PVT Analysis Principles and Application
PVT Analysis Principles and Application
(eq. 6.1)
By specification of two variables, the third will be stipulated.
Single-Component System
Water is one of the most thoroughly studied chemical compounds.
Therefore, it is discussed as a single-component system in this context. The
possible phases are ice (solid state), water (liquid state) and steam (gaseous
state). The phase diagram in figure 6.1 illustrates at which state of the system -
characterized by p and T - two or all three phases are in equilibrium:
•The sublimation curve OA signifies the equilibrium between the solid
and vapor.
•The melting point curve OB combines the states of equilibrium between
the solid and liquid state.
•The vapor pressure curve OC specifies the states of the system at which
the liquid and vapor coexist. On this curve, the “wet” vapor is in equilibrium
with the “saturated” liquid.
• At the triple point O, all three phases are in equilibrium. In case of water,
the thermodynamical data at this point are p = 610.6 Pa and T = 273.16 K.
• The end point C of the vapor pressure curve is the critical point and
signifies the highest temperature and pressure at which the liquid and vapor
coexist (p2(H2O) =22.09 MPa, T= 647.15 K