Mole Ratio Redox

Christopher Kinzel, Ava Boyle, Eleanora Church, Jake Henderson
Determining the Mole Ratios in a Redox Reaction
A balanced chemical reaction equation gives the mole ratios of the reactants and the products as coefficients. When
some of the chemical formulas are not known, an experiment must be conducted to help determine the mole ratios.
We can also evaluate this reaction in terms of reduction-oxidation processes.
This experiment uses two common substances as the reactants: hypochlorite ion (OCl–) from household bleach and
thiosulfate ion (S2O32–), the active ingredient in a photographic “fixer” solution used to develop film. In the
reaction, hypochlorite ions oxidize the thiosulfate ions according to the unbalanced and incomplete reaction
equation below:
A OCl– + B S2O32– → products
It is possible to identify the coefficients, A and B, for the reactants, without knowing the products of the reaction.
The process that you will use to determine the coefficients is called continuous variations. You will prepare a series of
mixtures of the two reactants. Each mixture will have the same total volume and the same total number of moles of
reactants. The reaction is exothermic, thus the mixture that generates the most heat energy will be the reaction that
completely consumes both the hypochlorite and the thiosulfate ions. You will use this mixture to establish the
coefficients, and therefore the mole ratio, for the reaction.
OBJECTIVES
In this experiment, you will
● Measure the enthalpy change of a series of redox reactions.
● Determine the stoichiometry of an oxidation-reduction reaction in which the reactants are known but the
products are unknown.
MATERIALS
● Vernier computer interface ● two 25 mL graduated cylinders
● computer w/ Logger Pro ● two 50 mL graduated cylinders
● Temperature Probe ● plastic pipets
● Stir Station with stir bar ● stir rod Figure 1
● Electrode support clamp ● 0.50 M sodium hypochlorite, NaOCl, sol’n
● two 10 mL graduated cylinders ● 0.50 M sodium thiosulfate, Na2S2O3, solution in
● three 250 mL beakers 0.2 M sodium hydroxide, NaOH
SAFETY
Behavioral: Equipment: Chemical:
● No horseplay in the ● Always wash and clean NaOCl and Na2S2O3:

lab equipment before and ● Flammable
● Always wear proper after use ● If inhaled: breathe fresh air and do
protective equipment ● Be careful when not block airways
(goggles, apron, etc.) handling glass, and ● If ingested, rinse mouth and seek
● Follow steps immediately notify the medical attention
properly and in order teacher if it breaks ● If contact with skin occurs, rinse it
● Ask the teacher is ● Keep water away from off with water
there is an accident the computer and other ● If contact with eyes occurs, remove
or confusion electronic devices contacts (if you have them) and
rinse well for several minutes
Christopher Kinzel, Ava Boyle, Eleanora Church, Jake Henderson
PRE-LAB EXERCISE
Determine the chemical equation for the reaction between NaOCl and Na2S2O3. Balance this redox reaction using
the half-reaction method.
Na2S2O3 + 4NaOCl + 2NaOH → 2Na2SO4 + 4NaCl +H2O
PROCEDURE
1. Obtain and wear goggles.
2. Connect a Temperature Probe to Channel 1 of the Vernier computer interface. Connect the interface to the
computer with the proper cable.
3. Start the Logger Pro program on your computer. Open the file “09 Mole Ratio” from the Advanced Chemistry with
Vernier folder.
4. Obtain about 200 mL of each of the reactant solutions, NaOCl and Na2S2O3.
5. Measure out precisely 25.0 mL of the 0.50 M NaOCl solution. Pour this solution into a beaker.
6. Immerse the tip of the Temperature Probe, supported by the electrode support clamp (see Figure 1), in the
beaker of NaOCl solution.
7. Measure out precisely 25.0 mL of the 0.50 M Na2S2O3 solution. Note: Do not mix the two solutions yet.
8. Click to begin data collection. Let the program gather and graph a few initial temperature readings, and
then add the Na2S2O3 solution. Then turn the Stir Station on to a slow setting.
9. Data collection will stop after 3 minutes. You may click to end data collection before three minutes have
passed, if the temperature readings are no longer changing.
10. Examine the graph to calculate and record the maximum temperature change.
a. To determine the highest temperature, click the Statistics button, . The minimum and maximum
temperatures are listed in the statistics box on the graph. It may be necessary to examine the graph to
determine the initial temperature, if the minimum temperature is not suitable.
b. Open Page 2 of this experiment file by clicking on the Next Page button, . The table in this file is already
set up for you to enter data. In the first line in the table, enter the volume of hypochlorite for the trial you
just completed, as well as the temperature change, in °C.
c. Return to Page 1 of the experiment file.
11. Rinse out and dispose of the reaction mixture as directed.
12. Repeat the necessary steps to continue testing various ratios of the two solutions, keeping the total volume at
50.0 mL, until you have three measurements on either side of the ratio that produced the greatest temperature
change.
13. You may analyze the Page-2 graph (change in temperature vs. volume of hypochlorite)to determine the mole
ratio with intersecting lines:
a. Drag the mouse cursor across the linear region of data that precedes the maximum change in temperature, then
click on the Linear Fit button, . Repeat this for the data that follows the maximum change in temperature,
then click on the Linear Fit button, .
b. Choose Interpolate from the Analyze menu. Then move the mouse cursor to the volume reading where both
linear fits display the same temperature value.
14. Print a copy of your final Page 2 graph (change in temperature vs. volume of hypochlorite).
GRAPH:
RESULTS
1. Determine the whole number mole ratio of the two reactants. Use the information in the graph you created on
Page 2 of the experiment file (temperature change vs. volume of hypochlorite).
(0.5 M NaOCl)(0.04L) = 0.02 mol NaOCl
(0.5 M Na2S2O3)(0.01L) = 0.005 mol Na2S2O3
4:1 ratio
2. The molarities of the reactant solutions were equal in this experiment. Is this necessary, or even important, for
the success of the experiment?
If the molarity of the solutions were different, that would lead to more number of moles of a certain
reactant and that reactant would become the excess reactant. So, to get the correct balanced equation,
we need to maintain the same molarity for both the reactants.
3. Which solution was the limiting reactant in each trial?

The reactant with the least amount of moles was the limiting reactant in each trial.
4. Indicate what species undergoes oxidation, what species undergoes reduction as well as the oxidizing agent and
reducing agent.
The NaOCl undergoes oxidation and Na2S2O3 undergoes reduction. Na2S2O3 is the oxidizing agent
and NaOCl is the reducing agent.
5. Compare your experimental mole ratio to your pre-lab exercise balanced reaction. Does the mole ratio that you
determined in your experiment match the actual reaction equation’s coefficients for the two reactants? Explain,
especially if your mole ratios do not match the coefficients.
Yes, the mole ratios determined by the experiment matched the reaction equation’s coefficients.

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Christopher Kinzel, Ava Boyle, Eleanora Church, Jake Henderson

Determining the Mole Ratios in a Redox Reaction

● No horseplay in the ● Always wash and clean NaOCl and Na2S2O3:

Na2S2O3 + 4NaOCl + 2NaOH → 2Na2SO4 + 4NaCl +H2O

3. Which solution was the limiting reactant in each trial?

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