Aim : To analyze the given inorganic salt for acidic and basic radical. Pb(NOs): Preliminary Investigation Physical state Solid i" Fe®* .Mn®* Fe™ absent) Colour Creamish white (Cu, Co™. Odour No characteristic odour (NH; .S* « - CH,COO absent) Solubility Soluble in water Flame Test Dull Bluish white flame is obtained (Pb may be) (A) Identification of Acidic Radical a- Preliminary test: Experiment Observation Inference. T | Salt solution + dil H,SO, solution | No gasisevolved | Group A (CO .CH,COO .NOz SO; .S* absent) 2 | Salt + Conc™ H2SO, + Heat Brown Colourled gas Group B (NO; may be present) (NO,) is evolved (b)_Confirmative test: ‘Experiment Observation Taference 7 Diphenyl amine test : Deep blue coloured NOs - confirmed salt + Conc" _H,SO, + diphenyl amine. solution 2 Ring Test : ‘Brown ring is formed at ‘NO; - confirmed Salt + Freshly prepared FeSO, + Conc” the junction of two liquids H,SO, along the side of the test tube Identification of Basic Radical a- Preliminary test : Experiment Observation Inference 1 ‘Salt solution + NaOH. ‘No Smell of ammonia ‘Zero group NH," | absent [2 Salt Solution + dil HCI ‘White ppt of PbCI. is Tgroup (Pb™ may be] Filter the above ppt and boil it with water | formed and divide into parts. Identification of Basic Radical a- Confirmative test : i Experiment Observation inference T Kl test : 1" part + KI Pb I, (Yellow Ppt) Pb" Confirmed K,C1Oy Test : 2" pant + K:CrOs Yeon ot of PbCrO, 1s | Pb™ Confirmed ToTi-al reaction for Acidic Radicalimi : Lo anulyze the given inorganic salt for acidic and basic radical. [CuSOy) Preliminary Investigation Physical state Solid Colour Blue (Cu®* may be) Qdeur No characteristic odour (absence of NH; .S* ,CH,COO ) Solubility Soluble in water. Flame Test Bluish green flame (Cu”* may be) (A) Identification of Acidic Radical a- Preliminary test : | Experiment ‘Observation Tnference 7 | Salt solution + dil H,SO, solution | No gas is evolved] Group A | (ca. s*.s0% No; cH,cOoO absent) Z| Sale> Conc* H;S0, + Heat No gas evolved ‘Group B anions (cr, Be NO, .C,O% areabsent) () Confirmative test : i Experiment ‘Observation Inference T BaCl; fest: Salt Solution + BaCl, Solution | White Ppt formed 50;" confirmed | | Add dil. HCl or dil HNO, | Ppt remains insoluble [2 | Lead Acetate Test :- White ppt. formed SO" confirmed | | Salt Solution + lead acetate solution | | Aad ammonium acetate Solution (CH,COONH,) | Ppt becomes soluble | to above ppe Identification of basic Radical a- Preliminary test : Experiment Observation Inference 1_| Saltsolution = NaOH + heat Nosmell ofammonia | Zero Group. (WH; alisent) z ‘Salt solution + dil. HCL No white Ppt Group T, (Pb™ absent) [3 | Atove solution > FS gas Black Ppt is formed Group Hl, (Cu 7 Pb” may be present ) ? Dissolve above ppt in HNO} Solution turms bluish green 35___| Divide the above solution in 2 parts () Confirmative test : Experiment Observation Inference 1 | NH,OH test: 1* part” Deep ule colow 7] Cae NH, OH 2 _| Potassium Ferrocynide test: | Chocolate brown Ga? continmed Hind part + KylFe(CNel | ppt of Copper fervocyanide is formedAim : To analyze the given inorganic salt for acidic and basic radical. Al (SOs Preliminary Investigation Physical state > Solid Colour 9 White (Cu*, Fe”, Fe”,Ni, Mn’, Co™absent) Qdour 3 No characteristic odour (absence of NH; .S’ ,CH,COO ) Solubility Soluble in water. Flame Test No characteristics flame (Pb"?, Sr“, Cu", Ca"?, Ba"?.Ni"?, Zn”absent) (A) Identification of Acidic Radical a- Preliminary test: E Experiment Observation Inference i Salt solution + dil H,SO, “No gas is evolved | Group A (co .S?,SOP NO, CH,COO ) 2 ‘Salt + Conc” H,SO, + Heat No gas evolve Group B anions (ct Br 61 .NO,.COR 3 it Bac 7 oe White pptis formed “| Group € anion (SO; may be) (0) Contiemative test Experiment ‘Observation Inference 1 BaCl, test Salt Solution + BaCl, White Ppt ‘SOF confirmed Add dil HCI to above ppt Ppt remains insoluble z Lead Acetate Test :- Salt Solution + (CH;COO), Pb. solution | White ppt SOR confirmed ‘Add CHyCOO NH, to above ppt. Ppt dissolves in ammonium acetate, B- Identification of Basic Radical {(@) Preliminary test : C Experiment Observation Inference 1 | Salt solution + NaOH + | No smell of NH, | Zero heat Group.(NH; absent) 2_| Saltsotution + dil. HCI [No Ppt Group 1, (Pb™ absent) 3 | To the above solution | No ppt Group (Ca, PL, pass _HyS gas As‘ Cu” absent) 4 | Boil H,S gas and add | White gelatinous | Group Ili (AI may be) NH,CI+NHOH & — | ppt. divide the Solution in two parts. (b) Confirm: Experiment Observation i _Inference T “Take test : 1" part + = + HCI + 2 drops of _ | Blue ppt.floats over Al” confirmed colourless solution = = Z Tea ‘mation of white ‘Al confirmed Sind part + NH1\Cl + Boil the solution Hinous ppt ne esFel Fe*Nr Mts CoM are No characterisic above: (S". NEY). CH,COO Vabsent ‘Sotabie i wane, Geees flashes (Za may be) 2 Preliminary text: Cy 4 od Taferener T | Sakstce - HS, No gasis evohed , | i es |S* .SG_NO, CH,COO absent) [20] Sait Cone SO, - Hex Colorless eas taving | Group B anions | | poneers smell which | (CT may be) boy [presutzedese | LJ Sms | Pass the vapour ina esx tbe conraining N2OH solution | Add (CH,COOE - (CH,COO}. Pb Exo t above solstice P (AgNO, Tex: Sak Scisacn- AZNO; t | Dissolve pet in NHLOH (a) Pretiminary test : L | Observation Inference 1 | Seitscizice -"20H- | No smell of NH [Zn coss. | Bex { | (AH; absent) ig | Sek scleton - 2. HO | Nowhite Pp | Group Lepr absent) 3 To the hove sotatica Ne | Group IL (Ca. AST. aE eee a Boil atone solic | Nope | | Group i TFe™. remove H,S ad acd i | Fe AIP absent] (NLC) ~ NOH: | | Lens, { i Toarematiepes | Witepeis (Group IN [aa may | HS es | obmained bel | Dissolve the wtize pee in| teen eeee | L pars } [CHEMISTRY PRACTICAISI Dave NAO. Experiment [Observation Inference (RFA Te 1 part + KEFECI Wie pee of ee Za conformed | ferocyarie FE [Bless whese pat (za confirmed 2 eieal reaction for Ric Radical A inere Teal: F[Alem Tis analy the gyven inorganic 92} 90" BIDHE ay ean sour emer Preliminary Investigation Physical state Solid 2 sation are sheen) Colost — White (Cu’, Fe", Fe Mn"? COM are abise : OH No characteristic adour (NH; CH,COO .S* )absent st : Solubiliry Soluble in water © Physical Test Solid (A) Identification of Acidic Radical 2 Preliminary test: [Observation | Inference HSO’ | No gas Is evolved | Group A | \cot .S* SO; NO, CH,COO absent) ‘Salt < Conc H,S0, + Heat Reddish orange Group B anion pours which turns | (Br may be) | starch paper yellow (b) Confirmative test: CL Experiment T Observation | Inference fi | AgNO, Test : Salt Solution «AgNO, Yellow ppt. Br confirmed 1 | | Dissolve ppt in NH.OH Ppt. remains partially | |e | | Orange red vapour of Br, | Br confirmed H,SOre Heat | B. Identification of Basic Radical (2) Preliminary test: Observation Inference Salt solution + NeOH > heat No smell of Ni Zero Group. (NIT absent) + dil HCI No white Ppt Group 1 (Pb™ absent) | To the dhorve solution pass HS gas ~~] No ppt Group II (Cu™ . As, Cd. Pb™ | ae _ | absent ) oi) above vlution to remove HS and add | No ppt. Group III [Fe"". Fe" AI” absent | No ppt Group IV [Zn Co™ }o -_ | Mn absent] [6 Remeve 1,5 pas by boiling, | White ppt V group (Ca L Add (Nu)? CO, t0 it | | Ammonium sulphate Tes [Nop | Mlnd part « (11950. | 4 TAmmoniutn oxataw Tos | No ppt {td port « ammonium (511) ,C;04 | PHT vane wet Perform flame | Apple green flame | Be {| tee vents sate _ | =Physical state Solld Colour Green (NI may be) Qudour : No characteristic odour (absence of CH;COO . NH, S*) Solubility Soluble in water, Flame Test No Characteristic flame absence of Cu, Pb, Zn"*.Cu’" Br?) (a) Identification of Acidic Radical a. Preliminas Observation | Inference ‘No gas is. Group A 7 dil HCL evolved (cop .s*.sO; NO, Ct 1,COO abset 2 | Salt+ Cone” | Colourless | Group B anions H,SO, + Heat | pungent CI may be present ‘smelling gas (HCI) is evolved which gives white dense fumes of NH,Cl. (b)_Confirmative test: Experiment Observation Inference. 1 ‘AgNO, Test = Curdy white ppt CI confirmed Salt Solution+ AgNOy Dissolve ppt. in NH,OH Ppt become soluble 2 ‘Chromyl chloride test : Salt + Kr,Cr,0;(s) Reddish orange vapours (1:2) + cone. HS, + heat of chromyl chloride are evolved CY confirmed ass the vapour in a test tube containing _| Solution becomes Yellow NH,OH ‘Add (CHjCOOH + Pb(CH;COO), ‘Yellow ppt of lead chromate is formed B- Identification of Basic Radical Preliminary test : Experiment Observation Inference T Salt solution + NaOH +Heat No smell of NH, Zero Group, (NH; absent) = Salt solution + dil. HCI No white Ppt Group 1. Pb” absent 3 Pass HS gas through above NCI ‘No ppt. Group Hl, (Cu. As", Cd", Pb”) absent 7 Remove HS gas by boiling & add NITCI (6) | No ppt Group UIT [Fe Fe®AP* absent + NH OH in excess. 1 5 Pass HS gas through above solution Black ppt. Group IV [Ni or Co May be Dissolve the ppt by boiling with aqua repia present} {Cone HCI + Cone, HNOj| evaporate to dryness add water & divide in 2 parts . “(o) Confirmative test : Experiment DMG test Lpart NaOH est 2° pa