Physical Science Week 11-12-1
Physical Science Week 11-12-1
One way to determine the limiting reagent is to compare the mole ratio of the amount of reactants used.
This method is most useful when there are only two reactants. One reactant (A) is chosen, and the balanced
chemical equation is used to determine the amount of the other reactant (B) necessary to react with A. If the
amount of B actually present exceeds the amount required, then B is in excess, and A is the limiting reagent. If the
amount of B present is less than is required, then B is the limiting reagent.
To begin, the chemical equation must first be balanced. The law of conservation states that the quantity of
each element does not change over the course of a chemical reaction. Therefore, the chemical equation is balanced
when the amount of each element is the same on both the left and right sides of the equation. Next, convert all
given information (typically masses) into moles, and compare the mole ratios of the given information to those in
the chemical equation.
For example: What would be the limiting reagent if 75 grams of C2H3Br3 reacted with 50.0 grams of O2 in
the following reaction:
Another method of determining the limiting reagent involves the comparison of product amounts that
can be formed from each reactant. This method can be extended to any number of reactants more easily
than the previous method. Again, begin by balancing the chemical equation and by converting all the given
information into moles. Then use stoichiometry to calculate the mass of the product that could be produced
for each individual reactant. The reactant that produces the least amount of product is the limiting reagent.
For example: What would be the limiting reagent if 80.0 grams of Na2O2 reacted with 30.0 grams
of H2O in the reaction?
Key Points
The theoretical yield for a reaction is calculated based on the limiting reagent. This allows researchers to
determine how much product can actually be formed based on the reagents present at the beginning of the
reaction.
The actual yield will never be 100 percent due to limitations.
Percent yield = actual yield
theoretical yield × 100
Percent yield measures how efficient the reaction is under certain conditions.
Key Terms
actual yield: The amount of product actually obtained in a chemical reaction.
percent yield: Refers to the efficiency of a chemical reaction; defined as the actual yield x 100
theoretical yield
theoretical yield: The amount of product that could possibly be produced in a given reaction, calculated
according to the starting amount of the limiting reagent.
For example, consider the preparation of nitrobenzene (C6H5NO2), starting with 15.6g of benzene (C6H6) in
excess of nitric acid (HNO3):
In theory, therefore, if all C6H6 were converted to product and isolated, 24.6 grams of product would be
obtained (100 percent yield). If 18.0 grams were actually produced, the percent yield could be calculated:
Activity:
Solving Problems:
1.Glucose, C6H12O6, reacts with oxygen to give CO2 and H2O. What mass of oxygen (in grams) is required for
complete reaction of 25.0 g of glucose? What mass of CO2 and water (in grams) are formed?
Equation : , C6H12O6 + O2 CO2 + H2O note: balance first the equation
2. Zinc reacts with aqueousHydrochloric AcidtoproduceHydrogengas andZinc Chloride. Identify the limiting
reactant for each of the following situations: a) 12 atoms of Zinc and 8molecules of HCl.
b)3 mol of Zn and 4 mol of HCl
c) 40g of Zn and 56g of HCl.
3. In an experiment, 80gof Zn are allowed to react with 105g of HF as shown in the following balanced
chemical reaction:
Zn + 2HF ________ ZnF2 + H2