Mitchell 1986
Mitchell 1986
Mitchell 1986
October 4, 1984
JAMES K. MITCHELL
255
257
INTRODUCTION
259
260
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crease. All of the changes in physical properties are quite consistent with
these compositional changes (Mitchell, 1976). What has been lacking un-
til very recently has been a suitable explanation for why these compo-
sitional changes occur. The recent dissertation research of Lessard (1981)
at the Univ. of California, Berkeley provides such an explanation.
The quick clay which formed the basis for Lessard's study was from
LaBaie near the Saguenay River in Quebec. It was deposited in the
LaFlamme Sea, an extension of the Champlain Sea, about 10,000 years
ago following the last glaciation. The sampling site is about 20 km from
Saint-Jean Vianney, where a slide involving 20 km2 of land area and an
estimated volume of 200 million m3 occurred 400 to 500 years ago. A
flowslide occurred in the same clay in 1971 with a loss of 31 lives and
destruction of 40 homes (Tavenas et al., 1971).
The LaBaie clay is a banded, silty clay that is medium to stiff in its
undisturbed state. Samples were obtained using 76 mm diameter Shelby
tubes. The undisturbed strength, as determined by fall cone tests (Hansbo,
1957) varies from 50 to 70 kPa (1,000 to 1,400 psf). The remolded strength
was too low to be reliably measured by the fall cone test; it is estimated
to be less than 0.07 kPa (15 psf). The sensitivity of freshly sampled clay
is greater than 500.
Some geotechnical characteristics of the clay and their variation with
depth are given in Fig. 4. The values shown were determined within
one month after sampling using material that had been carefully ex-
truded and coated with several layers of wax immediately after sam-
262
pling. The low values of liquid limit and plasticity index and the very
high values of liquidity index are characteristic of quick clays. Mineral-
ogical analyses yielded the results in Table 1. The amount of clay min-
erals is quite small, which means that much of the clay size fraction is
composed of rock flour.
The results of pore water chemistry analyses are given in Fig. 5. So-
dium and bicarbonate are the dominant ionic species. The concentra-
tions of adsorbed calcium and magnesium are low, which is character-
istic of quick clays. The chloride concentration is some 1,800 times less
than that in sea water, which indicates the clay has undergone extensive
leaching. The relatively high bicarbonate concentrations and the high
pH are characteristic of reducing environments and the consequences of
sulfate reduction in clays. Blackish bands through the light-to-dark blue-
gray clay are probably related to the presence of metastable iron sulfide.
The experimental program for the study of aging effects in this clay
involved sample storage under a variety of conditions and determination
263
FIG. 5.—Compositional Data on the Quick Clay from LaBaie as a Function of Depth:
(a) Organic Content, CaC03 Content, and pH (after Lessard, 1981); (b) Ionic Con-
centrations in the Pore Water
0 5 10 !5
TIME AFTER SAMPLING-MONTHS TIME AFTER SAMPLING - MONTHS
1 1 1
SAMPLE STORAGE
CONDITIONS
WAXED: -
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CONCENTRATION-meq/1
scribed above, amorphous materials, especially iron oxides, may also play
a part. When precipitated at particle contacts, these materials can act as
a cementing agent. They would be expected to increase the strength and
brittleness of the undisturbed clay both in situ and during sample aging.
The generation of additional iron oxides and hydroxides during the ox-
idation processes associated with quick clay aging could also lead to higher
undisturbed strengths in good quality samples than in situ. Amorphous
materials should not have a major effect on the strength of freshly re-
molded samples, however, because their contribution would be lost dur-
ing the remolding process.
Implications for Practice.—The aging of quick clays is an excellent ex-
ample of how even seemingly small changes in environmental condi-
tions can result in significant changes in properties. These changes can
occur over time periods typical of those associated with the field and
laboratory testing phases of many projects—e.g., several weeks to a few
months. If extreme care is not exercised during sample storage, labo-
ratory tests may give misleading results. Simple pH measurements at
the time of sampling, and then again at the time of testing, can provide
a rapid and easy means for assessing whether aging processes have oc-
curred. To minimize aging effects it is recommended that:
1. Exposure of samples to air be minimized.
2. Thick wax caps be used with rust-free Shelby tube samples.
3. Samples be stored at low temperatures to slow down the reaction
rates.
Recognition and clarification of the aging phenomenon leads also to
the possibility that the processes described above could be responsible
for some of the time-dependent strength gain in remolded marine clays
that has in the past been attributed to thixotropic hardening (Skempton
and Northey, 1952; Mitchell, 1960).
Finally, the possibility for quick clay "stabilization" by air injection
suggests itself. If the in situ clay could be partly exposed to oxygen,
perhaps by diffusion, then the associated reduction in sensitivity could
lessen the potential for catastrophic flow slides. This is because a higher
remolded strength would lessen the severity of progressive failure fol-
lowing a local disturbance.
AGING OF SANDS
FIG. 8.—Cross Section of Jebba Dam and Foundation Zones Densified by Vibro-
compaction and Blasting
UPSTREAM V.
COFFERDAM j ^ i * V-..„_ LEGEND:
0 10 20 30 40 50 0 10 20 30 40
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FIG. 10.—CPT Records before and Shortly after a Blasting Densification Test
269
0 10 20 30 40 50 0 10 20 30 40 0 10 20 30 40 SO
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FIG. 11,—CPT Records illustrating Penetration Resistance Increase with Time af-
ter Blasting Densification of Clean Sand—Test Program
pies are presented by Solymar (1984) and Mitchell and Solymar (1984).
The latter show additional data that indicate time-dependent increases
in penetration resistance following sand densification by dynamic com-
paction and vibrocampaction as well.
The surprising soil behavior, then, is that in-situ densification of sat-
urated clean sands can cause a reduction in penetration resistance, but
that with time the penetration resistance can increase to values greater
than before the densification. The problem is to explain this behavior,
to recognize conditions where it can occur, and to allow for it in an
appropriate manner in the geotechnical engineering of projects.
Explanation.—Calculations supported by water level measurements in
observation wells established that excess pore water pressures generated
by the sand disturbance could not have been the cause, as these pres-
sures were fully dissipated in a matter of hours. The observed behavior
can be explained, however, in terms of a very simple hypothesis. Sands
when initially deposited or immediately after in situ densification re-
spond as young, unbonded materials. Within weeks or months inter-
particle bonding and structure develops, leading to a "sensitivity." Sub-
sequent disturbance of the sand causes a structure breakdown and loss
of strength.
A special test done at the Jebba project excellently illustrates this sen-
sitivity and loss of strength. The rig for facilitating placement of charges
270
0 10 20 30 40 50 0 10 20 30 40 0 10 20 30 40 0 10 20 30 40 0 10 20 30 40
PRE -BORING):
*'
1 \\ o
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i-
n
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BEFORE BLASTING 2 DAYS AFTER 3 0 DAYS A F T E R 57 DAYS AFTER 157 DAYS AFTER
2ND B L A S T 3 " 0 BLAST 3R° BLAST 3"° BLAST
COVERAGE COVERAGE COVERAGE COVERAGE
FIG. 12.—CPT Records Illustrating Penetration Increase with Time after Blasting
Densification of Clean Sand—Production Blasting
(
c !\ IT
CPT A
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271
f:
FIG. 14.—-Penetration Resistance Profiles for a Hydraulic Fill at Two Times after
Placement
272
properties of some sands may in some cases have been caused by the
densification being inadequate to compensate for strength loss due to
structure breakdown.
5. Test programs for the evaluation of deep-densification effectiveness
should be designed so as to enable assessment of time effects.
O
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MOISTURE CONTENT-%
274
the parameters needed for flexible pavement design using the State of
California method (California Department of Transportation, 1978, 1981).
R-values as a function of compaction moisture content for both treated
and untreated soil are shown in Fig. 16.
The results of these tests and traffic information were used to establish
the pavement-thickness design indicated in Fig. 17. The street width was
90 ft, curb-to-curb, and consisted of four, 12-ft-wide travel lanes, two
parking lanes, and a center divider/left lane median strip. Construction
was done during the spring of 1975. Construction specifications were
typical for this type of work. The only significant difficulty during con-
struction was that the subgrade was wet and soft in some localized areas,
making it difficult or impossible in some cases to achieve the specified
compaction. It was concluded from quality control tests and field in-
spections, however, that overall the lime-treated material was placed and
compacted in accordance with the engineers' recommendations.
275
1. The failure was not traffic-induced, and the structural design of the
pavement section was adequate.
2. Construction was done generally in accordance with the specifi-
cations.
3. The heave developed in the lime-treated soil. In the failed zones
the soil has a much lower density and higher water content than either
the untreated soil or the intact, treated soil. Some comparisons are given
in Table 2.
276
Was the unusual behavior of the lime-treated soil due to unique char-
acteristics of the soil, the lime, the compaction water, the construction
procedures, or the curing? Interest centered on the soils, because no
significant abnormalities could be found in the other factors.
Fine-grained soils in the desert southwest of the United States con-
trast with soils in other areas in that they often contain significant amounts
of sulfate and carbonates. Sodium sulfate, Na 2 S0 4 , and gypsum, CaS0 4
• 2H 2 0, are the common sulfate forms, and calcium carbonate, CaC0 3 ,
and dolomite, MgC0 3 , are the usual carbonate forms. The dominant
clay minerals in these soils are expansive smectites.
The question to be addressed, then, was: can there be a series of events
such that a lime-treated soil of this type will be strong and intact just
after compaction but will, under certain conditions, deteriorate at some
later time? Tests were done to investigate the soil composition and
chemistry and the reaction products, and how they were related to the
observed behavior.
The results of these tests provided the following information:
These findings taken together lead to the following hypothesis for the
series of events leading to the unexpected Swelling and pavement fail-
ure.
When quicklime and soil are initially mixed in the presence of water,
the quicklime hydrates according to
CaO + H z O -> Ca(OH)2 + heat
Some calcium goes into solution and exchanges with sodium on the clay,
and along with light cementation by carbonate and gypsum, suppresses
the swelling tendencies of the expansive clay minerals when the treated
soil is exposed to water at short times after compaction. The result is a
compacted soil that exhibits negligible swell and a high R-value after
soaking. Some of the strength increase as compared to the untreated soil
may also be attributed to the reduction in water content caused by the
hydration of CaO.
In the presence of sodium sulfate, however, the available lime is de-
pleted according to
Ca(OH)2 + Na 2 S0 4 -» CaS0 4 + 2NaOH
If the pH rises to 12.4, then silica (Si02) and alumina (A1203) will dissolve
from the clay, or they may be present in amorphous form initially. These
compounds can then combine with the calcium, carbonate, and sulfate
present in the soil to form ettringite arid thaumasite.
This will further deplete the available lime, leading to a drop in pH,
which will, in turn, prevent the formation of cement (CSH), since ad-
ditional Si0 2 can not be dissolved from the clay. The expansive char-
acteristics of the clay minerals can then reassert themselves. Of greater
importance, however, is the fact that ettringite and thaumasite are very
expansive materials (Mehta and Hu, 1978).
If then the treated material is given access to water, a large amount
of swell may occur. This swell may exceed that exhibited by the un-
treated soil. In the case of the Las Vegas street, the water probably gained
access through joints between the asphalt concrete pavement and the
278
30 m
8
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-8
FIG. 21.—Soil Profile and Test Fill at Vasby, Sweden (Mesri and Choi, 1985)
0.1
TIME FACTOR
1.0 10
TIME -YEARS
FIG. 22.—Vasby Test Fill Pore Pressures Compared with Terzaghi Theory Predic-
tions
1
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FIG. 23.—Settlement and Pore Pressure Observations for the Penang, Malaysia
Test Fill (from Adachi and Todo, 1979)
281
(1972), Choa et al. (1981). At the New Liskeard, Ontario highway em-
bankment, pore pressures continued to increase for up to four months
after all fill placement, and there was little pore pressure dissipation over
the next 2-1/2 years, although surface settlements of up to 2 feet were
measured (Stermac et al., 1967). Under a test fill in Penang, Malaysia,
a plot of settlement versus time suggested the rate of consolidation set-
tlement has become very low even though excess pore water pressures
of 50 to 60 percent of their initial value remained (Adachi and Todo,
1979). Fig. 23 illustrates this case and shows settlements continuing at
essentially constant pore water pressure.
The surprising aspect of soil behavior to be examined and explained,
if possible, is continuing consolidation and settlement without corre-
sponding dissipation of pore pressures. The associated changes in shear
strength are also of interest.
Hypothesis.—Of the four problems discussed in this lecture, this is
the only one that may be amenable to quantification using soil mechan-
ics theory. There is general agreement among the investigators who have
described anomalous pore pressure behavior during clay consolidation
that it arises because of structural breakdown during compression. Soft,
sensitive clays are characterized by void-ratio versus log-pressure curves
of the type shown in Fig. 24. A review of cases shows that invariably
the clays are slightly overconsolidated, with OCR values typically in the
range of 1 to 2. When such clays are subjected to stress, only a small
deformation is required before the state corresponding to u'p, the effec-
tive preconsolidation pressure, is reached. Any small increase in effec-
tive stress above a'v leads to a very great increase in compressibility as
a result of a tendency for the structure to collapse. This can be accom-
panied by a large decrease in permeability.
The increase in compressibility and decrease in permeability lead im-
mediately to an abrupt and large decrease in the coefficient of consoli-
dation. Thus the rate of consolidation becomes greatly slowed. The im-
portance of changes in compressibility and permeability on clay
consolidation was discussed by Leonards and Altschaeffl (1964).
More recently Mesri and Choi (1985) proposed a method to take these
effects into account. A multi-layer analysis that includes variation of con-
solidation parameters with depth and during the consolidation process,
is carried out. Their reanalysis of the Vasby case agreed with measured
and predicted settlements, as seen in Fig. 25.
Predicted pore pressure distributions at Vasby by Mesri and Choi (1985)
agree in form with measured values, as may be seen in Fig. 26. This
lends additional support to the importance of taking compressibility and
permeability variations into account. Nonetheless, the measured values
of pore pressure are still greater than the predicted values. Mesri and
Choi suggested that instrumentation problems and interpretation un-
certainties may account for the differences. Large strain and self-weight
282
Vasby, Sweden
1947
Observed
Predicted by
Mesriond Chpi(l985)
10 20 30 40
Excess Pore Water Pressure, kPa
FIG. 26.—Observed Excess Pore Pressures and Pressures Predicted by the Method
of Mesri and Choi (1985)
effects (Schiffman et al., 1984) may also retard the rate of pore pressure
dissipation.
It is likely, however, that continued structural readjustment of the clay
during consolidation is a major factor. Structure breakdown when ef-
283
FIG. 27.—Observed and Predicted Pore Pressure versus Time after Consolidation
under Isotropic Stress for Undisturbed San Francisco Bay Mud (Bonaparte, 1981)
CONCUJSIQNS
1. Soils are not inert materials. They can, and often do, change with
time and changes in conditions.
2. What soils are arid how they behave depends, as does the behavior
of people, on both genetic and environmental factors. Hence, a thor-
ough understanding and appreciation for the geologic history and for-
mational processes of a soil deposit are essential. Anticipation of future
performance must be based on consideration of all conceivable physical,
chemical, and biological changes. Regrettably, we don't know enough
about the latter, and additional, carefully designed and executed re-
search is needed.
3. None of the first three cases could have been anticipated or ex-
plained through application of either conventional or advanced soil me-
chanics theory or sophisticated mathematical analysis methods. Fur-
thermore, the use of soil mechanics theory and numerical methods for
analyses and prediction using properties obtained from tests on aged
samples in the case of quick clays, or immediately after placement or
densification in the case of some sands could give grossly misleading
results.
4. The foregoing statements are not intended to imply that soil me-
chanics does not have an important role in geotechnical engineering. For
example, quantification of the anomalous pore pressure phenomena de-
scribed in the preceding section should be possible using existing prin-
ciples of soil mechanics.
5. We need to learn better how to expect the unexpected, especially
when confronted with new problems in new environments or settings.
Terzaghi had a remarkable ability to change his mind and revise his
285
ACKNOWLEDGMENTS
APPENDIX.—BIBLIOGRAPHY
Adachi, K., and Todo, H. (1979). "A Case Study on Settlement of Soft Clay in
Penang," Proc. 6th Asian Regional Conference on Soil Mechanics and Foundation En-
gineering, Singapore, Vol. 1, pp. 117-120.
Arulanandan, K., Shen, C. K., and Young, R. B. (1971). "Undrained Creep Be-
havior of a Coastal Organic Silty Clay," Geotechnique, Vol. 21, No. 4, pp. 359-
Becker, D. E., Crooks, J. H. A., Jeffries, M. G., and McKenzie, K. (1984). "Yield
Behavior and Consolidation, II: Strength Gain," Proc, ASCE Symposium on Sedi-
mentation Consolidation Models, Prediction and Validation, pp. 382-398.
Bjerrum, L., and Rosenqvist, I. Th. (1956). "Some Experiments with Artificially
Sedimented Clays," Geotechnique, Vol. 6, pp. 124-136.
286
Chang, Y. C. E. (1981). "Long Term Consolidation Beneath the Test Fills at Vasby,
Sweden," Swedish Geotechnical Institute, Report No. 13, Linkoping, 148 pp.
Chang, Y. C. E., Broms, B., and Peck, R. B. (1973). "Relationship Between the
Settlement of Soft Clays and Excess Pore Pressure Due to Imposed Loads," Proc.
8th International Conference on Soil Mechanics and Foundation Engineering, Moscow,
Vol. 1, pp. 93-96.
Choa, V., Karunaratne, G. P., Ramaswamy, S. D., Vijiratnam, A., and Lee, S.
L. (1981). "Drain Performance in Changi Marine Clay," Proc. 10th International
Conference on Soil Mechanics and Foundation Engineering, Stockholm, Vol. 3, pp.
623-626.
Crooks, J. H. A., Becker, D. E., Jeffries, M. G., and McKarzie, K. (1984). "The
Significance of Effective Stress Paths and Yield Behavior on the Field Consoli-
dation of Soft Clays," Proc. ASCE Symposium on Prediction and Case Histories of
Consolidation Performance, San Francisco, CA, Oct., 1984.
287
Mesri, G., and Choi, Y. K. (1979). "Excess Pore Water Pressures During Con-
solidation," Proc. 6th Asian Conference on Soil Mechanics and Foundation Engineering,
Singapore, Vol. 1, pp. 151-154.
Mitchell, J. K. (1976). Fundamentals of Soil Behavior, John Wiley & Sons, New York,
NY, 422 p.
Mourn, J., Loken, T., and Torrance, J. K. (1971). "A Geotechnical Investigation
of the Sensitivity of a Normally Consolidated Clay from Drammen, Norway, Geo-
techniaue, Vol. 21, No. 4, pp. 329-340.
Schiffman, R. L., Pane, V., and Gibson, R. E. (1984). "The Theory of One-Di-
mensional Consolidation of Saturated Clays, IV. An Overview of Nonlinear Fi-
nite Strain Sedimentation and Consolidation," Proc, ASCE Symposium on Sedi-
mentation Consolidation Models, Prediction and Validation, pp. 1-29.
288
Soderblom, R. (1969). "Salt in Swedish Clays and its Importance for Quick-Clay
Downloaded from ascelibrary.org by UNIVERSITE LAVAL on 07/05/14. Copyright ASCE. For personal use only; all rights reserved.
Formation: Results from Some Field and Laboratory Studies," Swedish Geotech-
nical Institute, Proceedings, 22, 63 pp.
Stermac, A., Lo, K. Y., and Barsvary, A. K. (1967). "The Performance of an Em-
bankment on a Deep Deposit of Varved Clay," Canadian Geotechnical Journal, Vol.
4, No. 1, pp. 45-61.
Tavenas, F., Chagron, J.-Y., and LaRochelle, P. (1971). "The St.-Jean Vianney
Landslide: Observations and Eyewitness Accounts," Canadian Geotechnical Jour-
nal, Vol. 8, pp. 463-478.
Terzaghi, K. (1941). "Undisturbed Clay Samples and Undisturbed Clays," Journal
of the Boston Society of Civil Engineers, Vol. 28, No. 3, pp. 211-231.
Torrance, J. K. (1976). "Pore Water Extraction and the Effect of Sample Storage
on the Pore Water Chemistry of Leda Clay," American Society for Testing and Ma-
terials, Special Technical Publication, 599, pp. 147-157.
Villet, W. C. B., and Mitchell, J. K. (1981). "Cone Resistance, Relative Density
and Friction Angle," in Cone Penetration Testing and Experience, G. M. Norris and
R. D. Holtz, Ed., ASCE, pp. 178-208.
289