Aryl Halides Nagic Notes

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A7 halids

pe pratioms
Haloreulion d eniere

h r e recls +Hc

dak

+Hc

e e
(slses) zekible
HTa)
eactia
HNNO
SHI+H T 3 Ho t 3

fme to
azent
Remole H2 b ing oidking
H s T f m e d coutine
time (wT, H)produc
usl
Mechan e+Fecl
c)d-Fed
c- Fecl
Fece HetFeh

d
FloFlom Phene

Io+Pl Lo+ Pocl, + Hc


hanol chloao BenJene

) RASchiq pno (e
+2%
+2H + 21
Vafburs choTe gernene
VapouM

FCm diJoniu_ salF


Nh
NaN+He
Bevnlene a i l e n i a m chbzide
o-

Anine

Sand m e He7 aactia)

+
uCN cN

P
3Y
3B slaNoytHe
-S
13

H
i8
GatteanM oacham

Hel/n Le+t

BP4+ N + B.
HBy

Halo genati@ d 7Te luene

CH3
Alcl
Cmina (maJo
Touen2

cH-

CH7 Ct2 J-BN G S


NBS

enjyl optide -BroMO


ScACcira mide
.
Cel6u1eM quid
chlono RevJene a
and Aslule in oate

Aluleoputc subshitakon Jtoactic


Inent tocndy
chbao 8enlane
7eactiom ot zoo tep,
BubaitutiaM
nleacleophlic doule
Pasntial
be c a u e c- bnd a c u s
Neke nanée
odnd due to
b - oH
)Diaplate wmeuat ONA
H
Nost
Naot

L 5 3 o oa t m
2 S6diuM
phanel
phanoxide
amins fou
b) Subsotian am
H

Preu

D s plle ment k ølKo 7au


oct
C op p S a l nla c
o t c oda 2o0C
Aniasle

Sodiu
Mettheide
)subsiJakm b-Cd ou
P 7 d i u e

Benga nüBaile
A

dr E )
R 2tR R - t 2Ny
CHX +2na t XeU7
CH-CH-X +2Na+ ACh-Cd cu CH-chzCu
+2x
x el , I

N' unH -FittEn aeackiom


t 2 r d a 4 clicu, Ctie
Twene

atk BetR

t2Nad

T+2atlo
0ajaul (R-J)
nu7naad

DEe
phon mege3ium

Jod-7
c h b u d e

Reackom i t_Meoy

3ooát
n l a s H , 350
C,

ok

6 T

+ U e l

alodoopl(a
cith
nde
Reachvhy

o
nddition zactiom (BenJzne
ina'on
nat'om

Alanlh
H)

Aline2 Cine
S u b s t i u t i o n

cdinect
&ubshi tutiom

Mechansm

+c
+

+NH

thH
+NH

+K menol
HE1T)
Na lh

(aJon mind)

NO NOv
NahNa
(mino)/

Mad)

Electnophsesubslkudim zaachttm
l a c d a y

Jalo n a t a

mino
(maT )

M a o .

itratidML

Sulphon e t i o n

-chlo no (3eniovne

Sulpuonc
awd -chlo iO
3evdaR
e del- cafts nlkqladi
othe paa cucin

Cel h
-chloao 4-choo
Tbuen Tuen

ma
ieden-C7ajt Acqukian
alea
el-c
2-chlo l o
9at hlorde
AT))
H c e t o p h e n a n e

-chloJO

Aceto phano/e

Me chand
alelgc4T-A Cu
cHa-( +Alc

Alclu
+Hc
Alclh
d

(na.

spe
heliclo cheuicel pro2tias
Ben
CH
Io t S+H
)
+ Soc
Bens plcohol

C ph-cH-CA
KoHp h - c 4 p - o t (en3-laleo)
hól/
f2-H

Le /phaure
Amnne

lcohel)A
CH2- - -
CHCoondá

fh-ed2-0-c+Nacl
cWzOnls

ph-o al)
ulliamso

lh-o
gc
( t o pPph
CooH

ce

(Majo7/
pol halo Kane^

hol Th
e

bio
PN Nafions

herk zth lco


M O A L

Llaatnq pouden
Caoc+ 4 taloH)z+dL

cU-CHoy +d CH

+Jc cel-- + 3 H
CHCHo
ehlota

Hdyoyt 2 CHd +(HCooa


+ Ca loH),
2 e-cHo
chonofaM

oM ACetone

CH--CH +3el eel- -C+34

ee-i-H+ ca(o 2Cucl(coo,Ca


F7om Cey Nedu citm ct Fe t Steam
Fe+Kzo Hel
24) cHch +
P u n e
Saple
chloofon t obtained

alkali
disdilation
d chloal hydnate sith
laOH Coola + Ho
+H
CH C

Phy cal Prepnhes

coih characteri'-
coleunles qnid
9 iA a

- btíe mell

Tn soble i Gsate

citTreen flamee
)Vapous SuAn

&)AMaeshetie
Cha Cal paopentes

in n
an to
tto
OProsena Ayht oxdied
edS r e d iih
n
, chlono forn
Poison phosgene. e oouted bottle.
w
co c l
cHac(o)
phojone

chls7ne saglke onlatned phosU, Gues


PPE i t h gloSolukon.
t Hl°2.
C>hita po
R e c k c f e o n

Zn+H
cHhc4He
CHe+2H
Ehan meleue
Z n t sleamtls] CHu + 3Hel.
eHc 6su

ehlounatt
oau.
)
Ssan F eely+ HC
cHcl+ d caLon Jefla cloaide

Trealed coith NaoH


dvolyss
+3Nac

CHC t 3Naol

laok H-l-o4
H
+ H cooNa

S o a i u w f m a l e
c ninatiaj

N-e-c + He
cHcl + NO
(Airo ch
chlono picain

a
In&echi cide )
ued

&)iH AetsMe
CH-C-c
CHch+ c
cd
chloetone

e)Heatin oih A Po ca de

HCECH+6
CHC+6Rj+ cCH
ACetlene

+3 Nad
H- C-o CH
+ (2HsoNa
e
SodiuM Thoxd
Eh 07ho-fomale
( A l amine steactiun

A +3Kel43 H,6
CH+ 3KoH
CAle)
Pumay amine phen
Canbylamne (7reten
ezgare
Alc ko C 2 H s - N = c

CHg-cHp-lH +CHlh
Eh cnblamine

Mechan8m

,e
H - c l + oH

ct BA electiophile

e - - e

, dy N
1

AlKoH

CHS
Remon -Tce m a n n acti(n
oH
OH
laoH cHO

phend Sality lel deyde cHO


P hdaoy
benzalde yde
Me chamiswM

4
c

H
OH

Hao

Pheuoide ton

C 2
L

cHoH} cH~
1 o

-2c
oH
H cHO
DoFo_
(EHIz)

e panat

+Hcoona+5
NaoH CHT, J
CcH2
+ ut +6 Todpun +5NaT+SHS

Ehonol

eHT, +3NAT + cHoo


i C + 3 T , _ * LenaoH
l- +3H

-cut3 +3a,° CHT t3T C o


CH

ProA71 fie
erallne kad.
detloto
9-Aa
in
in uare bdF souble
) t has einselaLle
- n c solvenbs
sleam Volakle
MP119, tA a
wxd as an antsepie
C T exlenvely
J d r e i n g woumdA
nLon Te a (hloaide
P r ep a a A h o y

e
oo
)CH +4e ce tHc
Exces
Sbele
alela1sbeds
AlelN
C2
t 3cl, ccly
calas
e e l y +ely+6S
CS223zcl

Pro pe kie
coloan le u t d havin
chonackeniske 3mell

-EAflnable and poihonouS


F {A nou
oluble
Solble tn
in
buF
) Tnsouble tn wote)
Tonac solvenfs
Solven da otls, fat
E Xtallent

oaXes and r e a s e s
kcwuca Pnoenies

SuPehafed cc t 2Hel
ccyH2o
Steam >sodcphosgene
haating e(oH)+ukel
ccly 4KsH un Alable

c(o H2o
2KoH ) K%loz
COt

SNacfÍO
Retme?1-Ti
eManu
3
+ nNacl+H20
pH
Salicye a i d ,
Phand
mechani^m

o
+ laoH

3OH
NaoU
oH
-3 cl
-Hyo
CeOA Ht rtooy
cnadhs oachicm
i e del
-

H+C i+cl+H

ale
( d i c h l o n o dighewl ethaue)

Ta Exkngushe

AndeN h e Mame Pynanee

R e a c h o m t h L

sbo 3celPL +256


2 5b/
3 ecl t
F Teons

he
The chlono fluono cALon
CompoLnds chy
ae knon a uons
nd 2 H

F LO Stable non toxic, non-on7OMV


wnaachUe. a ndd
eakiy iquefialle gases ases

Freon-2 £dlej Aed

lomenclature Freo

Freon 12 (ee
denote a toy
mumlen
)The tmt
Ths Second nuben donos te numlkn & F afo

amaivMin all aplated by el atow

CH- F O

Fruon 11
Fruon 2 CF2 ch
FTeon 1? CFac
CH FTuoV
Fruon 22 <2Fcly
Fruon 3 <2 F cl
on 2 c

iov22 can ixisk a

C-

Fon 1210 FdM1

ermt
7uon 13 (qPzclh)
Can

-el

FuOn 13 1o
FeoN I 2 I

Fruon-24 CoM txnt

- C

F70on 2212
3eacti
pakm pre ons (gwatA

cl 2 Sbel,
3cdy2 SbF CFz
F r e o n

as
)FreoNS
URed efrigeNonNonts,

in osol 6nd Joams.


n2elontS
7 np
eellants

e3oe layen doflecho


nten n the
chlaaofluns lbon) aN
Tebokenb7okeM
move Jo uppe kafen Jek
Mosphere
MoApherne

nadliaelian
Hhe U.V
doan
d o u n

137 Jas
i
ife time CFL-12
The the o n e
CFe desto
The de (omositiGn
Jaes
CP c + hv l t hG
d

C - H
lled
caled
bond ca
HCFC The F e o n s wi
at Iouen altituces
deslioyed
HCF , ane
tosphere- (oso
ne las )
bedon0 e y aaCh stna
Fo)-2 CHcl F
CHcl F2-
Ro 12 upheed b
)

d1
)
HFC-123 (ed-cF) wd a su^h tui
FOl makhM pleske goams
DD7

14 >CH-ecl

K
- cel
-
dichlono dphen
T Y chloz Ethan.

TwRAC2,2 his lh-chlono phan-1,,


Tuhlono 2trane.

buF po cwenJul

e o s a chea Spread
SPT2Od
toes hat
mesauu
MSechti de fo
han cANY 4phus
malania and ice

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