Permaquik Crystalline Waterproofing

Version: 2.
2
Revision Date: 11/11/2022
SAFETY DATA SHEET

1. Identification
Material name: PQ-200 GREY CRYSTALLINE

Material: 878200G830
Recommended use and restriction on use

Recommended use: Cement, Portland, chemicals
Restrictions on use: Not known.
Manufacturer/Importer/Supplier/Distributor Information
Tremco Canadian Sealants
220 Wicksteed Ave
Toronto ON M4H 1G7
CA
Contact person: EH&S Department

Telephone: 1-800-263-6046
Emergency telephone number: 1-800-424-9300 (US); 1-613-996-6666 (Canada)
2. Hazard(s) identification
Hazard Classification
Health Hazards
Skin Corrosion/Irritation Category 2
Serious Eye Damage/Eye Irritation Category 1
Skin sensitizer Category 1
Carcinogenicity Category 1A
1.
Specific Target Organ Toxicity - Category 3
Single Exposure
2.
Specific Target Organ Toxicity - Category 1
Repeated Exposure
Target Organs
1. Respiratory tract irritation.
2. Lung
Unknown toxicity - Health

Acute toxicity, oral 86.7 %
Acute toxicity, dermal 86.7 %
Acute toxicity, inhalation, vapor 100 %
Acute toxicity, inhalation, dust 100 %
or mist
Label Elements
Hazard Symbol:
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Signal Word: Danger
Hazard Statement: Causes skin irritation.

Causes serious eye damage.
May cause an allergic skin reaction.
May cause cancer.
May cause respiratory irritation.
Causes damage to organs through prolonged or repeated exposure by
inhalation.
Precautionary
Statements
Prevention: Wash thoroughly after handling. Wear protective gloves/protective

clothing/eye protection/face protection. Contaminated work clothing should
not be allowed out of the workplace. Obtain special instructions before use.
Do not handle until all safety precautions have been read and understood.
Use personal protective equipment as required. Use only outdoors or in a
well-ventilated area. Do not breathe dust/fume/gas/mist/vapors/spray. Do
not eat, drink or smoke when using this product.
Response: IF INHALED: Remove person to fresh air and keep comfortable for
breathing. IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing. IF ON
SKIN: Wash with plenty of soap and water. If skin irritation or rash occurs:
Get medical advice/attention. Immediately call a POISON CENTER/doctor.
Specific treatment (see on this label). Wash contaminated clothing before
reuse.
Storage: Store locked up. Store in a well-ventilated place. Keep container tightly
closed.
Disposal: Dispose of contents/container to an appropriate treatment and disposal

facility in accordance with applicable laws and regulations, and product
characteristics at time of disposal.
Hazard(s) not otherwise None.

classified (HNOC):
3. Composition/information on ingredients
Mixtures
Chemical Identity CAS number Content in percent (%)*
Portland cement 65997-15-1 50 - <100%

Crystalline Silica (Quartz)/ Silica Sand 14808-60-7 20 - <50%
Sodium carbonate 497-19-8 10 - <20%
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Tartaric Acid 87-69-4 1 - <5%

* All concentrations are percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume.
4. First-aid measures
Description of necessary first-aid measures
Inhalation: Move to fresh air.
Skin Contact: Get medical attention. Destroy or thoroughly clean contaminated

shoes. Immediately remove contaminated clothing and shoes and
wash skin with soap and plenty of water. If skin irritation or an allergic
skin reaction develops, get medical attention.
Eye contact: Immediately flush with plenty of water for at least 15 minutes. If easy
to do, remove contact lenses. Call a physician or poison control
center immediately.
Ingestion: Call a POISON CENTER/doctor if you feel unwell. Rinse mouth.
Personal Protection for First- Self-contained breathing apparatus and full protective clothing must
aid Responders: be worn in case of fire.
Most important symptoms/effects, acute and delayed
Symptoms: Prolonged or repeated contact with skin may cause redness, itching,
irritation and eczema/chapping. Extreme irritation of eyes and mucous
membranes, including burning and tearing. Respiratory tract irritation.
Hazards: No data available.
Indication of immediate medical attention and special treatment needed
Treatment: Symptoms may be delayed.
5. Fire-fighting measures
General Fire Hazards: No unusual fire or explosion hazards noted.
Suitable (and unsuitable) extinguishing media
Suitable extinguishing Use fire-extinguishing media appropriate for surrounding materials.

media:
Unsuitable extinguishing Do not use water jet as an extinguisher, as this will spread the fire.
media:
Specific hazards arising from During fire, gases hazardous to health may be formed.
the chemical:
Special protective equipment and precautions for fire-fighters
Special fire-fighting No data available.

procedures:
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Special protective equipment Self-contained breathing apparatus and full protective clothing must be
for fire-fighters: worn in case of fire.
6. Accidental release measures
Personal precautions, See Section 8 of the SDS for Personal Protective Equipment. Do not touch
protective equipment and damaged containers or spilled material unless wearing appropriate
emergency procedures: protective clothing. Keep unauthorized personnel away.
Accidental release measures: In the event of a spill or accidental release, notify relevant authorities in
accordance with all applicable regulations.
Methods and material for Collect spillage in containers, seal securely and deliver for disposal
containment and cleaning according to local regulations.
up:
Environmental Precautions: Do not contaminate water sources or sewer. Prevent further leakage or
spillage if safe to do so.
7. Handling and storage

Handling
Technical measures (e.g. Local Mechanical ventilation or local exhaust ventilation may be required.
and general ventilation): Observe good industrial hygiene practices. Observe occupational exposure
limits and minimize the risk of inhalation of dust.
Safe handling advice: Ventilate well, avoid breathing vapors. Use approved respirator if air
contamination is above accepted level. Use mechanical ventilation in case
of handling which causes formation of dust.Wash hands thoroughly after
handling. Do not handle until all safety precautions have been read and
understood. Obtain special instructions before use. Use personal protective
equipment as required. Do not get in eyes. Avoid contact with skin. Avoid
contact with eyes, skin, and clothing.
Contact avoidance measures: No data available.
Hygiene measures: Observe good industrial hygiene practices. Wash hands before breaks and
immediately after handling the product. Do not get in eyes. Wash
contaminated clothing before reuse. Avoid contact with skin. Contaminated
work clothing should not be allowed out of the workplace.
Storage
Safe storage conditions: Store locked up.
Safe packaging materials: No data available.
8. Exposure controls/personal protection
Control Parameters
Occupational Exposure Limits
Chemical Identity Type Exposure Limit Values Source
Portland cement - Respirable TWA 1 mg/m3 US. ACGIH Threshold Limit Values, as
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fraction. amended (2011)

Portland cement - Total dust. PEL 15 mg/m3 US. OSHA Table Z-1 Limits for Air
Contaminants (29 CFR 1910.1000), as
amended (02 2006)
Portland cement - Respirable PEL 5 mg/m3 US. OSHA Table Z-1 Limits for Air
fraction. Contaminants (29 CFR 1910.1000), as
amended (02 2006)
Portland cement TWA 50 millions of US. OSHA Table Z-3 (29 CFR 1910.1000), as
particles per amended (2000)
cubic foot of
air
Crystalline Silica (Quartz)/ TWA 0.05 mg/m3 US. OSHA Specifically Regulated Substances
Silica Sand - Respirable dust. (29 CFR 1910.1001-1053), as amended (03
2016)
OSHA_AC 0.025 mg/m3 US. OSHA Specifically Regulated Substances
T (29 CFR 1910.1001-1053), as amended (03
2016)
Crystalline Silica (Quartz)/ PEL 0.05 mg/m3 US. OSHA Table Z-1 Limits for Air
Silica Sand - Respirable dust. Contaminants (29 CFR 1910.1000), as
amended (03 2016)
Crystalline Silica (Quartz)/ TWA 2.4 millions US. OSHA Table Z-3 (29 CFR 1910.1000), as
Silica Sand - Respirable. of particles amended (2000)
per cubic foot
of air
TWA 0.1 mg/m3 US. OSHA Table Z-3 (29 CFR 1910.1000), as
amended (2000)
Crystalline Silica (Quartz)/ TWA 0.025 mg/m3 US. ACGIH Threshold Limit Values, as
Silica Sand - Respirable amended (02 2020)
fraction.
Chemical name Type Exposure Limit Values Source
Portland cement - Total dust. TWA 10 mg/m3 Canada. Quebec OELs. (Ministry of Labor -
Regulation respecting occupational health and
safety), as amended (09 2017)
Portland cement - Respirable TWA 5 mg/m3 Canada. Quebec OELs. (Ministry of Labor -
dust. Regulation respecting occupational health and
Portland cement - TWA 1 mg/m3 Canada. British Columbia OELs. (Occupational
Respirable. Exposure Limits for Chemical Biological
Substances, Occupational Health and Safety
Regulation 296/97, as amended) (06 2017)
Portland cement - Respirable TWA 1 mg/m3 Canada. Ontario OELs. (Control of Exposure to
fraction. Biological or Chemical Agents), as amended
(08 2017)
Crystalline Silica (Quartz)/ TWA 0.10 mg/m3 Canada. Ontario OELs. (Control of Exposure to
Silica Sand - Respirable Biological or Chemical Agents), as amended
fraction. (06 2015)
Crystalline Silica (Quartz)/ TWA 0.1 mg/m3 Canada. Quebec OELs. (Ministry of Labor -
Silica Sand - Respirable dust. Regulation respecting occupational health and
Crystalline Silica (Quartz)/ TWA 0.025 mg/m3 Canada. British Columbia OELs. (Occupational
Silica Sand - Respirable Exposure Limits for Chemical Biological
fraction. Substances, Occupational Health and Safety
Regulation 296/97, as amended) (06 2020)
Appropriate Engineering Mechanical ventilation or local exhaust ventilation may be required.

Controls Observe good industrial hygiene practices. Observe occupational exposure
limits and minimize the risk of inhalation of dust.
Individual protection measures, such as personal protective equipment
Eye/face protection: Wear a full-face respirator, if needed. Wear safety glasses with side shields
(or goggles) and a face shield.
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Skin Protection
Hand Protection: Additional Information: Use suitable protective gloves if risk of skin contact.
Skin and Body Protection: Wear suitable protective clothing. Wear chemical-resistant gloves,
footwear, and protective clothing appropriate for the risk of exposure.
Contact health and safety professional or manufacturer for specific
information.
Respiratory Protection: In case of inadequate ventilation use suitable respirator. Seek advice from
local supervisor.
Hygiene measures: Observe good industrial hygiene practices. Wash hands before breaks and
immediately after handling the product. Do not get in eyes. Wash
contaminated clothing before reuse. Avoid contact with skin. Contaminated
work clothing should not be allowed out of the workplace.
9. Physical and chemical properties
Appearance
Physical state: solid
Form: Powder
Color: Gray
Odor: Odorless
Odor threshold: No data available.
pH: No data available.
Melting point/freezing point: No data available.
Initial boiling point and boiling range: No data available.
Flash Point: No data available.
Evaporation rate: No data available.
Flammability (solid, gas): No
Upper/lower limit on flammability or explosive limits
Flammability limit - upper (%): No data available.
Flammability limit - lower (%): No data available.
Explosive limit - upper: No data available.
Explosive limit - lower: No data available.
Vapor pressure: No data available.
Vapor density: No data available.
Relative density: 2.90
Solubility(ies)
Solubility in water: Miscible with water.
Solubility (other): No data available.
Partition coefficient (n-octanol/water): No data available.
Auto-ignition temperature: No data available.

Decomposition temperature: No data available.
Viscosity: No data available.
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10. Stability and reactivity
Reactivity: No data available.
Chemical Stability: Material is stable under normal conditions.
Possibility of hazardous No data available.

reactions:
Conditions to avoid: Avoid heat or contamination.
Incompatible Materials: No data available.
Hazardous Decomposition Thermal decomposition or combustion may liberate carbon oxides and
Products: other toxic gases or vapors.
11. Toxicological information
Information on likely routes of exposure

Inhalation: In high concentrations, vapors, fumes or mists may irritate nose, throat and
mucus membranes.
Skin Contact: May be harmful in contact with skin. Causes skin irritation. May cause an
allergic skin reaction.
Eye contact: Causes serious eye damage.
Ingestion: May be harmful if swallowed.
Symptoms related to the physical, chemical and toxicological characteristics
Inhalation: No data available.
Skin Contact: No data available.
Eye contact: No data available.
Ingestion: No data available.
Information on toxicological effects
Acute toxicity (list all possible routes of exposure)
Oral
Product: ATEmix: 13,300 mg/kg
Dermal
Product: Not classified for acute toxicity based on available data.
Inhalation
Product:
Repeated dose toxicity

Product: No data available.
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Skin Corrosion/Irritation
Serious Eye Damage/Eye Irritation

Respiratory or Skin Sensitization

Carcinogenicity
IARC Monographs on the Evaluation of Carcinogenic Risks to Humans:
Crystalline Silica Overall evaluation: Carcinogenic to humans.

(Quartz)/ Silica
Sand
US. National Toxicology Program (NTP) Report on Carcinogens:

Crystalline Silica Known To Be Human Carcinogen.
(Quartz)/ Silica
Sand
US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050), as amended:

Crystalline Silica
(Quartz)/ Silica Cancer
Sand
Germ Cell Mutagenicity
In vitro
In vivo
Reproductive toxicity
Specific Target Organ Toxicity - Single Exposure

Specific Target Organ Toxicity - Repeated Exposure

Target Organs
Specific Target Organ Toxicity - Single Exposure: Respiratory tract irritation.
Specific Target Organ Toxicity - Repeated Exposure: Lung
Aspiration Hazard
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Other effects: Constituents of this product may include crystalline silica which, if in
inhalable form, may cause silicosis, a form of progressive pulmonary
fibrosis. Inhalable crystalline silica is listed by IARC as a group I carcinogen
(lung) based on sufficient evidence in occupationally exposed humans and
sufficient evidence in animals. Crystalline silica is also listed by the NTP as
a known human carcinogen. Constituents may also contain asbestiform or
non-asbestiform tremolite or other silicates as impurities, and above de
minimis exposure to these impurities in inhalable form may be carcinogenic
or cause other serious lung problems.
12. Ecological information
Ecotoxicity:
Acute hazards to the aquatic environment:
Fish
Aquatic Invertebrates
Chronic hazards to the aquatic environment:
Fish
Aquatic Invertebrates
Toxicity to Aquatic Plants

Persistence and Degradability
Biodegradation
BOD/COD Ratio
Bioaccumulative potential
Bioconcentration Factor (BCF)
Partition Coefficient n-octanol / water (log Kow)

Mobility in soil: No data available.
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Other adverse effects: No data available.
13. Disposal considerations
Disposal methods: Dispose of waste at an appropriate treatment and disposal facility in

accordance with applicable laws and regulations, and product
characteristics at time of disposal.
Contaminated Packaging: No data available.
14. Transport information
TDG:
Not Regulated
CFR / DOT:
Not Regulated
IMDG:
Not Regulated
Further Information:
The above shipping description may not be accurate for all container sizes and all modes of transportation.
Please refer to Bill of Lading.
15. Regulatory information
US Federal Regulations
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
None present or none present in regulated quantities.
US. Toxic Substances Control Act (TSCA) Section 5(a)(2) Final Significant New Use Rules (SNURs)
(40 CFR 721, Subpt E)
US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050), as amended

Chemical Identity OSHA hazard(s)
Crystalline Silica kidney effects
(Quartz)/ Silica Sand lung effects
immune system effects
Cancer
CERCLA Hazardous Substance List (40 CFR 302.4):

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Superfund Amendments and Reauthorization Act of 1986 (SARA)
Hazard categories
Immediate (Acute) Health Hazards
Delayed (Chronic) Health Hazard
Skin Corrosion or Irritation
Serious eye damage or eye irritation
Respiratory or Skin Sensitization
Carcinogenicity
Specific target organ toxicity (single or repeated exposure)
US. EPCRA (SARA Title III) Section 304 Extremely Hazardous Substances Reporting Quantities and
the Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) Hazardous
Substances
US. EPCRA (SARA Title III Section 313 Toxic Chemical Release Inventory (TRI) Reporting
Not regulated.
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Clean Water Act Section 311 Hazardous Substances (40 CFR 117.3)
US State Regulations
US. California Proposition 65

For more information go to www.P65Warnings.ca.gov.
International regulations
Montreal protocol
Not applicable
Stockholm convention
Not applicable
Rotterdam convention
Not applicable
Kyoto protocol
Not applicable
VOC:
Regulatory VOC (less water and : 0 g/l
exempt solvent)
VOC Method 310 : 0.00 %
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Inventory Status:
Canada DSL Inventory List: All components in this product are
listed on or exempt from the
Inventory.
Japan (ENCS) List: One or more components in this

product are not listed on or exempt
from the Inventory.
Canada NDSL Inventory: One or more components in this

from the Inventory.
Philippines PICCS: One or more components in this

from the Inventory.
US TSCA Inventory: All components in this product are

Inventory.
Japan ISHL Listing: One or more components in this

from the Inventory.
Japan Pharmacopoeia Listing: One or more components in this

from the Inventory.
Australia AICS: All components in this product are

Inventory.
EINECS, ELINCS or NLP: All components in this product are

Inventory.
China Inv. Existing Chemical All components in this product are

Substances: listed on or exempt from the
Inventory.
Korea Existing Chemicals Inv. (KECI): All components in this product are
Inventory.
New Zealand Inventory of Chemicals: All components in this product are

Inventory.
Mexico INSQ: One or more components in this

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from the Inventory.
Ontario Inventory: One or more components in this

from the Inventory.
Taiwan Chemical Substance Inventory: One or more components in this

from the Inventory.
16.Other information, including date of preparation or last revision
Version #: 2.2
Further Information: No data available.
Disclaimer: For Industrial Use Only. Keep out of Reach of Children. The hazard
information herein is offered solely for the consideration of the user, subject
to their own investigation of compliance with applicable regulations, including
the safe use of the product under every foreseeable condition.
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Version: 2.

SAFETY DATA SHEET

Material name: PQ-200 GREY CRYSTALLINE

Recommended use and restriction on use

Contact person: EH&S Department

Unknown toxicity - Health

Signal Word: Danger

Hazard Statement: Causes skin irritation.

Prevention: Wash thoroughly after handling. Wear protective gloves/protective

Disposal: Dispose of contents/container to an appropriate treatment and disposal

Hazard(s) not otherwise None.

Chemical Identity CAS number Content in percent (%)*

Portland cement 65997-15-1 50 - <100%

Tartaric Acid 87-69-4 1 - <5%

Inhalation: Move to fresh air.

Skin Contact: Get medical attention. Destroy or thoroughly clean contaminated

Ingestion: Call a POISON CENTER/doctor if you feel unwell. Rinse mouth.

Most important symptoms/effects, acute and delayed

Hazards: No data available.

Indication of immediate medical attention and special treatment needed

Treatment: Symptoms may be delayed.

General Fire Hazards: No unusual fire or explosion hazards noted.

Suitable (and unsuitable) extinguishing media

Suitable extinguishing Use fire-extinguishing media appropriate for surrounding materials.

Special protective equipment and precautions for fire-fighters

Special fire-fighting No data available.

6. Accidental release measures

7. Handling and storage

Contact avoidance measures: No data available.

Safe storage conditions: Store locked up.

Safe packaging materials: No data available.

8. Exposure controls/personal protection

fraction. amended (2011)

Chemical name Type Exposure Limit Values Source

Appropriate Engineering Mechanical ventilation or local exhaust ventilation may be required.

Individual protection measures, such as personal protective equipment

9. Physical and chemical properties

Auto-ignition temperature: No data available.

10. Stability and reactivity

Reactivity: No data available.

Chemical Stability: Material is stable under normal conditions.

Possibility of hazardous No data available.

Conditions to avoid: Avoid heat or contamination.

Incompatible Materials: No data available.

11. Toxicological information

Information on likely routes of exposure

Eye contact: Causes serious eye damage.

Ingestion: May be harmful if swallowed.

Symptoms related to the physical, chemical and toxicological characteristics

Inhalation: No data available.

Skin Contact: No data available.

Eye contact: No data available.

Ingestion: No data available.

Information on toxicological effects

Acute toxicity (list all possible routes of exposure)

Repeated dose toxicity

Serious Eye Damage/Eye Irritation

Respiratory or Skin Sensitization

IARC Monographs on the Evaluation of Carcinogenic Risks to Humans:

Crystalline Silica Overall evaluation: Carcinogenic to humans.