SAFETY DATA SHEET

1. Identification
Product identifier GREENLITE-45-L PLUS
Other means of identification
Brand Code 5469, 062A
Recommended use For Industrial Use Only
Recommended restrictions Users should be informed of the potential presence of respirable dust and respirable crystalline
silica as well as their potential hazards. Appropriate training in the proper use and handling of this
material should be provided as required under applicable regulations.
Manufacturer/Importer/Supplier/Distributor information
Manufacturer
Company name HarbisonWalker International
Address 1305 Cherrington Parkway, Suite 100
Moon Township, Pennsylvania 15108 US
Telephone General Phone: 412-375-6600
Website www.thinkHWI.com
Emergency phone number CHEMTREC 24 HOUR 1-800-424-9300
EMERGENCY #

2. Hazard(s) identification
Physical hazards Not classified.
Health hazards Carcinogenicity Category 1A
Specific target organ toxicity, repeated Category 1
exposure
Environmental hazards Not classified.
OSHA defined hazards Not classified.

Label elements

Signal word Danger

Hazard statement May cause cancer. Causes damage to organs through prolonged or repeated exposure.
Precautionary statement
Prevention Obtain special instructions before use. Do not handle until all safety precautions have been read
and understood. Do not breathe dust/fume/gas/mist/vapors/spray. Wash thoroughly after
handling. Do not eat, drink or smoke when using this product. Wear protective gloves/protective
clothing/eye protection/face protection.
Response If exposed or concerned: Get medical advice/attention.
Storage Store in a manner to minimize airborne dust.
Disposal Dispose of contents/container in accordance with local/regional/national/international regulations.
Hazard(s) not otherwise None known.
classified (HNOC)
Supplemental information Crystalline silica may be present at low concentrations; most of this is encapsulated in the coarse
aggregate or as part of the clays or sands.

3. Composition/information on ingredients
Mixtures
Chemical name Common name and synonyms CAS number %
Mullite 1302-93-8 20 - 40

Material name: GREENLITE-45-L PLUS SDS US

5469, 062A Version #: 01 Issue date: 08-14-2018 1/7

 Chemical name Common name and synonyms CAS number %
Amorphous Silica SILICA, AMORPHOUS, FUMED 7631-86-9 2.5 - 10
SILICA (CRYSTALLINE FREE)
Cristobalite 14464-46-1 2.5 - 10
Quartz (SiO2) 14808-60-7 2.5 - 10
Fumes, Silica 69012-64-2 1 - 2.5
Titanium Dioxide 13463-67-7 0.1 - 1
Other components below reportable levels 40 - 60
Crystalline silica may be present at low concentrations; most of this is encapsulated in the coarse aggregate or as part of the clays or
sands.

4. First-aid measures
Inhalation Move to fresh air. Call a physician if symptoms develop or persist.
Skin contact Wash off with soap and water. Get medical attention if irritation develops and persists.
Eye contact Rinse with water. Get medical attention if irritation develops and persists.
Ingestion Rinse mouth. Get medical attention if symptoms occur.
Most important Prolonged exposure may cause chronic effects.
symptoms/effects, acute and
delayed
Indication of immediate Provide general supportive measures and treat symptomatically. Keep victim under observation.
medical attention and special Symptoms may be delayed.
treatment needed
General information IF exposed or concerned: Get medical advice/attention. If you feel unwell, seek medical advice
(show the label where possible). Ensure that medical personnel are aware of the material(s)
involved, and take precautions to protect themselves.

5. Fire-fighting measures
Suitable extinguishing media Use fire-extinguishing media appropriate for surrounding materials.
Unsuitable extinguishing Not available.
media
Specific hazards arising from Not applicable.
the chemical
Special protective equipment Not available.
and precautions for firefighters

6. Accidental release measures

Personal precautions, Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Wear
protective equipment and appropriate protective equipment and clothing during clean-up. Ensure adequate ventilation. Local
emergency procedures authorities should be advised if significant spillages cannot be contained. For personal protection,
see section 8 of the SDS.
Methods and materials for Stop the flow of material, if this is without risk. Following product recovery, flush area with water.
containment and cleaning up Put material in suitable, covered, labeled containers. For waste disposal, see section 13 of the
SDS.
Environmental precautions Avoid discharge into drains, water courses or onto the ground.

7. Handling and storage

Precautions for safe handling Do not handle until all safety precautions have been read and understood. Keep formation of
airborne dusts to a minimum. Provide appropriate exhaust ventilation at places where dust is
formed. Do not breathe dust. Avoid prolonged exposure. When using, do not eat, drink or smoke.
Should be handled in closed systems, if possible. Wear appropriate personal protective
equipment. Wash hands thoroughly after handling. Observe good industrial hygiene practices.
Conditions for safe storage, Store in original tightly closed container. Store away from incompatible materials (see Section 10
including any incompatibilities of the SDS).

8. Exposure controls/personal protection

Occupational exposure limits
The following constituents are the only constituents of the product which have a PEL, TLV or other recommended exposure limit.
At this time, the other constituents have no known exposure limits.

Material name: GREENLITE-45-L PLUS SDS US

5469, 062A Version #: 01 Issue date: 08-14-2018 2/7

 US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)
Components Type Value Form

Cristobalite (CAS PEL 0.05 mg/m3

14464-46-1)
Quartz (SiO2) (CAS PEL 0.05 mg/m3
14808-60-7)
Titanium Dioxide (CAS PEL 15 mg/m3 Total dust.
13463-67-7)
US. OSHA Table Z-3 (29 CFR 1910.1000)
Components Type Value Form

Amorphous Silica (CAS TWA 0.8 mg/m3

7631-86-9)
20 mppcf
Cristobalite (CAS TWA 0.05 mg/m3 Respirable.
14464-46-1)
1.2 mppcf Respirable.
Fumes, Silica (CAS TWA 0.8 mg/m3
69012-64-2)
20 mppcf
Quartz (SiO2) (CAS TWA 0.1 mg/m3 Respirable.
14808-60-7)
2.4 mppcf Respirable.
Titanium Dioxide (CAS TWA 5 mg/m3 Respirable fraction.
13463-67-7)
15 mg/m3 Total dust.
50 mppcf Total dust.
15 mppcf Respirable fraction.
US. ACGIH Threshold Limit Values
Components Type Value Form

Cristobalite (CAS TWA 0.025 mg/m3 Respirable fraction.

14464-46-1)
Mullite (CAS 1302-93-8) TWA 1 mg/m3 Respirable fraction.
Quartz (SiO2) (CAS TWA 0.025 mg/m3 Respirable fraction.
14808-60-7)
Titanium Dioxide (CAS TWA 10 mg/m3
13463-67-7)
US. NIOSH: Pocket Guide to Chemical Hazards
Components Type Value Form

Amorphous Silica (CAS TWA 6 mg/m3

7631-86-9)
Fumes, Silica (CAS TWA 6 mg/m3
69012-64-2)
Quartz (SiO2) (CAS TWA 0.05 mg/m3 Respirable dust.
14808-60-7)
Biological limit values No biological exposure limits noted for the ingredient(s).
Exposure guidelines Occupational exposure to nuisance dust (total and respirable) and respirable crystalline silica
should be monitored and controlled. Occupational exposure to nuisance dust (total and respirable)
and respirable crystalline silica should be monitored and controlled.
Appropriate engineering Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates
controls should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation,
or other engineering controls to maintain airborne levels below recommended exposure limits. If
exposure limits have not been established, maintain airborne levels to an acceptable level.
Individual protection measures, such as personal protective equipment
Eye/face protection If contact is likely, safety glasses with side shields are recommended.

Skin protection
Hand protection Suitable gloves can be recommended by the glove supplier.
Other Use of an impervious apron is recommended.

Respiratory protection Use a NIOSH/MSHA approved respirator if there is a risk of exposure to dust/fume at levels
exceeding the exposure limits.
Thermal hazards Wear appropriate thermal protective clothing, when necessary.
Material name: GREENLITE-45-L PLUS SDS US

5469, 062A Version #: 01 Issue date: 08-14-2018 3/7

General hygiene Observe any medical surveillance requirements. Always observe good personal hygiene
considerations measures, such as washing after handling the material and before eating, drinking, and/or
smoking. Routinely wash work clothing and protective equipment to remove contaminants.

9. Physical and chemical properties

Appearance
Physical state Solid.
Form Solid.
Color Grey.
Odor Not available.
Odor threshold Not available.
pH Not available.
Melting point/freezing point Not available.
Initial boiling point and boiling Not available.
range
Flash point Not available.
Evaporation rate Not available.
Flammability (solid, gas) Not available.
Upper/lower flammability or explosive limits
Flammability limit - lower Not available.
(%)
Flammability limit - upper Not available.
(%)
Explosive limit - lower (%) Not available.
Explosive limit - upper (%) Not available.
Vapor pressure Not available.
Vapor density Not available.
Relative density Not available.
Solubility(ies)
Solubility (water) Not available.
Partition coefficient Not available.
(n-octanol/water)
Auto-ignition temperature Not available.
Decomposition temperature Not available.
Viscosity Not available.
Other information
Explosive properties Not explosive.
Oxidizing properties Not oxidizing.

10. Stability and reactivity

Reactivity The product is stable and non-reactive under normal conditions of use, storage and transport.
Chemical stability Material is stable under normal conditions.
Possibility of hazardous No dangerous reaction known under conditions of normal use.
reactions
Conditions to avoid Contact with incompatible materials.
Incompatible materials Powerful oxidizers. Chlorine.
Incompatibility is based strictly upon potential theoretical reactions between chemicals and may
not be specific to industrial application exposure.
Hazardous decomposition No hazardous decomposition products are known.
products
Material name: GREENLITE-45-L PLUS SDS US

5469, 062A Version #: 01 Issue date: 08-14-2018 4/7

11. Toxicological information
Information on likely routes of exposure
Inhalation Prolonged inhalation may be harmful.
Skin contact No adverse effects due to skin contact are expected.
Eye contact Direct contact with eyes may cause temporary irritation.
Ingestion Expected to be a low ingestion hazard.
Symptoms related to the Direct contact with eyes may cause temporary irritation.
physical, chemical and
toxicological characteristics
Information on toxicological effects
Acute toxicity Not known.
Skin corrosion/irritation Prolonged skin contact may cause temporary irritation.
Serious eye damage/eye Direct contact with eyes may cause temporary irritation.
irritation
Respiratory or skin sensitization
Respiratory sensitization Not a respiratory sensitizer.
Skin sensitization This product is not expected to cause skin sensitization.
Germ cell mutagenicity No data available to indicate product or any components present at greater than 0.1% are
mutagenic or genotoxic.
Carcinogenicity In 1997, IARC (the International Agency for Research on Cancer) concluded that crystalline silica
inhaled from occupational sources can cause lung cancer in humans. However in making the
overall evaluation, IARC noted that "carcinogenicity was not detected in all industrial
circumstances studied. Carcinogenicity may be dependent on inherent characteristics of the
crystalline silica or on external factors affecting its biological activity or distribution of its
polymorphs." (IARC Monographs on the evaluation of the carcinogenic risks of chemicals to
humans, Silica, silicates dust and organic fibres, 1997, Vol. 68, IARC, Lyon, France.) In June
2003, SCOEL (the EU Scientific Committee on Occupational Exposure Limits) concluded that the
main effect in humans of the inhalation of respirable crystalline silica dust is silicosis. "There is
sufficient information to conclude that the relative risk of lung cancer is increased in persons with
silicosis (and, apparently, not in employees without silicosis exposed to silica dust in quarries and
in the ceramic industry). Therefore, preventing the onset of silicosis will also reduce the cancer
risk..." (SCOEL SUM Doc 94-final, June 2003) According to the current state of the art, worker
protection against silicosis can be consistently assured by respecting the existing regulatory
occupational exposure limits. May cause cancer. Occupational exposure to respirable dust and
respirable crystalline silica should be monitored and controlled.
IARC Monographs. Overall Evaluation of Carcinogenicity
Amorphous Silica (CAS 7631-86-9) 3 Not classifiable as to carcinogenicity to humans.
Cristobalite (CAS 14464-46-1) 1 Carcinogenic to humans.
Fumes, Silica (CAS 69012-64-2) 3 Not classifiable as to carcinogenicity to humans.
Quartz (SiO2) (CAS 14808-60-7) 1 Carcinogenic to humans.
Titanium Dioxide (CAS 13463-67-7) 2B Possibly carcinogenic to humans.
US. National Toxicology Program (NTP) Report on Carcinogens
Cristobalite (CAS 14464-46-1) Known To Be Human Carcinogen.
Reasonably Anticipated to be a Human Carcinogen.
Quartz (SiO2) (CAS 14808-60-7) Known To Be Human Carcinogen.
US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not regulated.
Reproductive toxicity This product is not expected to cause reproductive or developmental effects.
Developmental effects
Quartz (SiO2) 0
Developmental effects - EU category
Quartz (SiO2) 0
Embryotoxicity
Quartz (SiO2) 0
Reproductivity
Quartz (SiO2) 0
Specific target organ toxicity - Not classified.
single exposure

Material name: GREENLITE-45-L PLUS SDS US

5469, 062A Version #: 01 Issue date: 08-14-2018 5/7

Specific target organ toxicity - Causes damage to organs through prolonged or repeated exposure.
repeated exposure
Aspiration hazard Not an aspiration hazard.
Chronic effects Causes damage to organs through prolonged or repeated exposure. Prolonged inhalation may be
harmful. Prolonged exposure may cause chronic effects.

12. Ecological information

Ecotoxicity The product is not classified as environmentally hazardous. However, this does not exclude the
possibility that large or frequent spills can have a harmful or damaging effect on the environment.
Persistence and degradability No data is available on the degradability of this product.
Bioaccumulative potential No data available.
Mobility in soil No data available.
Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation
potential, endocrine disruption, global warming potential) are expected from this component.

13. Disposal considerations

Disposal instructions This product, in its present state, when discarded or disposed of, is not a hazardous waste
according to Federal regulations (40 CFR 261.4 (b)(4)). Under RCRA, it is the responsibility of the
user of the product to determine, at the time of disposal, whether the product meets RCRA criteria
for hazardous waste.
Hazardous waste code Since this product is used in several industries, no Waste Code can be provided by the supplier.
The Waste Code should be determined in arrangement with your waste disposal partner or the
responsible authority.
Waste from residues / unused Not available.
products
Contaminated packaging Not available.

14. Transport information

DOT
Not regulated as dangerous goods.
IATA
Not regulated as dangerous goods.
IMDG
Not regulated as dangerous goods.
Transport in bulk according to Not applicable.
Annex II of MARPOL 73/78 and
the IBC Code

15. Regulatory information

US federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication
Standard, 29 CFR 1910.1200. All chemical substances in this product are listed on the TSCA
chemical substance inventory where required.
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
Not regulated.
CERCLA Hazardous Substance List (40 CFR 302.4)
Not listed.
SARA 304 Emergency release notification
Not regulated.
US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not regulated.
Superfund Amendments and Reauthorization Act of 1986 (SARA)
Hazard categories Immediate Hazard - No
Delayed Hazard - Yes
Fire Hazard - No
Pressure Hazard - No
Reactivity Hazard - No
SARA 302 Extremely hazardous substance
Not listed.

Material name: GREENLITE-45-L PLUS SDS US

5469, 062A Version #: 01 Issue date: 08-14-2018 6/7

 SARA 311/312 Hazardous No
chemical
SARA 313 (TRI reporting)
Not regulated.

Other federal regulations

Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Not regulated.
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Not regulated.
Safe Drinking Water Act Not regulated.
(SDWA)
US state regulations WARNING: This product contains a chemical known to the State of California to cause cancer.
US - California Proposition 65 - CRT: Listed date/Carcinogenic substance
Quartz (SiO2) (CAS 14808-60-7) Listed: October 1, 1988
Titanium Dioxide (CAS 13463-67-7) Listed: September 2, 2011
US. California. Candidate Chemicals List. Safer Consumer Products Regulations (Cal. Code Regs, tit. 22, 69502.3,
subd. (a))
Cristobalite (CAS 14464-46-1)
Quartz (SiO2) (CAS 14808-60-7)
Titanium Dioxide (CAS 13463-67-7)
International Inventories
Country(s) or region Inventory name On inventory (yes/no)*
Australia Australian Inventory of Chemical Substances (AICS) No
Canada Domestic Substances List (DSL) Yes
Canada Non-Domestic Substances List (NDSL) No
China Inventory of Existing Chemical Substances in China (IECSC) Yes
Europe European Inventory of Existing Commercial Chemical No
Substances (EINECS)
Europe European List of Notified Chemical Substances (ELINCS) No
Japan Inventory of Existing and New Chemical Substances (ENCS) No
Korea Existing Chemicals List (ECL) No
New Zealand New Zealand Inventory Yes
Philippines Philippine Inventory of Chemicals and Chemical Substances No
(PICCS)
United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory No
*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)
A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing
country(s).

16. Other information, including date of preparation or last revision

Issue date 08-14-2018
Version # 01
Disclaimer This information is based on our present knowledge on creation date. However, this shall not
constitute a guarantee for any specific product features and shall not establish a legally valid
contractual relationship.
Revision information Product and Company Identification: Product Codes

Material name: GREENLITE-45-L PLUS SDS US

5469, 062A Version #: 01 Issue date: 08-14-2018 7/7