MATERIAL SAFETY DATA SHEET

(USA)

(Complies with USA OSHA 29 CFR 1910.1200 and ANSI Z 400.1)

Version: 2 Revision date: 19 May 2009
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND THE COMPANY/UNDERTAKING

Product code: F110

Product name: EZEFLO* F110 Surfactant
Company identification: Schlumberger Technology Corporation
110 Schlumberger Drive
Sugar Land, Texas 77478, USA
Telephone: 1-281-285-7873

Emergency telephone number: USA: +1-281-595-3518 (24hr)

2. HAZARDS IDENTIFICATION

EMERGENCY OVERVIEW

DANGER

Main physical hazards: Flammable liquid.

Main health hazards: Causes eye irritation. Causes skin irritation. Contains methanol. Can be
fatal or cause blindness if swallowed. Cannot be made non-toxic. Toxic:
danger of very serious irreversible effects in contact with skin. May cause
Central Nervous System (CNS) depression.
Other hazards: Vapors may cause flash fire or explosion.
Precautions: Keep away from open flames, hot surfaces and sources of ignition. Avoid
contact with eyes. Do not get on skin or clothing. Wash thoroughly after
handling. Do not breathe vapors or spray mist.
HMIS classification: Health: 3 Flammability: 3 Physical hazard: 0

Form: Liquid Color: Clear colorless Odor: Alcohols

Principle routes of exposure:
Eye contact. Skin contact. Respiratory system.

3. COMPOSITION/INFORMATION ON INGREDIENTS

Component CAS-No Weight % - Range

Methanol 67-56-1 15-40
Ethoxylated alcohols Proprietary 10-30
Ethoxylated alcohols #2 Proprietary 10-30

4. FIRST AID MEASURES

Eye contact: Immediately flush eyes with water for 15 minutes while holding eyelids
open. Seek medical attention.

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Skin contact: Take off contaminated clothing and shoes immediately. After contact with
skin, wash immediately with plenty of soap and water for at least 15
minutes. Seek medical attention.
Ingestion: Do not induce vomiting without medical advice. Call a physician or Poison
Control Center immediately. Never give anything by mouth to an
unconscious person. If vomiting occurs spontaneously, minimize the risk of
aspiration by properly positioning the affected person.
Inhalation: Move to fresh air in case of accidental inhalation of vapors. Call a physician
or Poison Control Centre immediately. If breathing has stopped or heart has
stopped, trained personnel should immediately administer artificial
respiration or CPR, as required.

5. FIRE-FIGHTING MEASURES

Fire hazard: Flammable liquid.

OSHA Flammability Class: II
Flash point: 28 °C / 84 °F
Method: Pensky-Martens CC
Autoignition temperature: No data available.
Flammability limits in air:
Lower: 6.0% (methanol)
Upper: 36.5% (methanol)
Oxidizing properties: None.

Suitable extinguishing media:

Alcohol Foam, CO2, Dry Chemical.

Extinguishing media which must not be used for safety reasons:

None known.

Special exposure hazards arising from the substance or preparation itself, its combustion
products, or released gases:
Vapors are heavier than air and may spread along floors. Vapors may cause flash fire or explosion.

Other information:
Vapors are heavier than air and may spread along floors.

Special protective equipment for firefighters:

Wear self contained breathing apparatus for fire fighting if necessary. Wear protective fire fighting clothing
and avoid breathing vapors.

NFPA rating:
Health: 3
Flammability: 3
Instability: 0
Special: None

6. ACCIDENTAL RELEASE MEASURES

Main physical hazards: Flammable liquid.

Other hazards: Vapors may cause flash fire or explosion.
Personal precautions: Do not breathe vapors or spray mist. Keep away from heat, sparks, and
flame. Do not get on skin or clothing. Wash thoroughly after handling. Avoid
contact with eyes.

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Methods for cleaning up: Contain with dikes. Use explosion proof equipment to recover. Remove all
sources of ignition. Soak up residual on inert absorbant (sand). Put in steel
or plastic drum approved for flammables.
Environmental precautions: Prevent further leakage or spillage. Keep out of waterways.

7. HANDLING AND STORAGE

Handling:
Precautions: Keep away from open flames, hot surfaces and sources of ignition. Avoid
contact with eyes. Do not get on skin or clothing. Wash thoroughly after
handling. Do not breathe vapors or spray mist.
Safe handling advice: Keep airborne concentrations below exposure limits. Wear suitable
protective equipment.
Technical measures/ Keep away from heat, sparks, and flame. Store out of direct sunlight in well
storage conditions: ventilated area. Keep container closed when not in use. Use with adequate
ventilation.
Packaging requirements: Steel or high density polyethylene (HDPE) container approved for
flammables. To avoid ignition of vapors by static electricity discharge, all
metal parts of the equipment must be grounded.
Incompatible products: Oxidizing agents.

8. EXPOSURE CONTROLS / PERSONAL PROTECTION

Engineering measures Control the source. Enclosure of the process. Other suitable methods.
to reduce exposure:
Hygiene measures: Keep airborne concentrations below exposure limits. Avoid contact with
skin, eyes and clothing. Do not breathe vapors or spray mist. Wear suitable
protective equipment.
Respiratory protection: In case of insufficient ventilation, wear suitable respiratory equipment.
Eye protection: Tightly fitting safety goggles.
Hand protection: Impervious gloves. Butyl. Viton.
Skin and body protection: Chemical resistant suit. Chemical resistant boots.
Occupational Exposure Limits
ACGIH - TLVs OSHA - PELs
Com ponent TWA / Ceiling STEL ACGIH - Skin TWA / C STEL Final PELs
- Skin
Methanol 200 ppm 250 ppm Skin Notation 200 ppm TWA - -
260 mg/m3 TWA
Ethoxylated alcohols - - - - - -
Ethoxylated alcohols #2 - - - - - -

Particles Not Otherw ise Regulated/Specified [PNOR or PNOS] (insoluble or poorly soluble):
OSHA PEL's for Inert or Nuisance Dust are covered by PNOR limits: respirable fraction: 5 mg/m3; total dust 15 mg/m3.
ACGIH PNOS Recommendations: airborne concentrations should be kept below 3 mg/m3, respirable particulate, and 10 mg/m3,
inhalable particles.

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9. PHYSICAL AND CHEMICAL PROPERTIES

Chemical characterization: Mixture of organic compounds.

Fire hazard: Flammable liquid.
Form: Liquid
Color: Clear colorless
Odor: Alcohols
Odor threshold: No information available.
pH: 7
Boiling point/range: No data available.
Flash point: 28 °C / 84 °F
Method: Pensky-Martens CC.
Flammability limits in air:
Lower: 6.0% (methanol)
Upper: 36.5% (methanol)
Bulk density: Not applicable.
Melting point/range: No data available.
Decomposition temperature: > 232 °C / 450 °F
Solubility:
Water solubility: Dispersible.
Fat solubility: No information available.
Partition coefficient See also SECTION 12
(n-octanol/water):
Relative density: 0.9 (@ 20°C)
Vapor pressure: No data available.
Vapor density: > 1 (air = 1)
Viscosity: ~ 5 mPa.s
Evaporation rate: No data available.
% Volatile (VOC): 30

10. STABILITY AND REACTIVITY

Stability:
Stable under recommended storage conditions

Conditions to avoid:
Keep away from heat and sources of ignition.

Incompatibility with other substances:

Oxidizers.

Hazardous decomposition products:

When heated strongly or burned, oxides of carbon and harmful organic chemical fumes are released.

Hazardous polymerization:
Hazardous polymerization does not occur.

Other hazards:
Vapors may cause flash fire or explosion.

11. TOXICOLOGICAL INFORMATION

PRODUCT TOXICOLOGICAL INFORMATION

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Information given is based on data on the components and the toxicology of similar products.

Acute Health Hazard

Eye contact: Severe eye irritation. Causes pain and redness. Prolonged or repeated
contact may cause mild burn.
Skin contact: Severe skin irritation. Toxic: danger of very serious irreversible effects in
contact with skin. Substance may be absorbed through the skin which can
contribute to damage to the optic nerve resulting in permanent vision
changes , loss of vision, or total blindness. See COMPONENT
TOXICOLOGICAL INFORMATION below.
Ingestion: Contains methanol. Can be fatal or cause blindness. Cannot be made non-
toxic. May cause Central Nervous System (CNS) depression. Aspiration
hazard. Aspiration may cause pulmonary edema and pneumonitis.
Inhalation: Toxic; can cause illness or death. Toxic: danger of very serious irreversible
effects through inhalation. See COMPONENT TOXICOLOGICAL
INFORMATION below.
Sensitization - lung: Not known to cause allergic reaction.
Sensitization - skin: See COMPONENT TOXICOLOGICAL INFORMATION below.
Toxicologically synergistic None known.
products:
Other information: May cause headache, narcosis. May cause dizziness, nausea, vomiting,
diarrhea.

Chronic Health Hazard

Carcinogenic effects: None known.

Mutagenic effects: See COMPONENT TOXICOLOGICAL INFORMATION below.
Teratogenic effects: Possibly causes birth defects.
Reproductive toxicity: Not known to adversely affect reproductive functions and organs.
Target organ effects: See COMPONENT TOXICOLOGICAL INFORMATION below.

COMPONENT TOXICOLOGICAL INFORMATION

Com ponent Target Organ Effects LD50 / LC50

Methanol skin, eyes, CNS, GI tract, respiratory system = 15800 mg/kg (Dermal LD50; Rabbit)
= 5628 mg/kg (Oral LD50; Rat)
= 64000 mg/kg (Inhalation LC50; Rat) 4 hr
Ethoxylated alcohols - -
Ethoxylated alcohols #2 - -

Com ponent IARC Group 1 or 2: ACGIH - OSHA Listed NTP:

Carcinogens: Carcinogens
Methanol - - - -
Ethoxylated alcohols - - - -
Ethoxylated alcohols #2 - - - -

Com ponent OTHER TOXICOLOGICAL INFORMATION

Methanol Causes eye irritation. Toxic by ingestion and inhalation. Danger of very serious irreversible
effects if sw allow ed. Can be aspired into lungs during ingestion or vomiting. Aspiration can
cause potentially fatal injury to the lungs. Chronic inhalation has show n to cause diminished
vision. Acute oral and dermal exposure has show n to cause optic nerve effects, diminished
vision and brain effects (necrosis and hemorrhaging). At first, symptoms of severe exposure
are nausea, headache, vomiting, dizziness. The latent period is follow ed by development of
metabolic acidosis and severe visual effects. Coma and death are usually due to respiratory
failure. Fetotoxic and teratogenic effects observed in controlled animal studies.
Ethoxylated alcohols Harmful if sw allow ed. Risk of serious damage to eyes.

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Ethoxylated alcohols #2 Harmful if sw allow ed. Risk of serious damage to eyes.

12. ECOLOGICAL INFORMATION

PRODUCT INFORMATION

COMPONENT INFORMATION

Methanol
Bioaccum ulation: log Pow = -0.7
Persistence / degradability: Biodegradable.
Freshw ater Fish Species = 13 mg/L (LC50; rainbow trout (fingerling))
Data

13. DISPOSAL CONSIDERATIONS

Waste from residues / unused products:

Treat as hazardous waste. Dispose of in accordance with local regulations.

Contaminated packaging:
Dispose of in accordance with local regulations. If reusable containers are used, send them back to the
product supplier, after the required rinsing.

EPA RCRA Hazardous Waste Code:

D001

14. TRANSPORT INFORMATION

DOT:
UN/NA Number: UN 1992
CERCLA RQ: 2100 Gallons (methanol)

Packing size: < 2100 gals

Hazard class: 3 Subsidiary hazard(s): 6.1
Proper shipping name: Flammable liquid, toxic, n.o.s (contains methanol), 3, (6.1), UN 1992, PG III
Label(s): Flammable Liquid 3, Toxic 6.1

Packing size: > 2100 gals

Hazard class: 3 Subsidiary hazard(s): 6.1
Proper shipping name: Flammable liquid, toxic, n.o.s (contains methanol), 3, (6.1), UN 1992, PG III, RQ
Label(s): Flammable Liquid 3, Toxic 6.1

IMDG/IMO
Shipping name: FLAMMABLE LIQUID, TOXIC, N.O.S. (Methanol)
Label(s): Flammable Liquid 3, Toxic 6.1
Class or Div.: 3 Subsidiary risk(s): 6.1
UN number: UN 1992
Packing group: III
EMS: F-E, S-D

ICAO/IATA
Shipping name: Flammable liquid, toxic, n.o.s (contains methanol)
Label(s): Flammable Liquid 3, Toxic 6.1

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Class or Div.: 3 Subsidiary risk(s): 6.1

UN number: UN 1992
Packing group: III
Packing instruction 309 Max Net Qty/Pkg: 60 L
(passenger aircraft):
Packing instruction 310 Max Net Qty/Pkg: 220 L
(cargo aircraft):
TDG (Canada):
Shipping name: FLAMMABLE LIQUID, TOXIC, N.O.S. (contains methanol), 3, (6.1), UN 1992, PG
III
Label(s): Flammable Liquid 3, Toxic 6.1
PIN: UN 1992
Class: 3 Subsidiary hazard(s): 6.1
Packing group: III

Note 1:
For the applicab le placard selection refer to the appropriate transport regulations; the selection may vary
depending on the cargo size and categories of other hazardous materials in the cargo.

15. REGULATORY INFORMATION

International Chemical Inventories

USA, Toxic Substances Control This product complies with TSCA requirements.
Act inventory (TSCA):
Canada, Domestic Substance This product complies with DSL requirements.
List (DSL):
U.S.A. Regulations

OSHA Hazard Communication Standard:

(Complies with USA OSHA 29 CFR 1910.1200 and ANSI Z 400.1)

EPA RCRA Hazardous Waste Code:

D001

EPA, Sections 311 and 312 - Material Safety Data Sheet Requirements (40 CFR 370):

Immediate (Acute) Health Hazard: YES

Delayed (Chronic) Health Hazard: YES
Fire Hazard: YES
Sudden Release or Pressure Hazard: None
Reactive Hazard: None

EPA, Sections 313 - List of Toxic Chemicals (40 CFR 372):

This product contains the following substance(s), which appear(s) on the List of Toxic Chemicals:

Additional Regulatory Information

Methanol
EPA, CERCLA Section 102a/103 Hazardous Substances (40 CFR 302.4): Listed
CERCLA/SARA - Hazardous Substances and their RQs: 2270 kg final RQ
5000 lb final RQ
EPA, SARA TITLE III Section 304, Extremely Hazardous Substances (40 CFR 355.40): None
California Proposition 65: None
Ethoxylated alcohols
EPA, CERCLA Section 102a/103 Hazardous Substances (40 CFR 302.4): None
CERCLA/SARA - Hazardous Substances and their RQs: None
EPA, SARA TITLE III Section 304, Extremely Hazardous Substances (40 CFR 355.40): None
California Proposition 65: None

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Methanol
Ethoxylated alcohols #2
EPA, CERCLA Section 102a/103 Hazardous Substances (40 CFR 302.4): None
CERCLA/SARA - Hazardous Substances and their RQs: None
EPA, SARA TITLE III Section 304, Extremely Hazardous Substances (40 CFR 355.40): None
California Proposition 65: None

International Hazard Class

WHMIS Hazard Class:
B2 (Flammable Liquids)
D1A (Immediate and Serious Toxic Effects - Very Toxic Material)
D1B (Immediate and Serious Toxic Effects - Toxic Material)
D2A (Other Toxic Effects - Very Toxic Material)
D2B (Other Toxic Effects - Toxic Material)

16. OTHER INFORMATION

Current references:
1. Threshold Limit Values for Chemical Substances and Physical Agents and Biological Exposure Indices.
American Conference of Governmental Industrial Hygienists, Cincinnati OH.
2. IARC Monograms on the Evaluation of the Carcinogenic Risk of Chemicals to Man. World Health
Organization, International Agency for Research on Cancer. Geneva, Switzerland.
3. Annual Report on Carcinogens. National Toxicology Program. U.S. Department of Heath and Human
Services, Pub lic Health Service.
4. NIOSH Registry of Toxic Effects of Chemical Substances (RTECS). National Institute for Occupational safety
and Health. Cincinnati, OH.
5. LOLI Database.

Explanation of terms:
ACGIH: American Conference of Governmental Industrial Hygienist
ACGIH-TL: Threshold Limit Value
DSL: Domestic Substance List
HMIRC: Hazardous Materials Information Review Commission
IARC: International Agency for Research on Cancer
NTP: National Toxicology Program
NIOSH: National Institute of Occupational Safety & Health
NIOSH-REL: Recommended Exposure Limit
OSHA: Occupational Safety & Health Administration
OSHA-PEL: Permissible Exposure Limit
TSCA: Toxic Substance Control Act (Inventory)

Occupational Exposure Limits indicators: TWA - Time Weighted Average; STEL - Short Term Limit; C - Ceiling
Limit;units: [mg/m 3]

ACGIH Notations:
"Skin" refers to the potential significant contribution to the overall exposure by the cutaneous route, including
mucous membranes and the eyes, either by contact with vapors or by direct skin contact with the substance.
"A" notation indicates carcinogenicity as follows:
ACGIH classification: A1 - Confirmed Human Carcinogen; A2 - Suspected Human Carcinogen; A3 - Confirmed
Animal Carcinogen with Unknown Relevance to Humans; A4 - Not Classifiable as a Human Carcinogen; A5 - Not
suspected as a Human Carcinogen.
"SEN" refers to the potential for an agent to product sensitization as confirmed by human and animal data.

Section(s) revised: 12

Prepared by: Well Services Safety & Environment (WSSE).

Revision date: 19 May 2009

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The information and recommendations contained herein are based upon tests believed to be reliable. How ever, Schlumberger
does not guarantee their accuracy or completeness NOR SHALL ANY OF THIS INFORMATION CONSTITUTE A WARRANTY,
WHETHER EXPRESSED OR IMPLIED, AS TO THE SAFETY OF THE GOODS, THE MERCHANTABILITY OF THE GOODS, OR THE
FITNESS OF THE GOODS FOR A PARTICULAR PURPOSE. Adjustment to conform to actual conditions of usage may be required.
Schlumberger assumes no responsibility for results obtained or for incidental or consequential damages, including lost profits
arising from the use of these data. No w arranty against infringement of any patent, copyright or trademark is made or implied.

End of the Material Safety Data Sheet

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