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Ideal Gas Equation Sheet

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Isaac Hanssen

This document outlines key formulae relating to pressure, volume, temperature and other properties for ideal gases undergoing various thermodynamic processes including isometric, isobaric, isothermal, isentropic and polytropic processes. It provides the equations of state, relationships between pressure, volume and temperature, expressions for changes in internal energy, heat and entropy, as well as specific heat capacities for different processes.

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Ideal Gas Equation Sheet

Uploaded by

Isaac Hanssen
71 views1 page
This document outlines key formulae relating to pressure, volume, temperature and other properties for ideal gases undergoing various thermodynamic processes including isometric, isobaric, isothermal, isentropic and polytropic processes. It provides the equations of state, relationships between pressure, volume and temperature, expressions for changes in internal energy, heat and entropy, as well as specific heat capacities for different processes.

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chem

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Ideal Gas Equation Sheet(3)

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This document outlines key formulae relating to pressure, volume, temperature and other properties for ideal gases undergoing various thermodynamic processes including isometric, isobaric, isothermal, isentropic and polytropic processes. It provides the equations of state, relationships between pressure, volume and temperature, expressions for changes in internal energy, heat and entropy, as well as specific heat capacities for different processes.

Copyright:

© All Rights Reserved
Download as PDF, TXT or read online from Scribd
Download as pdf or txt
71 views1 page

Ideal Gas Equation Sheet

Uploaded by

Isaac Hanssen
This document outlines key formulae relating to pressure, volume, temperature and other properties for ideal gases undergoing various thermodynamic processes including isometric, isobaric, isothermal, isentropic and polytropic processes. It provides the equations of state, relationships between pressure, volume and temperature, expressions for changes in internal energy, heat and entropy, as well as specific heat capacities for different processes.

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Engineering Thermodynamics ENSC3024: Ideal Gas Formulae

For constant mass systems undergoing internally reversible processes.

Process Isometric Isobaric Isothermal Isentropic Polytropic


➔ V=C p =C T=C S=C 𝑝𝑉 𝑛 = 𝐶
𝑝1 𝑉1 ϒ = 𝑝2 𝑉2 ϒ 𝑝1 𝑉1 𝑛 = 𝑝2 𝑉2 𝑛

𝑇2 𝑉1 ϒ−1 𝑇2 𝑉1 𝑛−1
p, V, T 𝑇2 𝑝2 𝑇2 𝑉2 =( ) =( )
= = 𝑝1 𝑉1 = 𝑝2 𝑉2 𝑇1 𝑉2 𝑇1 𝑉2
relations 𝑇1 𝑝1 𝑇1 𝑉1
𝑝2 (ϒ−1)⁄ϒ 𝑝2 (𝑛−1) ⁄𝑛
= ( ) = ( )
𝑝1 𝑝1
2 𝑉2 𝑝2 𝑉2 − 𝑝1 𝑉1 𝑝2 𝑉2 − 𝑝1 𝑉1
− ∫ 𝑝𝑑𝑉 0 𝑝(𝑉2 − 𝑉1 ) 𝑝1 𝑉1 ln ( )
1 𝑉1 1−ϒ 1−𝑛

2 𝑉2 ϒ(𝑝2 𝑉2 − 𝑝1 𝑉1 ) 𝑛(𝑝2 𝑉2 − 𝑝1 𝑉1 )
− ∫ 𝑉𝑑𝑝 𝑉(𝑝1 − 𝑝2 ) 0 𝑝1 𝑉1 ln ( )
1 𝑉1 1−ϒ 1−𝑛

𝑚 ∫ 𝑐𝑣 𝑑𝑇 𝑚 ∫ 𝑐𝑣 𝑑𝑇 𝑚 ∫ 𝑐𝑣 𝑑𝑇 𝑚 ∫ 𝑐𝑣 𝑑𝑇
𝑈2 − 𝑈1 0
𝑚𝑐𝑣 (𝑇2 − 𝑇1 ) 𝑚𝑐𝑣 (𝑇2 − 𝑇1 ) 𝑚𝑐𝑣 (𝑇2 − 𝑇1 ) 𝑚𝑐𝑣 (𝑇2 − 𝑇1 )

𝑚 ∫ 𝑐𝑣 𝑑𝑇 𝑚 ∫ 𝑐𝑝 𝑑𝑇 𝑚 ∫ 𝑇 𝑑𝑠 𝑚 ∫ 𝑐𝑛 𝑑𝑇
Q 𝑉2 0
𝑚𝑐𝑣 (𝑇2 − 𝑇1 ) 𝑚𝑐𝑝 (𝑇2 − 𝑇1 ) 𝑚𝑐𝑛 (𝑇2 − 𝑇1 )
𝑝1 𝑉1 ln ( )
𝑉1
Index, n ∞ 0 1 ϒ -∞ to ∞

ϒ−1
Specific 𝑐𝑛 = 𝑐𝑣 ( )
𝑐𝑣 𝑐𝑝 ∞ 0 1−𝑛
heat, c
[ϒ = C]

𝑚 ∫ 𝑐𝑝 𝑑𝑇
𝑚 ∫ 𝑐𝑝 𝑑𝑇 𝑚 ∫ 𝑐𝑝 𝑑𝑇 𝑚 ∫ 𝑐𝑝 𝑑𝑇
𝐻2 − 𝐻1 0
𝑚𝐶𝑝 (𝑇2 − 𝑇1 )
𝑚𝐶𝑝 (𝑇2 − 𝑇1 ) 𝑚𝑐𝑝 (𝑇2 − 𝑇1 ) 𝑚𝑐𝑝 (𝑇2 − 𝑇1 )
𝑐𝑣 𝑑𝑇 𝑐𝑛 𝑑𝑇
𝑚∫ 𝑐𝑝 𝑑𝑇 𝑄 𝑚∫
𝑇 𝑚∫ 𝑇
𝑇2 𝑇 𝑇 𝑇2
𝑇2 𝑉2 0
𝑚𝑐𝑣 ln ( ) 𝑚𝑐𝑛 ln ( )
𝑆2 − 𝑆1 𝑇1 𝑚𝑐𝑝 ln ( ) 𝑚𝑅 ln ( ) 𝑇1
𝑇1 𝑉1
𝑝2 𝑉2 𝑐𝑣 𝑑𝑇 𝑉2 𝑐𝑝 𝑑𝑇 𝑝2
𝑚𝑐𝑣 ln ( ) + 𝑚𝑐𝑝 ln ( ) ; 𝑚 ∫ + 𝑚𝑅 ln ( ) ; 𝑚 ∫ − 𝑚𝑅 ln ( )
𝑝1 𝑉1 𝑇 𝑉1 𝑇 𝑝1

Data for Air


𝑐𝑝 = 1.005 𝐾𝐽⁄𝑘𝑔𝐾, 𝑐𝑣 = 0.72 𝐾𝐽⁄𝑘𝑔𝐾, ϒ = 1.4, R = 0.287 𝐾𝐽⁄𝑘𝑔𝐾

Compiled by lcs, modified by ks and acrt

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