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Eclogite facies relics in metabasites from the Sierra de Guadarrama (Spanish

Central System): P-T estimations and implications for the Hercynian
evolution

Article in Mineralogical Magazine · October 2000

DOI: 10.1180/002646100549814 · Source: OAI

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 facies relics metabasites from the
Guadarrama (Spanish System):

1
L BARBER0 ,* AND C. VILLASECA2
1Departamento de Geologia, Facultad C C del Mar, Universidad de Cadiz, 11510 Puerto Real, Cadiz, Spain
2
Departamento de P etrologia y Geoquimiea, Facultad C C Geologieas, Universidad Complutense, 28040 Madrid,
Spain

Relics of HP-MT eclogitic assemblages related to the first metamorphic stage of the Hercynian nrr"TP'TlU

in the Sierra de Guadarrama (Spanish Central SCS) are as boudins of IJi'-'-'JJLU-V

metabasites enclosed by felsic Textures indicate a metarnolrph

iHUUU--'H('Ll<.'-'

the MT eclogite facies (as deduced from the presence of and rutile included in garnet) and
through medium to Iow pressure and retrograde amphibolite-greenschist facies.
Thermobarometric calculations in the ecIogitic yield pressures of -14 kbar for ternp,eraLtUlres
in the range 725-775°C. for the indicates a Sl.ll�nlltlC,;m(
drop in (P < 10 kbar) for similar temperatures vary from gabbro to
lellCC)tonaJlltc:s showing the typical Fe enrichment of the tholeiitic series. Chemical characteristics
indicate a derivation from low-pressure of tholeii tic melts more enriched than typical
MORB compositions. Their original location far from continental margins as evidenced by the absence
of ophiolitic material in the area and their association with platform sediments suggests that
eclogitization was related to intracontinental crustal subduction and The P-T conditions
estimated in the metabasites for the first metamorphic stage are similar to ones deduced for the
metasediments and suggest that the Hercynian crust could have reached a thickness of
-70-80 km, which is more than the double the present thickness.

KEYWORDS: assemblage, Central evolution, MORE.

Introduction the Hercynian orogeny is characterized by three

stages of re-crystallization related to a
THE Sierra de Guadarrama is located in the axial metamorphic cycle (Villaseca, 1983; Arenas et
zone of the Iberian branch of the Hercynian belt aI. , 1991) . The initial (Ml)
1) in the so-called Central Iberian Zone (San coincides with the first and with part of the
Jose et al, 1990). This sector represents a second deformative events (Dl and D2) and is
intracontinental as seen from its location a medium associated
far from recognized ophiolitic complexes or with crustal thickening and progressive burial.
supposed The nearest ophio- The most characteristic Dl compres­
litic shear zone sional structure in the study area is a series of km­
is located >320 km to the southwest even after the scale ductile shear zones of orthogneisses
shortening which occurred during the Hercynian imbricated with thin sheets of metasediments
orogeny. The evolution related to et al. , 1991} In works,
me:taJTIorpJllC conditions of Ml have
not been established which was
explained as a consequence of the
* E-mail: Ims. barbero @uea es by the second stage (M2)' Villaseca
D Post-Hercynian sediments • Metasediments D
Dlductile
sbear zones

t:::J Granites D Orthogneisses t22J Leucogneisses '" Metabasites

FIG. 1. (a) Geological map ofa sector of the Central Spain Region (Hercynian orogen) and its location in the Ibelian
Hercynian Belt (grey alea). The two insets are the main regions where the studied metabasites crop out; (b) the
Tenzuela sector; and (c) the Collado Hermoso sector.

(1983) describes these metabasic rocks as having scale ductile extensional shear zones such as the
a relict eclogitic assemblage, citing the presence Berzosa-Riaza zone to the east of the studied area
of Na-rich pyroxenes included in garnets. The (Escuder Viruete et al., 1998). During M2, this
maximum pressure attained was estimated to be orogenic segment reached the highest temperature
-7-11 kbar. In a more recent work on these (715°C, 4-5 kbar, Villaseca, 1983; Arenas et aI.,
metabasi tes, Villaseca and Barbero (1994) made a 1991) and a decompressional evolution occurred.
brief revision of the PT conditions of the first Mineral parageneses of the M2 stage are generally
Hercynian metamorphic episode concluding that well preserved and define a granulite facies
the minimum pressure achieved was -9 kbar, metamorphic zone with orthoclase, cordierite
probably reaching up to 12-15 kbar for tempera­ and sillimanite. Migmatization occurred mainly
tures in the range 650-750°C. The second in the quartzo-feldspathic meta-igneous and
metamorphic stage (M2' paroxysmal meta­ metapeli tic protoliths associated with these
morphism) coincides with the final development metabasites. In nearby granulitic terranes such
of the second deformation episode (D2), which is as the Anatectic Complex of Toledo located 100
essentially an extensional event which overprints km to the south of the study area, the
and transposes DJ structures generating some km- metamorphic climax reached 800±5 0°C and
5 ± 1 kbar more peraluminous towards more basic composi­
tions, thus having S-type characteristics.
of the parageneses Two types of basic rocks appear
decompressional stage. The M3 mineral assem­ in the area, both of them restricted exclusively to
blages reflect greenschist facies conditions of the central domain of the Sierra de Guadarrama
-450°C and 2 kbar (Villaseca, 1983; Arenas et The metabasites with eclogitic relics have never
al , 1991). been found within the abundant
In the present work, new mineral chemical data lower Ordovician orthogneisses (Fig. 1). These
on the relict eclogitic of the Ml older metabasites crop out as discontinuous
stage are with the aim of bands, boudins or lenses within the Precambrian
determining the P-T eclogitic conditions attained metasediments against which they present sharp
during the Hercynian metamorphic evolution of contacts. were intensively recrystallized
this area. Moreover, new whole-rock chemical during the Hercynian orogeny, transformed
data on these metabasites have been obtained into a nd
which, together with previous data (Villaseca, mela-amphibolites. Based on several character­
198 3; Villaseca et al. , 1993), may place istics (discussed below) they are interpreted as
of the basic derived from tholeiitic sills of undetermined
times. Precambrian age, at least to the
orthogneisses of Lower Ordovician age. A
variation in composition from
gabbros towards leucotonalites is observed
The Sierra de Guadarrama is rnrnT)n"prj of (Villaseca, 1983). It is only in these metabasites
metamorphic rocks, both metasedimentary and in which the residual eclogitic mineral assem-
types, into which voluminous studied in the work appear.
late intruded A second group metabasites, of
coronitic metagabbros and metadiorites, intruded
The metasedimentary sequences, of uncertain into all of the previous series (not
age, crop out under the Sardic alone into the Proterozoic
(L o w e r O r d o v i c ian-M i d d l e D e v o n i a n ) . sequences, but also into the Lower Ordovician
Significant palaeontological remains are absent, felsic orthogneisses). Because of their tendency to
which together with the fact that these sechrrlentary appear in shear zones related to the vV_'HI-'.lv"'WJ1HU

sequences are intruded by many deformation stage, they have been to be

rocks, make s tratigraphic correlation
H.l,.La--L,,-"v'JUL> early Hercynian in age, associated with the
very difficult. A succession of schists and crustal (Villaseca, 1985)
with and discontinuous These coronitic metagabbros, in contrast to the
of marbles, amphibolites and calc-silicate metabasites described previously, are not as
rocks form the majority of the series. This series of intensely and some of them even
Proterozoic age is assigned to the so-called igneous textures in the internal zones
Esquisto Grauvaquico of the Central the massifs. No evidence of important high­
Iberian Zone (San Jose et a!. , 1990). The presence pressure re-crystallization has been found in this
of abundant layers of with a hornfels- metabasite and garnet-bearing varieties are very
like appearance surrounded by types rare. They are as conti­
is characteristic. These types nental tholeiitic sills because of their low alkalies
comprise different augen, porphyritic, and leuco­ and high Ti and Fe contents (Villaseca, 1985)
cratic varieties intruded into the pre-Ordovician
seq uence, described
.........�-.... methods
V!",',",U-LU-,..cLU obtained

rocks sugge st an early O rd ovic ia n age For this -50 samples of amphibolitic
(470-500 Ma Rb-Sr whole rock, Vialette et al , metabasites from the region of Turegano (near
1987; -487 Ma, U-Pb zircon 1) were
a!. , 1995). These Lower Ordovician The mineral are
are mainl y Table 1. Electron microprobe analyses were
them have a on seven polished sections
with a tendency to be t h r e e d i ff e r e n t e s: a J E O L
TABLE 1. Relation of the blastesis of the different mineral phases with respect to the three metamorphic stages
of the Spanish Central System.

Metamorphic stages
Eclogite facies MI I Granulite facies M2 I Greenschist facies M3
Garnet ••••••

Omphacite ...... . ..... . ....

Diopside
Rutile
Quartz
AnWO AnI»
Plae;ioclase
Orthopyroxene
Dmenite ......

Titanite P,,!!-Hbl
Ca-amphibole ? ..... AeIInoIlte
..••••.....•.•.

Epidote
Cblorite
Biotite

SUPERPROBE JXA 8900-M at Complutense bearing amphibolites with a massive structure and
University of Madrid; a JEOL SUPERPROBE an eclogite-like appearance, generally found as
733 at St Andrews University (UK); and a rounded masses included within t he former rock
CAMECA SX-50 at Oviedo University (Spain). types. Some pegmatitic varieties with conspic­
In all cases, the operating conditions were 15 kV, uous amphibole, plagioclase and quartz crystals
20 nA. and a beam diameter of 2-5 flm, and ZAF appear. A second important group of small
correction procedure was used. Analyses outcrops of metabasites are located to the south
performed on the same mineral grain in the of the Collado Hermoso village (Fig. le).
different microprobes gave similar results. Different mineral assemblages, which are the
Whole-rock major elements were determined result of the successive metamorphic recrystaJli­
by ICP-AES and trace elements by ICP-MS at zation stages, can be dist inguished. In Table I the
CNRS (Nancy, France) following the method of relation between the blastesis of the different
Govindaraju and Mevelle (1987). Three whole­ mineral phases and the three metamorphic stages
rock chemical analyses have been taken from of the area are summarized.
Villaseca (1983) (Table 5). The mineral abbrevia­
tions follow those used by Kretz (1983).
Eclogitic relict paragenesis

This comprises minerals grown during the MI

Sample description
stage including garnet, Na-rich-clinopyroxene,
Metabasic rocks containing high-pressure relics amphibole (?), ilmenite (?), rutile and apatite.
appear in the Tun!gano region (Fig. 1) as boudins Most of these minerals are found as inclusions in
of variable size included in the metasediments. garnet domains.
The largest outcrop occurs near Tenzuela
(Fig. Jb) where a varied and complex massif of
2 Granulitic paragenesis
metabasites of -2000 m , showing concordant
sharp contacts with the surrounding metapelites This was imposed on the previous assemblage;
and marbles, is exposed. In this massif, several plagioclase, clinopyroxene (low-Na) , ortho­
types can be dist inguished: granoblastic leuco­ pyroxene, amphi bole and some b iotite and
amphi bolites with varied grain size; foliated mela­ K-feldspar in the more felsic varieties appear.
amphibolites interlayered with the former leuco­ These phases are related to the second meta­
cratic types; and medium- to fine-grained garnet- morphic re-crystallization.
 Finally, the retrogres<::i on of the previous Amphibole is the most abundant ferromagne­
during the M3 stage produces sian phase in these metabasites. It appears as
minerals such as chlorite, actinolite, quartz and subhedral but also as a
epidote (Table 1). continuous rim around ilmenite. It clearly grew
Garnet appears in proportions from later than the garnet, clinopyroxene and some of
accessory amounts up to 20% in certain samples the Sometimes amphibole appears to
2). It is more or less and be with �ic')<,Lv�Lac.v
varies in form from euhedral to anhedral (atoll or an incomplete corona around garnet. It also
ameboid forms); sizes are up to 2 mm and appears as secondary inclusions within garnet, in
of sieved textural appearance, as a consequence this case retrograded
of the abundant clinopyroxene, quartz, plagio­ transformation of previous clinopyroxene inclu­
clase, amphibole, orthopyroxene, biotite, apatite, sions. In the amphibole-rich varieties it appears as
rutile and ilmenite inclusions, usually observed nematoblastic crystals poikilitically
2). In these garnet domains, some "'''�LV''Lll)<, residual garnet and usually

of these minerals (clinopyroxene, quartz, rutile) a thin plagioclase film between both minerals.
should be interpreted as primary in cl usions Ilmenite is abundant in several types as
the garnet growth. Other �HJllf��"�� crystals in the nematoblastic matrix of

ortho­ the rock Rutile is only found as inclusions in

pyroxene, ilmenite) clearly post-date garnet garnet. Titanite can frequently be found asso-
growth and can be interpreted as secondary ciated with ilmenite. is another accessory
i n c l u s i o n s or r e a c t i o n products i n s i de p h a se i n t h e s e t ic m e t a g ab b r o s .
presence of coronas clinopyroxene
aro und clinopyroxene inclusions (Fig. 2d) surround some corroded quartz aggregates.
suggests that the enclosed in garnet
could have the second
Mineral r.,,"'rni�:t"II"v
stage, as could also be the case
for the orthopyroxene, amphibole, biotite, ilme­ Garnet
nite and quartz. The presence of a continuous The garnet in the metabasites is in
plagioclase corona around garnet, sometimes the range of almandine (58-69
with symplectitic intergrowths with (24-30 and pyrope (5-14
andlor ilmenite in the external part of the corona "n,'",,·cortllnp «5 . 5 and uvaro-
2c), is related to the M2 vite «0 . 7 (Table 2). Only in one
zation. In the most retrograde ""'.V)<,H",;>, from the Collado Hermoso sector (sample 82245),
garnet and have been is garnet slightly richer in grossular (30.0 to
destroyed, plagioclase 33. 6 and pyrope (12.0 to 14. 0
aggregates develop an exsolution-like texture as components (Fig. 3a) reflecting their relatively
seen in the alignment of tiny needle-like higher bulk-rock Ca composition. Garnets plot in
inclusions of apatite and diopsidic clinopyroxene. the field of group C as defined by
It is possible to find omphacitic clinopyroxene Coleman et al. (1965) (Fig. 3a). The majority of
as relics of the Ml paragenesis (as discussed in the the metabasites contain unzoned garnets (Fig.
mineral chemistry section), thus reflecting or garnets in which zoning is not well defined.
pressure conditions. Clinopyroxene is found Nevertheless, when present, is character­
either as small inclusions in the garnet or as ized by an increase in Fe and a decrease in Ca
euhedral crystals in the matrix, in this case from core to rim (samples 82244 and 96897,
together with the Such may have been caused by
clase, orthopyroxene and quartz, the grano­ a pressure decrease (Raheim and Green, 1975)
nematoblastic texture of the rock A thin and is in agreement with the presence of
clase film usually surrounds clinopyroxene inclu­ retrograde plagioclase coronas around garnet
sions, which isolates them from the garnet
(Fig. is much less abundant
CUnopyroxene
and appears either as small
included in the garnet or more commonly in the The contents in clinopyroxeneare estimated,
matrix. Orthopyroxene is restricted to certain based on charge balance considerations, as the
from the T enzuela massif (Fig. I } sum of cations is very close to 4 in all cases. As
FIG. 2. Microtextural aspects of different metabasites from the studied area (a) General aspect of a retro-eclogite
with plagioclase coronas around garnet and abundant ilmenite ClYStalS; the matI;x is composed mainly of
granoblastic amphibole and plagioclase (sample 82244). (b) Detail of a plagioclase corona around a euhedral garnet
(sample 71303). (c) Metabasite in a more retrograde stage showing a sieved-textured garnet and a coarse-grained
granoblastic matJ;x composed of plagioclase, clinopyroxene, amphibole (also smTOunding ilmenite) and ilmenite
(sample 96894). (d) Detail of an omphacitic clinopyroxene included in gamet with a typical plagioclase corona
b etween both minerals (sample 71300). (e ) Petrographic scheme drawn from a microphotograph of sample 96894
showing the textural relations of the OIthopyroxene (Opx), plagioclase (PI), and amphibole (Amp) a.round a COIToded
garnet crystal. (j) Olthopyroxene inclusions in garnet from sample 96895.
 TABLE 2. Selected of garnet of tholeiitic metabasites from the Sierra de Guadarrarna.

71300 71300 71300 71300 96895 96895 82244 82244 82244 82244
103 rim 104 108 109 71 core 74 rim 69 rim 70 72 73 core

Si02 39. 02 3 8. 09 3 8. 4 1 3 8. 8 1 38. 42 38. 1 5 37. 02 37. 28 37.39 37 .68

Ti02 0. 1 6 0.06 0. 1 5 0. 22 0. 24 0. 20 0. 1 6 0. 07 0. 29 0. 1 7
A1203 20. 94 20. 89 20. 82 2 1 . 07 20.88 20. 84 20. 69 2 1 . 05 20.89 2 1 . 15
FeO 29. 88 3 0. 45 29. 1 8 28. 3 9 28. 2 1 29.58 28. 27 28. 49 28.74 28. 1 4
MnO 1.41 0.94 1 . 24 1 . 38 2. 45 0. 84 0. 33 0. 45 0. 43 0. 7 9
MgO 1 . 76 1 . 85 2. 4 1 2. 43 1 . 53 1 . 86 2. 87 2.72 2. 7 1 2. 62
CaO 9. 64 8.56 9. 1 7 9. 43 9. 94 9. 52 9. 77 9. 47 9. 47 9. 7 6
Na20 0. 00 0.00 0. 1 0 0. 00 0. 00 0. 00 0. 00 0. 00 0. 00 0. 00
Total 1 02. 82 1 00. 83 1 0 1 . 40 1 01.74 1 0 1 . 66 1 00. 98 99. 1 4 99.53 99.93 100. 3 1

Structural formula 0 = 12
3. 00 3 . 00 3. 00 3 . 00 3. 00 3.00 2. 97 2. 98 2. 98 2. 99
0. 00 0.00 0. 00 0. 00 0. 00 0. 00 0. 03 0. 02 0. 02 0. 0 1
1 . 92 1 . 95 1 . 93 1 . 94 1 . 94 1 . 95 1 . 93 1 . 96 1 . 95 1 . 97
0. 0 1 0.00 0. 0 1 0. 0 1 0. 0 1 0. 0 1 0. 0 1 0. 00 0. 02 0. 0 1

�t 0. 20
1 . 94
0.22
2.02
0. 28
1 . 92
0. 28
1 . 86
0. 1 8
1 . 86
0. 22
1 . 96
0. 34
1. 90
0.32
1 . 90
0. 3 2
1 . 92
0. 3 1
1 . 87
Mn 0. 09 0.06 0. 08 0. 09 0. 1 6 0. 06 0. 02 0. 03 0. 03 0. 05
Ca 0. 80 0.73 0. 77 0.79 0. 84 0. 81 0. 84 0. 81 0. 8 1 0. 83

End-members
Prp 6. 69 7 . 23 9. 25 9.36 5. 92 7. 20 1 1 . 06 1 0. 55 1 0. 47 10. 1 2
AIm 63. 85 66. 68 62. 7 6 6 1 . 45 61. 12 64.40 61. 14 62. 03 62.29 6 1 .02
3. 06 2.07 2.7 1 3 . 03 5.37 1 .84 0.72 0. 99 0. 94 1 .74
26. 40 24. 0 1 25. 27 26. 1 5 27.58 26.56 26. 97 26. 42 26. 27 27 . 1 2

was the case for the garnets, clinopyroxene varies Orthopyroxene

in composltlOn on the whole rock Orthopyroxene has been found only in some
chemistry, the metabasites 82244- 5 having the samples of the Tenzuela massif. Orthopyroxenes
more diopsidic composition (XI'vfg 0. 68 -0. 70)
= have compositions of -XMg 0. 29-0. 38 in sample
=

and the rest of the gabbroic types having Xl'vfg 96896 and XMg 0. 37 -0. 43 in sample 96 895, their
=

from 0.41 to 0. 64 4} In 71300 and chemical composition controlled by the

96896 (Table 3), the clinopyroxenes included in whole-rock Although they appear as
garnet contain greater Na and Al contents than inclusions in the garnet they are more abundant in
those in the matrix and also than those in the rest the matrix. Sometimes orthopyroxene appears to
of the sample. The component in these be associated with and amphibole
inclusions varies from 1. 0 to 20. 5 moL%, some of around garnet, its involvement in
the clinopyroxenes thus plotting in the omphacite garnet breakdown reactions as discussed below
field in Fig. 4. Omphacite relics are restricted to (Fig. 2e). No important chemical differences have
primary inclusions in garnet are absent been found between the different textural types,
from the matrix. with the of Ah03
included in garnet in sample 96895 has lower contents in orthopyroxene included in garnet (up
Na contents and MgI(Fe+Mg) ratios than that in to 1.1 wt.%, Table 3}
the matrix 4). Similar relict
have been found in the matrix of from
Amphjbole
the Czech Republic (Medaris et al., 1995) where
they have been as retro- Structural formulae have been calculated to 13
graded stages. cations Ca, Na and K; has been
 Grs+Andr

AIm

TypeB
� Type C
clogites 82
30

20

eclogites
10 Prp
FeJMg
Sps

70
core rim
C 70

60
AIm. 65

60 Aim

� 30 Grs
� 25
30 �
Q 20

20 :; 15

10
Prp
10 FeJMg
5

::::!::::!::=-:±:::t Sps
core rim core
)lm
FIG. 3. (a) Garnet composition pl ot in the Prp-(Grs+Andr)-(Alm+Sps) diagram. Note the more c alcic composition of
the garnets in sample 82245. Fields of type B and C eclogites after Coleman et al. (1965). (b) Typical unzoned garnet
profile in sample 96896. (c,d) Zoning profiles with an increase in Fe accompanied by a decrease in Ca from c ore to
rim indic ating a down pressure re-equilibration.

calculated according to Robinson et al. (1982) and (Fig. 5). This could be the result of local re­
the amphiboles are classified to Leake equilibration due to the large volume differences
et al. (1997), (Table 4} All analysed between the host garnet and the
are calcic types varying from to inclusion as stated by Spear (1991) for biotite
lerroT)ar:ga�:lte in the most basic types and from inclusions in garnet from metapelitic rocks. The
to and edenite in UH.LI-'''',"-Y'VH.''' included in garnet a slightly
the most evolved metagabbros 5, higher AI content in those of the
82244-5) the amphiboles included in matrix (Fig. 5). This tendency is reflecting
garnet tend to show more composi­ O'\\-'Tl-DH:ssure amphibole rpr'r.",t;;oi
tions when to those in the matrix zation as will be discussed below. No
 b

!
Ac
71300
71300

En Fs
Omphacik
96896

(Wo, En, Jd-

96896

96895
96895

96905
96905

82244

FIG. 4. (a) Clinopyroxene composition in tenns of jadeite-aeg irine-Q(di, en, fs); in samples 71300 and 96896 some
clinopyroxene inclusions plot in the field of omp hacite. (b) wollastonite-enstatite-ferrosilite classification diagram
for c1ino- and orthopyroxenes.

chemical variation has been found in amphibole clase included in garnet showed the highest albite
its location in relation content but nevertheless, its varies
to garnet domains. When comparing the amphi­ within a narrow range (An 10 to Ann). In contrast,
bole composition with that of other amphiboles 96895 shows plagioclase with a wide
from different we note that compositional variation (An50 to AnlO), the most
they plot in the field of intermediate pressure calcic being that included in garnet In the last two
terrains (Fig. 5). This points to a cases, inclusions are the result of the
intermediate to lower nrf"'"""rp retrograde reaction between eclogitic garnet and
as is common in other as evidenced by the presence of
(Messiga et al , 1992; Medaris et al , 1995} residual clinopyroxene surrounded by plagioclase
coronas inside the garnet (see 2d). In two
"ajlHl-n'-',�, a compositional profile from the contact
Plagjoc!ase
with the garnet towards the UH.Lf.HHU'ViLU,""
Most of the is found defining coronas has been performed, the plagioclase An45
around garnet, thus suggesting a post-eclogitic garnet and An28 towards the matrix. This
character 2). Nevertheless, three textural coincides with the decrease in grossular compo­
types of were inclu- nent in the thus the down­
sions, coronas and matrix. Plagioclase presents pressure re-equilibrium between garnet rims and
similar compositions from sample to sample but adjacent plagioclase. This An content of
in certain cases a wide range of variation within ,.JiL'",LV,""LU"',"" between garnet has
individual rocks occurs. In general, been observed in other
composition varies from An 10 to An50 the average (O'Brien et al. , 1992}
An20' The orthoclase content never exceeds In every sample, plagiodase in the matrix
1 mol.%. In gabbroic 71300, the presents similar to the ,.JiU",
. "J,""lL""..0
 TABLE 3. Selected clinopyroxene and analyses from tholeiitic metabasites from the Sierra de Guadarrama.

Orth opyroxene
Sa mple 71300 71300 71300 71300 71300 71300 96895 96895 96895 96895 96896 96896 96896 96895 96895 96896 96896 96896 96896
Texture incl. inc1. inc1. incl. matrix matrix incl. incl. m atrix matrix incl inc1. matrix inc1. inc1.
Analysis 61 62 105 (c 3) 92 101 105 53 54 79 28 154 162 151 45 34 38 39 140 130

Si02 50.65 51.01 52.24 51.80 50.90 49.93 50.40 50.76 52.02 51.47 52.84 50.66 50.42 49.60 50.04 50.55 50.44 48.51 49.22
Ti02 0.43 0.33 0.33 0.31 0.13 0.08 0.27 0.26 0.08 0.14 0.10 0.03 0.12 0.05 0.03 0.00 0.00 0.11 0.06
Ali)3 5.37 5.26 4.88 5.30 3.54 2.02 2.04 1.50 2.70 3.84 6.82 7.00 0.86 0.42 0.42 0.43 0.24 0.40 0.42
FeO 14.93 14.73 14.68 15.22 14.81 19.72 16.77 14.76 14.35 12.00 11.93 15.45 18.18 36.74 35.36 36.33 36.08 39.06 37.88
MnO 0.16 0.23 0.13 0.00 0.08 0.00 0.26 0.21 0.04 0.14 0.22 0.35 0.40 0.59 0.52 0.41 0.53 1.03 0.80
MgO 7.23 7.30 7.49 6.88 9.46 7.23 8.60 9.96 10.06 10.03 7.44 5.99 7.87 12.37 11.56 12.21 12.37 9.15 10.62
Ca O 17.71 17.35 17.90 18.95 21.48 21.04 21.43 21.98 20.32 20.04 17.75 18.17 21.13 0.64 0.86 0.62 0.58 0.96 0.70
Na 20 2.77 2.90 2.48 2.59 0.81 0.65 0.29 0.04 1.05 1.67 2.66 1.98 0.46 0.00 0.02 0.11 0.00 0.00 0.03

Total 99.33 99.18 100.12 101.05 101.24 100.67 100.08 99.52 100.64 99.34 99.83 99.66 99.50 100.60 98.85 100.73 100.28 99.21 99.73

Struc tural formula 0 = 6

Si 1.93 1.94 1.97 1.94 1. 91 1.93 1.95 1.96 1.96 1.94 1.97 1.93 1.97 1.97 2.00 2.00 2.00 1.99 1.99
AllV 0.07 0.06 0.03 0.06 0.09 0.07 0.05 0.04 0.04 0.06 0.03 0.07 0.03 0.02 0.00 0.00 0.00 0.01 0.01
Ti 0.01 0.01 0.01 0.01 0.00 0.00 0.01 0.01 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00
AlVI 0.17 0.18 0.19 0.18 0.07 0.02 0.04 0.02 0.08 0.11 0.27 0.25 0.01 0.00 0.02 0.02 0.01 0.01 0.01
Fe3+ 0.08 0.08 0.00 0.05 0.07 0.09 0.02 0.01 0.03 0.06 0.00 0.00 0.05 0.05 0.00 0.00 0.00 0.00 0.00
Fe2+ 0.40 0.40 0.46 0.43 0.40 0.55 0.52 0.47 0.42 0.32 0.37 0.49 0.55 1.18 1.19 1.20 1.20 1.34 1.28
Mn2+ 0.01 0.01 0.00 0.00 0.00 0.00 0.01 0.01 0.00 0.00 0.01 0.01 0.01 0.02 0.02 0.01 0.02 0.04 0.03
Mg 0.41 0.41 0.42 0.39 0.53 0.42 0.49 0.57 0.56 0.56 0.41 0.34 0.46 0.73 0.69 0.72 0.73 0.56 0.64
Ca 0.72 0.71 0.72 0.76 0.87 0.87 0.89 0.91 0.82 0.81 0.71 0.74 0.88 0.03 0.04 0.03 0.02 0.04 0.03
Na 0.20 0.21 0.18 0.19 0.06 0.05 0.02 0.00 0.08 0.12 0.19 0.15 0.03 0.00 0.00 0.01 0.00 0.00 0.00

End-members
QUAD 78.90 78.01 81.62 80.74 93.80 94.99 97.78 99.69 92.19 87.42 79.51 84.35 96.44
Jd 14.16 15.44 18.38 15.14 3.17 1.01 1.38 0.22 5.54 8.44 20.49 15.65 0.60
Aegirine 6.94 6.55 0.00 4.12 3.02 3.99 0.84 0.09 2.27 4.15 0.00 0.00 2.96
En 36.54 35.77 36.71 37.11 28.31 32.35
Fs 62.11 62.31 61.95 61.95 69.56 66.11
Wo 1.36 1.92 1.34 1.34 2.14 1.54
 TABLE 4. Selected amphibole analyses of tholeiitic metabasites from the Sierra de Guadarrama

71300 71300 71300 71300 71300 96895 96895 96897 96897 96987
Text Corona Inclusion Inclusion Inclusion
4 25 17 24 116 14 65 72 107 108

Si02 43. 27 40. 1 0 40. 28 40.58 40.36 42. 96 42. 06 44. 79 43. 47 43. 1 2
Ti02 1.91 1 . 35 1 . 23 1.01 1 . 98 0. 82 0. 1 0 1 . 19 1 . 04 0. 52
A1203 9.24 13.75 1 2. 05 13. 6 1 1 2 . 42 13 . 69 13. 03 9. 04 1 0. 60 1 1 . 20
FeO 17. 96 20. 40 2 1 . 85 20.84 23. 27 1 8.58 23. 81 1 9. 60 20. 9 1 20. 5 2
M nO 0. 00 0. 24 0. 20 0. 1 4 0. 24 0. 1 9 0. 64 0. 24 0. 1 9 0. 1 4
M gO 1 0.57 7. 23 7. 16 7. 1 0 5. 92 7. 08 5. 30 9. 02 7. 93 8. 0 1
C aO 1 0. 7 1 1 1 . 44 1 0. 9 1 1 0.58 9. 62 10. 49 1 1. 7 1 1 0. 8 1 1 1 . 06 1 1 . 28
Na20 2. 69 2. 99 3. 00 3. 24 3. 05 2.37 0. 24 1 . 88 2. 1 4 1 . 98
K20 0. 1 4 0. 23 0. 00 0. 00 0. 1 8 0. 1 4 0. 09 0. 05 0. 03 0. 04
Total 96. 49 97.73 96. 68 97. 09 97 . 03 96.32 96. 98 96. 63 97.35 96. 8 1

Structural fonnula 13-CN K

TSi 6.5 1 6. 1 1 6. 20 6. 17 6. 1 8 6. 50 6. 37 6.74 6. 5 6 6. 52
TAl 1 . 49 1 . 89 1 . 80 1 . 83 1 . 82 1 . 50 1 . 63 1 . 26 1 . 44 1 . 48
Total T 8. 00 8. 00 8. 00 8.00 8.00 8.00 8. 00 8. 00 8. 00 8. 00

CAt 0. 1 5 0. 57 0.38 0. 6 1 0. 4 1 0. 94 0. 69 0.34 0. 44 0. 52

3
CFe + 0. 00 0. 35 0. 00 0. 00 0. 86 0. 26 1 . 03 0. 60 0. 57 0. 59
C Ti 0.22 0. 1 5 0. 1 4 0. 1 2 0.23 0. 09 0. 0 1 0. 13 0. 1 2 0. 06
C M� 2.37 1 . 64 1 . 64 1.61 1 . 35 1 . 60 1 . 20 2. 02 1.78 1 . 81
CFe + 2. 26 2. 25 2. 8 1 2. 65 2. 1 2 2. 09 1. 99 1 . 86 2. 07 2. 00
C Mn 0. 00 0. 03 0. 03 0. 02 0.03 0. 02 0. 08 0. 03 0. 02 0. 02
Total C 5 . 00 5. 00 5 . 00 5. 00 5. 00 5. 00 5. 00 5 . 00 5. 00 5. 00

B Ca 1 . 73 1 . 87 1 . 80 1 . 72 1.58 1 . 70 1. 90 1 . 74 1.79 1 . 83
BNa 0. 27 0. 1 3 0. 20 0. 28 0. 42 0. 30 0. 07 0. 26 0. 2 1 0. 17
Total B 2. 00 2. 00 2. 00 2. 00 2. 00 2. 00 1 . 97 2. 00 2. 00 2. 00

ANa 0.5 1 0. 75 0. 69 0. 68 0. 48 0. 39 0. 00 0. 29 0. 4 1 0. 4 1
AK 0. 03 0. 04 0. 00 0. 00 0. 03 0. 03 0. 02 0. 0 1 0. 00 0. 0 1
Total A 0.54 0. 79 0. 69 0. 68 0. 52 0. 42 0. 02 0.30 0. 42 0. 42

Total 15.54 15.79 15. 69 15. 68 15.52 15 . 42 1 4. 99 15. 30 15. 42 15. 42

cations

of the inclusions and coronas. As a degree of differentiation, the most variable types
tendency towards more calcic composition close those cropping out at Tenzuela massif
to the garnet domain is seen. 1) (Villaseca, 1983). In other outcrops the
metagabbroic composition dominates. The CIPW
normative compositions range from olivine­
h""',....... ;.",.. ...' ... and n""r ... ..' CJ&l'n&l�." of the
normative «15 in the gabbros towards
metabasite protoliths 'l'H"t'7_Tlr"CTYI"t",p for rocks with Si02 contents of

The major and trace elements of nine metabasites >49 wt. %. The metabasic series vary from silica
are in Table 5. Three are taken saturated to oversaturated. The most differentiated
from Villaseca (1983) with new trace and REE rock (leucotonalite 67041, Table 5) has
carried out at the CRPG-CNRS 0. 51 wt. % normative corundum The '''"U "Y �'''-=L'''-'

France) chemical composition together with their very

The low K20 content defines a tholeiitic affinity for
a these metabasites. This tholeiitic character is also
 o 7 1300 matrix
Edenite Pargasite • 71300 inclusion 0.8
D 96895 matrix
• • 96895 inclusion
0.6
D

Ferroedenite
I"'�OOO 0.4

Ferropargasite 0.2

a
7.5 7.0 6.5 6.0 5.5 5.0 4.5

. 96897
Edenite Pargasite
6. 7635 1 0.8
82245 . 96905
-------;t
•
� 0.6
/u
.-�,�
76352 0.4

Ferroedenite Ferropargasite 0.2

7.5 7.0 6.5 6.0 5.5 5.0 4.5

Si (p.t: u.)
b 7 1300 inclusions 0.9
c
0.8

0.7
0.6 �

�
;;
< 6 0.5 •
0.4 71300 Matrix / �
z •
0.3
0.2

0.1

0.5 1.5 25 0.5 1.5

Allv
FIG. 5. (a) Composition of Ca-amphibo1es from the Central S pain metabasites (Leake et al. , 1 997); (b) concentration
of AI in four and six fold c oordinates sites for inclusion and matrix amphibo1es of sample 7 1300; (c) Na(M4 ) vs.
A1VI+Fe 3-t-+Ti diagram of amphibo1es from Central Spain metabasites c ompared to amphibo1es of different
metamorphic facies series. Shaded field: S anbagawa and Franciscan high pressure facies series; dotted line:
Dalradian intennediate pressure facies; continuous line: Haast River intennediate pressure facies; dashed line:
Abukuma low pressure terrane ; from Laird and AIbee ( 1 98 1 ) .

shown by the high F e content of the metabasites The HFSE and REE are usually regarded as
in the AFM diagram (Fig. 6a). The P205 contents trace elements remaining unaffected by meta­
are generally high compared to other tholeiitic morphic processes (Rollinson, 1993). All the
series. In fact, in the MnO-TiOrP205 diagram analysed metabasites are richer in Th, Nb, Zr and
(Fig. 6b) these metabasites plot from tholeiitic LILE than averaged MORB composition (Fig. 6c).
towards more alkaline fields (Mullen, 1983). In fact, in the ZrlY vs. Zr dia gram (not shown),
 FeOt
a

Calc-alkaline

MgO MnO*10

100

10

Rb Th Nb La Sr P Zr Ti La Nd Srn Gd Dy Er Yb
Ba K Ce Nd Srn Gd Y Yb Ce Eu Lu

FIG. 6. (a) AFM diagram for the Central Spain metabasites showing the typical Fe enrichment of the tholeiitic series ;
fields after Irvine and B aragar (1971). (b) MnO-TiOTP205 discrimination diagram with fields after Mullen (1983).
(c) N-type M ORB (S aunders and Tarney , 1984; Sun, 1980) normalized diagram for metabasites; CAB , island-arc
c alc-alkaline basalt; IAT, island-arc tholeiite; O IT , ocean-island tholeiite; OIA, ocean-island alkali basalt. (d) C l
chondrite (Evensen et al. , 1978) normalized REE diagram.

these metabasites plot mostly in within-plate fields, In summary, we believe that the metabasic
far from the composition of oceanic or plate­ pro tolith derived from low-pressure crys tal
margin basalts (Pearce and Norry, 1979). Although fractionation of tholeiitic melts more enriched
the metagabbros varieties exhibit :flat chondrite­ than typical MORB compositions. Their associa­
normalized REE patterns (LaNNbN =1 . 0-1 .8) tion with typical continental platform sediments
they show absolute concentrations of -20 times such as mature pelites, calc-silicates, marbles and
chondrite (Fig. 6d). The more silica-rich metaba­ minor quarzites, defines a continental affinity and
sites display fREE-enriched patterns (LaN/YbN = not an oceanic character for these tholeiitic sills.
3. 6) and some negative Eu anomaly, but HREE The high degree of evolution acquired by these
patterns are consistently:flat suggesting that neither metabasites is illustrated by the presence of felsic
garnet nor amphibole were important phases types which is in agreement with intracontinental
involved in the petrogenesis of the tholeiites. scenarios proposed by Hess (1989).
 TABLE 5. Major and trace element of selected metabasites.

71300 968 95 968 96 62984 71303 82244 9512 66726 67056 67041

Si02 44. 41 46. 34 48. 23 48. 60 49.50 50. 43 5 1.79 63.92 69.44 72.77
Ti02 4.36 3.81 3. 46 2. 89 2. 22 1.94 1. 93 1 . 28 0. 58 0. 43
Al203 1 3 . 02 12. 82 13. 12 1 4.73 13.59 13. 43 1 4. 1 4 1 4. 1 1 13. 68 14.36
Fe203 20. 1 1 18. 66 17.75 13.38 14. 08 14. 5 1 1 2.55 7 . 73 5. 28 3. 21
MnO 0. 40 0.31 0. 28 0. 22 0. 27 0.23 0. 22 0.08 0. 04 0.03
4.36 4.77 4. 1 9 4. 88 7.52 5.43 6. 42 1 .37 0. 66 0. 62
9.5 1 9.54 8. 95 8. 1 3 10.53 10. 64 1 0.50 4. 64 3. 3 2. 43
Na:f) 3.56 3 . 33 3.39 3.53 1 . 27 2.94 1 . 70 5.72 5. 08 5. 49
K20 0. 43 0. 15 0.3 6 1 . 46 0. 24 0.05 0. 3 1 0 . 43 1. 46 0.5 1
P20S 0.32 0 . 45 0.52 0. 64 0. 26 0. 1 2 0. 25 0 . 29 0. 2 0. 06
LOI 0. 90 0 0 1.50 1 . 23 0.39 0. 46 0 . 22 0. 22 0. 4
T otal 1 0 1 . 38 99. 92 99. 95 99. 96 100 . 7 1 100. 4 1 100. 27 99.79 99. 94 100. 3 1

Ba 1 23 25 67 1 29 241 28 1 17 224 123

Rb 10 4 15 54 5 9 12 30 12
Sr 61 62 76 136 87 109 141 122 324
Nb 15 12 15 7 24 20
Zr 154 191 24 1 1 90 100 102 541 665 564
Y 42 50 63 25 40 91 74 53
Th 5 1.3 1.84 17 4 14 15
Ga 29 22 24 24 21 27 26

La 4. 9 1 9.06 1 3. 04 7.09 39.70 41.72

Ce 1 2. 23 23. 0 1 3 6. 66 17.72 83.77 98.07
Nd 8. 79 16. 33 24. 61 1 1 . 89 50. 1 8 45.78
S rn 3.78 5.25 7. 9 4.43 13.28 1 1. 37
Eu 1.55 1.8 2.52 1.23 3.36 2. 22
Gd 6. 46 7 . 52 9.59 5.20 1 2.96 1 1. 13
Dy 8. 28 8.32 1 0. 96 6.22 1 4.58 1 1. 46
Er 3.76 4.8 6. 1 4 3.33 7.55 6. 86
Yb 3.89 4.5 1 5.88 3.73 8.70 6. 66
Lu 0. 68 0.74 0. 93 0.67 1 . 46 1 . 05

P-T conditions Reaction 1 marks the transition from to

facies conditions.
r,� aLlI U.lLLv

For kinetic reasons, mafic rocks tend to preserve ""H�"'�I-'.,,_au presence of plagioclase and

high-press ure parageneses relati ve to felsic rocks coronas around garnet and
(O'Brien et aI., 1992) The presence of scarce amphibolitization of the rock 2)
included in garnet in certain as H20 pressure increases are controlled by
samples indicates that the P-T evolution of these reactions such as:
rocks passed through a high P stage.
Grt + ---"" PI (>An) + Amp (2)
M 2 granulitic re-crystallizationis proven by the
presence of coronas around clino­ of the M2
pyroxen e in cl usions in garnet (Fig. 2). This metamorphic The local
indicates the occurrence of the reaction: presence of orthopyroxene in the inner coronas
around garnet 2e) indicates a reaction of the
Grt + ---"" PI «An) + (low Na) (1)
form
instead of reactions GADS,
Grt + (± ---"" Opx + PI (3)
O'Brien e t al., 1992) as
present an olivine-normative '.AJ>.H!-,V0LUVU. which is less common than reaction 2
 because of minor vanatlOns in the whole-rock Inclusion omphacite and adjacent core garnet
composition of the metabasites and/or the were used in all cases.
presence of minor volatile phases during the Pressure-temperature estimates have also been
eclogite retrogression. The last two reactions are made using TWEEQU techniques as described by
probably coupled because: (1) the outer amphi­ Berman (1991) using the end-member properties
bole-rich rim is concentric to the orthpyroxene + and thermodynamic database of Berman (1988;
plagioclase inner rim (Fig. 2e); and (2) both the 1990). The solution models used in the calcula­
orthopyroxene and the amphibole were formed tions are from Berman ( 1 990) for garnet;
during granulitic conditions as deduced from the Fuhrman and Lindsley (1988) for plagioclase,
P-T estimates as discussed below. and ideal models are used for pyroxenes. Reaction
This metamorphic evolution is represented in curves were calculated for the mineral composi­
terms of ACF diagrams in Fig. 7. The tie-lines tions given in Tables 2-4 and the assemblages
connecting ld-rich clinopyroxene and garnet deduced from petrographic studies (Table 1)
(eclogite paragenesis) switch to a new tie-line con sidered to be representative of the firs t
connecting Ca-rich plagioclase and amphibole Hercynian metamorphic episode. Intersections
(reaction 2), and Na-rich plagioclase and diop­ gi ving standard deviations of ±0.5 bar and
sidic clinopyroxene (reaction 1). In certain ±20°C after no more than one iteration in the
microdomains of some metagabbros (sample exclusion analysis are regarded as yielding
96895, Fig. 7) reaction 3 can take place together acceptable results. Core-inclusions representing
with reaction 2 with the new orthopyroxene­ peak pressure conditions and border and matrix
plagioclase assemblage formed in the inner zones phases representative of the later retrogression
towards the garnet (Fig. 2). stages are treated separately.
The peak pressure eclogitic conditions are The eclogite-granulite transition paragenesis in
documented by the paragenesis Alm-Grs-Prp sample 71300 with omphacitic pyroxene inclusions
garnet + omphacite + rutile + quartz. in garnet, produce a tight crossing of reactions (two
Combination of the garnet-clinopyroxme Fe­ independent) at pressures of -14 kbar and
Mg exchange thermometer (Ellis and Green, temperatures of -760°C (Fig. 9). This is consid­
1979; Krogh, 1988) and the geobarometer based ered to represent the highest pressure attained in
on the reaction: albite in plagioclase jadeite (in
= the area. Similar P-T values are obtained, never­
omphacite) + quartz (Holland, 1980) yields theless, for other samples like 76352, 82244 and
press ure-temperature condi tions (Fig. 8) of 96895 for equilibrium parageneses Grt + PI + Cpx
-14±2 kbar and 700±50°C (sample 71300), + Qtz + Hm + Rt resulting in tight crossing of all
12±2 kbar and 675±50°C (sample 82244). equilibria (two independent)as illustrated in Fig. 9.

A A

c F c F

FIG. 7. ACF diagrams showing the tie-line switching from gnt-cpx (id rich) assemblages toward a typical granulite
facies paragenesis with plagioc1ase and amp hibole and/or orthopyroxene.
 ······
·teS ..
MI
£'C1ogt ··
..
......
..
14 ····
8.zJ4zr
9;')··G··· 73804
•
••
•••
••

If-
\.
__ . - -,____

10 �
jQ= Q. J_ �___ __ ___ I---
96895
·s
-

6 �

400 600 800

Ten1perature (OC)
FIG. 8. PT diagram in which the results of several classical thermobarometers in different samples (textured
quadrangular areas with respective sample numb er ) for theMI and M2 metamorphic stages are shown. M2 peak
conditions from MaJtln Romera et al. (1999). M3 metamorphic conditions from Villaseca (1983) and A rena s e/. at. .
(1991). Thick gley alTOW shows a p ossible PT metamorphic path for the Sierra de Guadanama sector as deduced
from the metamorphic conditions of the th.ree main metamorphic stages. Jadeite isopleths ale after GaspaJik and
Lindsley (1980 ); Hbl in reaction after Winkler (1976); Ky-And-Sill is after Holdaway (1971); facies boundruies
drawn after Spear (1993).

Relics of high-pressure M I assemblages in the obtained. For example, calculations performed on

related layered metasedimentary sequence have sample 82244 , for tbe equilibrium parageneses
also been identified (Villaseca, 1983; Villaseca Grt + PI + Cpx + Qtz + Ilm + Rt witb garnet core
and Barbero, 1994). These relics consist of composition and Cpx, PIg, Ilm and Rl inclusions
kyanite, Mg-rich garnet (Alm63-Pir33-Gros3- produce tight crossing of all equilibria at
SpSI), rutile and occasional staurolite from pressures in the range of 12-13 kbar and T in
wbicb pressure estimates of -8-15 kbar for the range 700 to 750°C. Results in tbe same
temperatures of 700±25°C have been reported sample for garnet rim compositions and matrix
(Villaseca and Barbero, 1994). So, the similarity phases give P-T conditions of 8 kbar at
of P-T conditions deduced for the MI stage for temperatures of -700°C. Similar decompressional
both the paragneisses and the related metabasi tes P-T paths are obtained for other samples thus
indicates that tbe whole complex bas experienced confirming the validity of these calculations
the same burial history. (Figs 8, 9). Temperature conditions obtained for
In metabasi tes with well-developed plagioclase the M2 episode, without taking amphibole into
coronas around garnet, it is possible to estimate account in the calculations, are consistent with
core and rim conditions and a record of the two those deduced from the conventional garnel­
main re-crystallization episodes M I and M2 is amphibole thermometer (Graham and Powell,
 + Cpx(Inc) + Plg(Inc)
I1m+ Rt
18
12.8 +/-0.2 kbar
750 +/-18° C

14

200 400 600 800 200 400 800

600
Temperature (OC Temperature
)

18 18

14 14

f: 10 f: 10
=
� =
� �
f: �
� �
6 6

2
2

200 400 600 800

200 400 600 800
(OC ( OC
) )

FIG. 9. PT estimates based on the TWQ intersections for cores-inclusions and rims-matrix of individual s amples
using the mineral assemblages shown in the insets and some of the reactions Oabelled) of the Appendix. See text for
further details of the activity models used, thermodynamic data set and uncertainties of the intersections .
 1984) which results in the range 680 to Peak pressure conditions based on the eclogitic
750°C Similar results are obtained using the two relics in the metabasites studied in this work are
pyroxene thermometer from Wood and Banno estimated to be -14 kbar and 750°C Pressure­
(1973) considering matrix phases (800-850°C in temperature estimates made on garnet rims and
sample 96895, 750-800°C in sample 96896) and matrix phases vary from 6 to 10 kbar and 680 to
also with the geotherm- 800°C As the metamorphic climax conditions of
ometer from garnet the area have been estimated to be at even lower
rims and adjac ent matrix orthopyroxene pressures (4-6 kbar, Villaseca, 1983), the total
(760-800°C, 96896). Pressures during decompression range h as to be -8-10 kbar
the M2 episode must be < 7-8 kbar as the 8). The P-T path thus obtained shows an
component in clinopyroxene is <10% isothermal decompression, and in any case, an
8) which is consistent with the results important increase in temperature related to
obtained using the consistent thermo- thermal relaxation is not observed. Such an
database as discussed above. isothermal of
The related paragneisses enclosing the eclogi tic deep-placed metamorphic rock to be rapid
metabasic lenses evolve with them, compared to the rate of thermal relaxation and
displaying biotite, cordierite, and subsequent cooling, but not so rapid as to preserve
sillimanite as part of a M2 abundant relics. Whether the
paJrag,en,eSl:S, whose must clearly cross into exhumation is related to extension of an over­
the s i l li m a ni t e s t a b il i t y fi e l d 8). thickened and lor thermally weakened orogenic
Thermobarometric estimates based on garnet - 1989; Ruppel and 1994) or
biotite and GASP T in the range (H_'_V�jL�f_n l"H'.'-'U by rates of synoro-
740-780°C and P of 4-6 kbar (Marlin Romera genic erosion (Jamieson et aI. , 1995; Willett et al. ,
et al. , 1999), which is in agreement with the 1993), or a combination of the two, is a difficult
conditions estimated in the to answer with the present data.
me tabasi tes. Nevertheless, the presence of a system of
extensional detachments such as the Berzosa­
Riaza shear zones in the Sierra de Guadarra,
Discussion
(Escuder Viruete et al. , 1998) suggests that the
High-pressure mineral reflecting the near isothermal decompression path could be
pressure conditions in rocks from the axial largely controlled by these extensional tectonics.
sectors are scarce. In the extrusion the
Hercynides from central the main remains transition from the eclogite field to the sillimanite
of a event are the rare omphacitic field. Isostatic erosion and
l l ".·� U �'VU in garnet described in this and Thompson, 1984) never reaches such a large­
previous works (Villaseca, 1 983; Villaseca and scale advection of heat and the P-T path never
Barbero, 1994). The first Hercynian tectonometa­ reaches the sillimanite field (Thompson et aI. ,
HRa V" lv phase recorded in the Central 1997). With the data available,
System is Devonian in age, and is marked by the this decompression has occurred a time
of P alaeozoic sedimenta tion span of -40-50 Ma.
(Gutierrez Marcos et al. , 1990). In coincidence lt is remarkable that these high-pressure
with this assumption are the ages of 370-380 Ma rocks occur in an intracontinental
which Wildberg et al. , (1989) obtained from section of the orogen, a
zircon from different and ortho­ thickening of the continental crust during the
gneisses from the eastern part of the Sierra de collision. The new barometric esti­
Guadarrama and which they assume reflect the mates made in this work allow us to a
first event (Dl)' burial depth for these metabasites of -55 km
The metamorphic cl imax with associated (considering an average for the crust in
crustal anatexis is estimated to have occurred at this sector of -2. 7 g
-325-330 Ma based on data that there is no evidence of tectonic
such as U-Pb in monazite from of the imbrication of different slices since
eastern part of the S ierra de Guadarrama times, and that the present thickness
(Valverde Vaquero et al. , 1995; Escuder Viruete of the crust in Central is -31 km (Paulssen
et a!., 1998} and Visser, 1993) the crust the
 Ml stage could have reached a thickness of References
- 70 80 km, which is more than the double the
-

present thickness. This has important conse­ Arenas , R. , Fuster, 1. M. , GonzaIez Lodeiro, F. , Macay a,
quences when modelling the Hercynian tecto­ 1. , MartIn-Parra, L. M. , Marunez-Catalan, 1. R and
nothermal evolution in the Central Iberian Zone, Villaseca, e. ( 1 99 1 ) Evoluci6n metamorfica de la
as the crus tal thickening is a major factor regi o n de S egovia (S ierra de Guadarram a).
controlling melting conditions during orogenesis Geogaceta , 4, 195 -20 1.
(Patino Douce and Johnston, 1991). B arbero, L . ( 1 995 ) Granulite facies metamorphism in
the Anatectic Complex of T oledo, Spain: late
Eclogites described in other Hercynian Iberian
Hercy nian tectonic evolution by crustal extension.
sectors have been related to eo - Hercyn ian
1. Geol Soc. , 152 , 3 65-82.
(430-365 Ma) subduction processes 0 f conti­
Berman, R. G. ( 1 988) Internally -co nsistent thermo­
nental wedges under oceanic crust as in the case
dynamic data for minerals in the system N a20-
of eclogites from the northwest branch (Martinez
K20-CaO -MgO -FeO-Fe203-SiOyTiOT H20-C02, 1.
Catalan et al. , 1996) or southwestern sectors (Leal
Petrol , 29, 445-522.
et al , 1996). These eclogites are incorporated
Berman , R. G. ( 1 990) Mixing properties of C a-Mg-Fe­
t e c t o n i c a l l y int o m a j o r a l l oc h t h on o u s ­
Mn garnets. Amer. Mineml , 75, 328-44.
parautochthonous units and are closely related to Berman , R G. ( 1 99 1 ) Thermobarometry using multi­
mantle-derived peridotitic bodies, as is also equilibrium calc ulations: a new technique with
typical in most of the European Hercynian petrological applic ations. Canad Mineml , 29 ,
eclogite-facies rocks (Carswell and Cuthbert, 833 - 55.
1986; Bouchardon et al , 1989). In contrast, the Blu ndy , 1. D . an d H ollan d, T. J . B . ( 1 990) C alcic
eclogite-facies metabasites studied in the present amphibole equilibria and a new amphibole-plagio­
work do not show any relationship with ultramafic c1ase geothermometer. Contrib. Mineml Petrol ,
mantle-derived rocks and lack a geochemical 104 , 208-24.
oceanic affinity, their chemical features being B ouchardon, 1. -L. , Santailier, D. , Briand, D. , Menot, R. -P.
consistent with an intraplate continental affinity. and Piboule, M. ( 1 989) Eclogites in the French
The absence of tectonic contacts between the P aleo zo ic Orogen : geody na mic sig nifi c ance.
metabasites and host rock and the cofacial Tectonophysics, 169, 3 17-32.
metamorphic evolution argues against any Carswell, D. A and Cuthbert, S. 1. ( 1 986) Eclogite facies
suggestion that the host rocks have never metamorphism in the lower continental crust Pp.
endured such high pressure conditions because 193- 209 in: The Nature of the Lower Continental
they came into contact with the eclogites much Crust (1. B. Dawson, D. A Carswell, 1. Hall and K H
later at some shallower depth. Thus is seems We depohl , editors). Spec. Pub!. , 24. Geological
reasonable to state that no differences in S ociety , London.
metamorphic grade exist between the metabasites Coleman, R G. , Lee, D. E. , Beatty, L.B. and Brannock,
W.W. ( 1 965) Ec10gites and eclogites : their differ­
and the host rocks, the metabasites having
ences and similarities . Geol Soc. Amer. Bull , 76 ,
suffered in situ eclogite-facies metamorphism
483-508.
and thus do not represent allochthonous units.
E1lis, 0. 1. and Green, D. H ( 1 979) An experimental
Burial of the whole metamorphic sequence and
study of the effect of Ca upon garnet-clinopyroxene
subsequent eclogitization of the basic rocks might
Fe-Mg exc hange equilibria Contrib. Mineml.
be related to intracontinental subduction thick­
Petrol , 7 1 , 13 -22.
ening during the Hercynian collision.
England, P. e. and Thompson , A B. ( 1 984) Pressure­
temperature-time paths of regional metamorphism I.
Acknowledgements Heat transfer during the evolution of regions of
thickened continental crust 1. Petrol , 25, 894 -928.
Alfredo Femandez Larios and Jose GonzaIez del Escuder Viruete, 1. , Hemaiz, P. P. , V al verde-V aquero,
Tanago are thanked for their assistance in P. , R odriguez Femandez, R . and Dunning, G. ( 1 998)
micropro be a nalysis performed at CAI of Variscan syncollisional extension in the Iberian
Mi cro scopia Electro ni ca fro m Complu tense Massif: structural, metamorphic and geochronologi­
University. F. 1. Fernandez, P. 1. Q'Brien and an cal evidence from the Somosierra sector of the Sierra
anonymous reviewer are thanked for their de Gu adarrama (Central Iberian Zone, Spain).
constructive comments. This work was supported Tectonophysics, 290, 87 - 109.
financially by the project DGYCIT PB96-0661 of Evensen, N. M. , Hamilton, PJ. and O ' Nions , R. K ( 1 978)
the Spanish Ministerio de Educaci6n y Cultura. Rare earth abundances in chondritic meteorites.
 Geochim Cosmochim Acta, 42 , 1 1 99- 2 1 2. Amphiboles of the International Mineralogical
Fuhnnan, M. L. and Lindsley , D. H. , ( 1 988) Ternary­ Association Commission on New Minerals and
fel dsp ar m o delling an d therm ometry. Amer. Mineral N ames. Mineml Mag. , 61 , 295 -3 2 1 .
Mineml , 73 , 20 1 - 15 . Leal, N. , Pedro, I , Moita. P . , Fonseca, P. , Arauj o, A
Gasparik, T . and Lindsley , D. ( 1 980) Phase equilibria at and Munha, l ( 1 996) Metamorfismo nos sec tores
high pressure of pyroxenes containing monovalent meridionais da zona de Ossa- Morena: Actualizaq ao
and trivalent ions. Pp. 309 - 99 in : Pyroxenes (Ch.T. de conhecimentos . Estudios sobre a geologia da
Prewi tt, edi tor). Reviews in Mi neral o gy , 7 . zona de Ossa-Morena (Maci<;o Iberico) Livro
Mineralogical S ociety of America, Washington D C Homenagem ao Pro! Fmncisco GOn(;alves, Evom,
Govindaraj u , K and Mevelle, G. ( 1 987 ) Fully auto­ 1 1 9- 32.
mated dissolution and separation methods for the Macaya, l, GonzaIez-Lodeiro, F. , M artinez Catalan,
inductively coupled plasma atomic emision spectro­ l R. and Alvarez, F. ( 1 99 1 ) Continuous defonnation,
metry rock analysis - Application to the detennina­ ductile thrusting and backfolding of cover and
tion of rare-earth elements. 1. Anal Atom Spectr. , 2, basement in the Sierra de Guadarrama, Hercynian
615 -2 1 . orogen of central Spain. Tectonop hysics, 19 1 ,
Graham, e M. and Pow ell , R. ( 1 98 4) A garnet­ 29 1 - 309.
hornblende geothennometer: c alibration, tes ting Marunez Catalan, l R. , Arenas, R. , Dfaz Garda, F. ,
and applic ation to the Pelona Schist, S outhern Rubio Pascual, F. I , Abati, I and Marqu{nez, l
California 1. Metam Geol. , 2, 13 -3 1 . ( 1 99 6 ) Variscan ex hum ati on of a s ubduc ted
Gutierrez Marco, l e , San J ose , M. A and Pieren, A P . Paleozoic continental margin: The basal units of
( 1 990 ) Cen tral Iberian Z one. Pos t-C ambrian the Ordenes C omplex , Galicia, NW Spain. Tectonics,
P aleozoic s tratigra phy. Pp. 1 60 -7 1 in : Pre­ 15, 1 06 - 2 1 .
Mesozoic Geology of Iberia (R. D . Dallmeyer and Marun Romera, e , Villasec a. C and Barbero, L. ( 1 999)
B. Martinez Garc{a, editors) . S pringer Verlag, Berlin. Materiales an ate ctic os en el area de S otosalbos
H arley , S . L. ( 1 984) An experimental study of the (Segovia, Sierra de Guadarrama). Caracterizaci6 n
partitioning of Fe and Mg between garnet and petro16 gica, geoqu fmica e isotopica (Sr, N d). Actas II
orthopyroxen e. Contrib. Mineml. Petrol. , 8 6 , Congreso Ibthico de Geoqutmica, Lis boa, 329 -32.
359 -73. Medaris, G. , Jellnek , E and M{sar, Z. ( 1 995) Czec h
Hess, P. C ( 1 989) Origins of Igneous Rocks. Harvard eclogites: Terrane settings and implications for
University Press, Cambridge, MA Variscan tec tonic evolution of the B o hemian
H oldaway, M I ( 1 97 1 ) S tability of andalusite and the Massif. Eur. 1. Mineml. , 7 , 7 - 28.
aluminium silicate phase diagram. Amer. 1. Sci., 27 , Messiga, B . , Tribuzio, R. and Caucia, F. ( 1 9 92 )
97 - 132. Amphibole evolution i n Varican eclogite-amphibo­
H olland, T. l B . ( 1 980) The reac tion albite= j adeite + lite from the S avona crystalline massif (Western
quartz detennined experimentally in the range Ligurian Alps, Italy): Controls on the decompres­
600 - 1 200 ° C Amer. Mineml. , 65, 1 29-3 4. sional P-T-t path. Lithos , 27 , 2 1 5 -30.
Irvine, T N. and B aragar, W. R. A. ( 1 97 1 ) A guide to the Mu1len, E D. ( 1 983 ) MnO/TiO::/P205: a minor element
chemical classification of the common volcanic discriminant for basaltic rocks of oceanic environ­
rocks. Canad 1. Earth Sci. , 8 , 523 - 48. ments and its implications for petrogenesis. Earth
Jamieson , R.A. , Culshaw, N. G. and Corrigan, D. ( 1 995 ) Planet Sci. Lett. , 62 , 53 - 62.
North-west propagation fo the Grenvi1le orogen: O ' Brien, P. l , Rohr, e , Okrusc h, M. and P atzak, M
Grenvillian structure and metamorphism near Key ( 1 992) Ec10 gite facies relics and a multistage
Harbour, Georgian B ay , Ontario, Canada 1. Metam breakdown in metabasites of the KTB pilot hole,
Geol , 1 3 , 1 85 - 207 . NE B avaria: Implic ations for the Variscan tectono­
Kretz, R. ( 1 983) S ymbols for rock fonning minerals. metamorphic evolution of the NW B ohemian Massif.
Amer. Mineml. , 68 , 277 -9. Contrib. Mineml Petrol , 1 12 , 26 1 -78.
Krogh, El ( 1 988 ) The garnet-clinopyroxene Fe-Mg Patino Douce, A B. and Johnston, A D. ( 1 99 1 ) P hase
geothennometer - a reinterpretation of existing equilibria and melt produc tivity in the pelitic system:
experimental data Contrib. Mineml Petrol , 99 , implications for the origin of peraluminous grani­
44 - 8. toids and aluminous granulites. Contrib. Mineml
Laird, l and Albee, A L. ( 1 98 1 ) Pressure-temperatures Petrol , 1 07 , 202 - 1 8.
and time indicators in mafic schists: their application Paulssen, H. and Visser, I ( 1 993) The crustal s truc ture
to reconstructing the polymetamorphic history of in Iberia inferred from P-wave coda. Tectonophysics ,
Vennont Amer. 1. Sci. , 28 1 , 1 27-75. 221 , 1 1 1 -23.
Leake, B . B. and 20 others ( 1 997 ) Nomenclature of Pearce, lA and Norry, M. I ( 1 97 9 ) Petrogenetic
amp hibole s : Report of the S ubcommittee on implications of Ti, Zr, Y and Nb variations in
 volc anic rocks. Contrib. Mineral. Petrol. , 69 , Thompson, A B. , Schulmann, K and Jezek, 1 ( 1 997 )
33 - 47. Extrusion tectonics and elevation of lower crustal
R aheim, A. and Green, D. H ( 1 975) Experimental metamorphic rocks in c onvergent orogens . Geology ,
detenni nation of the temperature and pressure 25 , 491 - 4.
dependence of the Fe-Mg partition coefficient of Valverde Vaquero, P. Hernaiz, P. P. , Escuder, I and
c oexis ting garnet and c1inopyroxene. Contrib. Dunning, G. R. ( 1 995 ) Comparison of the pre­
Mineml Petrol , 48 , 179 -203. Cambrian and Paleozoic evolution of the Sierra de
Ridley , 1 ( 1 989 ) Vertical movement in orogenic belts Guadarram a (Central Iberian Zone, S pain) and the
and the timing of metamorph ism relative to Gondwana margin, NFLD Appalachians (GMNA}
defor mation. Pp. 1 03 - 1 5 i n : Evoluti on of Terra Abstracts , 7, 278.
Metamorphic Belts (l S. 1 Daly, R. A Cliff and Viallete, Y. , Casquet, C , Fuster, 1 M , Ibarrola, E. ,
B . W. D . Yardle y , e di tor s ). Spec. P ub!. , 4 3 . Navidad, M , Peinado, M. and Vill as ec a, C ( 1 987 )
Geologic al S ociety, London. Geochronological study of orthogneisses from the
Ringwood, A B. ( 1 975 ) Composition and Petrology of Sierra de Guadarram a (Spanish Central S ystem).
the Earth's Mantle. McGraw Hill, New York. Neues farhh. Mineml. Mh , H I 0, 465 -79.
Robinson, P . , Spear, F. S . , Schumacher, l C , Laird, l , Villasec a. C ( 1 983 ) Evolucion metam6ifzca del sector
Klein , C , Evans, B. W. and Doolan, B. L. , ( 1 982 ) centro-septentrional de la Sierm de Guadarmma.
Phase relations of metamorphic amphiboles : natural PhD Thesis, Univ. Complutense de Madrid
occurrence and theory. Pp. 1 -27 in: Amphiboles and Villasec a. C ( 1 985) Microdioritas de afinidad toleftica
other Hydrous Pyriboles - Mineralogy (D. R. Veblen en las bandas de cizalla de Segovia Estudios
and P. H Ribbe, editors) . Reviews in Mineralogy , Geol6gicos , 4 1 , 1 1 -5.
9B . Mineralogical Society of America, Washington Villasec a. C and Barbero, L. ( 1 994) Estimaci6 n de las
DC condiciones del metamorfismo hercfnico de alta
R ollins on , H . ( 1 993 ) Using Geochemi cal Data: presi6 n de la Sierra de Guadarrama Geogaceta ,
Evaluati on, Presenta tion and Interpre tation . 16 , 27 -30.
Longman, Essex. Villasec a. C , Barbero, L. and Rogers, G. ( 1 998) Crustal
Ruppel, C and H odges , K-V. ( 1 994) Presssure­ origin of Hercynian peraluminous granitic batholiths
temperature-time paths from two-dimensional ther­ of Central Spain: petrological, geoc hemical and
mal models: pro grade , retrograde, and inverted isotopic (Sr, Nd) constraints. Lithos , 43 , 55 -79.
metamorphism. Tectonics , 1 3 , 17 - 44. Villasec a. C , Barbero, L. , Huertas, M l , Andonaegui, P.
S an Jose , M A , Pieren, A P. , Garc fa-Hidalgo, I F. , and B ellido , F. ( 1 993 ) A cross-section through
Herranz, P. , Pelaez, l R. and Perej 6n , A ( 1 990 ) Hercynian gmnites of the Centml Iberian Zone.
Central Iberian Zone. Anteordovician S tratigraphy. Excursion Guide. C S. I. C , Madrid
Pp. 1 47 -59 in: Pre-Mesozoic Geology of Iberia Wildberg, H D. H , Bischoff, L. and B aumann, A. ( 1 989)
(R. D. D allmeyer and E. M artfnez Garcfa, editors) . U-Pb ages of zircon from meta-igneous and meta­
Springer Verlag, Berlin. sedimentary rocks of the Sierra de Guadarrama:
S aunders, A D. and Tarney, 1 ( 1 984) Geochemical implications for the Central Iberian crustal evolution.
characteristics of basaltic volcanism within back-arc Contrib. Mineml Petrol , 1 03 , 253 - 62.
basins . Pp. 5 9-76 in : Marginal Basin Geology (B. P. Willett, S. D. , Beaumont, C and Fullsack, P. ( 1 993 )
Kokelar and M F. Howells, editors ). Spec. Pub!. , 16. Mechanical models for the tectonics of doubly
Geologic al S ociety, London. vergent c ompressional orogens. Geology , 21 , 37 1 -4.
Spear, F. S . ( 1 99 1 ) On the interpretation of peak Winkler, H G. F. ( 1 97 6) Petrogenesis of Metamorphic
metamorphic temperatures in light of garnet diffu­ Rocks. S pringer, Berlin.
sion during c ooling. f. Metam Geol. , 9, 379 - 88. Wood, B.I and Banno, S. ( 1 973 ) Garnet-orthopyroxene
Spear, F S . ( 1 993) Metamorphic Phase Equilibria and and orthopyroxene-c1inopyroxene relationships in
Pressure-Tempemture-Time Paths. Monograph of simple and complex systems. Contrib. Mineml
the Mineralogical S ociety of America, Washington Petrol. , 42, 1 09 - 24.
DC
S un , S. S . ( 1 980) Lead isotopic study of young volcanic
rocks from mid-ocean ridges, ocean islands and
islands arcs. Phil Tmns. R. Soc. , A297 , 409 - 45 .
 AP P EN D IX

Selected equilibria used in analysis (Bennan, 1991). Numbers refer to those in the intersection
diagrams in 9.

1. Jd + Qz Ab =

2. Py + 2 Grs + 3 A b 3 An + 3 Di + 3 Jd
=

3. 2 Grs + Py + 3 Q z 3 Di + 3 An (Grt-Cpx-Plg-Qz barometer)

=

4. Alm + 2 Grs + 3 Qz 3 Hd + 3 An=

5. 3 A b + Alm + 2Grs 3 Jd + 3 Hd 3 An
=

6. Alm + 3 Di Py + 3 H d
= thermometer)
7. 4 H d + Py + 4 R t 3 Qz + 4
= + 3 D i An
8. 2 Rt + Py + 2 Hd + Grs 2 An + 3 Di + 2 Urn
=

9. Alm + 3 Hd + 6 Rt 6 Qz + 6 llm + Grs

=

1 0. 6 Rt + Py + 6 Hd 3 Di + Grs + 6 Urn
=

A bbreviations: Ab, albite; An, anortite; Alm, almandine; Di, diopside; Grs, grossular; Hd, hedenbergite; Ilm ,
ilmenite; Jd, j adeite; Py, pyrope; Q z, beta quartz; Rt, rutile. Other abbreviations follow Kretz ( 1 983 ).

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