Carbon Resources Conversion 6 (2023) 215–228

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Carbon Resources Conversion

journal homepage: www.keaipublishing.com/en/journals/carbon-resources-conversion

Microwave-assisted pyrolysis of waste plastics for their resource reuse: A

technical review
Xuan Hu a, Dachao Ma a, c, *, Guangyi Zhang b, d, Mengxue Ling a, Qiaoling Hu a, Kangyi Liang a,
Jiacheng Lu a, Yifan Zheng a
a
School of Resources, Environment and Materials, Guangxi University, Nanning 530004, China
b
School of Ecology and Environment, Beijing Technology and Business University, Beijing 100048, China
c
Key Laboratory of Environmental Protection, Guangxi University, Nanning 530004, China
d
State Key Laboratory of Multiphase Complex Systems, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, China

A R T I C L E I N F O A B S T R A C T

Keywords: Rapidly increasing plastics have been used and finally become wastes, resulting in increasing pressures to the
Review environment. Microwave-assisted pyrolysis is a promising technology for converting organic wastes as waste
Waste plastics plastics into value-added products. At present, many works on microwave-assisted pyrolysis of plastics have been
Microwave-assisted pyrolysis
published, but the achievements, challenges, and future directions of microwave-assisted pyrolysis of waste
Challenges
plastics have not been well summarized and discussed. In this work, the principle of microwave-assisted pyrolysis
technology is introduced. Then, the progress of its application to recover useful products from plastics is
reviewed and discussed in terms of key parameters including microwave power, pyrolysis temperature, reaction
time, types of catalyst, microwave absorbents and feedstock mixing ratio. Especially, the yields and properties of
the produced oil, gas and char are correlated with the process parameters. Finally, the existing challenges and
prospects of disposal/reuse of waste plastics by microwave-assisted pyrolysis technology are discussed.

1. Introduction effective management and recycling for waste plastics.

In recent years, many technologies have been developed to recycle
With advantages of strong corrosion resistance, low manufacturing waste plastics which can be classified into four types: Primary recycling
cost, durability, light weight, good plasticity and insulation, plastics refers to transforming recyclable waste plastics into products directly.
have been widely used in various fields such as agriculture, industry, Secondary recycling, also known as mechanical recycling, is a physical
construction, packaging, and defense industries. As shown in Fig. 1, the method to convert waste plastics into products through sorting,
global production of the plastic is keep increasing annually by 4%. Ac­ grinding, cleaning and extrusion [8,9]. Tertiary recycling uses chemical
cording to statistics, 9.2 billion tons of plastic is accumulatively pro­ and thermochemical methods to recover various components of waste
duced by 2017 [1]. As estimated, the accumulative plastic production plastics, converting polymers into monomers or fuels. Quaternary
will reach 34 billion tons by the end of 2050 with over 500 million tons recycling means recovering energy from waste plastics by incineration
per year [2]. Unfortunately, around 50% of plastic is disposed without [10,11]. Pyrolysis can crack plastic into high-value products such as
recycling [3,4]. liquid hydrocarbons, coke and gases for energy or further chemical re­
The plastic life stream from manufacturing to disposal will emit a finery [12–14]. It can reduce the carbon footprint since the whole pro­
huge amount of greenhouse gases (GHG), occupying 4.5% of global cedure emits less detrimental gases than traditional incineration and
emission, which will consume 10%-13% of the carbon emission quota by landfill [15–17]. Thus pyrolysis has attracted a lot of attention.
2050 [6]. What’s more, with approximately 8–11 million tons of plastics The conventional pyrolysis technologies normally use thermal heat
dumping into the oceans every year, microplastics in the oceans have to heat up the feedstock such as coal [18–20], biomass [21–23], waste
kept being absorbed and accumulated by animals, eventually ingested plastics [24,25]. The heat energy to stimulate the reaction can be ob­
by human through the food chain [7]. Therefore, it is crucial to make tained from partial combustion of the feedstock, while it will emit CO2.

* Corresponding author at: School of Resources, Environment and Materials, Guangxi University, No. 100, Daxue East Road, Nanning 530004, China.
E-mail address: [email protected] (D. Ma).

https://doi.org/10.1016/j.crcon.2023.03.002
Received 3 October 2022; Received in revised form 25 February 2023; Accepted 2 March 2023
Available online 5 March 2023
2588-9133/© 2023 The Authors. Publishing services by Elsevier B.V. on behalf of KeAi Communications Co. Ltd. This is an open access article under the CC
BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/).
X. Hu et al. Carbon Resources Conversion 6 (2023) 215–228

The external heat carriers such as hot nitrogen, steam, limestone and etc. collision between polarized molecules. The second mechanism is the
can also heat up the feedstock to start the reaction. However, due to the interface polarization, also known as space charge polarization or
heat and mass transferring limitation in the conventional heat method, Maxwell-Wagner polarization. Due to the conductivity or dielectric
the energy efficiency is low and the products fraction cannot be well constant is nonuniform in the medium, interface polarization will occur
controlled. The low heat conductivity of plastics makes the mass and as accumulation and inhomogeneous distribution of free charge. The
heat transferring worse. Microwave-assisted pyrolysis has become a third mechanism is the conduction mechanism, which the microwaves
promising technology as it can realize fast, selective heating and is easy motivate the moving of free ions in the medium to generate current. At
to control the reaction conditions [26,27]. the same time, the movement causes the collision among ions, thereby
Nowadays, literatures on microwave-assisted pyrolysis of plastics are generate heat energy [36,37].
intensively published to explore the changes of yields and properties of
products with reaction conditions and types of plastics. The challenges, 3. Microwave reactors for plastic pyrolysis
and limitations as well as future directions of this technology especially
for waste plastics are rarely reported. This paper reviews the progress of At present, the research on microwave-assisted pyrolysis of waste
microwave-assisted pyrolysis in treating waste plastics and the pros­ plastics is almost carried out in laboratory-scale batch-type reaction
pects. The product distribution of different types of plastics under mi­ devices as shown in Figs. 4-5. The reactors are usually consisted of mi­
crowave is summarized. The parameters affecting the microwave- crowave generator, reactor with sealed cover to prevent the leaking of
assisted pyrolysis process, such as microwave power, temperature, radiation, and collection system outside of the reactor to separately
residence time, and catalyst are evaluated. The study devotes to retro­ collect liquid and gaseous products. The capacity for those reactors is
spect extensively the recent works on microwave-assisted technology as mostly less than 20 g/batch [38–40]. Recently, a continuous microwave-
a profitable method applied to the pyrolysis of waste plastics. assisted pyrolysis (CMAP) system has been developed as shown in Fig. 6.
It has a silicon carbide downdraft mixed bed with a total microwave
2. Principle of microwave-assisted pyrolysis output power of 9 kW. The feedstock can be stored in the hopper and
continuously fed by an auger feeder with capacity of 10 kg/h. Contin­
As shown in Fig. 2, microwave radiation is a kind of electromagnetic uous reaction system is one of the promising research orientations for
radiation with a wavelength from 1 cm to 1 m and a frequency from 0.3 the commercialization of microwave-assisted pyrolysis technologies [2].
to 300 GHz [28,29]. At present, microwave is widely used in various
fields such as radar [30], communication [28], household heating oven 4. Progress in microwave-assisted pyrolysis of plastics
[31], drying equipment [32] and etc.. In order to avoid interference
between telecommunication and cellular frequencies, each of these ap­ Municipal solid waste mainly includes five types of polyolefin plas­
plications has unique wave band. Generally speaking, radar trans­ tics, polyethylene (PE), polypropylene (PP), polyvinyl chloride (PVC),
missions use wavelengths which range from 0.01 m to 0.25 m, while polystyrene (PS) and polyethylene terephthalate (PET). In recent years,
telecommunications use the rest of the wavelengths [26]. Frequencies of microwave heating technology has been widely used in the pyrolysis of
915 MHz (λ = 32.8 cm) and 2450 MHz (λ = 12.25 cm) are used for these waste plastics to produce a liquid product without any pretreat­
industry and household appliances, respectively [33]. ment, which can be used as a chemical or fuel source [42,43].
As shown in Fig. 3, conventional heating usually heat up the feed­
stock particles on the surface firstly. Then the energy will transfer into
4.1. Microwave-assisted pyrolysis of plastics
the center by heat conduction. Thus, the materials with low thermal
conductivity such as plastic, wood will perform low energy efficiency in
Microwave-assisted pyrolysis can convert wasted plastics into value-
conventional pyrolysis. Differently, microwave energy interacts with
added products [44]. The liquid products produced from microwave-
feedstock by three ways: (1) Highly conductive materials regarded as
assisted pyrolysis of plastics can be further converted to low sulfur
conductor, will reflect microwaves; (2) Microwaves can directly pene­
naphtha and diesel fuel by distillation [45]. As shown in Fig. 7, different
trate insulators such as glass, plastic and ceramics without being
plastics have various yields of oil under microwave irradiation.
absorbed; (3) Some dielectric mediums (e.g., water, wood, etc.) can
PS shows the highest average oil yield as 68.92 wt%. The oil com­
adsorb microwave energy, consequently can be heated up from the in­
ponents were mainly monocyclic aromatic hydrocarbons and polycyclic
side of the particle in the microwave field [34,35]. Therefore, the mi­
aromatic hydrocarbons, followed by cycloolefins and olefins, which
crowave heating can break through the limitation of heat conduction.
were similar to the components of aviation oil [53], which is consistent
Based on the movement of the molecules, microwaves heat up the ma­
with the conclusions from Undri’s work [47]. While LDPE has the lowest
terial through three main mechanisms. The first mechanism is dipole
average oil yield as 15.74 wt%. In addition, Table 1 shows studies for the
polarization, which generates heat through high-speed rotation and
pyrolysis of wasted plastics under microwave field. The products of

Fig. 1. Global plastics production capacity change trend [5].

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Fig. 2. The electromagnetic spectrum [28].

Fig. 3. The temperature gradients of microwave and conventional heating [37].

conventional pyrolysis [50]. This was because the repeated presence of

Cl atoms in the PVC skeleton provided polar nature.
Although the prospect of simple plastic under microwave-assisted
pyrolysis has been confirmed, the waste plastics in real life are often
mixtures. For this type of waste, Aishwarya and Sindhu induced the
microwave-assisted pyrolysis of plastic mixture. Compared with the
homogenous plastics, the oil produced from the microwave-assisted
pyrolysis of plastic mixtures is slightly viscous, but the mixture of con­
sistency is uniform and is completely liquid at room temperature. It can
also be viewed as transportation fuel. Due to the amorphous nature of
the char, it can become an ingredient of tar [51]. The halogenated
plastic formed by a part of waste from Electric and Electronic Equipment
from end-life computers was also converted into high-quality liquid oil
in different reaction conditions. The calorific value was above 30 MJ/kg,
suitable as fuel [52].

4.2. Microwave catalytic pyrolysis of plastics

Fig. 4. Schematic of microwave-assisted pyrolysis experimental setup by Sur­
iapparao [41]. Although the microwave-assisted pyrolysis technology shows ad­
vantages for most feedstocks [54], the pyrolysis process requires a large
microwave-assisted pyrolysis HDPE and LDPE were naphtha, gasoline amount of energy owing to the poor thermal conductivity of plastics.
and residue, and the quality of liquid oil was similar with diesel [48]. It What’s more, the products from plastics by microwave-assisted pyrolysis
was easy to obtain fuel intermediates and petrochemicals from the are mixtures with different carbon chain lengths (such as wax, diesel/
microwave-assisted pyrolysis of PP [49]. PVC could be dechlorinated by gasoline hydrocarbons), limiting their application in the industrial scale
microwave heating. At the same temperature, the selectivity for [38,39]. In order to overcome the defects and get more valuable prod­
dechlorination by microwave-assisted pyrolysis was higher than that by ucts with less energy consumption, adding catalysts to the microwave-

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Fig. 5. The schematic diagram of the microwave-assisted pyrolysis system integrated with zeolite catalysis process by Zhang [38].

Fig. 6. Schematic diagram of the CMAP system [2].

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Fig. 7. The average of oil yield in microwave pyrolysis of different plastic [46].

found that MgO could convert volatile components into gas effectively,
Table 1
promote the formation of alkanes, and catalyze diesel fractions into
Effect of microwave on different types of plastic.
gasoline fractions during the microwave pyrolysis of LDPE [57]. Ding
Type of plastic Mode of Effect of microwave pyrolysis on Refs learned that NiO had hydrogen absorption capacity which could
heating different plastics
decompose LDPE into a large number of olefins [39]. Carbon based
PS Microwave Gave a liquid (yield 86.5 wt%) [47] materials such as SiC and activated carbon can also improve the reaction
containing higher amount of single efficiency. In the microwave pyrolysis of HDPE, the distribution of liquid
ring aromatic compounds;
gas and solid may be used as fuel
products was concentrated on gasoline and diesel fractions as activated
HDPE, LDPE Microwave Composition of fuels from HDPE and [48] carbon performed a good catalytic role [60]. Although catalyst is
LDPE pyrolysis are naphtha, gasoline, conducive to the microwave pyrolysis of waste plastics, the catalyst will
and residues be poisoned or inactivated in the reaction. The waste catalyst will
PP Microwave PP (around 96 wt%) was converted [49]
become solid residue mixed with the produced char [63]. Thus, it is
into useful liquid and gaseous
hydrocarbons desirable to find a substitute of catalyst for the pyrolysis of waste
PVC Microwave Selectivity of dechlorination with [50] plastics.
microwave irradiation was higher
than that with conventional heating,
as was the case with the 4.3. Microwave-assisted co-pyrolysis of plastics and biomass
dechlorination ratio
Mixture of waste Microwave The condensate produced could be [51] As biomass is renewable and carbon neutral, it is a promising sub­
plastics used as a transport fuel relatively
easily;
stitute for fossil fuels to alleviate the energy crisis and control the
char could be used as a component in emission of harmful pollutants [64]. Pyrolysis can convert biomass into
tar valuable biochar, bio-oil and syngas [65,66]. However, the bio-oil
Halogenated Microwave A large amount of various different [52] derived from biomass usually has low calorific value, high viscosity,
plastics liquid fractions (76.6 wt%) were
high acidity, and high oxygen content, limiting its application [67,68].
formed together with a remarkable
reduction of the solid residue (14.2 wt As shown in Table 3, polyolefin plastic is a kind of hydrogen-rich com­
%) pound, which can be a hydrogen donor in the co-pyrolysis process with
biomass, balancing the distribution of carbon, hydrogen and oxygen in
the feedstocks, improving synergistically the quality of bio-oil,
assisted pyrolysis process is necessary [55]. Fig. 8 presents the optimum providing a win–win strategy in utilization of plastics and biomass
oil yield from LDPE with catalysts by microwave while different cata­ with low cost and high efficiency [69–71].
lysts exhibit a marked variability in performance under exposure to
microwave. Catalysts like zeolite, sodium methoxide, metal, etc. can
reduce the reaction temperature and activation energy, and improve the 4.4. Microwave-metal interaction
selectivity of the products.
Table 2 lists studies on microwave catalytic pyrolysis of plastics. So far, all the work about the microwave-assisted pyrolysis tech­
HSZM-5 can improve the cracking degree of waste plastics during the nology to treat waste plastics are focusing on catalysts, microwave ab­
microwave-pyrolysis process, promoting the aromatization of the sorbents or co-pyrolysis with synergistic substances to improve the
products, and further convert wax into liquid oil [61,62]. ZSM-5 can reaction efficiency. In addition to these conventional microwave heating
convert long-chain olefins into small hydrocarbons and improve the methods, there is a special microwave action method - Microwave metal
selectivity in isomerization and aromatization reactions. Increasing the pyrolysis. Specifically, the metal is placed in the reactors in shape of
amount of ZSM-5 can improve the yield of monocyclic aromatic hy­ cylindrical, coil, etc. When microwaves are absorbed by metals and
drocarbons in LDPE pyrolysis oil by 10% and enhance the hydrogen accumulating to a certain, they will ionize and break through the sur­
production [38]. Metal oxides are also commonly used catalysts. Fan rounding medium, forming hot spots locally where the temperature
reach the melting point of metals in a short time [80]. As shown in

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Fig. 8. Effect of different catalysts on product yield

from LDPE by microwave. Data adapted from
Zhang et al. [38] LDPE and ZSM-5 (pyrolysis tem­
perature: 450 ◦ C, holding time: 10 min), Ding et al.
[39] LDPE and HY (pyrolysis temperature: 500 ◦ C,
holding time: 20 min), Istoto et al. [48] LDPE
(pyrolysis temperature: 500 ◦ C, holding time: 60
min), Hassan et al. [56] LDPE and Zeolite (pyrolysis
temperature: 550 ◦ C, holding time: 90 min) and
Fan et al. [57] LDPE and MgO (pyrolysis tempera­
ture: 500 ◦ C, holding time: 20 min).

Table 4, this technology can be used as an effective alternative way to

Table 2
convert waste plastics into fuel quickly, which has a great application
Effect of catalyst on microwave-assisted pyrolysis process.
prospect.
Type of Type of catalyst Catalyst effect Refs
plastic
5. Factors influencing microwave-assisted pyrolysis of plastics
LDPE Natural zeolite Zeolite catalyst pushed faster the [56]
degradation process of plastic The yield and quality of the final products from microwave-assisted
and raised liquid products yield
PET Sodium methoxide The time needed to achieve complete [58]
pyrolysis of plastics are strongly related to the parameters. As shown in
degradation of PET was only 5 min and Table 5, microwave power, pyrolysis/catalytic temperature, reaction
showed no degradation without time, catalyst type, absorbent, and raw material ratio are the significant
catalyst factors.
HDPE FeAlOx FeAlOx took only 20 s to exact almost [59]
When the microwave power was increased from 300 to 1400 W, the
97% of the hydrogen from waste
plastics. time for microwave to heat the mixed waste from room temperature to
HDPE Activated carbon Activated carbon could make the liquid [60] 300 ◦ C was shortened by two thirds [85]. Dai’s research on microwave-
and molecular products concentrate on gasoline and assisted co-pyrolysis of PVC and microalgae found that when the power
sieves diesel fractions; Molecular sieves was increased from 800 to 1000 W, the heating rate was increased from
promoted the cracking of
hydrocarbons
257 to 402 ◦ C/min [78]. The increase of power is conducive to the
PP and HZSM-5 HZSM-5 improved the integrity of co- [61] formation of bio-oil, but the response of oil yield to microwave power is
chili pyrolysis and promoted the not monotonic as shown in Fig. 9. As the microwave power vary from
straw aromatization of the pyrolysis products 450 to 800 W, the yield of oil from microwave-assisted pyrolysis of PS
LDPE ZSM-5 ZSM-5 had a positive effect in [38]
with SiC was first increased and then decreased at around 650 W, while
converting LDPE into valuable
aromatics and enhancing the the yield of gas and wax was opposite to that of oil products [53]. This
production of hydrogen. was because the increased microwave power generated more energy,
LDPE MgO MgO catalyst improved the cracking of [57] which further decomposed solid products into liquids and gases. Sur­
the macromolecular volatiles and iapparao also confirmed this inference in the microwave-assisted co-
promoted the hydrogenation of
alkenes for alkanes formation as well
pyrolysis of PP and graphite [41]. In addition, the composition in liquid
as catalytic conversion of diesel product was different under different microwave power. At 300 W,
fraction to gasoline fraction. aliphatic hydrocarbons dominated the liquid fraction from PP pyrolysis.
LDPE HZSM-5 HZSM-5 catalyst narrowed the carbon [62] With the power increasing to 600 W, the selectivity of monocyclic aro­
number distribution and facilitated
matic hydrocarbons increased and the content of cycloalkanes decreased
aromatic formation; Resulted in
different shape selectivity. [49]. Therefore, it is extremely important to choose appropriate mi­
LDPE NiO and HY zeolite NiO catalyst increased the yield of ON [39] crowave power.
compound and extracted hydrogen Temperature and retention time are also crucial factors in the
from alkanes to produce alkenes; HY microwave-assisted pyrolysis process. In the microwave pyrolysis pro­
could convert alkenes into aromatics
and cyclo-alkenes
cess of waste PET bottles, the conversion rate of PET increased from
28.46% to 100% with the temperature rose from 40 to 70 ◦ C [58]. As
shown in Fig. 10, the liquid product yields have the peak temperature for
most of the studies. In the study on microwave-assisted pyrolysis of PS,
the oil yield reached its maximum at around 460 ◦ C. This was because
when the pyrolysis temperature was higher than 460 ◦ C, the secondary

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Table 3
Microwave-assisted co-pyrolysis of various kinds of waste plastics and solid biomass.
Type of Type of Plastic to biomass Oil yield(wt.%) Gas yield(wt.%) HHV(Oil, MJ/kg) Refs
plastics biomasses

Biomass Mixture Composition Biomass Mixture Biomass Mixture

Alone Alone Alone

PET Rice husk 1:3,1:5,1:1,3:1,5:1 26 12–29 Monoaromatic oxygenates 42.1 39–69 13.1 34–36 [72]
and biphenyl hydrocarbons
are the major compounds

PP, PS Groundnut shell, 1:1 29–40 51–60 PS-biomass: improved the 36–50 23–31 PS 11–18 38–42 [73]
bagasse, rice PS production of aromatic 46–57 PP
husk, prosopis 25–41 hydrocarbons;
juliflflora and PP PP-biomass: promoted
mixed wood aliphatic hydrocarbons and
sawdust enhanced the selectivity
towards alkanes
PP, PS Wheat straw 1:1 54.4 26–37 High selectivity of aromatics 35.4 51–68 17.5 40–42 [74]

LDPE Microwave- 7:3,3:7,5:5 20 17 Increased the hydrocarbons 36.13 38.9 _ _ [75]

torrefied lignin (80%) and aromatic
hydrocarbons;
Reduced the phenols
LDPE Paper, pulp, 1:19 _ 27.1 Furfural and 2-Fruancarbox­ _ 41.3 _ _ [76]
cellulose aldehyde, 5-methyl-;
Generated aromatic
compounds and small
organic molecules
PP Chili straw 7:3,5:5,3:7 _ _ Increased the hydrocarbons _ _ _ _ [62]
and reduced the oxygenates
_ _ _
PVC Sophora wood 1:1,1:3,1:5 43 46–48 Reduced the content of HCl [77]
chlorine-containing (Decrease
compounds; from 30%
Increased the light to 15%)
hydrocarbons and char
Decreased the content of
PVC Microalgae 1:9,3:7,5:5,7:3,9:1 44.42 23–38 nitrogenous and oxygenous 25.92 19.8–57.6 32.71 33–39.73 [78]
organic matter;
Increased the content of
aromatic hydrocarbons

HDPE Chlorella vulgaris 1:0,4:1,2:1,1:1,3:2, _ _ Increased the hydrocarbons _ _ 21.55 _ [79]

1:4 and alcohols;
Decreased the nitrogen-
containing compounds and
the oxygen-containing
compounds

decomposition of volatile compounds resulted in lower oil yield [53]. with microwave-assisted co-pyrolysis of PS and SiC, the reaction time
This phenomenon was consistent well with the experimental results of was reduced by two thirds through co-pyrolysis of PS and char
Duan [87]. In addition, the composition of oil will also change signifi­ respecting to the same oil yield. The loading of absorbent will affect the
cantly according to the temperature. Higher temperature can suppress fraction of pyrolysis products. Increasing the loading of SiC can raise the
the aromatization reaction, leading to the reduction of aromatic content oil yield. Meanwhile, with too high SiC loaded, the secondary decom­
in the product [60]. Finding a suitable reaction temperature is essential position of volatile compounds into small molecular hydrocarbons will
for regulating the reaction process of microwave-assisted pyrolysis of result in lower oil yield [53]. In a word, absorbent plays an important
plastics. Generally, longer resident time means higher oil yield [56]. role in microwave-assisted pyrolysis. As well as, the media loss factor,
Jing studied on microwave-assisted pyrolysis of HDPE, the highest oil specific surface area, water content, ash content of the absorbent itself
yield of 82.36 wt% could be obtained by appropriately prolonging the are closely related to the quality and the distribution of pyrolysis
retention time [60]. In contrast, the oil yield would reduce with the products [86,92].
decrease of time at low power. This was because the secondary cracking In the microwave-assisted pyrolysis, feeding ratio of waste plastics to
was difficult to undergo for oil [88]. absorbent can affect not only the fraction of char, oil and gas, but also
Due to poor microwave absorption ability of plastics [36,90], it is the composition of products. In the experiment of ex-situ catalytic py­
necessary to introduce microwave absorbent to receive and convert rolysis of LDPE with MgO, it was observed that when the ratio of catalyst
microwave energy, improving the energy efficiency. The heating rate for to plastic increase from 0 to 1/10, the oil yield decreased from 46.3 wt%
different microwave absorbent varies with intrinsic structures and to 30.3 wt% and the gas yield increased from 52.8 wt% to 67.0 wt%.
delocalized electrons in the valence band. Suriapparao [41] found that, However, when the ratio exceeded 1/10, there was little change in the
in microwave-assisted pyrolysis of PP, the heating rate was the highest yield of oil and gas [57]. Ding also found similar phenomenon [39]. For
with the addition of fly ash as absorbent. While, SiC was the lowest. microwave absorbents synthesized from different raw materials such as
Bartoli [91] performed that char powder obtained from the microwave- rice husk, corn husk and coconut sheath, the highest oil yield of PP and
assisted pyrolysis of tires is a potential microwave absorbent. Compared PS pyrolysis appeared at the same mixing ratio of feedstock to absorbent

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Table 4
Effect of microwave-metal interaction on microwave-heating plastics.
Operating parameters Optimum Yield
Type of Type of Shape of metal
plastic metal Refs

Power (W) T (◦ C) t Oil (wt. Gas (wt. Solid (wt.

(min) %) %) %)

PS Iron Cylindrical mesh of ironl 700 1100–1200 10 80 15 5

[81]

PS and coal Copper Copper coil _ The melting point range 16 66 6 18

of copper [82]

PS Aluminum Aluminum coil,strips and _ The melting point of 8–40 88 10 2 [44]

cylinder aluminum

PS Copper Copper coil _ 1000–1100 5–15 85 12 3

[83]

PS, PP, Iron Iron coil 500–2500 154–937 30 _ _ _

LDPE [84]

PS, PP, Iron Iron coil 500–2500(with an 250–800 19 88.7 6.7 4.6
LDPE increment of 200 W) [46]

[86]. In addition, properly increasing the feeding ratio of biomass can hydrogen which can be used as chemical material or green energy.
improve the quality of bio-oil from the co-pyrolysis of waste plastics and
biomass [78]. 7. Conclusion and prospect

6. Application of microwave technology Compared with traditional pyrolysis, microwave-assisted pyrolysis is

a promising technology to convert waste plastics into value-added
The first commercial microwave oven was invented by P. Spencer of products. The reaction process can be controlled by changing micro­
Raytheon company in 1952 [93]. Currently, microwave technology has wave power, pyrolysis temperature, reaction time, catalyst, microwave
already played an important role in various fields. Firstly, it is widely absorbent, raw material blending ratio, and etc. The produced oil can
used in the food and herb industry for sterilization, drying and thawing directly replace petroleum oil. Despite of many advantages, there are
process. As shown in Fig. 11(a), it is a sterilization system consisted of still bottlenecks limit the progress of microwave-assisted pyrolysis of
microwave cavities, which is suitable for various packaged food prod­ plastics.
ucts weighed in 0.30 kg to 2.50 kg. Compared with traditional heating Nowadays, most of the research on microwave-assisted pyrolysis of
treatment methods as steam or hot water, it can reduce processing time waste plastics needs to be carried out with absorbent due to the poor
and penetrate into deep inside of the foods [94]. The household mi­ dielectric property of the plastic. However, the specific role of the
crowave oven is also intensively used in daily life for heating food [95]. absorbent in the energy conversion and catalyzing the reaction in the
In the mining and metallurgical industries, the thermal stress induced by microwave-assisted pyrolysis process is still unclear. Considering the
microwave can soften the hard rocks which is depicted in Fig. 11(b). The heating efficiency mainly relies on the dielectric properties of the ma­
metal elements therein can be dissolved or extracted easier [96,97]. Due terial, it is indispensable to detect the change of dielectric properties,
to less noise and dust, it has better environmental benefits than tradi­ magnetic properties and thermal properties of absorbents and feedstocks
tional rock breakage methods such as drilling, blasting, jack hammers, under microwave. Additionally, care should be taken when measuring
etc [98]. Microwave heating is also applied in the ceramic industry, dielectric properties because the result accuracy is easily affected by the
where microwave can significantly reduce the calcination temperature, interval or uniformity of raw material [104–106].
thereby generating new composite materials [99,100]. What’s more, Another critical limitation is that it is hard to accurately measure the
microwave has shown positive effect on the germination of cones [101] reaction temperature with conventional measuring equipment such as
and wood drying [102]. Fig. 11(c) displays a cylindrical microwave thermocouple and infrared thermometer. The thermocouple will start to
vacuum drying chamber (60 cm in diameter and 150 cm in height) with melt as the reaction temperature is above 1000 ◦ C. Besides, the tem­
2450 MHz frequency magnetrons. Lv et al. found this drying chamber perature inside the core of feedstock is usually higher than the surface in
can prevent bamboo from cracking and shrinkage so as to improve the microwave-assisted pyrolysis, thus the temperature measured by
quality of bamboo and energy efficiency with response to the traditional infrared has a hysteresis phenomenon [107]. Moreover, the hotspot ef­
drying methods [103]. In addition, microwave technology also plays an fect induced by microwave will pose an extra challenge to the accurate
important role in the field of chemical organic synthesis. measurement of temperature [8]. In the future, the measurement tech­
Recently, microwave technology used to pyrolyze waste plastics into nology can be improved by combining thermocouple, thermal imaging
oil, gas and char has attracted increasing attention. Usually, the pro­ scanner and software, such as QW-BHM or Quick Wave 3D, so as to
duced liquid oil has similar characteristics to conventional diesel as a ensure the monitoring of internal real-time temperature, modeling the
fuel. Fan et al. got the highest oil yield in the world was 98.78 wt% under temperature field in the microwave reactor accurately [108,109].
the optimum condition by microwave pyrolysis waste PS. It is found the Until now, microwave-assisted pyrolysis of plastics is proven effec­
main components of pyrolysis oil were C8-C16 (64.79–85.93 area%) in tive only in the laboratory scale. In the future, it is essential to scale up
which styrene (C8H8) occupy 44.34–73.59 area%, indicating that the oil microwave treatment reactors from laboratory to pilot. In addition, the
has the potential to be converted into aviation oil [53]. Char produced economic viability of microwave-assisted pyrolysis of plastics is also
from microwave pyrolysis can be applied in treatment of water, flue gas, need to be focused. Zhou et al. found that the energy derived from the
and etc. [14]. The produced gases from microwave heating are almost gas product alone can satisfy the energy demand during the pyrolysis of

222
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Table 5
Effect of various factors on microwave-assisted pyrolysis of plastic.
Type of plastic Mass of Mass of Operating parameters Optimum Yield Others HHV Refs
plastic absorbent (MJ/kg)
(g) (g)

Power Temperature Time Catalyst Microwave Plastic to Plastic Oil (wt. Gas Solid
(W) (◦ C) (min) type absorbent absorbent to %) (wt.%) (wt.
ratio catalyst %)
ratio

Organochloride 50 g – 400, 800, 220–300 15–20 – Graphite, silicon 2:1 – – – – 87% 20.56 [85]
plastics 1200, carbide dechlorination
1400 rate
PVC and 50 g 10 %AC 800, 1000 550 40 – Activated — — 41.5 24.9 33.6 – 20–30 [78]
microalage carbon
(1:9, 3:7, 5:5,
7:3, 9:1)
PS 30 g 30, 45, 60, 450, 550, 340, 400, 460, 60 – Silicon carbide 98.78 0.56 0.66 – – [53]
75, 90 650, 750, 520, 580
850
PP 5–50 g – 180, 300, 600 – – Activated 5:1–100:1 – 89.34 10.57 0.09 – 36.37–44.45 [41]
450, 600, carbon, silicon
800 carbide,
graphite,
aluminium
powder, lignin
223

and fly ash

PP 50 g 50, 200, 300, 450, 600 – – Graphite – – 83.3 – – – 42–44 [49]
350 600
PET 0.3 g 0.2 g 300 30–70 1–7 Sodium – – – – – – 73.93% – [58]
methoxide Terephthalic
acid
PP and lignin 10 g 850 g – 200, 250, 300, – HZSM-5 Silicon carbide – 1:0, 1:1, 59.42 19.36 21.22 – – [87]
(1:0, 1:1, 1:2, 350 bed 2:1,4:1
2:1, 0:1)
LDPE 30 g 30 g – 300, 400, 500, 45, Zeolite Activated 1:1 1:1 28.12 69.00 2.88 Containing – [56]
550 60, catalyst carbon polymeric
75, 90 compounds
HDPE – – 20%-40% 520 0–90 Activated – 100:100, 2:1,4:1 87.75 5.25 7 – – [60]
of 900 W carbon and 100:330
molecular
sieves

Carbon Resources Conversion 6 (2023) 215–228

Halogenated 200 g 100 3000 386–450 30–60 – Iron and carbon 2:1 – 76.6 2.2 21.2 – 37 [52]
plastics
LDPE 20 g – 700 480 10 ZSM–5 – – 1.32:1, 32.58 65.13 1.89 – – [38]
4.68:1
LDPE 15 g 500 3000 350, 400, 450, 20 MgO Silicon carbide 3:100 15:1, 24.2–38.5 >56.6 <7.1 – – [57]
500, 550 10:1,
5:1, 3:1
PS, PP, PS + PP 10 g 1–4 180, 360, – 10,20 – Carbon and 10:0.5, – 84.30 15.7 – – 46.87 [86]
540,720, activated carbon 10:1, 10:2
900
X. Hu et al. Carbon Resources Conversion 6 (2023) 215–228

Fig. 9. Effect of microwave power on oil yield by microwave pyrolysis plastics. Data derived from these typical references: Suriapparao et al. [41] PP and graphite
(holding time: 40 min), Arshad et al. [46] PS/PP/LDPE and iron coil (holding time: 19–26 min), Fan et al. [53] PS and SiC (holding time: 60 min), Dai et al. [78] PVC
(holding time: 40 min), Rex et al. [86] PP,PS and rice husk activated carbon (holding time: 10–20 min).

Fig. 10. Effect of temperature on oil yield in the

microwave pyrolysis process. Data adapted from
Zhou et al. [2] HDPE (total microwave power: 9 kW,
holding time: 60 min), Zhang et al. [38] LDPE and
ZSM-5 (total microwave power: 1 kW, holding time:
10 min), Ding et al. [39] LDPE and HY (total micro­
wave power: 1.8 kW, holding time: 20 min), Fan et al.
[53] PS and SiC (total microwave power: 1 kW,
holding time: 60 min), Fan et al. [57] LDPE and MgO
(total microwave power: 3 kW, holding time: 20 min),
Zhao et al. [64] PP/bamboo and HZSM-S (total mi­
crowave power: 1 kW), Yu et al. [77] PVC and
sophora wood (total microwave power: 1 kW, holding
time: 30 min), Duan et al. [87] PP/liglin and HZSM-5
(total microwave power: 1 kW), Zeng et al. [89]
LDPE/waste cooking oil and HZSM-5 (total micro­
wave power: 1.4 kW, holding time: 30–70 min).

HDPE [2]. Before putting into practical application, it is necessary to microwave-assisted pyrolysis of plastics is also noteworthy.
conduct further studies on the techno-economic assessment of the
technology, considering the energy consumption, the cost of equipment,
labor and maintenance. In addition, the carbon footprint in the

224
X. Hu et al. Carbon Resources Conversion 6 (2023) 215–228

(a)

(b)

(c)

Drying

Fig. 11. Application examples of microwave technology: a microwave sterilization system (a) [94]; a microwave-induced cutting apparatus (b) [98]; a cylindrical
microwave vacuum drying chamber (c) [103].

225
X. Hu et al. Carbon Resources Conversion 6 (2023) 215–228

CRediT authorship contribution statement [19] Z. Chen, Y. Shi, D. Lai, S. Gao, Z. Shi, Y. Tian, G. Xu, Coal rapid pyrolysis in a
transport bed under steam-containing syngas atmosphere relevant to the
integrated fluidized bed gasification, Fuel 176 (2016) 200–208.
Xuan Hu: Conceptualization, Data curation, Formal analysis, [20] X.i. Zeng, F. Wang, Z. Han, Y. Sun, Y. Cui, G. Xu, Characterization and pilot scale
Investigation, Methodology, Visualization, Writing – original draft, test of a fluidized bed two-stage gasification process for the production of clean
Writing – review & editing. Dachao Ma: Conceptualization, Formal industrial fuel gas from low-rank coal, Carbon Resour. Convers. 1 (1) (2018)
73–80.
analysis, Funding acquisition, Methodology, Writing – original draft, [21] M. Haruna Adamu, X. Zeng, J. Zhang, F. Wang, G., Xu, Property of drying,
Writing – review & editing. Guangyi Zhang: Conceptualization, Meth­ pyrolysis, gasification, and combustion tested by a micro fluidized bed reaction
odology, Project administration. Mengxue Ling: Conceptualization, analyzer for adapting to the biomass two-stage gasification process, Fuel 264
(2020), 116827.
Methodology, Project administration. Qiaoling Hu: Conceptualization, [22] X.i. Zeng, K. Kahara, Y. Ueki, R. Yoshiie, G. Xu, I. Naruse, Characteristics of
Methodology, Project administration. Kangyi Liang: Conceptualiza­ Biomass Devolatilization and in Situ Char Gasification Tested by the Non-
tion, Methodology, Project administration. Jiacheng Lu: Conceptuali­ Isothermal Method, Energy Fuel 33 (10) (2019) 9805–9817.
[23] L.M. Terry, C. Li, J.J. Chew, A. Aqsha, B.S. How, A.C.M. Loy, B.L.F. Chin, D.
zation, Methodology, Project administration. Yifan Zheng: S. Khaerudini, N. Hameed, G. Guan, J. Sunarso, Bio-oil production from pyrolysis
Conceptualization, Methodology, Project administration. of oil palm biomass and the upgrading technologies: A review, Carbon Resour.
Convers. 4 (2021) 239–250.
[24] S.D. Anuar Sharuddin, F. Abnisa, W.M.A. Wan Daud, M.K. Aroua, A review on
Declaration of Competing Interest pyrolysis of plastic wastes, Energy Convers. and Manag. 115 (2016) 308–326.
[25] R. Kumar Mishra, K. Mohanty, Co-pyrolysis of waste biomass and waste plastics
(polystyrene and waste nitrile gloves) into renewable fuel and value-added
The authors declare that they have no known competing financial chemicals, Carbon Resour. Convers. 3 (2020) 145–155.
interests or personal relationships that could have appeared to influence [26] P.H.M. Putra, S. Rozali, M.F.A. Patah, A. Idris, A review of microwave pyrolysis as
a sustainable plastic waste management technique, J. of Environ. Manag. 303
the work reported in this paper. (2022), 114240.
[27] G. Lopez, M. Artetxe, M. Amutio, J. Bilbao, M. Olazar, Thermochemical routes for
the valorization of waste polyolefinic plastics to produce fuels and chemicals. A
Acknowledgments
review, Renew. Sustain. Energy Rev. 73 (2017) 346–368.
[28] F. Motasemi, M.T. Afzal, A review on the microwave-assisted pyrolysis technique,
This work was supported by National Natural Science Foundation of Renew. Sustain. Energy Rev. 28 (2013) 317–330.
China (52166011). [29] I.J. Siddique, A.A. Salema, E. Antunes, R. Vinu, Technical challenges in scaling up
the microwave technology for biomass processing, Renew. Sustain. Energy Rev.
153 (2022), 111767.
References [30] C. Li, Z. Peng, T.-Y. Huang, T. Fan, F.-K. Wang, T.-S. Horng, J.-M. Munoz-Ferreras,
R. Gomez-Garcia, L. Ran, J. Lin, A Review on Recent Progress of Portable Short-
Range Noncontact Microwave Radar Systems, IEEE Trans. Microw. Theory Tech.
[1] K. Kumar Jha, T.T.M. Kannan, Recycling of plastic waste into fuel by pyrolysis - a
65 (5) (2017) 1692–1706.
review, Mater. Today:. Proc. 37 (2021) 3718–3720.
[31] R. Yang, J. Chen, Mechanistic and Machine Learning Modeling of Microwave
[2] N. Zhou, L. Dai, Y. Lv, H. Li, W. Deng, F. Guo, P. Chen, H. Lei, R. Ruan, Catalytic
Heating Process in Domestic Ovens: A Review, Foods 10 (2021) 2029.
pyrolysis of plastic wastes in a continuous microwave assisted pyrolysis system
[32] M. Radoiu, Microwave drying process scale-up, Chem. Eng. and Process. -
for fuel production, Chem. Eng. J. 418 (2021), 129412.
Process. Intensif. 155 (2020) 108088.
[3] M. Bergmann, B.C. Almroth, S.M. Brander, T. Dey, D.S. Green, S. Gundogdu,
[33] A. Suresh, A. Alagusundaram, P.S. Kumar, D.-V. Vo, F.C. Christopher, B. Balaji,
A. Krieger, M. Wagner, T.R. Walker, A global plastic treaty must cap production,
V. Viswanathan, S. Sankar, Microwave pyrolysis of coal, biomass and plastic
Sci. 376 (2022) 469–470.
waste: a review, Environ. Chem. Lett. 19 (5) (2021) 3609–3629.
[4] J. Hopewell, R. Dvorak, E. Kosior, Plastics recycling: challenges and
[34] A. Zlotorzynski, The Application of Microwave Radiation to Analytical and
opportunities, Philos. Trans. R. Soc. B: Biol. Sci. 364 (1526) (2009) 2115–2126.
Environmental Chemistry, Crit. Rev. in Anal. Chem. 25 (1) (1995) 43–76.
[5] L.A. Amaral-Zettler, E.R. Zettler, T.J. Mincer, Ecology of the plastisphere, Nat.
[35] A.T. Hoang, S. Nižetić, H.C. Ong, M. Mofijur, S.F. Ahmed, B. Ashok, V.T.V. Bui, M.
Rev. Microbiol. 18 (3) (2020) 139–151.
Q. Chau, Insight into the recent advances of microwave pretreatment
[6] J.C. Prata, A.L.P. Silva, T.R. Walker, A.C. Duarte, T. Rocha-Santos, COVID-19
technologies for the conversion of lignocellulosic biomass into sustainable
Pandemic Repercussions on the Use and Management of Plastics, Environ. Sci. &
biofuel, Chemosphere 281 (2021), 130878.
Technol. 54 (13) (2020) 7760–7765.
[36] J.A. Menéndez, A. Arenillas, B. Fidalgo, Y. Fernández, L. Zubizarreta, E.G. Calvo,
[7] R. Geyer, J.R. Jambeck, K.L. Law, Production, use, and fate of all plastics ever
J.M. Bermúdez, Microwave heating processes involving carbon materials, Fuel
made, Sci. Adv. 3 (2017) e1700782.
Process. Technol. 91 (1) (2010) 1–8.
[8] H. Arshad, S.A. Sulaiman, Z. Hussain, Y. Naz, F. Basrawi, H. Sakidin, M.H. Yusof,
[37] X. Zhang, K. Rajagopalan, H. Lei, R. Ruan, B.K. Sharma, An overview of a novel
N. Sa’ad, D. Ling Chuan Ching, S.A. Abdul Karim, Microwave assisted pyrolysis of
concept in biomass pyrolysis: microwave irradiation, Sustain, Energy Fuel 1 (8)
plastic waste for production of fuels: a review, MATEC Web Conf. 131 (2017)
(2017) 1664–1699.
02005.
[38] X. Zhang, H. Lei, G. Yadavalli, L. Zhu, Y. Wei, Y. Liu, Gasoline-range
[9] M.N. Siddiqui, H.H. Redhwi, Pyrolysis of mixed plastics for the recovery of useful
hydrocarbons produced from microwave-induced pyrolysis of low-density
products, Fuel Process. Technol. 90 (4) (2009) 545–552.
polyethylene over ZSM-5, Fuel 144 (2015) 33–42.
[10] J. Yu, L. Sun, C. Ma, Y. Qiao, H. Yao, Thermal degradation of PVC: A review,
[39] K. Ding, S. Liu, Y. Huang, S. Liu, N. Zhou, P. Peng, Y. Wang, P. Chen, R. Ruan,
Waste Manag. 48 (2016) 300–314.
Catalytic microwave-assisted pyrolysis of plastic waste over NiO and HY for
[11] Y. Peng, Y. Wang, L. Ke, L. Dai, Q. Wu, K. Cobb, Y. Zeng, R. Zou, Y. Liu, R. Ruan,
gasoline-range hydrocarbons production, Energy Convers. and Manag. 196
A review on catalytic pyrolysis of plastic wastes to high-value products, Energy
(2019) 1316–1325.
Convers. and Manag. 254 (2022), 115243.
[40] D.V. Suriapparao, A. Yerrayya, G. Nagababu, R.K. Guduru, T.H. Kumar, Recovery
[12] D. Chen, L. Yin, H. Wang, P. He, Pyrolysis technologies for municipal solid waste:
of renewable aromatic and aliphatic hydrocarbon resources from microwave
A review, Waste Manag. 34 (12) (2014) 2466–2486.
pyrolysis/co-pyrolysis of agro-residues and plastics wastes, Bioresour. Technol.
[13] O.K.M. Ouda, S.A. Raza, A.S. Nizami, M. Rehan, R. Al-Waked, N.E. Korres, Waste
318 (2020), 124277.
to energy potential: A case study of Saudi Arabia, Renew. and Sustain. Energy
[41] D.V. Suriapparao, R. Vinu, Resource recovery from synthetic polymers via
Rev. 61 (2016) 328–340.
microwave pyrolysis using different susceptors, J. of Anal. and Appl. Pyrolysis
[14] R. Miandad, M. Rehan, A.-S. Nizami, M.-A.-E.-F. Barakat, I.M. Ismail, The energy
113 (2015) 701–712.
and value-added products from pyrolysis of waste plastics, Recycl, in: of solid
[42] M. Bhattacharya, T. Basak, A review on the susceptor assisted microwave
waste for biofuels and biochem, 2016, pp. 333–355.
processing of materials, Energy 97 (2016) 306–338.
[15] S.R. Hughes, J.C. López-Núñez, M.A. Jones, B.R. Moser, E.J. Cox, M. Lindquist,
[43] A. Undri, L. Rosi, M. Frediani, P. Frediani, Efficient disposal of waste polyolefins
L.Á. Galindo-Leva, N.M. Riaño-Herrera, N. Rodriguez-Valencia, F. Gast, D.
through microwave assisted pyrolysis, Fuel 116 (2014) 662–671.
L. Cedeño, K. Tasaki, R.C. Brown, A.l. Darzins, L. Brunner, Sustainable conversion
[44] Z. Hussain, K.M. Khan, S. Perveen, K. Hussain, W. Voelter, The conversion of
of coffee and other crop wastes to biofuels and bioproducts using coupled
waste polystyrene into useful hydrocarbons by microwave-metal interaction
biochemical and thermochemical processes in a multi-stage biorefinery concept,
pyrolysis, Fuel Process. Technol. 94 (1) (2012) 145–150.
Appl. Microbiol. Biotechnol. 98 (20) (2014) 8413–8431.
[45] R. Mohan, C. Bhalla, Studies on microwave pyrolysis of polypropylene, Int. J.
[16] M. Bernardo, N. Lapa, M. Gonçalves, B. Mendes, F. Pinto, I. Fonseca, H. Lopes,
Eng. Res. 5 (2016) 108–116.
Physico-chemical properties of chars obtained in the co-pyrolysis of waste
[46] H. Arshad, S.A. Sulaiman, Z. Hussain, M.Y. Naz, M.N.Z. Moni, Effect of Input
mixtures, J. of Hazard. Mater. 219–220 (2012) 196–202.
Power and Process Time on Conversion of Pure and Mixed Plastics into Fuels
[17] S. Nanda, F. Berruti, A technical review of bioenergy and resource recovery from
Through Microwave-Metal Interaction Pyrolysis, Waste and Biomass Valoriz. 12
municipal solid waste, J. Hazard. Mater. 403 (2021), 123970.
(6) (2021) 3443–3457.
[18] S. Xu, X. Zeng, Z. Han, J. Cheng, R. Wu, Z. Chen, O. Masĕk, X. Fan, G. Xu, Quick
pyrolysis of a massive coal sample via rapid infrared heating, Appl. Energy 242
(2019) 732–740.

226
X. Hu et al. Carbon Resources Conversion 6 (2023) 215–228

[47] A. Undri, M. Frediani, L. Rosi, P. Frediani, Reverse polymerization of waste [76] H. Lee, S. Papari, G. Bernardini, R. Gallorini, L. Rosi, F. Berruti, Value-added
polystyrene through microwave assisted pyrolysis, J. of Anal. and Appl. Pyrolysis products from waste: Slow pyrolysis of used polyethylene-lined paper coffee cup
105 (2014) 35–42. waste, Can. J. Chem. Eng. 101 (3) (2023) 1271–1285.
[48] E.H. Istoto, S.S. Widayat, Production of Fuels From HDPE and LDPE Plastic Waste [77] H. Yu, J. Qu, Y. Liu, H. Yun, X. Li, C. Zhou, Y. Jin, C. Zhang, J. Dai, X. Bi, Co-
via Pyrolysis Methods, E3S Web Conf. 125 (2019) 14011. pyrolysis of biomass and polyvinyl chloride under microwave irradiation:
[49] D.V. Suriapparao, G. Nagababu, A. Yerrayya, V. Sridevi, Optimization of Distribution of chlorine, Sci. of The Total. Environ. 806 (2022) 150903.
microwave power and graphite susceptor quantity for waste polypropylene [78] M. Dai, H. Xu, Z. Yu, S. Fang, L. Chen, W. Gu, X. Ma, Microwave-assisted fast co-
microwave pyrolysis, Process. Saf. and Environ. Prot. 149 (2021) 234–243. pyrolysis behaviors and products between microalgae and polyvinyl chloride,
[50] J. Kobayashi, M. Hori, N. Kobayashi, Y. Itaya, S. Hatano, S. Mori, Selective Appl. Therm. Eng. 136 (2018) 9–15.
Dechlorination of Polyvinyl Chloride by Microwave Irradiation, J. of Chem. Eng. [79] C. Chen, D. Fan, J. Zhao, Q. Qi, X. Huang, T. Zeng, Y. Bi, Study on microwave-
of Jpn. 52 (7) (2019) 656–661. assisted co-pyrolysis and bio-oil of Chlorella vulgaris with high-density
[51] K.N. Aishwarya, N. Sindhu, Microwave Assisted Pyrolysis of Plastic Waste, polyethylene under activated carbon, Energy 247 (2022), 123508.
Procedia Technol. 25 (2016) 990–997. [80] J. Sun, W. Wang, Q. Yue, Review on Microwave-Matter Interaction Fundamentals
[52] L. Rosi, M. Bartoli, M. Frediani, Microwave assisted pyrolysis of halogenated and Efficient Microwave-Associated Heating Strategies, Mater. 9 (2016) 231.
plastics recovered from waste computers, Waste Manag. 73 (2018) 511–522. [81] Z. Hussain, K.M. Khan, K. Hussain, Microwave–metal interaction pyrolysis of
[53] S. Fan, Y. Zhang, T. Liu, W. Fu, B. Li, Microwave-assisted pyrolysis of polystyrene polystyrene, J. of Anal. and Appl. Pyrolysis 89 (1) (2010) 39–43.
for aviation oil production, J. of Anal. and Appl. Pyrolysis 162 (2022), 105425. [82] Z. Hussain, K.M. Khan, N. Basheer, K. Hussain, Co-liquefaction of Makarwal coal
[54] V. Sridevi, D.V. Suriapparao, M. Tukarambai, A. Terapalli, P. Ramesh, C. Sankar and waste polystyrene by microwave–metal interaction pyrolysis in copper coil
Rao, R. Gautam, J.V. Moorthy, C. Suresh Kumar, Understanding of synergy in reactor, J. of Anal. and Appl. Pyrolysis 90 (1) (2011) 53–55.
non-isothermal microwave-assisted in-situ catalytic co-pyrolysis of rice husk and [83] Z. Hussain, K.M. Khan, K. Hussain, S. Perveen, Microwave-metal Interaction
polystyrene waste mixtures, Bioresour. Technol. 360 (2022), 127589. Pyrolysis of Waste Polystyrene in a Copper Coil Reactor, Energy Sources, Part A:
[55] Z. Chen, M. Monzavi, M. Latifi, S. Samih, J. Chaouki, Microwave-responsive SiC Recover, Util. and Environ. Eff. 36 (2014) 1982–1989.
foam@zeolite core-shell structured catalyst for catalytic pyrolysis of plastics, [84] H. Arshad, S.A. Sulaiman, Z. Hussain, M.N.Z. Moni, Effect of reaction time and
Environ. Pollut. 307 (2022), 119573. microwave power on coil temperature during microwave-metal interaction
[56] S.R. Juliastuti, N. Hendrianie, P.J. Ramadhan, D.H. Satria, Microwave pyrolysis pyrolysis of plastics, IOP Conf. Ser.: Mater. Sci. and Eng. 863 (2020), 012007.
of multilayer plastic waste (LDPE) using zeolite catalyst, AIP Conf. Proc. 1840 [85] Z. Liu, H.-Q. Wang, X.-D. Zhang, J.-W. Liu, Y.-Y. Zhou, Dechlorination of
(2017), 110001. organochloride waste mixture by microwave irradiation before forming solid
[57] L. Fan, Y. Zhang, S. Liu, N. Zhou, P. Chen, Y. Liu, Y. Wang, P. Peng, Y. Cheng, recovered fuel, Waste Manag. 62 (2017) 118–124.
M. Addy, H. Lei, R. Ruan, Ex-situ catalytic upgrading of vapors from microwave- [86] P. Rex, I.P. Masilamani, L.R. Miranda, Microwave pyrolysis of polystyrene and
assisted pyrolysis of low-density polyethylene with MgO, Energy Convers. and polypropylene mixtures using different activated carbon from biomass, J. of the
Manag. 149 (2017) 432–441. Energy Inst. 93 (5) (2020) 1819–1832.
[58] M.A. Mohsin, M.A. Alnaqbi, R.M. Busheer, Y. Haik, Sodium Methoxide Catalyzed [87] D. Duan, Y. Wang, L. Dai, R. Ruan, Y. Zhao, L. Fan, M. Tayier, Y. Liu, Ex-situ
Depolymerization of Waste Polyethylene Terephthalate Under Microwave catalytic co-pyrolysis of lignin and polypropylene to upgrade bio-oil quality by
Irradiation, Catal. in Ind. 10 (1) (2018) 41–48. microwave heating, Bioresour. Technol. 241 (2017) 207–213.
[59] X. Jie, W. Li, D. Slocombe, Y. Gao, I. Banerjee, S. Gonzalez-Cortes, B. Yao, [88] X. Jing, H. Wen, X. Gong, Z. Xu, Heating strategies for the system of PP and
H. AlMegren, S. Alshihri, J. Dilworth, J. Thomas, T. Xiao, P. Edwards, Microwave- Spherical Activated Carbon during microwave cracking for obtaining value-added
initiated catalytic deconstruction of plastic waste into hydrogen and high-value products, Fuel Process. Technol. 199 (2020), 106265.
carbons, Nat. Catal. 3 (2020) 902–912. [89] Y. Zeng, Y. Wang, Y. Liu, L. Dai, Q. Wu, M. Xia, S. Zhang, L. Ke, R. Zou, R. Ruan,
[60] X. Jing, J. Dong, H. Huang, Y. Deng, H. Wen, Z. Xu, S. Ceylan, Interaction Microwave catalytic co-pyrolysis of waste cooking oil and low-density
between feedstocks, absorbers and catalysts in the microwave pyrolysis process of polyethylene to produce monocyclic aromatic hydrocarbons: Effect of different
waste plastics, J. of Clean. Prod. 291 (2021), 125857. catalysts and pyrolysis parameters, Sci. of The Total. Environ. 809 (2022),
[61] X. Zhang, Z. Yu, X. Lu, X. Ma, Catalytic co-pyrolysis of microwave pretreated chili 152182.
straw and polypropylene to produce hydrocarbons-rich bio-oil, Bioresour. [90] Y. Zhang, Y. Cui, S. Liu, L. Fan, N. Zhou, P. Peng, Y. Wang, F. Guo, M. Min,
Technol. 319 (2021), 124191. Y. Cheng, Y. Liu, H. Lei, P. Chen, B. Li, R. Ruan, Fast microwave-assisted pyrolysis
[62] L. Fan, Z. Su, J. Wu, Z. Xiao, P. Huang, L. Liu, H. Jiang, W. Zhou, S. Liu, R. Ruan, of wastes for biofuels production – A review, Bioresour. Technol. 297 (2020),
Integrating continuous-stirred microwave pyrolysis with ex-situ catalytic 122480.
upgrading for linear low-density polyethylene conversion: Effects of parameter [91] M. Bartoli, L. Rosi, M. Frediani, A. Undri, P. Frediani, Depolymerization of
conditions, J. of Anal. and Appl. Pyrolysis 157 (2021) 105213. polystyrene at reduced pressure through a microwave assisted pyrolysis, J. of
[63] J. Scheirs, Overview of Commercial Pyrolysis Processes for Waste Plastics, Anal. and Appl. Pyrolysis 113 (2015) 281–287.
Feedstock Recycl. and Pyrolysis of Waste Plast. (2006) 381–433. [92] S. Neha, P. Rajput, N. Remya, Biochar from microwave co-pyrolysis of food waste
[64] Y. Zhao, Y. Wang, D. Duan, R. Ruan, L. Fan, Y. Zhou, L. Dai, J. Lv, Y. Liu, Fast and polyethylene using different microwave susceptors – Production,
Microwave-assisted ex-catalytic co-pyrolysis of bamboo and polypropylene for modification and application for metformin removal, Environ. Res. 210 (2022),
bio-oil production, Bioresour. Technol. 249 (2017) 69–75. 112922.
[65] H. Hassan, J.K. Lim, B.H. Hameed, Catalytic co-pyrolysis of sugarcane bagasse [93] B. Ondruschka, W. Bonrath, D. Stuerga, Development and Design of Reactors in
and waste high-density polyethylene over faujasite-type zeolite, Bioresour. Microwave-Assisted Chemistry, Microw. in Org. Synth. (2012) 57-103.
Technol. 284 (2019) 406–414. [94] J. Tang, Unlocking Potentials of Microwaves for Food Safety and Quality, J. of
[66] J. Zhang, G. Wang, S. Xu, Upgrading of biomass fast pyrolysis oil over a moving Food Sci. 80 (2015) E1776-E1793.
bed of coal char, Carbon Resour. Convers. 3 (2020) 130–139. [95] P. Guzik, P. Kulawik, M. Zając, W. Migdał, Microwave applications in the food
[67] C. Liu, H. Wang, A.M. Karim, J. Sun, Y. Wang, Catalytic fast pyrolysis of industry: an overview of recent developments, Crit. Rev. in Food Sci. and Nutr. 62
lignocellulosic biomass, Chem. Soc. Rev. 43 (22) (2014) 7594–7623. (29) (2022) 7989–8008.
[68] X. Zhang, Q. Zhang, T. Wang, B. Li, Y. Xu, L. Ma, Efficient upgrading process for [96] X. Li, S. Wang, Y. Xu, W. Yao, K. Xia, G. Lu, Effect of microwave irradiation on
production of low quality fuel from bio-oil, Fuel 179 (2016) 312–321. dynamic mode-І fracture parameters of Barre granite, Eng. Fract. Mech. 224
[69] W. Chen, S. Shi, J. Zhang, M. Chen, X. Zhou, Co-pyrolysis of waste newspaper (2020), 106748.
with high-density polyethylene: Synergistic effect and oil characterization, [97] B. Sabzezari, S.M. Koleini, S. Ghassa, B. Shahbazi, S. Chehreh Chelgani,
Energy Convers. and Manag. 112 (2016) 41–48. Microwave-Leaching of Copper Smelting Dust for Cu and Zn Extraction, Mater. 12
[70] S. Xiong, J. Zhuo, H. Zhou, R. Pang, Q. Yao, Study on the co-pyrolysis of high (2019) 1822.
density polyethylene and potato blends using thermogravimetric analyzer and [98] K. Teimoori, F. Hassani, Twenty years of experimental and numerical studies on
tubular furnace, J. of Anal. and Appl. Pyrolysis 112 (2015) 66–73. microwave-assisted breakage of rocks and minerals-a review, Appl. Phys. 14624
[71] Y. Xue, S. Zhou, R.C. Brown, A. Kelkar, X. Bai, Fast pyrolysis of biomass and waste (2020).
plastic in a fluidized bed reactor, Fuel 156 (2015) 40–46. [99] H. Tang, X. Shu, W. Huang, Y. Miao, M. Shi, S. Chen, B. Li, F. Luo, Y. Xie, D. Shao,
[72] D.V. Suriapparao, D.A. Kumar, R. Vinu, Microwave co-pyrolysis of PET bottle X. Lu, Rapid solidification of Sr-contaminated soil by consecutive microwave
waste and rice husk: effect of plastic waste loading on product formation, Sustain. sintering: mechanism and stability evaluation, J. of Hazard. Mater. 407 (2021)
Energy Technol. and Assess. 49 (2022), 101781. 124761.
[73] D.V. Suriapparao, B. Boruah, D. Raja, R. Vinu, Microwave assisted co-pyrolysis of [100] A. Kumar, P.M. Pandey, Statistical modelling of mechanical properties and bio-
biomasses with polypropylene and polystyrene for high quality bio-oil corrosion behaviour of Mg3Zn1Ca15Nb fabricated using microwave sintering,
production, Fuel Process. Technol. 175 (2018) 64–75. J. of Alloy. and Compd. 854 (2021), 156211.
[74] D.V. Suriapparao, R. Vinu, A. Shukla, S. Haldar, Effective deoxygenation for the [101] M. Aniszewska, W. Zychowicz, A. Gendek, The effectiveness of short-term
production of liquid biofuels via microwave assisted co-pyrolysis of agro residues microwave irradiation on the process of seed extraction from Scots pine cones
and waste plastics combined with catalytic upgradation, Bioresour. Technol. 302 (Pinus sylvestris L.), iForest - Biogeosci, and For. 13 (2020) 73–79.
(2020), 122775. [102] B.M. Balboni, B. Ozarska, J.N. Garcia, G. Torgovnikov, Microwave treatment of
[75] Q. Bu, K. Chen, W. Xie, Y. Liu, M. Cao, X. Kong, Q. Chu, H. Mao, Hydrocarbon rich Eucalyptus macrorhyncha timber for reducing drying defects and its impact on
bio-oil production, thermal behavior analysis and kinetic study of microwave- physical and mechanical wood properties, Eur. J. of Wood and Wood Prod. 76 (3)
assisted co-pyrolysis of microwave-torrefied lignin with low density polyethylene, (2018) 861–870.
Bioresour. Technol. 291 (2019), 121860. [103] H.-F. Lv, X.-X. Ma, B. Zhang, X.-F. Chen, X.-M. Liu, C.-H. Fang, B.-H. Fei,
Microwave-vacuum drying of round bamboo: A study of the physical properties,
Constr. and Build. Mater. 211 (2019) 44–51.

227
X. Hu et al. Carbon Resources Conversion 6 (2023) 215–228

[104] S.O. Nelson, P.G. Bartley, Open-ended coaxial probe permittivity measurements [107] A. Undri, S. Meini, L. Rosi, M. Frediani, P. Frediani, Microwave pyrolysis of
on pulverized materials, IEEE Instrum. and Meas. Technol. Conf. Sens, Process, polymeric materials: Waste tires treatment and characterization of the value-
Netw. IMTC Proc. 1 (1997) 653-657. added products, J. Anal. Appl. Pyrol. 103 (2013) 149–158.
[105] J.P. Robinson, S.W. Kingman, C.E. Snape, S.M. Bradshaw, M.S.A. Bradley, [108] A.D. Russell, E.I. Antreou, S.S. Lam, C. Ludlow-Palafox, H.A. Chase, Microwave-
H. Shang, R. Barranco, Scale-up and design of a continuous microwave treatment assisted pyrolysis of HDPE using an activated carbon bed, RSC Adv. 2 (2012)
system for the processing of oil-contaminated drill cuttings, Chem. Eng. Res. and 6756–6760.
Des. 88 (2) (2010) 146–154. [109] M. Bartoli, M. Frediani, C. Briens, F. Berruti, L. Rosi, An Overview of Temperature
[106] A.A. Salema, F.N. Ani, J. Mouris, R. Hutcheon, Microwave dielectric properties of Issues in Microwave-Assisted Pyrolysis, Process. Saf. Environ. Prot. 7 (2019) 658.
Malaysian palm oil and agricultural industrial biomass and biochar during
pyrolysis process, Fuel Process. Technol. 166 (2017) 164–173.

228