Understanding Alkalinity RGFINAL
Understanding Alkalinity RGFINAL
Understanding Alkalinity RGFINAL
1 - THE BASICS
1.1 - The Problem
The body is remarkably adept at maintaining a blood pH between 7.35 and 7.45. Just as blood pH operates
within a certain range, so do other cell structures throughout the body, depending on what kind they are and to
which system they belong. This cellular pH can affect both the structure and chemical reactivity of cellular
molecules.
Water is the universal solvent for all life and its chemical properties affect how cells work. Beyond this,
water’s self-ionization plays a role in providing the hydrogen protons needed for certain cellular processes.
Even though the dissociation constant of water is incredibly small, its importance is very large because of the
reactive nature of hydrogen protons in biological systems. Hydrogen protons have profound effects on
metabolism and other cell processes disproportionate to their relatively small number resulting from water’s
self-ionization.
The body has a series of natural buffers which help the blood and cells resist changes in pH. These include
hemoglobin in the red blood cells, plasma proteins, the bicarbonate buffer, and the phosphate buffer. But
buffering does not eliminate acidity, rather it merely neutralizes it with an opposite charge. Neutralization
through buffering and neutralization through elimination are not the same. For this reason, these natural buffers
are able to maintain the pH level but fail to remove the acidic overload (excess hydrogen protons) modern life
imposes on the body. They will keep the cell and blood pH within a set range but acidic conditions can still
affect the body even within these ranges. Stressors come both from without and within the body. What we do
as individuals, or more accurately what we consume, plays an enormous role in how the body can withstand
both the pressures from outside as well as inside the body. Acidity (excess hydrogen protons) leads to
inflammation which in turn can lead to many other health problems.
A water molecule consists of one oxygen atom and two hydrogen atoms held together by a covalent bond. A
covalent bond is a chemical bond in which atoms share electron pairs. The water molecule is also a polar
molecule with an electrical dipole moment. This means it has both a positive and a negative side or pole.
Water as a substance can form a large number of intermolecular hydrogen bonds, which results in the tendency
of water molecules to clump together. All of these factors lead to the strong attractive forces water exhibits and
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make water a good polar solvent. In fact, water is a universal solvent, meaning substances dissolve in water
(lose their chemical integrity) rather than water losing its chemical integrity. This, however, is just the
beginning.
Even pure water consists of more than just water molecules. Through a process called self-ionization, two
different ions are formed from water molecules. When one water molecule donates a hydrogen proton to
another water molecule two new ions are formed. The first is called hydroxide (OH-), a negative ion (anion)
that is formed by the water molecule that donates one of its hydrogen protons. The second is called hydronium
(H3O+), a positive ion (cation) that is formed by the second water molecule when it accepts the donated
hydrogen proton. The hydroxide then becomes a hydrogen proton acceptor because it wants to return to being a
water molecule and hydronium becomes a hydrogen proton donor for the same reason. These ions exist in very
small amounts in the overall aqueous solution and usually for short durations but they do play an important role
in water and in the biology of the body. These ions occur because water has an amphiprotic nature, meaning it
can act as both an acid and a base. This then is the power of water; it can transform itself to suit its environment
and always seeks to maintain an equilibrium between the positive and the negative.
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the limits of the Arrhenius theory, a new theory emerged put forth separately by two different individuals and
became known as the Brønsted-Lowry theory, named for both of them. The Brønsted-Lowry theory holds that:
Acids are proton donors.
Bases are proton acceptors.
The proton in question is the hydrogen proton (hydrogen ion). Acids have at least one hydrogen proton that
they easily transfer to another substance through a process called deprotonation. Furthermore, since bases are
proton acceptors, they are in fact acceptors of hydrogen protons and this is called protonation. This concept of
hydrogen proton donation and acceptance is fundamental to understanding how alkaline waters work.
The Arrhenius theory gives us the foundation of hydrogen ions and hydroxide ions and the Brønsted-Lowry
theory gives us the concept of hydrogen proton transfer. With these theories as our basis, we can now discuss
the fundamental chemistry behind base aqueous solutions, aka alkaline waters, and acidic aqueous solutions.
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the calcium ions and hydroxide ions freely floating in the solution. So for every two free hydroxide ions there
is one corresponding calcium ion and one corresponding calcium hydroxide molecule.
Magnesium hydroxide, on the other hand, is even weaker because it has low solubility and does not dissociate
very well. Even though this is true, magnesium hydroxide is still used as a common component of antacids
because even with its weaker properties it is still effective.
Potassium hydroxide, sodium hydroxide, calcium hydroxide, and magnesium hydroxide are all strong bases
with strong alkalinity in an aqueous solution. Magnesium hydroxide is by far the weakest of the four because of
its solubility and dissociation issues. The other three each produce effective levels of free hydroxides in an
aqueous solution.
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2 - THE BATTLE
2.1 - Overview
How does the knowledge set forth above apply in the real world? What is the best way to arm the body to
handle the acidic load modern life produces both from without and within?
First let’s define exactly what the enemy is, so that we can then figure out how to defeat it. It is clear that since
hydronium is the most acidic species that can exist in an aqueous solution and that the body is by its very nature
an aqueous environment, hydronium necessarily becomes the most important acid to combat in the body. Other
acids may be present but they naturally convert to hydronium through dissociation. Excess hydrogen protons in
the form of hydronium is the real problem. The extra hydrogen proton in hydronium is still highly reactive and
like all acids, hydronium will donate it to another atom or molecule freely under the right circumstances. This
is what makes hydronium so potentially harmful to the human body. First, because hydronium ties up free
water molecules it changes the hydration parameters of the body. Second, although the hydrogen proton may
be attached to a water molecule, it is basically free to act as if it is a free ion since acids by definition are proton
donors. This potential reactivity of the extra hydrogen proton can be combatted by neutralization.
2.2 - Neutralization
As noted earlier, alkalinity is a measure of the quantitative ability of a base to neutralize an acid. There are two
basic methods of neutralization, buffering through addition of alkaline substances and elimination through
transformation. The most common method of neutralization is the addition of an alkaline substance that
provides a negative charge to counter the positive charge of the hydrogen proton. This is the basis of most of
the buffering systems found in the body. This is also the basis of most alkaline waters. In alkaline waters this is
accomplished by the addition of alkaline minerals, trace minerals, or electrolytes. But the addition of an
alkaline substance does not remove the acidity, rather it merely counters it with an opposite charge. In this case
the aqueous solution becomes pH neutral but the troublesome hydrogen proton in the form of hydronium still
remains.
The other form of neutralization is elimination by transformation. When hydroxide ions come into contact with
hydrogen protons they combine and form new water molecules. Here is the basic formula:
OH- + H+ → H2O
This transformation of the hydrogen proton and hydroxide ion into a new water molecule neutralizes the acid
because a water molecule is neutral. Further it removes the hydrogen proton from the aqueous solution and in
fact increases the aqueous solution. The next section will look more closely at the role of hydroxide as an acid
fighter.
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According to the Arrhenius theory, the hydroxide ion readily combines with the hydrogen proton to form water
and thus neutralize the acidic nature of the hydrogen proton. Arrhenius goes further and states that hydrogen
protons freely dissociate from their acids in aqueous solutions much like the hydroxide ions from potassium
hydroxide, sodium hydroxide, and calcium hydroxide do. At this point it is important to reiterate that the
hydrogen proton does not actually exist as a free species in an aqueous solution but combines with a water
molecule to form hydronium. So in reality a hydroxide ion combines with a hydronium ion to form two new
water molecules. The chemical equation is this:
OH- + H3O+ → H2O + H2O
Furthermore, the hydroxide ion itself has a low solubility and therefore does not break apart easily. By its very
nature as part of the water molecule structure, it has an inherent drive to return to its natural state as a water
molecule. This then is the power of the hydroxide ion.
These facts lead to a very simple question, how do you supply the most possible free hydroxide ions in an
alkaline water? Several factors play into answering this question. As noted, both potassium hydroxide and
sodium hydroxide are monovalent which means they have one hydroxide ion for every mineral ion. Calcium
hydroxide and magnesium hydroxide, on the other hand, are divalent so they have two hydroxide ions for every
mineral ion. The simple math would support the idea then that the calcium and magnesium hydroxides must
provide more free hydroxide ions but this is misleading. As noted, magnesium hydroxide has a very low
solubility, so it does not produce many free hydroxide ions. Calcium hydroxide is relatively soluble except
when in the presence of potassium hydroxide or sodium hydroxide, then its solubility decreases rapidly. This
means if an alkaline water is using many different minerals in its ionization process to create its hydroxide, the
potassium and sodium hydroxides would produce the highest degree of free hydroxide ions and the calcium
hydroxide would be inhibited from doing so. It also means more minerals are necessary because of their
monovalent properties.
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protons. Although they all uniformly use the term hydrogen proton, as noted earlier, a free hydrogen proton
will immediately attach to any molecule with which it can share an electron. Since other water molecules are
within reach, the newly freed hydrogen proton will protonate one of these water molecules and form the
hydronium ion. This electro-magnetism is applied in the presence of minerals, most notably sodium, potassium,
calcium, and magnesium among others. The mineral hydroxide rich water produced in this process is the
alkaline water product and the acid rich hydrogen (hydronium) water is discarded or used for other purposes.
This basic method for producing negative ions is used by both ready to drink alkaline waters and alkaline water
machines for home use.
Since this is the way most of the industry creates negative ions (hydroxide), is this the only way to do it? The
short answer is no. In most alkaline waters, the free hydroxide ions available are limited by the amount of
minerals present because of the reasons noted in section 2.3. But does this always have to be the case? The
simple answer is no.
3 – A DIFFERENT METHOD
3.1 – Hydroxide Rich Water Approach
As noted in section 2.2, most alkaline waters use the addition of alkaline minerals, trace minerals, or
electrolytes as the basis of their alkalinity and therefore their approach to combatting acidity. This means
buffering rather than elimination is the main method of neutralization. To bolster the buffering capabilities of
these minerals, most alkaline waters also undergo ionization as discussed in section 2.4. This forms hydroxide
which is necessarily limited by this method of production. Because most alkaline waters see addition of
minerals as the most important tool and hydroxide as only a secondary tool, their ability to take advantage of the
acid eliminating potential of hydroxide is limited.
A far better approach is to seek to increase the amount of free hydroxide ions available because these neutralize
excess acid by elimination rather than just buffering as demonstrated in section 2.3. The best way to increase
free hydroxide ions is to add hydroxide from natural sources to the water rather than creating them through
electromagnetically induced ionization. Sodium hydroxide, potassium hydroxide, and calcium hydroxide are the
best candidates to provide the most free hydroxide ions in an aqueous solution. Historically, sodium hydroxide
and potassium hydroxide were both produced by combining calcium hydroxide with either sodium carbonate
(soda ash) or potassium carbonate (potash), respectively. Today they are manufactured through easier, cheaper
processes. Calcium hydroxide, on the other hand, is still created from calcium carbonate (limestone) through
the introduction of heat and then water. All three of these are good sources of free hydroxide ions but each has
different strengths and weaknesses.
As noted in section 1.4, both sodium hydroxide and potassium hydroxide are monovalent. This means they
only have one hydroxide ion for each mineral ion. Calcium hydroxide, on the other hand, is divalent meaning it
has two hydroxide ions for each mineral ion. Calcium hydroxide, therefore, has the potential to have twice as
many hydroxide ions available for the same amount of mineral content as the other two.
Also noted in section 1.4, both sodium hydroxide and potassium hydroxide almost completely dissociate in an
aqueous solution which means the hydroxide ions and the minerals ions break apart almost completely.
Calcium hydroxide is relatively soluble so its ions do not break apart completely like the others do. Calcium
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hydroxide will break apart at a rate of about 50%. This means for every two free hydroxide ions there will be
one calcium ion and one calcium hydroxide molecule.
Any of these three when added to water will provide an abundance of free hydroxide ions. Each can also be
naturally processed to remove much of the mineral content while concentrating the free hydroxide ion content
through precipitation and other means. The water then becomes a hydroxide rich water rather than just an
alkaline water. Hydroxide rich water by its very nature is a far stronger acid fighter than alkaline waters that
rely chiefly on minerals for their alkalinity. Combatting acidity by transforming excess hydrogen protons back
into water molecules eliminates the acidity rather than just countering it by buffering. Elimination through
transformation reduces the acidic load while also providing hydration. This hydration can then be used by the
body or easily removed through normal channels.
4 – CONCLUSION
4.1 – The Source Matters
Most alkaline waters focus first and foremost on adding minerals to increase alkalinity. They then use
electromagnetically induced ionization to create negative ions, aka hydroxide. This process, by its very nature,
limits the amount of free hydroxide ions that can be produced and utilized. Adding naturally sourced mineral
hydroxides provides far more hydroxide ions than electromagnetically induced ionization can. Naturally
sourced mineral hydroxides also allow for the concentration of free hydroxide ions and the minimization of
mineral ions. By focusing on the hydroxide and not the minerals, it is possible to create a hydroxide rich water.
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Alkalinity based on hydroxide content is far more effective in combatting acidity than alkalinity based on
mineral content.
REFERENCES
● 1.1 Properties of Water
Source: http://www.anaesthesiamcq.com/FluidBook/fl1_1.php
Source: http://www.anaesthesiamcq.com/AcidBaseBook/ab2_6.php#261
Source: http://www.tiem.utk.edu/~gross/bioed/webmodules/phbuffers.html
● Arrhenius theory
Source: https://www.britannica.com/science/Arrhenius-theory
Source: Myers, Richard (2003). The Basics of Chemistry. Greenwood Publishing Group. pp. 157–161. ISBN 978-0-313-
31664-7.
Source: https://www.britannica.com/science/Bronsted-Lowry-theory
Source: Masterton, William; Hurley, Cecile; Neth, Edward (2011). Chemistry: Principles and Reactions. Cengage Learning.
p. 433. ISBN 1-133-38694-6.
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● Alkalinity Table (hydroxides and carbonates)
Source: http://www.aquatext.com/tables/alktables.htm
● Hydroxide
Source: https://en.wikipedia.org/wiki/Hydroxide
Source: Marx, D.; Chandra, A; Tuckerman, M.E. (2010). "Aqueous Basic Solutions: Hydroxide Solvation, Structural
Diffusion, and Comparison to the Hydrated Proton". Chem. Rev. 110 (4): 2174–2216.
● Calcium hydroxide
Source: https://en.wikipedia.org/wiki/Calcium_hydroxide
● Sodium hydroxide
Source: https://en.wikipedia.org/wiki/Sodium_hydroxide
● Potassium hydroxide
Source: https://en.wikipedia.org/wiki/Potassium_hydroxide
● Hydronium
Source: http://chemwiki.ucdavis.edu/Core/Physical_Chemistry/Acids_and_Bases/Aqueous_Solutions/
The_Hydronium_Ion
Source: https://en.wikipedia.org/wiki/Hydronium
Source: https://en.wikipedia.org/wiki/Acid%E2%80%93base_reaction
● Lactic Acid/Lactate
Source: http://www.unm.edu/~lkravitz/Article%20folder/lactate.html
Source: http://www.sport-fitness-advisor.com/lactic-acid.html
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