Chapter 4 9th Class Long Questions

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Unit

4 Structure of Molecules

Long Answer Questions


QI. Define Ionic bond. How Ionic bond is formed in sodium chloride?
Ans: Definition
"A bond formed due to transfer of electron from one atom to another atom, is called
ionic bond".
Formation of sodium chloride
2Na —2NaC1
Sodium chloride is a simple compound formed from sodium (Z l) and chlorine
(Z = 17). The ground state electronic configuration of these elements is shown below:
IINa= 1s 2 , 2s 2 , 2p6 , 3s
-
= 1s2 , 2s 2 , 2p6 , 3s2 , 3p2
This shows that sodium has only OR") while chlorine has seven electrons in their
valence shells. Sodium has the tendency to lose valence Sheli electron and form a positive ion,
while chlorine has the tendency to gain an electron in its valence shell to form a negative
Na + e
catholi (sodium positiveion )

x • or CI
anion (chlotidc negative 1 on )

When sodium loses one electron it forms a Na+ ion, while CI- is formed when chlorine
gains that electron. Both these atoms are now oppositely charged ions. They stabilize
themselves by combining with each other due to electrostatic force of attraction between them
and a low energy state. (Na+ + Cl- —+NaCl)
Q2. What is Covalent Bond? Explain its different types with examples.
Ans. Covalent Bond:
"A bond which is formed due to mutual sharing of electrons is called covalent bond'
Types of covalent bonds
i. Single Covalent bond (-)
When one electron is contributed by each bonded atom, one bond pair is formed and
forms a single covalent bond. It is indicated by (-).
Examples of molecules with single covalent bonds are hydrogen (H2), chlorine (C12), methane
(CH4) etc.
H.xH H. + —H or H 2

H —C—H

ii. Double Covalent bond (=)

ni. Triple Covalent Bond (E)


When each bonded atom contributes three electrons, three bond pairs are shared and
a triple bond is formed. It is indicated by (9.
Example of molecules with triple covalent bonds are nitrogen (N2) and ethyne (C2H2).

Q3. Write a note on coordinate covalent bond.


Ans: Definition
"Coordinate covalent or dative covalent bonding is a type of covalent bonding in
which the bond pair of electrons is donated by one bonded atom only". It is also known as
Dative covalent bond?
Concept of donor and acceptor
An atom which donates the electron pair is called donor and an atom which accepts the
electron pair, is called acceptor. A small arrow (+) is usually used to indicate the formation of
coordinate covalent bond. The arrow head will toward an atom which usually accepts the
electron.
Formation of coordinate covalent bond in NH4+ radical
Nitrogen from ammonia molecule donates its lone pair of electrons to H+ in order to
form a coordinate covalent bond.

llx•rq:

Formation of coordinate covalent bond between NH3 and BF3


Nitrogen from ammonia molecule donates its Ione pair of electrons to the borÆi of

boron tnfluoride
molecule in order to form a coordinate covalent bond.
Q4. Differentiate between polar and non-polar covalent bond
Ans.
Non-polar covalent bond Polar covalent bond
A covalent bond is formed between two A covalent bond is formed between two
similar atoms (homo-atoms), the shared different types of atoms
pair of electrons is attracted by both the (hetro-atoms) then the bond pair of electron
atoms equally. will not be attracted equally by the bonded
atoms.
These bonds are formed by equal sharing These bonds are formed by equal sharing
of electron pair between the two bonding of electron pair between the two bonding
atoms having same electronegative values. atoms having different electronegative
values.
This type of bond is called a pure covalent This type of bond is called an impure
bond. covalent bond.
Example: The bond formation in 1--12, Example: The bond formation in C02, HCI,
C12, 02, N2 etc. HF, H20 etc.
Q5. Write a note on hydrogen bonding.
Ans. Definition
"The force of attraction between partially positive hydrogen atom of one molecule and
highly electronegative atom of another molecule is called hydrogen bonding" Explanation
Hydrogen bonding is a special type of intermolecular forces present in the permanently
polar molecules. This bonding can be considered unique dipole- dipole attraction. This force
of attraction develops between molecules that have a hydrogen atom bonded to a small, highly
electronegative atom with lone pairs of electrons such as nitrogen, oxygen and fluorine, The
covalent bond between hydrogen atom and other atom becomes polar enough to create a partial
positive charge on hydrogen atom and a partial negative charge on the other atom. The small
size and high partial positive charge on the hydrogen atom enables it to attract the partially
negative lone pair on the N, O or F atom of the other molecule.

a
between

Q6. Different between ionic and covalent compounds.


Ans. Ionic Compound Covalent bond

They consist of positive and negative They are neutral


Ions
u. The exist in solid state. ii. The exist in solids li Llids and 'ases.
111. They have high melting and boiling
Ili. They have comparatively low melting
oints. and boilin oints.
iv. Strong forces of attractions are present
IV. Weak forces are present between their
between their articles. articles.
v. They have definite shape. v. The have no definite sha e.
vi. They are formed usually when metal
vi. They are formed usually when nonmetal
react with non-metals. reacts with non-metals.
vii. Examples are: Sodium chloride, vii. Examples are: glucose, benzene etc
otassium chloride etc
Q.7. Write a note on Metallic Bond.
Ans. Metallic Bond
The metallic bond is defined as a bond formed between metal atoms (positively charged
ions) due to mobile or free electrons.
Explanation
In case of metals, the hold of nucleus over the outermost electrons is weak because of large
sized atoms and greater number of shells in between nucleus and valence electrons.
Furthermore, because of low ionization potentials, metals have the tendency to lose their outer
electrons easily. Resultantly, these loose or free electrons of all metal atoms move freely in the
spaces between atoms of a metal. None of these electrons is attached to any particular atom.
Either they belong to a common pool, or belong to all the atoms of that metal. Nuclei of metal
atoms appear submerged in sea of these free mobile electrons. These mobile electrons are
responsible for holding the atoms of metals together forming a metallic bond. A simple
metallic bond is shown in figure.

Fig. A schematic diagram of copper wire showing its positive nuclei (+) embedded in sea of
free electrons (o) making Metallic bonding

Short Answer Questions


Q.l. Why atoms form a chemical bond?
Ans. Atoms form a chemical bond to achieve stability by acquiring inert gas electron
configuration.
Q.2. Why noble gases are non-reactive in nature'?
Ans. The noble gases do have 2 or 8 electrons in their valence shells. It means that all the noble
gases have their valence shell completely filled. Their atoms do not have vacant space in their
valence shell to accommodate extra electrons. Therefore, noble gases do not gain, lose or share
electrons. That is why they are non-reactive, at ordinary conditions. Q.3. How an atom can
accommodate eight electrons in its valence shell?
Ans. An atom can accommodate eight electrons in Its valence shell in three ways
i. By giving valence shell electrons (if they are less four) to other atoms ii. By gaining
electrons from other atoms (if the valence shell has five or more electrons in it) iii. By sharing
valence electrons with other atoms Q.4. When atoms are considered to be unstable?
Ans. The atoms having less than 2 or 8 electrons in their valence shells are unstable.

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