) and (D)

Paragraph for Question Nos. 32 and 33

Halogens or interhalogens combine with halide ions to form polyhalide ions. The most common example
of polyhalide formation has been provided by increased solubility of I2 in water in presence of KI due to
formation of triiodide ion I3 .

Complex ion such as I5 , I7 and I9 have also been reported. Many polyhalides are known which contain
two or three different halogen atoms

32. Identify the correct statement

(A) ICl2 and I3 have bent structure involving sp3d hybridization

(B) CsI3   CsI + I2 , Rb ICl2  

 RbCl + ICl

(C) I3 , ICl4  and BrF4  are square pyramidal involving sp3d hybridization

(D) Polyhalides are unstable crystalline compounds soluble in water

33. Identify the group(s) of species written in sequence of pseudo halides, polyhalide and interhalogen
respectively from left to right
(A) BeI2 ,SCN– ,IF7 (B) SCN– ,BrI2 ,IF5

(C) SCN– ,IF5 ,BrI2 (D) CN5 ,IF5 , BrI2

Paragraph for Question Nos. 34 and 35

Metals are extracted from their ores by a wide variety of techniques. The most common ores are oxides.
Most metals are obtained by direct treatment of their ores with chemical agents but extraction of certain
others require electrolysis.
Relative ease of extraction of metal from its oxide can be estimated using Ellingham diagram. The
diagram plots the free energies of formation of various oxides per mole of consumed oxygen as a
function of absolute temperature.

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JEE (Advanced) CoE (XII)-2022-23 UT-4A_Paper-2 (Code-B)

E  Cu + O2  Cu2O
D  2Zn + O2  2ZnO

34. Identify the correct statement about (A), (B) and (C)
(A) Line (C) represents formation of CO2 from C(s) as its S is positive
(B) Line (B) represents formation of CO from carbon as its S = 0
(C) Line (A) represents formation of CO2 from CO(g) as its S is negative
(D) The plots are independent of values of S
35. According to the above diagram which one of the following choices appears best for the reduction of ZnO
above 1000 K?
(A) ZnO + C  Zn + CO (B) ZnO + CO  Zn + CO2
(C) ZnO + C  Zn + CO2 (D) ZnO + CO2  Zn + CO2
SECTION-4
Matching Column Type
This section contains two questions. Each question contains two Columns (Column I and Column II). Column I has
four entries (A), (B), (C) and (D), Column II has five entries (P), (Q), (R), (S) and (T). Match the entries
in Column I with the entries in Column II. Each entry in Column I may match with one or more entries in Column II.
The OMR contains a 4 × 5 matrix whose layout will be similar to the one shown below:
For each entry in Column I, darken the bubbles of all the matching entries. For example, if entry (A) in Column I
matches with entries (Q), (R) and (T), then darken these three bubbles in the OMR. Similarly, for entries (B), (C)
and (D)
(A) (P) (Q) (R) (S) (T)
(B) (P) (Q) (R) (S) (T)
(C) (P) (Q) (R) (S) (T)
(D) (P) (Q) (R) (S) (T)

36. Match the nitrogen oxides given in Column-I with their properties given in Column-II

Column-I Column-II

(A) N2O (P) Colourless

(B) NO (Q) Brown gas
(C) NO2 (R) Acidic
(D) N2O5 (S) Neutral
(T) Laughing gas

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UT-4A_Paper-2 (Code-B) JEE (Advanced) CoE (XII)-2022-23

37. Match the Xenon compounds given in Column-I with their shapes and oxidation state given in Column-II

Column-I Column-II
(A) XeF2 (P) Distorted octahedral
(B) XeF4 (Q) T-shaped
(C) XeF6 (R) Square planar
(D) XeOF2 (S) Linear
(T) Having +4 oxidation state
SECTION-5
Integer Value Correct Type
This section contains 3 questions. The answer to each of the questions is a double-digit integer, ranging
from 00 to 99. The answer will have to be appropriately bubbled in the OMR as per the instructions as follows.
Examples- If the correct answer to question numbers X, Y and Z (say) are 76, 0 and 9 respectively, then
mark 76, 00 and 09 in OMR respectively

0 1 2 3 4 5 6 7 8 9
X
0 1 2 3 4 5 6 7 8 9

0 1 2 3 4 5 6 7 8 9
Y
0 1 2 3 4 5 6 7 8 9

0 1 2 3 4 5 6 7 8 9
Z
0 1 2 3 4 5 6 7 8 9

38. AXn is an interhalogen compound in which A is central element and X is a substituent element. Find out
the sum of all possible values of n.

39. Xenon reacts with fluorine in different molar ratio under different conditions giving different Xenon fluorine
compounds. Find out the value of X:Y where X is the mole ratio (Xe:F2) when Xe reacts with F2 forming
XeF4 and Y is the mole ratio (Xe:F2) when Xe reacts with F2 forming XeF6.

40. Copper can be extracted from its ore by self-reduction method. When 2 moles of cuprous oxide formed
by roasting of Cu2S undergo self-reduction X is the number of moles of copper metal formed and Y is the
coordination number of Zinc in the complex formed in the extraction of Ag by the following reactions

Ag2S + NaCN  Ag-Complex

Ag-Complex + Zn  Zn-Complex + Ag

then calculate the value of (X × Y).

PART – III: MATHEMATICS

SECTION -1
Only One Option Correct Type
This section contains 6 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) out of
which ONLY ONE is correct

 P4 
41. The value of P for which the function f  x     1 x 5  3 x  ln5, decreases for all real x is
 1 P 
 

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