Chesterton # 477-1 MSDS

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SAFETY DATA SHEET

in accordance with 1907/2006/EC (REACH, as amended by 453/2010/EC) 29 CFR 1910.1200 and WHMIS 2015
Revision date: 26 April 2018 Initial date of issue: 16 March 2010 SDS No. 1082-8a
SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
1.1. Product identifier
477-1
1.2. Relevant identified uses of the substance or mixture and uses advised against
A high quality carbon yarn pump and valve packing lubricated with Tetrafluoroethylene (PTFE). Applicable for many demanding
high temperature applications to 566°C (1050°F), with a wide chemical resistance range of pH 0 to 13.
1.3. Details of the supplier of the safety data sheet
Company: Supplier:
A.W. CHESTERTON COMPANY
860 Salem Street
Groveland, MA 01834-1507, USA
Tel.: +1 978-469-6446 Fax: +1 978-469-6785
(Mon. - Fri. 8:30 - 5:00 PM EST)
SDS requests: www.chesterton.com
E-mail (SDS questions): [email protected]
E-mail: [email protected]

Canada: A.W. Chesterton Company Ltd., 889 Fraser Drive,


Unit 105, Burlington, Ontario L7L 4X8 - Tel. 905-335-5055
EU: Chesterton International GmbH, Am Lenzenfleck 23,
D85737 Ismaning, Germany - Tel. +49-89-996-5460
1.4. Emergency telephone number
24 hours per day, 7 days per week
Call Infotrac: 1-800-535-5053
Outside N. America: +1 352-323-3500 (collect)
SECTION 2: HAZARDS IDENTIFICATION
2.1. Classification of the substance or mixture
2.1.1. Classification according to Regulation (EC) No 1272/2008 [CLP] / 29 CFR 1910.1200 / WHMIS 2015 / GHS
This product does not meet the criteria for classification in any hazard class according to Regulation (EC) No 1272/2008 on
classification, labelling and packaging of substances and mixtures.
2.1.2. Classification according to Directives 1999/45/EC and 1975/324/EEC
This product does not meet the criteria for classification in any danger category according to Directive 1999/45/EC on
classification, packaging and labelling of dangerous preparations.
2.1.4. Classification according to WHMIS 1988
D2B: Toxic materials causing other effects
2.1.5. Australian classification
Not classified as hazardous according to criteria of Safe Work Australia.
2.1.6. Additional information
For full text of R-phrases: see SECTIONS 2.2 and 16.
2.2. Label elements
Labelling according to Regulation (EC) No 1272/2008 [CLP] / 29 CFR 1910.1200 / WHMIS 2015 / GHS
Hazard pictograms: None
Signal word: None
Hazard statements: None
Precautionary statements: None

© A.W. Chesterton Company, 2015 All Rights Reserved. ® Reg. US Patent and TM Office Page 1 of 7
Product: 477-1
Date: 26 April 2018 SDS No. 1082-8a

Supplemental information: None


2.3. Other hazards
None expected in industrial use. PTFE is nonhazardous at ambient temperatures. At temperatures above 260°C (500°F), toxic
decomposition products may be emitted. Due to toxic decomposition, avoid smoking (wash hands to avoid transfer to tobacco
products) when handling PTFE products.
SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS
3.2. Mixtures
Hazardous Ingredients¹ % Wt. CAS No./ REACH Classification Classification
EC No. Reg. No. (CLP/GHS) (67/548/EEC)
Graphite/Carbon 75-85 7782-42-5 NA Not classified Not classified
231-955-3

Indications of danger acc. to 67/548/EEC: Not applicable

¹ Classified according to: * 29 CFR 1910.1200, 1915, 1916, 1917, Mass. Right-to-Know Law (ch. 40, M.G.L..O. 111F), California Proposition 65
* 1272/2008/EC, 67/548/EEC, 99/45/EC, REACH
* WHMIS 2015
* Safe Work Australia [NOHSC: 1008 (2004)]

SECTION 4: FIRST AID MEASURES


4.1. Description of first aid measures
Inhalation: If overcome by decomposition fumes, remove to fresh air. If not breathing, administer artificial respiration.
Contact physician.
Skin contact: Wash skin with soap and water. Contact physician if irritation persists.
Eye contact: Flush eyes for at least 15 minutes with large amounts of water. Contact physician if irritation persists.
Ingestion: not applicable
4.2. Most important symptoms and effects, both acute and delayed
PTFE is nontoxic at ambient temperatures. However, small quantities of toxic gases may be produced at temperatures above
260°C (500°F), due to decomposition. Inhalation of these decomposition products may cause temporary flu-like symptoms.
Graphite dust and carbon fibers may cause mechanical irritation of the skin, eyes and nasal passages. Repeated inhalation of
nuisance dust in excess of exposure limits over an extended period of time may result in injury to the lungs. Symptoms can include
cough, shortness of breath and decrease in pulmonary function.
4.3. Indication of any immediate medical attention and special treatment needed
Treat symptoms.
SECTION 5: FIRE-FIGHTING MEASURES
5.1. Extinguishing media
Carbon Dioxide, dry chemical, foam or water spray
5.2. Special hazards arising from the substance or mixture
Toxic fumes may be emitted at temperatures above 260°C (500°F).
5.3. Advice for firefighters
Recommend Firefighters wear self-contained breathing apparatus to protect against hazardous decomposition products.
Flammability Classification: not determined
HAZCHEM Emergency Action Code: 2 Z
SECTION 6: ACCIDENTAL RELEASE MEASURES
6.1. Personal precautions, protective equipment and emergency procedures
Avoid contamination of tobacco products. Utilize exposure controls and personal protection as specified in Section 8.
6.2. Environmental Precautions
No special requirements.

© A.W. Chesterton Company, 2015 All Rights Reserved. ® Reg. US Patent and TM Office Page 2 of 7
Product: 477-1
Date: 26 April 2018 SDS No. 1082-8a

6.3. Methods and material for containment and cleaning up


No special steps required. Nontoxic.
6.4. Reference to other sections
Refer to section 13 for disposal advice.
SECTION 7: HANDLING AND STORAGE
7.1. Precautions for safe handling
Do not smoke when handling product; wash hands after handling to avoid transfer to tobacco products.
7.2. Conditions for safe storage, including any incompatibilities
Store in a cool, dry area.
7.3. Specific end use(s)
No special precautions.
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1. Control parameters
Occupational exposure limit values
Ingredients OSHA PEL¹ ACGIH TLV² UK WEL³ AUSTRALIA ES⁴
ppm mg/m3 ppm mg/m3 ppm mg/m3 ppm mg/m3
Graphite 15 mppcf (resp) (resp) 2 (resp) 4 (resp) 3
(inhal) 10

¹ United States Occupational Health & Safety Administration permissible exposure limits.
² American Conference of Governmental Industrial Hygienists threshold limit values.
³ EH40 Workplace exposure limits, Health & Safety Executive
⁴ Adopted National Exposure Standards for Atmospheric Contaminants in the Occupational Environment [NOHSC:1003].
8.2. Exposure controls
8.2.1. Engineering measures
No special requirements. If using under extreme heat, use local exhaust.
8.2.2. Individual protection measures
Respiratory protection: Not normally needed.
Protective gloves: Recommended
Eye and face protection: Not normally needed.
Other: None
8.2.3. Environmental exposure controls
Refer to sections 6 and 12.

© A.W. Chesterton Company, 2015 All Rights Reserved. ® Reg. US Patent and TM Office Page 3 of 7
Product: 477-1
Date: 26 April 2018 SDS No. 1082-8a

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES


9.1. Information on basic physical and chemical properties
Physical state solid Odour not applicable
Colour black Odour threshold not determined
Initial boiling point not applicable Vapour pressure @ 20C None
Melting point not determined % Aromatics by weight None
% Volatile (by volume) None pH not determined
Flash point None Relative density not applicable
Method not applicable Weight per volume not applicable
Viscosity not applicable Coefficient (water/oil) not determined
Autoignition temperature not determined Vapour density (air=1) not applicable
Decomposition temperature not determined Rate of evaporation (ether=1) not applicable
Upper/lower flammability or not applicable Solubility in water insoluble
explosive limits
Flammability (solid, gas) not applicable Oxidising properties not applicable
Explosive properties not applicable
9.2. Other information
None
SECTION 10: STABILITY AND REACTIVITY
10.1. Reactivity
Refer to sections 10.3 and 10.5.
10.2. Chemical stability
Stable
10.3. Possibility of hazardous reactions
No dangerous reactions known under conditions of normal use.
10.4. Conditions to avoid
Extreme heat above 260°C (500°F).
10.5. Incompatible materials
Fluorine, Chlorine Trifluoride and related compounds and molten alkali metals.
10.6. Hazardous decomposition products
Carbon Monoxide, Carbon Dioxide, trace amounts of Hydrogen fluoride, Perfluorocarbon olefins, and other toxic fumes may be
evolved above 260°C (500°F).
SECTION 11: TOXICOLOGICAL INFORMATION
11.1. Information on toxicological effects
Primary route of exposure Inhalation (PTFE decomposition fumes), skin contact
under normal use:
Acute effects: PTFE is nontoxic at ambient temperatures. However, small quantities of toxic gases may be produced at
temperatures above 260°C (500°F), due to decomposition. Inhalation of these decomposition products may
cause temporary flu-like symptoms. Graphite dust and carbon fibers may cause mechanical irritation of the
skin, eyes and nasal passages.
Chronic effects: Repeated inhalation of nuisance dust in excess of exposure limits over an extended period of time may
result in injury to the lungs. Symptoms can include cough, shortness of breath and decrease in pulmonary
function.
Carcinogenicity: As per 29 CFR 1910.1200 (Hazard Communication), this product contains no carcinogens as listed by the
National Toxicology Program (NTP), the International Agency for Research on Cancer (IARC), the
Occupational Safety and Health Administration (OSHA) or Regulation (EC) No 1272/2008.
Aspiration hazard: Not applicable
Other information: None known
SECTION 12: ECOLOGICAL INFORMATION
Ecotoxicological data have not been determined specifically for this product. The information given below is based on a knowledge
of the components and the ecotoxicology of similar substances.
12.1. Toxicity
not determined

© A.W. Chesterton Company, 2015 All Rights Reserved. ® Reg. US Patent and TM Office Page 4 of 7
Product: 477-1
Date: 26 April 2018 SDS No. 1082-8a

12.2. Persistence and degradability


Graphite/Carbon: inorganic substance, exists in nature.
12.3. Bioaccumulative potential
not determined
12.4. Mobility in soil
Solid. Insoluble in water. In determining environmental mobility, consider the product's physical and chemical properties (see
Section 9).
12.5. Results of PBT and vPvB assessment
Not available
12.6. Other adverse effects
None known
SECTION 13: DISPOSAL CONSIDERATIONS
13.1. Waste treatment methods
Unused product is not a regulated waste. Dispose in accordance with local, state and federal regulations. Can be disposed in a
secure, properly licensed landfill. Check local, state and national/federal regulations and comply with the most stringent
requirement. This product is not classified as a hazardous waste according to 2008/98/EC.
European List of Wastes code: 06 13 99
SECTION 14: TRANSPORT INFORMATION
14.1. UN number
ADR/RID/ADN/IMDG/ICAO: NOT APPLICABLE
TDG: NOT APPLICABLE
US DOT: NOT APPLICABLE
14.2. UN proper shipping name
ADR/RID/ADN/IMDG/ICAO: NON-HAZARDOUS, NON REGULATED
TDG: NON-HAZARDOUS, NON REGULATED
US DOT: NON-HAZARDOUS, NON REGULATED
14.3. Transport hazard class(es)
ADR/RID/ADN/IMDG/ICAO: NOT APPLICABLE
TDG: NOT APPLICABLE
US DOT: NOT APPLICABLE
14.4. Packing group
ADR/RID/ADN/IMDG/ICAO: NOT APPLICABLE
TDG: NOT APPLICABLE
US DOT: NOT APPLICABLE
14.5. Environmental hazards
NOT APPLICABLE
14.6. Special precautions for user
NOT APPLICABLE
14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code
NOT APPLICABLE
14.8. Other information
NOT APPLICABLE

SECTION 15: REGULATORY INFORMATION


15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1. EU regulations
Authorisations under Title Not applicable
VII:
Restrictions under Title None
VIII:

© A.W. Chesterton Company, 2015 All Rights Reserved. ® Reg. US Patent and TM Office Page 5 of 7
Product: 477-1
Date: 26 April 2018 SDS No. 1082-8a

Other EU regulations: None


15.1.2. National regulations
US EPA SARA TITLE III Hazardous Materials Identification System (HMIS)
312 Hazards: 313 Chemicals: 4 = Severe Hazard HEALTH 0
3 = Serious Hazard
Immediate None 2 = Moderate Hazard FLAMMABILITY 0
1 = Slight Hazard
0 = Minimal Hazard
PHYSICAL HAZARD 1
* = See Section 8 Personal Protection *

Other national None


regulations:
15.2. Chemical safety assessment
No Chemical Safety Assessment has been carried out for this substance/mixture by the supplier.
SECTION 16: OTHER INFORMATION
Abbreviations ADN: European Agreement concerning the International Carriage of Dangerous Goods by Inland Waterways
and acronyms: ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road
ATE: Acute Toxicity Estimate
BCF: Bioconcentration Factor
CLP: Classification Labelling Packaging Regulation (1272/2008/EC)
ES: Exposure Standard
GHS: Globally Harmonized System
ICAO: International Civil Aviation Organization
IMDG: International Maritime Dangerous Goods
LC50: Lethal Concentration to 50 % of a test population
LD50: Lethal Dose to 50% of a test population
LOEL: Lowest Observed Effect Level
N/A: Not Applicable
NA: Not Available
NOAEL: No Observed Adverse Effect Level
NOEL: No Observed Effect Level
PBT: Persistent, Bioaccumulative and Toxic substance
(Q)SAR: Quantitative Structure-Activity Relationship
REACH: Registration, Evaluation, Authorisation and Restriction of Chemicals Regulation (1907/2006/EC)
RID: Regulations concerning the International Carriage of Dangerous Goods by Rail
SDS: Safety Data Sheet
STEL: Short Term Exposure Limit
STOT: Specific Target Organ Toxicity
TDG: Transportation of Dangerous Goods (Canada)
US DOT: United States Department of Transportation
vPvB: very Persistent and very Bioaccumulative substance
WEL: Workplace Exposure Limit
WHMIS: Workplace Hazardous Materials Information System
Other abbreviations and acronyms can be looked up at www.wikipedia.org.
Key literature references Commission de la santé et de la sécurité du travail (CSST)
and sources for data: European chemical Substances Information System (ESIS)
European Chemicals Agency (ECHA) - Information on Chemicals
Hazardous Substances Data Bank (HSDB)
Hazardous Substances Information System (HSIS)
Swedish Chemicals Agency (KEMI)
Procedure used to derive the classification for mixtures according to Regulation (EC) No 1272/2008:
Classification Classification procedure
Not applicable Not applicable
Relevant H-statements: None
Relevant R-phrases: None
Hazard pictogram names: None
Changes to the SDS in this revision: Sections 1.3, 2.1, 2.2, 3, 16.
Date of last revision: 26 April 2018
Further information: None

© A.W. Chesterton Company, 2015 All Rights Reserved. ® Reg. US Patent and TM Office Page 6 of 7
Product: 477-1
Date: 26 April 2018 SDS No. 1082-8a

This information is based solely on data provided by suppliers of the materials used, not on the mixture itself. No warranty is expressed or implied
regarding the suitability of the product for the user’s particular purpose. The user must make their own determination as to suitability.

© A.W. Chesterton Company, 2015 All Rights Reserved. ® Reg. US Patent and TM Office Page 7 of 7

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