Aryl Halides Nagic Notes
Aryl Halides Nagic Notes
Aryl Halides Nagic Notes
pe pratioms
Haloreulion d eniere
h r e recls +Hc
dak
+Hc
e e
(slses) zekible
HTa)
eactia
HNNO
SHI+H T 3 Ho t 3
fme to
azent
Remole H2 b ing oidking
H s T f m e d coutine
time (wT, H)produc
usl
Mechan e+Fecl
c)d-Fed
c- Fecl
Fece HetFeh
d
FloFlom Phene
) RASchiq pno (e
+2%
+2H + 21
Vafburs choTe gernene
VapouM
Anine
+
uCN cN
P
3Y
3B slaNoytHe
-S
13
H
i8
GatteanM oacham
Hel/n Le+t
BP4+ N + B.
HBy
CH3
Alcl
Cmina (maJo
Touen2
cH-
L 5 3 o oa t m
2 S6diuM
phanel
phanoxide
amins fou
b) Subsotian am
H
Preu
Sodiu
Mettheide
)subsiJakm b-Cd ou
P 7 d i u e
Benga nüBaile
A
dr E )
R 2tR R - t 2Ny
CHX +2na t XeU7
CH-CH-X +2Na+ ACh-Cd cu CH-chzCu
+2x
x el , I
atk BetR
t2Nad
T+2atlo
0ajaul (R-J)
nu7naad
DEe
phon mege3ium
Jod-7
c h b u d e
Reackom i t_Meoy
3ooát
n l a s H , 350
C,
ok
6 T
+ U e l
alodoopl(a
cith
nde
Reachvhy
o
nddition zactiom (BenJzne
ina'on
nat'om
Alanlh
H)
Aline2 Cine
S u b s t i u t i o n
cdinect
&ubshi tutiom
Mechansm
+c
+
+NH
thH
+NH
+K menol
HE1T)
Na lh
(aJon mind)
NO NOv
NahNa
(mino)/
Mad)
Electnophsesubslkudim zaachttm
l a c d a y
Jalo n a t a
mino
(maT )
M a o .
itratidML
Sulphon e t i o n
-chlo no (3eniovne
Sulpuonc
awd -chlo iO
3evdaR
e del- cafts nlkqladi
othe paa cucin
Cel h
-chloao 4-choo
Tbuen Tuen
ma
ieden-C7ajt Acqukian
alea
el-c
2-chlo l o
9at hlorde
AT))
H c e t o p h e n a n e
-chloJO
Aceto phano/e
Me chand
alelgc4T-A Cu
cHa-( +Alc
Alclu
+Hc
Alclh
d
(na.
spe
heliclo cheuicel pro2tias
Ben
CH
Io t S+H
)
+ Soc
Bens plcohol
C ph-cH-CA
KoHp h - c 4 p - o t (en3-laleo)
hól/
f2-H
Le /phaure
Amnne
lcohel)A
CH2- - -
CHCoondá
fh-ed2-0-c+Nacl
cWzOnls
ph-o al)
ulliamso
lh-o
gc
( t o pPph
CooH
ce
(Majo7/
pol halo Kane^
hol Th
e
bio
PN Nafions
Llaatnq pouden
Caoc+ 4 taloH)z+dL
cU-CHoy +d CH
+Jc cel-- + 3 H
CHCHo
ehlota
oM ACetone
alkali
disdilation
d chloal hydnate sith
laOH Coola + Ho
+H
CH C
coih characteri'-
coleunles qnid
9 iA a
- btíe mell
Tn soble i Gsate
citTreen flamee
)Vapous SuAn
&)AMaeshetie
Cha Cal paopentes
in n
an to
tto
OProsena Ayht oxdied
edS r e d iih
n
, chlono forn
Poison phosgene. e oouted bottle.
w
co c l
cHac(o)
phojone
Zn+H
cHhc4He
CHe+2H
Ehan meleue
Z n t sleamtls] CHu + 3Hel.
eHc 6su
ehlounatt
oau.
)
Ssan F eely+ HC
cHcl+ d caLon Jefla cloaide
CHC t 3Naol
laok H-l-o4
H
+ H cooNa
S o a i u w f m a l e
c ninatiaj
N-e-c + He
cHcl + NO
(Airo ch
chlono picain
a
In&echi cide )
ued
&)iH AetsMe
CH-C-c
CHch+ c
cd
chloetone
e)Heatin oih A Po ca de
HCECH+6
CHC+6Rj+ cCH
ACetlene
+3 Nad
H- C-o CH
+ (2HsoNa
e
SodiuM Thoxd
Eh 07ho-fomale
( A l amine steactiun
A +3Kel43 H,6
CH+ 3KoH
CAle)
Pumay amine phen
Canbylamne (7reten
ezgare
Alc ko C 2 H s - N = c
CHg-cHp-lH +CHlh
Eh cnblamine
Mechan8m
,e
H - c l + oH
ct BA electiophile
e - - e
, dy N
1
AlKoH
CHS
Remon -Tce m a n n acti(n
oH
OH
laoH cHO
4
c
H
OH
Hao
Pheuoide ton
C 2
L
cHoH} cH~
1 o
-2c
oH
H cHO
DoFo_
(EHIz)
e panat
+Hcoona+5
NaoH CHT, J
CcH2
+ ut +6 Todpun +5NaT+SHS
Ehonol
ProA71 fie
erallne kad.
detloto
9-Aa
in
in uare bdF souble
) t has einselaLle
- n c solvenbs
sleam Volakle
MP119, tA a
wxd as an antsepie
C T exlenvely
J d r e i n g woumdA
nLon Te a (hloaide
P r ep a a A h o y
e
oo
)CH +4e ce tHc
Exces
Sbele
alela1sbeds
AlelN
C2
t 3cl, ccly
calas
e e l y +ely+6S
CS223zcl
Pro pe kie
coloan le u t d havin
chonackeniske 3mell
oaXes and r e a s e s
kcwuca Pnoenies
SuPehafed cc t 2Hel
ccyH2o
Steam >sodcphosgene
haating e(oH)+ukel
ccly 4KsH un Alable
c(o H2o
2KoH ) K%loz
COt
SNacfÍO
Retme?1-Ti
eManu
3
+ nNacl+H20
pH
Salicye a i d ,
Phand
mechani^m
o
+ laoH
3OH
NaoU
oH
-3 cl
-Hyo
CeOA Ht rtooy
cnadhs oachicm
i e del
-
H+C i+cl+H
ale
( d i c h l o n o dighewl ethaue)
Ta Exkngushe
R e a c h o m t h L
he
The chlono fluono cALon
CompoLnds chy
ae knon a uons
nd 2 H
lomenclature Freo
Freon 12 (ee
denote a toy
mumlen
)The tmt
Ths Second nuben donos te numlkn & F afo
CH- F O
Fruon 11
Fruon 2 CF2 ch
FTeon 1? CFac
CH FTuoV
Fruon 22 <2Fcly
Fruon 3 <2 F cl
on 2 c
C-
ermt
7uon 13 (qPzclh)
Can
-el
FuOn 13 1o
FeoN I 2 I
- C
F70on 2212
3eacti
pakm pre ons (gwatA
cl 2 Sbel,
3cdy2 SbF CFz
F r e o n
as
)FreoNS
URed efrigeNonNonts,
nadliaelian
Hhe U.V
doan
d o u n
137 Jas
i
ife time CFL-12
The the o n e
CFe desto
The de (omositiGn
Jaes
CP c + hv l t hG
d
C - H
lled
caled
bond ca
HCFC The F e o n s wi
at Iouen altituces
deslioyed
HCF , ane
tosphere- (oso
ne las )
bedon0 e y aaCh stna
Fo)-2 CHcl F
CHcl F2-
Ro 12 upheed b
)
d1
)
HFC-123 (ed-cF) wd a su^h tui
FOl makhM pleske goams
DD7
14 >CH-ecl
K
- cel
-
dichlono dphen
T Y chloz Ethan.
buF po cwenJul
e o s a chea Spread
SPT2Od
toes hat
mesauu
MSechti de fo
han cANY 4phus
malania and ice