Total Iupac Mains

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SINGLE OPTION CORRECT TYPE

1. Which of the following has a sp-hybridised carbon atom?


A) Cyclopropene B) Bicyclobutene C) Propadiene D) 1,3-butadiene

2. Which is the correct structure of 5, 6, 6-trimethyl-3-heptyne?

A) B)

C) D)

3. The compound having only primary hydrogen atoms is


A) Butane B) Isobutene C) Cyclohexane D) 2,3-dimethylbut-2-ene

4. Which of the following can be correct description of C6H14 ?


A) 2-methyl pentane : 2-tertiary, 2 secondary and 3 primary carbons.
B) 2, 3-dimethyl butane : 3-tertiary, 4 primary carbons.
C) 2,2-dimethyl butane : 1 quaternary, 1 secondary and 4 primary carbons.
D) 2-ethyl-2-methyl propane : 1 quaternary, 1 secondary and 4 primary carbons.

5. What is correct in the IUPAC name of a compound 4,4-dichloro-1-bromocyclohexane?


A) Locants positions are wrongly numbered.
B) Locants name are written in correct order.
C) Parent name is incorrect.
D) There is only one carbon without any hydrogen on it.

6. Which is wrong about C4H6 ?


A) It represents an alkyne B) It represents a diene
C) It represents a bicyclo compound D) It represents a spiro alkane

7. Which of the following pair of compounds do not have the same empirical formula?
A) Carboxylic acid-Acid anhydride B) Carboxylic acid-Ester
C) Aldehyde-Ketone D) Alcohols-Ethers

8. Which of the following cannot be IUPAC name of compound C4H8O2 ?


A) Butanoic acid B) Butanedial C) Ethylethanoate D) Methyl propanoate
9. Which of the following compounds has isopropyl group?
A) 2,2,3,3-tetramethylpentane B) 2,2-dimethylpentane
C) 2,2,3-trimethylpentane D) 2-methylpentane

10. Name of the compound given below is

A) 2,3-diethylheptane B) 3-methyl-4-ethyloctane
C) 5-ethyl-6-methyloctane D) 4-ethyl-3-methyloctane

O
11. What is the correct IUPAC name of O ?
A) Dioxy butane B) 2, 6-dioxy butane
C) 1, 2-dimethoxy ethane C) Dimethyl ethyl ether

12. The structure of 4-methylpent-2-en-1-ol is


A)  CH3 2 C  CHCH2CH 2OH B)  CH3 2 CHCH  CHCH2OH
C) CH3CH2CH  CHCH2OH D) CH3CHOHCH  C  CH3 2

13. The IUPAC name of is


H3C CH CH2 CH CH2Cl
C2 H 5 OH
A) 1-chloro-4-methylhexane-2-ol B) 1-chloro-4-methylhexan-2-al
C) 1-chloro-4-ethylpenta-2-ol D) 1-chloro-2-hydroxy-4-methylhexane

14. The IUPAC name of the following compound is


O C CH CH2
OH NH2 OH
A) 3-amino-2hydroxy propanoic acid B) 2-amino-propan-3-o1-1-oic acid
C) 2-amino-3-hydroxy propanoic acid D) Amino hydroxyl propanoic acid

15. An aldehyde has molecular formula C5H10O. Which cannot be an IUPAC name of this
aldehyde?
A) Pentanal B) 2-methyl butanal
C) 3-methyl pentanal D) 2, 2-dimethyl propanal
16. In which class for compounds will the following compound be named?
ClH2C CH CH2 C CH2NO2
OH O
A) Nitro compounds B) Alcohols C) Alkyl halides D) Ketones

17. The correct structure of 5-(2-chlorobutoxy) pentanoyl chlorides is


O Cl O

A) O Cl B) O Cl
Cl
O O

C) O Cl D) O Cl
Cl Cl

18. Ethanoyl chloride is the IUPAC name of


A) CH3CH2Cl B) CH3COCl C) CCl3CHO D) CH2ClCOOH

19. The IUPAC name of


H 5 C2 O
C O
H3C CH
CH3
A) Ethoxy methanone B) Ethyl-2-methyl propanoate
C) Ethoxypropanone D) 2-methyl ethoxy propanone

20. The IUPAC name of the following compound is


O
H 5C2
O
H3C
O
A) Propionic acetic anhydride B) Ethanoic propanoic anhydride
C) Aceto ethanoate D) Ethanoic anhydride
21. The IUPAC name of compound is

Cl

O
A) 2-ethyl-3-methyl butanoyl chloride B) 2,3-dimethyl pentanoyl chloride
C) 3,4-dimethyl pentanoyl chloride D) 1-chloro-1-oxo-2,3-dimethyl pentane
22. Which of the following is an incorrect name according to IUPAC?
A) 2-cyclopropyl butane B) 1-bromo-2, 2-dichloro cyclobutane
C) Cyclohexyl cyclohexane D) 1-cyclobutyl cyclobutane

23. What is the name of the following compound according to IUPAC convention?
O

O
A) 2-(1-methyl-2-oxopropyl) cyclopropanone.
B) 2-(2-oxopropyl) cyclopropanone.
C) methyl-(2-oxocyclopropyl) propanone.
D) 3-(2-oxocyclopropyl) butanone.

24. The IUPAC name of the following compound is

HO
A) 3,3-dimethyl-1-hydroxycyclohexane. B) 1,1-dimethyl-3-hydroxycyclohexane.
C) 3,3-dimethylcyclohexanol. D) 1,1-dimethyl-3-cyclohexanol.

25. What is the correct IUPAC name of the following compound?


CH3

A) 3, 5-diethenyl toluene B) 1, 3-diethenyl-5-methyl benzene


C) 3-ethenyl-5-methyl styrene D) 1, 3, 5-triethenylmethyl benzene

26. Which is the correct structural formula of 4-hydroxy benzene-1, 3-dicarbonitrile?

CN OH
CN
HO NC OH CN

A) B) C) D)
CN
NC OH
CN CN
27. The IUPAC name of the following compound is
OH

CN
Br
A) 4-bormo-3-cyanophenol B) 2-bromo-5-hydroxybenzonitrile
C) 2-cyano-4-hydroxybromobenzene D) 6-bromo-3-hydroxybenzonitrile

28. The IUPAC name of C 6H 5COCl is


A) Benzoylchloride B) Benzene chloroketone
C) Benzene carbonylchloride D) Chlorophenyl ketone

29. Which of the following compounds and their names are correctly matched?

OH
CHO

A) COOH B)
HO
2-formyl pentanoic acid
1,3-diethyl-1,4-butanediol
OH
O
CH C CH3
C) OH D)

3-hydroxymethyl 1,1-dicyclopropyl propanone


benzonitrile

30. Which of the following compounds has wrong IUPAC name?


H3C CH CH2 CHO H3C CH CH CH3
A) CH3 B) OH CH3
3-methylbutanal 2-methylbutan-3-ol
O

CH3CH2CH2COOCH2CH3 H3 C CH C C2 H5
C) D)
Ethylbutanoate CH3
2-methylpentan-3-one
1. C 2. C 3. D 4. D 5. D 6. D 7. A

8. B 9. D 10. D 11. C 12. B 13. A 14. C

15. C 16. D 17. A 18. B 19. B 20. B 21. B

22. B 23. D 24. C 25. B 26. D 27. B 28. A

29. D 30. B

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