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    CHEMISTRY 12th Subejctive

    Uploaded by

    Vivek Sanwal
    1. The document discusses concepts related to reaction order and rate constants in chemistry. It provides example problems to determine the order of reactions based on changes in concentration or time. 2. Key points covered include how reaction order is determined experimentally, how rate constants have different units depending on reaction order (e.g. zero order is s-1), and using rate laws and rate constants to calculate time for a given fraction of reactants to react. 3. Example problems calculate half-lives, reaction rates when concentrations change, order based on how rate changes with concentration, and matching reaction orders to graph shapes showing changes in concentration over time.

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    CHEMISTRY 12th Subejctive

    Uploaded by

    Vivek Sanwal
    14 views3 pages
    1. The document discusses concepts related to reaction order and rate constants in chemistry. It provides example problems to determine the order of reactions based on changes in concentration or time. 2. Key points covered include how reaction order is determined experimentally, how rate constants have different units depending on reaction order (e.g. zero order is s-1), and using rate laws and rate constants to calculate time for a given fraction of reactants to react. 3. Example problems calculate half-lives, reaction rates when concentrations change, order based on how rate changes with concentration, and matching reaction orders to graph shapes showing changes in concentration over time.

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    CHEMISTRY 12th subejctive

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    1. The document discusses concepts related to reaction order and rate constants in chemistry. It provides example problems to determine the order of reactions based on changes in concentration or time. 2. Key points covered include how reaction order is determined experimentally, how rate constants have different units depending on reaction order (e.g. zero order is s-1), and using rate laws and rate constants to calculate time for a given fraction of reactants to react. 3. Example problems calculate half-lives, reaction rates when concentrations change, order based on how rate changes with concentration, and matching reaction orders to graph shapes showing changes in concentration over time.

    Copyright:

    © All Rights Reserved
    Download as DOCX, PDF, TXT or read online from Scribd
    Download as docx, pdf, or txt
    14 views3 pages

    CHEMISTRY 12th Subejctive

    Uploaded by

    Vivek Sanwal
    1. The document discusses concepts related to reaction order and rate constants in chemistry. It provides example problems to determine the order of reactions based on changes in concentration or time. 2. Key points covered include how reaction order is determined experimentally, how rate constants have different units depending on reaction order (e.g. zero order is s-1), and using rate laws and rate constants to calculate time for a given fraction of reactants to react. 3. Example problems calculate half-lives, reaction rates when concentrations change, order based on how rate changes with concentration, and matching reaction orders to graph shapes showing changes in concentration over time.

    Copyright:

    © All Rights Reserved
    Download as DOCX, PDF, TXT or read online from Scribd
    Download as docx, pdf, or txt
    of 3

    CHEMISTRY

    1. Which of the following observations is incorrect about the order of a reaction?

    a. Order of a reaction is always a whole number


    b. The stoichiometric coefficient of the reactants doesn’t affect the order
    c. Order of reaction is the sum of power to express the rate of reaction to the concentration terms of the
    reactants.
    d. Order can only be assessed experimentally
    2. The rate constant of zero-order reactions has the unit

    a. s-1
    b. mol L-1 s-1
    c. L2 mol-2 s-1
    d. L mol-1 s-1
    3. A substance ‘A’ decomposes by a first-order reaction starting initially with [A] = 2.00M and after
    200min, [A] becomes 0.15M. For this reaction t1/2 is

    a. 53.72 min
    b. 50.49 min
    c. 48.45 min
    d. 46.45 min
    4. In the reaction 2A + B → A2B, if the concentration of A is doubled and that of B is halved, then the
    rate of the reaction will

    a. increase 2 times
    b. increase 4 times
    c. decrease 2 times
    d. remain the same
    5. The rate constant of a reaction is k=3.28 × 10-4 s-1. Find the order of the reaction.
    a) Zero order
    b) First order
    c) Second order
    d) Third order
    6. In a reaction, if the concentration of reactant A is tripled, the rate of reaction becomes twenty-seven
    times. What is the order of the reaction?

    7. How can you determine the rate law of the following reaction?

    2NO(g) + O₂(g) → 2NO₂ (g)

    8. Express the rate of the following reaction in terms of the formation of ammonia :
    N2(g) + 3H2(g) → 2NH3(g)

    9. Explain the difference between the instantaneous rate of a reaction and average rate of a reaction.

    10. For a general reaction A ⎯→ B, the plot of concentration of A vs time is given in Fig. Answer the
    following question on the basis of graph.

    (a) What is the order of the reaction ?


    (b) What is the slope of the curve?

    (c) What is the unit of the rate constant?

    11. Match the graph given in Column I with the order of reaction given in Column II. More than one item
    in Column I may link to the same item in Column II.

    Column I Column II

    (a) (i) 1st order

    (b) (ii) Zero order

    (c)

    (d)

    12. The rate constant for a reaction of zero order in A is 0.0030 mol L -1 s-1. How long will it take for the
    initial concentration of A to fall from 0.10 M to 0.075 M?

    OR

    The thermal decomposition of HCO2H is a first order reaction with a rate constant of 2.4 × 10 -3 s-1 at a
    certain temperature. Calculate how long will it take for three-fourths of initial quantity of HCO 2 H to
    decompose. (log 0.25 = -0.6021).

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