Z 15 LC Distacc - Cera Liq: Safety Data Sheet

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SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006

Z 15 LC distacc.cera liq
Version 9.0 SDB_GB Revision Date 25.11.2020 Print Date 25.11.2020

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier


Trade name : Z 15 LC distacc.cera liq

UFI : 1W50-809V-Y00Y-QHAJ

1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the : Release agent
Substance/Mixture

1.3 Details of the supplier of the safety data sheet


Company : ELANTAS Europe S.r.l.
Strada Antolini 1
43044 Collecchio
Italy
Telephone : +3907363081
Telefax : +390736402746
E-mail address : [email protected]

1.4 Emergency telephone number


+39 0736 3081 (8-17 h)

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture

Classification (REGULATION (EC) No 1272/2008)


Flammable liquids, Category 2 H225: Highly flammable liquid and vapour.

Skin irritation, Category 2 H315: Causes skin irritation.

Specific target organ toxicity - single H336: May cause drowsiness or dizziness.
exposure, Category 3, Central nervous
system

Aspiration hazard, Category 1 H304: May be fatal if swallowed and enters


airways.

Long-term (chronic) aquatic hazard, H411: Toxic to aquatic life with long lasting effects.
Category 2

2.2 Label elements

Labelling (REGULATION (EC) No 1272/2008)

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SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006

Z 15 LC distacc.cera liq
Version 9.0 SDB_GB Revision Date 25.11.2020 Print Date 25.11.2020

Hazard pictograms :

Signal word : Danger

Hazard statements : H225 Highly flammable liquid and vapour.


H304 May be fatal if swallowed and enters
airways.
H315 Causes skin irritation.
H336 May cause drowsiness or dizziness.
H411 Toxic to aquatic life with long lasting effects.

Precautionary statements : Prevention:


P210 Keep away from heat, hot surfaces, sparks,
open flames and other ignition sources. No
smoking.
P233 Keep container tightly closed.
P261 Avoid breathing dust/ fume/ gas/ mist/
vapours/ spray.
Response:
P301 + P310 IF SWALLOWED: Immediately call a
POISON CENTER/ doctor.
P331 Do NOT induce vomiting.
P370 + P378 In case of fire: Use dry sand, dry chemical
or alcohol-resistant foam to extinguish.

Hazardous components which must be listed on the label:


Naphtha (petroleum), hydrotreated light; Low boiling point hydrogen treated naphtha

2.3 Other hazards


This substance/mixture contains no components considered to be either persistent, bioaccumulative
and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

SECTION 3: Composition/information on ingredients

3.2 Mixtures
Chemical nature : Wax Solution

Hazardous components
Chemical name CAS-No. Classification Concentration
EC-No./List (REGULATION (%)
Registration number (EC) No
1272/2008)
Naphtha (petroleum), hydrotreated 64742-49-0 Flam. Liq.2; H225 >= 50 - <= 100
light; Low boiling point hydrogen 265-151-9 Skin Irrit.2; H315
treated naphtha 01-2119475515-33 STOT SE3; H336
Asp. Tox.1; H304
Aquatic Chronic2;
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SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006

Z 15 LC distacc.cera liq
Version 9.0 SDB_GB Revision Date 25.11.2020 Print Date 25.11.2020

H411
For explanation of abbreviations see section 16.

SECTION 4: First aid measures

4.1 Description of first aid measures


General advice : Keep warm and in a quiet place.

Show this safety data sheet to the doctor in attendance.

Take off all contaminated clothing immediately.

If inhaled : Move to fresh air.

Keep patient warm and at rest.

If symptoms persist, call a physician.

In case of skin contact : Wash off immediately with soap and plenty of water.
Do NOT use solvents or thinners.
If on clothes, remove clothes.
If skin irritation persists, call a physician.

In case of eye contact : Rinse immediately with plenty of water, also under the eyelids,
for at least 15 minutes.

If eye irritation persists, consult a specialist.

If easy to do, remove contact lens, if worn.

If swallowed : Keep at rest.

Do not induce vomiting without medical advice.

Keep respiratory tract clear.

If symptoms persist, call a physician.

4.2 Most important symptoms and effects, both acute and delayed
Symptoms : irritant effects

4.3 Indication of any immediate medical attention and special treatment needed
Treatment : The first aid procedure should be established in consultation
with the doctor responsible for industrial medicine.

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SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006

Z 15 LC distacc.cera liq
Version 9.0 SDB_GB Revision Date 25.11.2020 Print Date 25.11.2020

SECTION 5: Firefighting measures

5.1 Extinguishing media


Suitable extinguishing media : Foam

Sand

Carbon dioxide (CO2)

Water mist

Unsuitable extinguishing : Water spray jet


media

5.2 Special hazards arising from the substance or mixture


Specific hazards during : The pressure in sealed containers can increase under the
firefighting influence of heat.

Cool closed containers exposed to fire with water spray.

5.3 Advice for firefighters


Special protective equipment : In the event of fire, wear self-contained breathing apparatus.
for firefighters

Use personal protective equipment.

Further information : Use extinguishing measures that are appropriate to local


circumstances and the surrounding environment.
Immediately evacuate personnel to safe areas.

Prevent fire extinguishing water from contaminating surface


water or the ground water system.

Fire residues and contaminated fire extinguishing water must


be disposed of in accordance with local regulations.

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures


Personal precautions : Refer to protective measures listed in sections 7 and 8.
Evacuate personnel to safe areas.
Use personal protective equipment.
Ensure adequate ventilation.

Inform the responsible authorities in case of gas leakage, or of


entry into waterways, soil or drains.

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SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006

Z 15 LC distacc.cera liq
Version 9.0 SDB_GB Revision Date 25.11.2020 Print Date 25.11.2020

6.2 Environmental precautions


Environmental precautions : Do not allow uncontrolled discharge of product into the
environment.
Try to prevent the material from entering drains or water
courses.

Local authorities should be advised if significant spillages


cannot be contained.

6.3 Methods and material for containment and cleaning up


Methods for cleaning up : Soak up with inert absorbent material (e.g. sand, silica gel,
acid binder, universal binder, sawdust).
Contain spillage, and then collect with non-combustible
absorbent material, (e.g. sand, earth, diatomaceous earth,
vermiculite) and place in container for disposal according to
local / national regulations (see section 13).

Pick up and transfer to properly labelled containers.

6.4 Reference to other sections


For personal protection see section 8.

SECTION 7: Handling and storage

7.1 Precautions for safe handling


Advice on safe handling : Provide sufficient air exchange and/or exhaust in work rooms.

Avoid inhalation, ingestion and contact with skin and eyes.

Wear personal protective equipment.

Advice on protection against : Keep away from open flames, hot surfaces and sources of
fire and explosion ignition.

Hygiene measures : Provide adequate ventilation.

Wash hands and face before breaks and immediately after


handling the product.

7.2 Conditions for safe storage, including any incompatibilities


Requirements for storage : Keep containers tightly closed in a cool, well-ventilated place.
areas and containers Keep in properly labelled containers.

To maintain product quality, do not store in heat or direct


sunlight.

Advice on common storage : Keep product and empty container away from heat and
sources of ignition.

Keep away from food and drink.

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SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006

Z 15 LC distacc.cera liq
Version 9.0 SDB_GB Revision Date 25.11.2020 Print Date 25.11.2020

Other data : Stable at normal ambient temperature and pressure.

7.3 Specific end use(s)


Specific use(s) : Consult the technical guidelines for the use of this
substance/mixture.

SECTION 8: Exposure controls/personal protection

8.1 Control parameters


Contains no substances with occupational exposure limit values.
Derived No Effect Level (DNEL) according to Regulation (EC) No. 1907/2006:
Naphtha (petroleum), : End Use: Workers
hydrotreated light; Low boiling Exposure routes: Skin contact
point hydrogen treated Potential health effects: Long-term systemic effects
naphtha Value: 300 mg/kg
End Use: Workers
Exposure routes: Inhalation
Potential health effects: Long-term systemic effects
Value: 2085 mg/m3
End Use: Consumers
Exposure routes: Skin contact
Potential health effects: Long-term systemic effects
Value: 149 mg/kg
End Use: Consumers
Exposure routes: Inhalation
Potential health effects: Long-term systemic effects
Value: 447 mg/m3
End Use: Consumers
Exposure routes: Ingestion
Potential health effects: Long-term systemic effects
Value: 149 mg/kg
8.2 Exposure controls

Engineering measures
Effective exhaust ventilation system
effective ventilation in all processing areas
Personal protective equipment
Eye protection : Do not wear contact lenses.

Safety glasses with side-shields conforming to EN166

Ensure that eyewash stations and safety showers are close to


the workstation location.

Hand protection
Material : Protective gloves complying with EN 374.

Skin and body protection : Protective suit

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SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006

Z 15 LC distacc.cera liq
Version 9.0 SDB_GB Revision Date 25.11.2020 Print Date 25.11.2020

Respiratory protection : Use respiratory protection unless adequate local exhaust


ventilation is provided or exposure assessment demonstrates
that exposures are within recommended exposure guidelines.
In the case of vapour formation use a respirator with an
approved filter.
Equipment should conform to EN 14387

Apply technical measures to comply with the occupational


exposure limits.

Protective measures : Avoid contact with skin.

Wear suitable protective equipment.

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties


Appearance : liquid

Colour : off-white

Odour : characteristic

Odour Threshold : not determined

pH : 7, 1 %

Melting point/freezing point : Not applicable

Boiling point/boiling range : 90 °C

Flash point : -4 °C

Evaporation rate : not determined

Upper explosion limit : 7 %(V)

Lower explosion limit : 1 %(V)

Vapour pressure : 8 kPa (20 °C)

Relative vapour density : not determined

Density : 0,745 g/ml (25 °C)

Bulk density : not determined

Solubility(ies)
Solubility in other solvents : not determined
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SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006

Z 15 LC distacc.cera liq
Version 9.0 SDB_GB Revision Date 25.11.2020 Print Date 25.11.2020

Partition coefficient: n- : No data available


octanol/water

Ignition temperature : Not applicable

Auto-ignition temperature : > 200 °C

Thermal decomposition : Method: No data available

Viscosity
Viscosity, dynamic : 500 cPs (20 °C)

Viscosity, kinematic : not determined

Explosive properties : Not applicable

Oxidizing properties : Not applicable

9.2 Other information


Surface tension : not determined

Sublimation point : Not applicable

SECTION 10: Stability and reactivity

10.1 Reactivity
Stable under recommended storage conditions.
10.2 Chemical stability
No decomposition if stored and applied as directed.
10.3 Possibility of hazardous reactions
Hazardous reactions : No dangerous reaction known under conditions of normal use.

10.4 Conditions to avoid


Conditions to avoid : No decomposition if used as directed.

10.5 Incompatible materials


Materials to avoid : Incompatible with oxidizing agents.

10.6 Hazardous decomposition products


Hazardous decomposition : Stable under normal conditions.
products

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SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006

Z 15 LC distacc.cera liq
Version 9.0 SDB_GB Revision Date 25.11.2020 Print Date 25.11.2020

SECTION 11: Toxicological information

11.1 Information on toxicological effects

Acute toxicity

Product:
Acute oral toxicity : Remarks: No data available

Acute inhalation toxicity : Remarks: No data available

Acute dermal toxicity : Remarks: No data available

Acute toxicity (other routes of :


administration) Remarks: No data available

Skin corrosion/irritation

Product:
Remarks: No data available

Serious eye damage/eye irritation

Product:
Remarks: No data available

Respiratory or skin sensitisation

Product:
Remarks: No data available

Germ cell mutagenicity

Carcinogenicity

Product:
Remarks: No data available

Reproductive toxicity

Product:
Effects on fertility : Remarks: No data available

Remarks: No data available

Effects on foetal : Remarks: No data available


development Remarks: No data available

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SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006

Z 15 LC distacc.cera liq
Version 9.0 SDB_GB Revision Date 25.11.2020 Print Date 25.11.2020

STOT - single exposure

Product:
Remarks: Not applicable

STOT - repeated exposure

Repeated dose toxicity

Product:
Remarks: No data available

Aspiration toxicity

Further information

Product:
Remarks: No data available

SECTION 12: Ecological information

12.1 Toxicity

Product:
Toxicity to fish : Remarks: No data available

Toxicity to daphnia and other : Remarks: No data available


aquatic invertebrates

12.2 Persistence and degradability

Product:
Biodegradability : Remarks: No data available

Physico-chemical : Remarks: No data available


removability

12.3 Bioaccumulative potential

Product:
Bioaccumulation : Remarks: No data available

12.4 Mobility in soil


No data available
12.5 Results of PBT and vPvB assessment

Product:
Assessment : This substance/mixture contains no components considered
to be either persistent, bioaccumulative and toxic (PBT), or
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SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006

Z 15 LC distacc.cera liq
Version 9.0 SDB_GB Revision Date 25.11.2020 Print Date 25.11.2020

very persistent and very bioaccumulative (vPvB) at levels of


0.1% or higher..

12.6 Other adverse effects

Product:
Additional ecological : Remarks: An environmental hazard cannot be excluded in the
information event of unprofessional handling or disposal.

SECTION 13: Disposal considerations

13.1 Waste treatment methods


Product : In accordance with local and national regulations.

Container hazardous when empty.

Do not dispose of with domestic refuse.

Do not mix waste streams during collection.

Contaminated packaging : Empty containers should be taken to local recyclers for


disposal.

SECTION 14: Transport information

14.1 UN number

ADR/RID/ADN : UN 1993
IMDG : UN 1993
IATA : UN 1993
14.2 UN proper shipping name

ADR/RID/ADN : FLAMMABLE LIQUID, N.O.S.


(Hydrocarbons, C7, n-alkanes, isoalkanes, cyclics)
IMDG : FLAMMABLE LIQUID, N.O.S.
(Hydrocarbons, C7, n-alkanes, isoalkanes, cyclics)
IATA : Flammable liquid, n.o.s.
(Hydrocarbons, C7, n-alkanes, isoalkanes, cyclics)
14.3 Transport hazard class(es)

ADR/RID/ADN : 3
IMDG : 3
IATA : 3
14.4 Packing group

ADR/RID/ADN
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SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006

Z 15 LC distacc.cera liq
Version 9.0 SDB_GB Revision Date 25.11.2020 Print Date 25.11.2020

Packing group : II
Classification Code : F1
Hazard Identification Number : 33
Labels : 3
Tunnel restriction code : D/E
Remarks :
IMDG
Packing group : II
Labels : 3
EmS Code : F-E, S-E
Remarks : IMDG Code segregation group - none
IATA
Packing instruction (cargo : 364
aircraft)
Packing instruction : 353
(passenger aircraft)
Packing group : II
Labels : 3
14.5 Environmental hazards

ADR/RID/ADN
Environmentally hazardous : yes
IMDG
Marine pollutant : yes
IATA
Environmentally hazardous : yes
14.6 Special precautions for user
Remarks : The transport of dangerous goods, including their loading and
unloading, must be done by people who received the
necessary training required by Modal Regulations.

14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable for product as supplied.

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
REACH - Restrictions on the manufacture, placing on : Naphtha (petroleum), hydrotreated
the market and use of certain dangerous substances, light; Low boiling point hydrogen
preparations and articles (Annex XVII) treated naphtha
Number on list: 28

REACH - Candidate List of Substances of Very High : This product does not contain
Concern for Authorisation (Article 59). substances of very high concern
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SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006

Z 15 LC distacc.cera liq
Version 9.0 SDB_GB Revision Date 25.11.2020 Print Date 25.11.2020

(Regulation (EC) No
1907/2006 (REACH), Article 57).

REACH - List of substances subject to authorisation : Not applicable


(Annex XIV)

Regulation (EC) No 649/2012 of the European : Not applicable


Parliament and the Council concerning the export and
import of dangerous chemicals

Seveso III: Directive 2012/18/EU of the European Parliament and of the Council on the control of
major-accident hazards involving dangerous substances.
Quantity 1 Quantity 2
E2 ENVIRONMENTAL 200 t 500 t
HAZARDS

P5c FLAMMABLE LIQUIDS 5.000 t 50.000 t

34 Petroleum products: (a) 2.500 t 25.000 t


gasolines and naphthas,
(b) kerosenes (including jet
fuels), (c) gas oils
(including diesel fuels,
home heating oils and gas
oil blending streams),(d)
heavy fuel oils

15.2 Chemical safety assessment


Not applicable

SECTION 16: Other information

Full text of H-Statements


H225 : Highly flammable liquid and vapour.
H304 : May be fatal if swallowed and enters airways.
H315 : Causes skin irritation.
H336 : May cause drowsiness or dizziness.
H411 : Toxic to aquatic life with long lasting effects.
Full text of other abbreviations
Aquatic Chronic : Long-term (chronic) aquatic hazard
Asp. Tox. : Aspiration hazard
Flam. Liq. : Flammable liquids
Skin Irrit. : Skin irritation
STOT SE : Specific target organ toxicity - single exposure
Further information
Training advice : Provide adequate information, instruction and training for
operators.

The information provided in this Safety Data Sheet is correct to the best of our knowledge,
information and belief at the date of its publication. The information given is designed only as a
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SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006

Z 15 LC distacc.cera liq
Version 9.0 SDB_GB Revision Date 25.11.2020 Print Date 25.11.2020

guidance for safe handling, use, processing, storage, transportation, disposal and release and is
not to be considered a warranty or quality specification.

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