Normazione: Aluminium - and Zinc-Lamellar Base Anti-Corrosion Coating For Ferrous Material Parts

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PROCUREMENT

ALUMINIUM– AND ZINC–LAMELLAR SPECIFICATION


BASE ANTI–CORROSION COATING
FOR FERROUS MATERIAL PARTS 9.57513
normazione Page: 1/12
Date: 05/08/2006

-
CMD
SUPERVISING Dept. : E.D. – Ingegneria dei Materiali

MANAGING Dept. : E.D. – Ingegneria dei Materiali

Code
-
PURPOSE

Ch.
To define the characteristics that the non–electrolytic anticorrosive coatings with thin zinc and alu-
minum layer base must meet for parts made of ferrous material.

2
To define the modalities to be followed and equipment to be utilized for the execution of the control
tests of these characteristics.

Edition
This Procurement Specification consists of No. 12 pages and 2 annexes.

Change Date Description

–– 01/31/03 Edition1 – New. (DA)

= 05/08/06 Edition2 – Completely revised. (FD)

THIS DOCUMENT MUST NOT BE REPRODUCED OR CIRCULA TED TO THE THIRD PARTIES
WITHOUT PRIOR WRIT TEN CONSENT BY FIAT AUTO S.P.A. IN CASE OF DISPUTE
THE ONLY VALID REFERENCE IS THE ORIGINAL ITALIAN EDITION
CONFIDENTIAL

ANY PRINTED COPY IS TO BE DEEMED AS UNCHECKED; THEREFORE THE UPDATED COPY MUST BE CHECKED IN THE APPROPRIATE WEB SITE

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9.57513 Change

| § ”A” : TEST EQUIPMENT

Equipment necessary for tests is the one specified in the Standards listed in § “B”.

| § ”B” : REFERENCED DOCUMENTS


|50180 | Corrosion tests. TMD
|50473 | Determination of the resistance to gasoline of paints, enamels, etc. TMD
|50473/01 | Determination of the resistance to chemical aggression of products. TMD
|50757 | Measurement of metal coating thickness by magnetic method. TMD
|50758 | Measurement of metal coating and protection oxide layer thickness (micrographic
method). TMD
|7.G0114 | Measurement of bolt friction coefficient. PGE
|7.M5000 | Metal parts. Check of the absence of hexavalent chromium (Cr VI) in surface coatings.
PMD
|9.01102 | Quality of FIAT AUTO S.p.A. supplies. CFO
|9.01102/01 | Requirements for the statistic check of supplies. CFO
|9.01103 | Product quality and conformity certificate. CFO
|9.52605/01 | Bolts for normal and special use. CFO
|9.55367 | Single–side layer adhesive tapes. CMD
|9.57511 | Corrosion–resistant zinc, aluminum and chromate base chemical coating for ferrous
metal parts. CMD
|9.57512 | Corrosion–resistant zinc, aluminum and organic binder base chemical coating for ferrous
metal parts. CMD
|5541 | ISO metric threads with triangular profile, with pitch equal to or higher than 0.35 mm
– Tolerance system for movable couplings. UNI
THIS DOCUMENT MUST NOT BE REPRODUCED OR CIRCULA TED TO THE THIRD PARTIES

|B 487 | Standard test Method for Measurement of Metal and Oxide Coating Thickness by
WITHOUT PRIOR WRIT TEN CONSENT BY FIAT AUTO S.P.A. IN CASE OF DISPUTE

Microscopical Examination of a cross Section. ASTM


THE ONLY VALID REFERENCE IS THE ORIGINAL ITALIAN EDITION

|B 568 | Standard test Method for Measurement of coating Thickness by X–Ray Spectrometry.
ASTM

| § ‘‘C’’ : ANNEXES
CONFIDENTIAL

| 1 | Specifications Data Sheet


| 2 | Correspondence between Fiat Auto designation and commercial denominations

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Change
9.57513

1
GENERAL

1.1
This Procurement Specification covers non–electrolytic anticorrosive coatings derived from water or
solvent dispersions of zinc and aluminum flakes and following stoving, for ferrous material parts.
Stoving temperatures can vary from about 180°C for solvent–based organic systems, to about 300°C for
water–based inorganic systems.
Topcoat finishing additional treatments can be applied on the base coating to improve the corrosion and
abrasion resistance, to give a particular color and/or to modify the friction coefficient by adding, in this
case, special additives such as wax or PTFE.

1.2
Purpose
Main purpose of the coating dealt with in this Procurement Specification is to give to treated parts a high
resistance to corrosion and to ensure a controlled value of the friction coefficient.

Coatings covered in this Procurement Specification shall comply with prescriptions in


Annex CK of P.S. 9.01102 and shall be completely free from chromium compounds.

1.3
Field of application
Depending on the type of parts to be treated, non–electrolytic coatings with zinc and aluminum flake base
can be applied following one of these procedures:
– bulk dip / spin;
– rack dip / spin;
– rack spray, bulk (volute) or on pallet.

As a general rule, bulk processes are suitable for small or medium–size parts, while rack processes are
suitable for medium–size or large parts.
For parts with indents – blind holes, socket screw heads, nuts – and/or fine threads, it is necessary to use
systems and working cycles able to avoid product deposits in these areas or to guarantee their removal.

These coatings must not be utilized in the following cases:

THIS DOCUMENT MUST NOT BE REPRODUCED OR CIRCULA TED TO THE THIRD PARTIES
WITHOUT PRIOR WRIT TEN CONSENT BY FIAT AUTO S.P.A. IN CASE OF DISPUTE
– Self–locking nuts with polyamide core.
– Parts for which a good electrical conductivity is required (e.g. ground connections). THE ONLY VALID REFERENCE IS THE ORIGINAL ITALIAN EDITION

– Only as concerns the coatings obtained by water dispersions, for components made of
materials for which the temperatures of 300°C cause a decay of the mechanical
characteristics.
CONFIDENTIAL

Furthermore they are not recommended for:

– Internal and external threads < M6.


– Parts for which welding operations are foreseen after the application of coating.

For parts to be used on exposed areas (e.g.: under floor, engine compartment, vehicle exterior),
assembled with stainless steels, magnesium alloys copper alloys, rubber or other elements subject to
create contact corrosion with zinc, it is necessary to use coatings with appropriate additional finishings,
to specify on drawings.

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9.57513 Change

In these cases, it is always advisable to check the suitability of the solution chosen by means of targeted
corrosion tests, to be agreed upon between Customer and Supplier.

1.4
Flexibility and resistance to shocks
The coating must resist normal extensions and compressions required to springs, as well as normal
bending stresses to which elastic washers and flat springs are subject during the assembly, without
showing scaling or loss of adhesion from the base metal.
Moreover, it must resist the normal handling and storage conditions without showing scaling, detach-
ment from the base metal or other important damages.

1.5
Look
Unless otherwise specified on drawings, the coating shall present a uniform semi–opaque silver grey color
(Silver).
A different color can be required (e.g. black), it is usually obtained by applying one or more additional
finishing coats which can affect the thickness of the coating (indicatively greater than 15 mm total), making
it potentially critical for fine metric screw threads.

1.6
Classification, designation, indication on drawing and use

INDICATION
OLD CODE
TYPE ON DRAWING DESCRIPTION USE PROVISIONS
DESIGNATION NUMBER

Of general use, also for non–
threaded parts.
RIV/DAC 5 As a replacement of RIV/
RIV/DAC 8 DAC and FAR/ZN/OR I coa-
RIV/EC 5 Two applications P.S. 9.57511
I tings. To be prescribed for I
P.S. 9.57513 of base coating
FAR/ZN/OR I bolts and nuts when the va-
P.S. 9.57512 lues of the coefficient of fric-
tion (Cf) required are 0.12 to
0.30
To be prescribed particularly
THIS DOCUMENT MUST NOT BE REPRODUCED OR CIRCULA TED TO THE THIRD PARTIES

RIV/EC 5 F Two applications for bolts and nuts when the


WITHOUT PRIOR WRIT TEN CONSENT BY FIAT AUTO S.P.A. IN CASE OF DISPUTE

II P.S. 9.57513 of bulk lubricated ––– values of the coefficient of II


 base coating friction (Cf) required are 0.12
THE ONLY VALID REFERENCE IS THE ORIGINAL ITALIAN EDITION

to 0.18

To be prescribed for bolts


RIV/EC 5 LUB Two applications and nuts when the values of
III P.S. 9.57513 of base coating + ––– the coefficient of friction (Cf) III
 one of lubricant required are 0.10 to 0.16, or
CONFIDENTIAL

lower. 

Of general use, to be pre-


scribed when higher abra-
sion resistance, chemical
One or two appli-
agent resistance and contact
cations of base RIV/DAC 5 PL corrosion resistance are re-
RIV/EC 8 PL coating + one or P.S. 9.57511 quired. As a replacement of
IV P.S. 9.57513 two applications IV
FAR/ZN/OR II RIV/DAC 5 PL and FAR/ZN/
 of organic fini-
P.S. 9.57512 OR II coatings. To be pre-
shing or mineral
scribed for bolts and nuts
lubricant
when the values of the coef-
ficient of friction (Cf) required
are 0.10 to 0.16. 

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Change
9.57513
 If the Designers think it is necessary to bind the use of a specific product/process, it is possible to
indicate on the drawing the commercial name of the products used and of their Manufacturers (see
Annex 2 and § 2.5.3)
 The application of the lubricants can be carried out also on Type II coatings.
In this case, the drawing prescription of the coating shall be: RIV/EC 5 F LUB P.S. 9.57513 and shall
complulsorily be followed by the indication of the dispersion limits of the Cf required.
 All colors different from silver grey shall be explicitly indicated on drawing, e.g.: RIV/EC 8 PL Black P.S.
9.57513, or RIV/EC 5 LUB Green P.S. 9.57513 (see Annex 2).
 Cf dispersion limits different from 0.10 to 0.16 shall be specified on drawings (see § 2.5).

1.7
Dimensions and tolerances of the coated part
1.7.1
Non-threaded elements

1.7.1.1
If not otherwise indicated, dimensions and tolerances indicated on the part drawing are considered as
including the coating.

1.7.2
Coating thickness on bolts
1.7.2.1
When applied on threaded elements, the coating must not affect the normal assembly and dismounting
operations. The measure of the coating thickness is defined as per the tolerance of the ISO metric thread,
according to Standard UNI 5541, with tolerance classes:
– g , f and e for outer threads (screws);
– H and G for inner threads (nuts).
In case of outer threads, these tolerances are considered before applying the coating while, in case of
inner threads, they are considered after coating. After coating, the higher deviation must not exceed zero
(nominal dimension) in case of outer threads and be lower than zero in case of inner threads.
a) Screws The thickness values of coatings for screws are defined in function of thread pitch and
tolerance field of thread. Table 1 shows the maximum theoretical thickness values that

THIS DOCUMENT MUST NOT BE REPRODUCED OR CIRCULA TED TO THE THIRD PARTIES
can be required; they are obtained from the values of the main deviations from tolerance
WITHOUT PRIOR WRIT TEN CONSENT BY FIAT AUTO S.P.A. IN CASE OF DISPUTE
positions g, f and e.
THE ONLY VALID REFERENCE IS THE ORIGINAL ITALIAN EDITION

TABLE 1 - MAXIMUM THEORETICAL THICKNESS VALUES REQUIRED FOR SCREWS


Thread Theoretical thickness allowed on thread ( m m)
Thread pitch
(mm) Position of Position of Position of
Large pitch Thin pitch
tolerance g" tolerance f" tolerance e"
CONFIDENTIAL

0,50 M3 -- 5 9 12
0,70 M4 -- 5 9 14
0,80 M5 -- 6 9 15
1,00 M6 M81 6 10 15
M101.25
1.25 M8 7 10 15
M121.25
M141.5
M161.5
1.50 M10 M181.5 8 11 16
M201.5
M221.5

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9.57513 Change

Thread Theoretical thickness allowed on thread ( m m)


Thread pitch
(mm) Position of Position of Position of
Large pitch Thin pitch
tolerance g" tolerance f" tolerance e"
1.75 M12 -- 8 12 17
M242
M272
2.00 M14; M16 9 13 17
M302
M332
2.50 M18; M20; M22 -- 10 14 20
M363
3.00 M24; M27 12 16 21
M393
3.50 M30; M33 -- 13 17 22
4.00 M36; M39 -- 15 19 23

Even thickness values higher or lower than the indicated ones can be required.
Thicknesses higher than the indicated ones must be agreed upon by Purchaser and Supplier, for, in
addition to the main deviation, a part of the thread tolerance could be utilized and a decrease of some
micrometers could occur on the average diameter in position “h/H”; nevertheless, in any case the screw
– nut coupling must not be compromised.

b) Nuts Differently from the electrolytic coatings, the coatings dealt with in this Procurement
Specification tend to accumulate in inner threads too. Therefore the female threads
must be suitably increased in order to ensure the meeting of tolerance 6H after applying
the coating.

REQUIREMENTS FOR THE COATING QUALIFICATION

2.1
Submit the component to tests and checks indicated in the following paragraphs, checking the compliance
of the test result with the values/limits indicated in the design and/or in the annexed “Specifications Data
Sheet”, concerning the specific type.

2.2
THIS DOCUMENT MUST NOT BE REPRODUCED OR CIRCULA TED TO THE THIRD PARTIES
WITHOUT PRIOR WRIT TEN CONSENT BY FIAT AUTO S.P.A. IN CASE OF DISPUTE

Test environment (unless otherwise specified)


Temperature : 23 ± 5 °C
THE ONLY VALID REFERENCE IS THE ORIGINAL ITALIAN EDITION

Atmospheric pressure : 860 to 1060 mbar


Relative humidity : 45 to 70 %

2.3
CONFIDENTIAL

Coating materials and processes


The material and coating processes that are approved by FIAT AUTO are listed in Annex 2 .

2.4
Characteristics
The characteristics indicated below refer to the significant surface of the part.
The term significant surface means the surface part that is essential for the look and/or utilization of the
treated component.
It can be indicated on drawing or agreed upon when ordering; otherwise the whole part surface is
considered to be significant.
In case of bolts, the significant surface includes head and stem of screws, operation slots, possible
inseparable washers and the outer surface of nuts.

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9.57513

2.4.1
Visual inspection
The part surface must be free of defects such as porosity, inclusions, cracks, blisters, drops, etc. and of
zones without coating.
The coating must have a look conforming with what required in § 1.5, it must be catalyzed perfectly, with
a not greasy or sticky hand (for versions LUB too); it must resist normal handling, storage and installation
operations without flaking, scaling or, in any case, losing adhesion.
No accumulation of product that can affect the tightening operations must occur on bolts, on threads and
in operation slots.

2.4.2
Check the absence of hexavalent chromium compounds in the coating composition
As per Standard 7.M5000.

2.4.3
Thickness

2.4.3.1
Coating thickness for components other than bolts and nuts
The minimum local thickness, measured in significant surface zones by one of the methods indicated
below, must result as indicated in § 2.4.3.6, for the various types of coating.

2.4.3.2
Magnetic method
As per Standard ASTM B 568 or FIAT Standard 50757, making use of Magne–Gage, Mikrotest or other
equivalent equipment that permits an accuracy of at least ± 10 %.
To be utilized in current checks.

2.4.3.3
X–ray fluorescence method
As per Standard ASTM B 568.
Of general use, to be utilized preferably in case of small–size parts.
It requires a specific calibration for every type of coating.

2.4.3.4
THIS DOCUMENT MUST NOT BE REPRODUCED OR CIRCULA TED TO THE THIRD PARTIES
WITHOUT PRIOR WRIT TEN CONSENT BY FIAT AUTO S.P.A. IN CASE OF DISPUTE
Micrographic method
As per Standard ASTM B 487 or FIAT Standard 50758. THE ONLY VALID REFERENCE IS THE ORIGINAL ITALIAN EDITION
To be utilized in case of objection or when the methods indicated above cannot apply.

2.4.3.5
Bolt coating thickness
CONFIDENTIAL

The coating thickness on threaded elements must not compromise the normal tightening and dismounting
operations.
In the meantime, it must meet the requirements indicated in §§ 2.4.5 to 2.4.7.
Unless otherwise arranged, after coating, metric threaded parts shall be manually screwable on the test
gauges, ring type or thread plug type, with tolerance position “h” for external threads and “H” for internal
threads.
In this case the screwing operation, for the first 3 threads shall be done by exerting a max. torque
complying with values in P.S 9.56205/01 both for screws and for nuts.

2.4.3.5.1
Zones for the measurement of the bolt coating thickness
As a consequence of the variability of the coating thickness on screws and nuts, it is measured in points
significant from the point of view of anticorrosive protection.

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9.57513 Change

In case of hexagonal or outward–torsion, these points lies approximately at the center of the head surface
or of the stem end.
In case of cylindrical screws with countersunk hexagonal head and of screws with cross cut, the
measuring points lies on the flat surface of the head, between edge and countersunk hexagon, between
edge and cross cut, or on the side of the head. Countersunk and cut surfaces are excluded from the
measuring points.
In case of nuts, thickness is measured on a side of the hexagon or on a support plane.

2.4.3.5.2
Coating thickness measurement on bolts and nuts and small items
On a minimum of 10 parts for each homogeneous lot, measure, with the methods described above, the
coating thickness performing at least 4 different measurements for each part.
For each single part the arithmetical mean of measured values shall be within the limits indicated in
§2.4.3.6 as a function of the prescription indicated in the drawings.
Single measurements lower than 40% of the prescribed limit are not allowed.

2.4.3.6
Thickness limits
Thickness values must range within the following limits:

– RIV/EC 5  5 mm
– RIV/EC 5 F  5 mm
– RIV/EC 5 LUB  5 mm
– RIV/EC 8 PL  8 mm
As far as screws are concerned, the max. thickness, measured under the head, shall not exceed 25 mm.

2.4.4
Adhesion
The assessment of the adhesion of coating to base metal must be carried out by the following methods:

2.4.4.1
Adhesion when new
THIS DOCUMENT MUST NOT BE REPRODUCED OR CIRCULA TED TO THE THIRD PARTIES

2.4.4.1.1
WITHOUT PRIOR WRIT TEN CONSENT BY FIAT AUTO S.P.A. IN CASE OF DISPUTE

Take 3 samples for each type of part to be checked.


THE ONLY VALID REFERENCE IS THE ORIGINAL ITALIAN EDITION

2.4.4.1.2
On the part, choose the flattest possible and not–threaded surface, of at least 1 cm2 as test surface.

2.4.4.1.3
Degrease the surface to be tested by heptane.
CONFIDENTIAL

2.4.4.1.4
At environmental temperature, apply a plastic elastic adhesive vinyl tape strip on the surface
(Procurement Specification 9.55367) with an even and light manual pressure; avoid to let air bubbles.

2.4.4.1.5
Detach the tape from the part manually, pulling it rapidly from above downward, perpendicularly to the
surface to be tested.

2.4.4.1.6
Consider the worst result obtained in the 3 measurements carried out on every part.
The adhesion of coating to the base metal must be higher than the cohesion of the same coating.

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9.57513
2.4.4.1.7
The presence of small–size coating particles (3 mm2) is allowed on the tape; in total they can cover an
area lower than the 20 % of the surface to be tested.
On the contrary, neither coating fragments having dimensions of 3 – 4 mm2, nor any detachment from
the base metal are allowed on the tape.

2.4.4.2
Adhesion after aging

2.4.4.2.1
Submit the parts to be checked to a salty fog test, as per Standard 50180, method B1 for a duration of
96 h .

NOTA :In case of small–size elements, when incisions cannot be made (flat surfaces < 1 cm2), the
test can be carried out on samples having suitable dimensions and submitted to the treatment
together with the elements to be tested.

2.4.4.2.2
After drying and conditioning at environmental temperature for 10 min, repeat the operations as per
paragraphs 2.4.4.1.4 and 2.4.4.1.5.

2.4.4.2.3
Neither detachments 3 mm from the incision lines, nor the presence on the tape of coating frag-
ments caused by detachment form the base metal are allowed.

2.4.5
Resistance to corrosion

2.4.5.1
After at least 24 h from the coating baking operation end, take a number of parts so that the total of the
significant surfaces is 1 dm2.

2.4.5.2
Submit the parts to the corrosion test in salty fog as per Standard 50180 method A1.
Unless otherwise indicated, the various types of coating must meet the requirements indicated in
Table 2.

THIS DOCUMENT MUST NOT BE REPRODUCED OR CIRCULA TED TO THE THIRD PARTIES
TABLE 2
WITHOUT PRIOR WRIT TEN CONSENT BY FIAT AUTO S.P.A. IN CASE OF DISPUTE
Minimum time (h) of exposition within which they must not be THE ONLY VALID REFERENCE IS THE ORIGINAL ITALIAN EDITION
TYPE OF shown
COATING
Zinc corrosion products Base metal corrosion products
I RIV/EC 5 ––– 480
II RIV/EC 5 F ––– 480
CONFIDENTIAL

III RIV/EC 5 LUB ––– 480


IV RIV/EC 8 PL 144 720
* Only for finishing with colors different from silver grey (Silver)

2.4.5.3
If not otherwise specified, the assessment of the resistance to corrosion must be assessed with the naked
eye and at a normal reading distance. The presence of white zinc corrosion products, for an extension
5 % of the total exposed significant surface, is not a cause of reject.
The quantity of ferrous corrosion points must be 1/ dm2 (higher values are considered to be causes for
reject). The presence of corrosion products within zones that are not significant surfaces is not considered
to be a cause for reject.

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9.57513 Change

2.4.6
Resistance to temperature

2.4.6.1
Expose the parts to be tested in a constant temperature and humidity ventilated chamber for 3 h at
150±3°C (temperature measured on the part) and then submit them to the corrosion test in salty fog, as
per Standard 50180 method A1.

2.4.6.2
According to the type of coating, duration of exposition and requirements shall be the ones indicated in
Table 2.

2.4.7
Cathode protection of coating

2.4.7.1
By means of a suitable point, cut the coating on the part to be tested or on the sample until reaching the
base metal. The incision must have a width not larger than 0.5 mm.

2.4.7.2
Expose the sample to be tested in a salty fog chamber as per Standard 50180 method A1 for 96 h.

2.4.7.3
No ferrous corrosion must appear on the incision surface at the end of the test.

2.4.8
Resistance to gasoline (Test to be carried out only during the qualification phase)

2.4.8.1
Carry out the test as per the modalities and with the equipment described in Standard 50473.

2.4.8.2
Dry up the part and condition it in test environment for a duration of 120 min, then assess the surface
conditions.

2.4.8.3
THIS DOCUMENT MUST NOT BE REPRODUCED OR CIRCULA TED TO THE THIRD PARTIES

No surface defect is allowed (e.g. : spots, blisters, detachments) if compared to the unexposed part.
WITHOUT PRIOR WRIT TEN CONSENT BY FIAT AUTO S.P.A. IN CASE OF DISPUTE
THE ONLY VALID REFERENCE IS THE ORIGINAL ITALIAN EDITION

2.4.9
Resistance to the liquid window cleaner (Test to be carried out only during the qualification phase)

2.4.9.1
Carry out the test as per the modalities and with the equipment described in Standard 50473/01 Method
CONFIDENTIAL

B.

2.4.9.2
Dry up the part and condition it in test environment for a duration of 120 min, then assess the surface
conditions.

2.4.9.3
No surface defect is allowed (e.g. : spots, blisters, detachments) if compared to the unexposed part.

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9.57513

2.5
Bolt friction coefficient

2.5.1
Unless otherwise specified on drawings, coefficients of friction of bolts and nuts shall be within the
dispersion limits Cf = 0.12 to 0.30, as prescribed by P.S. 9.52605/01.
In case lower Cf values or narrower dispersion limits are required, e.g. Cf = 0.10 to 0.16, or Cf = 0.12 to
0.18, it is necessary to use self–lubricated coatings (Type F), or to apply suitable lubricating products
(Type LUB) or finishing products (Type PL) (See Annex 2).
If no requirements are present on the drawings, the following dispersion values shall be applied:
– RIV/EC 5 Cf = 0.12 to 0.30
– RIV/EC 5 F Cf = 0.12 to 0.18
– RIV/EC 5 LUB Cf = 0.10 to 0.16
– RIV/EC 8 PL Cf = 0.10 to 0.16.

2.5.2
Friction conditioner application check shall be carried out through the measurement of the coefficient of
friction as per Std. 7.G0114.
Other checking methods shall be agreed upon in advance and approved by Fiat Auto appropriate
departments (E.&D. /P.T.&S.).

2.5.3
The correspondence between Fiat Auto designations and approved commercial names of coatings and
friction conditioners are shown in Annex 2.
The use of products different from those indicated is allowed, as long as the requirements of this
Procurement Specification and of any specification indicated on the drawings are respected. Limitations
on use of forbidden substances or substances to be monitored, as per Annex CK of P.S. 9.01102, shall
be respected too.
The Specification Data Sheet of the product used, together with its application cycle parameters, shall be
available on Fiat Auto’s demand.

3
REQUIREMENTS FOR THE SUPPLY CHECK.

THIS DOCUMENT MUST NOT BE REPRODUCED OR CIRCULA TED TO THE THIRD PARTIES
(by Qualità di Stabilimento)

3.1 WITHOUT PRIOR WRIT TEN CONSENT BY FIAT AUTO S.P.A. IN CASE OF DISPUTE
THE ONLY VALID REFERENCE IS THE ORIGINAL ITALIAN EDITION
The supply check must be carried out as per requirements indicated in Procurement Specification
9.01102/01 (Limited distribution).

4
CONFIDENTIAL

REQUIREMENTS FOR THE SUPPLIER

4.1
The Supplier must meet the general requirements indicated in Procurement Specification 9.01102
‘‘SUPPLY QUALITY”.

4.2
Supplies for the product qualification
The Supplier must produce the product quantity required in the purchase order, attaching the relevant
required Quality and Conformity Certificate (see Proc. Spec. 9.01103); all the characteristics indicated
in the attached “Specifications Data Sheet”, concerning the specific type, shall be checked. No
“non–conformity” is allowed.

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9.57513 Change

4.3
Supplies for the production
The supplied product must meet the requirements indicated on drawing and in this Procurement
Specification. When defining the kind of production process to be followed and the severity of acceptance
tests, the Supplier must consider the classes of importance that FIAT defined for each one of the
characteristics to which requirements refer (see § 5).

NOTE: During both product qualification and supply control, checks can be carried out on components
that underwent non–destructive tests (indicated by NM in § 5); if the component underwent
destructive tests (M) it can be utilized no more for other tests or checks if not otherwise speci-
fied every time.

TABLE OF THE CLASSIFICATION OF CHARACTERISTICS

CLASSIFICATION OF CHARACTERISTICS TEST TYPE


Visual inspection Minor NM
Check the absence of hexavalent chromium
Minor M
compounds in the coating composition
Thickness Minor NM/M
Adhesion when new Major M
Adhesion after aging Minor M
Resistance to corrosion Major M
Resistance to temperature Minor M
Cathode protection of coating Minor M
Resistance to gasoline Minor M
Resistance to the liquid window cleaner Minor M
Friction coefficient Major M
THIS DOCUMENT MUST NOT BE REPRODUCED OR CIRCULA TED TO THE THIRD PARTIES
WITHOUT PRIOR WRIT TEN CONSENT BY FIAT AUTO S.P.A. IN CASE OF DISPUTE
THE ONLY VALID REFERENCE IS THE ORIGINAL ITALIAN EDITION
CONFIDENTIAL

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ALUMINIUM– AND ZINC–LAMELLAR 9.57513
BASE ANTI–CORROSION COATING FOR
FERROUS MATERIAL PARTS ANNEX 1
normazione Page: 1/1

Specifications Data Sheet

CMD
Test
CHARACTERISTICS LIMITS
Conditions

Code
Visual inspection –– § 2.4.1
Search of hexavalent chromium § 2.4.2
§ 2.4.2

-
in coating Standard 7.M5000
RIV/EC 5 5 m m

Ch.
RIV/EC 5 F 5 m m
Thickness § 2.4.3
243
5 m m

2
RIV/EC 5 LUB

RIV/EC 8 PL 8 m m

Edition
Absence of detachments of base
metal.
Adhesion when new § 2.4.4.1 Allowed cohesion detachment
20 % of the test surface.
Adhesion Fragment dimension 3 mm 2 .
§ 2.4.4.2 Absence of detachments from
and Standard base metal.
Adhesion after aging
50180 No detachment allowed 3 mm
method B1 from incision lines.
for 144 h
(only for
coatings of
RIV/EC 8 PL Product of zinc corrosion 5 % of
a color
other than § 2.4.5 the significant surface
Resistance Silver) and Standard
to corrosion RIV/EC 5 50180
method A1
RIV/EC 5 F for 480 h

THIS DOCUMENT MUST NOT BE REPRODUCED OR CIRCULA TED TO THE THIRD PARTIES
The quantity
Th tit off possible
ibl fferrous

WITHOUT PRIOR WRIT TEN CONSENT BY FIAT AUTO S.P.A. IN CASE OF DISPUTE
RIV/EC 5 LUB
corrosion points must be 1/dm2.
RIV/EC 8 PL for 720 h
THE ONLY VALID REFERENCE IS THE ORIGINAL ITALIAN EDITION
§ 2.4.6
and Standard
Resistance to temperature § 2.4.5.2
50180
method A1
CONFIDENTIAL

§ 2.4.7
No ferrous corrosion must appear
and Standard
Cathode protection of coating on the incision surface at the end of
50180
the test.
method A1
§ 2.4.8 No surface defect is allowed (e.g.:
Resistance to gasoline and Standard spots, blisters, detachments) if
50473 compared to the unexposed part.
§ 2.4.9
No surface defect is allowed (e.g.:
and Standard
Resistance to the liquid window cleaner spots, blisters, detachments) if
50473/01
compared to the unexposed part.
Method B
§ 2.5
Bolt friction coefficient § 2.5
Standard 7.G0114

PUBLISHED BY SATIZ - NORMAZIONE


ALUMINIUM– AND ZINC–LAMELLAR 9.57513
BASE ANTI–CORROSION COATING FOR
FERROUS MATERIAL PARTS ANNEX 2
normazione Page: 1/2

CMD
CORRESPONDENCE BETWEEN FIAT AUTO DESIGNATION AND COMMERCIAL DENOMINA-
TIONS

Code
Correspondence between FIAT Auto designation and commercial denomination of coating materials/
processes qualified as per Procurement Specification 9.57513 and Experimentation Standard

-
7.G0114.

Ch.
DRAWING COMMERCIAL DENOMINATIONS
TYPE SUPPLIER
INDICATION Base coating Finishing

2
DACRAL S.A. GEOMET 321 ––

Edition
SIDASA – UCG ZINTEK 200 ––

DELTA TONE 9000


I RIV/EC 5 DOERKEN – MKS ––
DELTA PROTEKT KL
100

MAGNI FLAKE B46*


MAGNI ––
(Magni 565)

II RIV/EC 5 F DACRAL S.A. GEOMET 500 ––

1186 Torque’N Tension Control


GEOMET 321
DACRAL S.A. Fluid 
GEOMET 500
Gleitmo 605 
SIDASA – UCG ZINTEK 200 Merwin 65 Oil 
III RIV/EC 5 LUB
Dacrolub 10 and Dracolub 15 
DELTA TONE 9000

THIS DOCUMENT MUST NOT BE REPRODUCED OR CIRCULA TED TO THE THIRD PARTIES
DOERKEN – MKS DELTA PROTEKT KL Gardolube L 6255 

WITHOUT PRIOR WRIT TEN CONSENT BY FIAT AUTO S.P.A. IN CASE OF DISPUTE
100
Gardolube 6255 T 
THE ONLY VALID REFERENCE IS THE ORIGINAL ITALIAN EDITION
PLUS L (Cf 0.08 to 0.14)
DACRAL S.A. GEOMET 321 PLUS ML (Cf 0.10 to 0.16)
PLUS M (Cf 0.12 to 0.18)

TOP LG (Cf 0.10 to 0.16)


CONFIDENTIAL

TOP LF (Cf 0.12 to 0.18)


SIDASA – UCG ZINTEK 200 TECHSEAL WL–14
(Cf 0.10 to 0.16)
IV RIV/EC 8 PL TECHSEAL WL
(Cf 0.12 to 0.18)

DELTA SEAL GZ
DELTA TONE 9000
(Cf 0.10 to 0.16)
DOERKEN – MKS DELTA PROTEKT KL
DELTA PROTEKT VH 301 GZ
100
(Cf 0.10 to 0.16)

MAGNI TOP B18


MAGNI MAGNI FLAKE B46
(Cf 0.10 to 0.16)

PUBLISHED BY SATIZ - NORMAZIONE


Page 2
9.57513 Change

DRAWING COMMERCIAL DENOMINATIONS


TYPE SUPPLIER
INDICATION Base coating Finishing
PLUS ML BLACK (GEO-
DACRAL S.A. GEOMET 321
BLACK) (Cf 0.10 to 0.16)

TOP BLACK (Cf 0.10 to 0.16)


TECHSEAL BLACK WL–14
SIDASA – UCG ZINTEK 200 (Cf 0.10 to 0.16)
RIV/EC 8 PL TECHSEAL BLACK WL
IV (Cf 0.12 to 0.18)
Nero
DELTA TONE 9000
DELTA SEAL GZ BLACK
DOERKEN – MKS DELTA PROTEKT KL (Cf 0.100.16)
100

MAGNI TOP B37


MAGNI MAGNI BASE D21
(Cf 0.10 to 0.16)

* Only for non–threaded components

 Finishing 1186 Torque’N Tension Control Fluid by Mac Dermid


(Reference dilutions = 3 : 7 in water)
 Finishing Gleitmo 605 by Gleitmolybdän Schmiermittel Gmbh
(Reference dilutions = from 1 : 5 to 1 : 6 in water)
 Finishing Merwin 65 oil by Rods Oil Ltd
(Reference dilutions = 1 : 2 in water)
 Finishing Dacrolub 10 (for Cf 0.08 to 0.14) and Dacrolub 15 (for Cf 0.12 to 0.18) by Dacral
S.A.
 Finishing Gardolube L 6255 by Chemetall
(Reference dilutions = 1 : 3 in water)
 Reference finishing Granolube 6352 T by Henkel
(Reference dilutions = 1 : 3 in water)
THIS DOCUMENT MUST NOT BE REPRODUCED OR CIRCULA TED TO THE THIRD PARTIES
WITHOUT PRIOR WRIT TEN CONSENT BY FIAT AUTO S.P.A. IN CASE OF DISPUTE
THE ONLY VALID REFERENCE IS THE ORIGINAL ITALIAN EDITION
CONFIDENTIAL

PUBLISHED BY SATIZ - NORMAZIONE

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