Worksheet Definite Proportions - Key

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Name:

Period: Subject:
Date:

Law of Definite Proportions


Solve for the appropriate value. Be sure to show your work and remember to use the correct
number of significant figures.

1. A 53.0 g sample of an unknown compound contains 13.5 g of oxygen. What is


the percent by mass of oxygen in the unknown compound?

13.5 g
= 0.25471698 = 25.5 %
53.0 g

2. If 11.1 g of hydrogen reacts completely with 88.6 g of oxygen to form hydrogen


peroxide, what is the percent by mass of hydrogen in hydrogen peroxide?

hydrogen + oxygen => hydrogen peroxide


11.1 g 88.6 g ?g

11.1 g + 88.6 g = 99.7 g


11.1 g 11.1 %
= 0.11133400 =
99.7 g

3. A 111.7 g sample of iron reacts with 100.0 g of oxygen to form iron oxide (rust).
After the reaction, there is 52.0 g of unreacted oxygen remaining. What is the percent by
mass of oxygen in the rust?

iron + oxygen => iron oxide (rust) + oxygen


111.7 g 100.0 g ?g 52.0 g

(111.7 g + 100.0 g) - 52.0 g = 159.7 g (this gives the total grams of rust)

100.0 g - 52.0 g = 48.0 g (this gives the oxygen that actually went into the rust)
48.0 g
= 0.30056356 = 30.1 %
159.7 g
4. If a 43.0 g sample of carbon dioxide (CO2) is found to be 27.3% by mass carbon,
then how much oxygen (in grams) is found in a 78.0 g sample of carbon dioxide?

oxygen = 27.3 % (Sample 1)


carbon dioxide

oxygen = 27.3 % (2nd sample)


78.0 g

oxygen = 78.0 g · 27.3 % = 78.0 g · 0.273 = 21.294 g = 21.3 g

5. A 57.6 g sample of methane (CH4) is found to contain 43.2 g of carbon. How


much hydrogen (in grams) would a 37.8 g sample of methane contain?
43.2 g carbon ? g carbon
57.6 g methane = 37.8 g methane
Sample 1 Sample 2

Solving for above, Sample 2 has 28.35 g carbon.

37.8 g methane - 28.35 g carbon = 9.45 g hydrogen

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