SAFETY DATA SHEET

NATULAR™ DT
Effective Date: 1 June 2015
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SECTION 1. Identification of the Substance/Mixture and of the Company

1.1 Product Identifier
Formulation Identifier: Natular™ DT
EPA Registration Number: 8329-602
1.2 Relevant Identified Uses of the Substance or Mixture and Uses Advised Against
Relevant Identified Uses: Insecticide for control of mosquito and midge larvae
Uses Advised Against: See product label for use restrictions
1.3 Details of the Supplier of the Safety Data Sheet
Clarke Mosquito Control Products, Inc.
675 Sidwell Court
St. Charles, IL 60174 U.S.A.
+1 (630) 894-2000
Email: [email protected]
1.4 Emergency Telephone Number
24-Hour Medical Emergency: POISON CONTROL Toll-free (800) 214 – 7753
24-Hour Transportation Emergency: INFOTRAC (800) 535-5053
SECTION 2. Hazards identification

United States (US)

According to OSHA 29 CFR 1910.1200 HCS (2012)
2.2 Classification of the Substance or Mixture
Not Classified Product does not meet the classification criteria for acute, delayed, or physical hazard
according to the 2012 OSHA HCS
Hazard Symbol(s): None
Signal Word: None
Hazard statements: None
Precautionary Statements: None
2.3 Other Hazards Not Classifiable Under OSHA 2012 HCS
See product label for any additional hazards
SECTION 3. Composition/Information on Ingredients
3.1 Components
Substance Name CAS No. Concentration % w/w
Spinosad: 7.48
Spinosyn A 131929-60-7
Spinosyn D 131929-63-0
Citric Acid, anhydrous 77-92-9 <5*
* The exact percentage (concentration) of composition has been withheld as trade secret.
Ingredients not identified are non-hazardous and/or are not required to be disclosed pursuant to 29 CFR 1910.1200 (2012), and
are withheld as trade secret.
SECTION 4. First Aid Measures

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4.1 Description of First Aid Measures

Eye Contact: Hold eye open and rinse slowly and gently with water for 15-20 minutes. Remove contact lenses, if
present, after the first 5 minutes then continue rinsing. Call a poison control center/doctor for treatment
advice.
4.2 Most Important Symptoms and Effects, Both Acute and Delayed.
Eye Contact: This product may release nuisance dust in handling or use. Dust may cause slight transient (temporary) eye
irritation.
4.3 Indication of Immediate Medical Attention and Special Treatment
Treatment: Appropriate supportive and symptomatic treatment as indicated by the patient’s condition is recommended.
For medical treatment information, contact the poison control hotline at 1-800-214-7753. Have the product
container or label with you when calling a poison control center or doctor, or going for treatment.
SECTION 5. Fire-Fighting Measures
5.1 Extinguishing Media
Suitable Extinguishing Media: Water Fog, Carbon Dioxide (CO2), Dry Chemical, Foam
Unsuitable Extinguishing Media: None known
5.2 Special Hazards Arising From the Substance or Mixture
Specific Hazards: Under fire conditions some components may decompose. Combustion products may
include CO and NOx.
5.3 Special Protective Equipment and Precautions for Fire-Fighters
Protection Against Fire: Wear positive pressure, self-contained breathing apparatus and protective firefighting
clothing (includes fire-fighting helmet, coat, pants, boots, and gloves).
Special Procedures: Fight fires from a protected location. Dike fire control water for later disposal. Keep
container cool by spraying with water.
SECTION 6. Accidental Release Measures
6.1 Personal Precautions, Protective Equipment and Emergency Procedures
General Precautions: Use appropriate protection (see section 8)
Environmental Precautions: Prevent product from entering into drains and waterways. Collect and dispose of this
material and its container in accordance with national and regional regulations. If the
product has contaminated surface water, inform the appropriate authorities. See Section 12
for additional ecological information.
6.2 Methods and Material for Containment and Cleaning Up
Clean Up Methods: Collect all material with shovel, other instrument, or by hand while using appropriate
personal protection equipment, and place in closable marked containers.
SECTION 7. Handling and Storage
7.1 Precautions for Safe Handling
Handling: Keep out of reach of children. Do not take internally. Avoid contact with skin and eyes.
Hygiene Measures: Wash thoroughly with soap and water after handling and before eating, drinking, chewing gum, using
tobacco or using the toilet.
7.2 Conditions for Safe Storage, Including Any Incompatibilities

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Storage: Product should be stored in compliance with local regulations. Store in a cool, dry, well-ventilated
place in the original container. Protect from excessive heat and cold. Do not store near food, drink,
animal feeding stuffs, pharmaceuticals, cosmetics or fertilizers. Keep out of reach of children.
SECTION 8. Exposure Controls / Personal Protection

These precautions are suggested for conditions where the potential for exposure exists. Emergency conditions may require
additional precautions.
8.1 Control Parameters
Component Name CAS No. List Type Value
3
Spinosyn A & 131929-60-7 DOW IHG TWA 0.3 mg/m
Spinosyn D 131929-63-0
8.2 Exposure controls
Engineering Controls: Use with adequate ventilation. Wash hands thoroughly after handling. Wash clothing before re-using.
Individual Protection Measures, such as Personal Protection Equipment:
Eye Protection: Safety Glasses, Goggles or Face Shield
Skin Protection: Wear suitable protective clothing
Hand Protection: It is good industrial hygiene practice to minimize skin contact. If required or preferred, use suitable
protective chemical resistant gloves such as latex, nitrile, or neoprene.
Respiratory Protection: None required
SECTION 9. Physical and Chemical Properties
9.1 Information on Basic Physical and Chemical Properties
Appearance: Solid, bi-layer tablet
Color: Tan/white
Odor: Earthy scent
Odor Threshold: Not Available
pH: 6.67
Melting Point: Not Determined
Freezing Point: Not Applicable
Initial Boiling Point: Not Applicable
Flash Point: Not Determined
Evaporation Rate: Not Applicable
Flammability: Not Determined
Explosion limits [U/L]: Not Applicable
Vapor Pressure: Not Applicable
Vapor Density: Not Applicable
Relative Density: 1.88 g/mL
Solubility: Not Determined
Partition Coefficient: Not Determined
Auto-Ignition Temperature: Not Determined
Viscosity : Not Applicable
Decomposition Temperature: Not Available
Explosive Properties: Not Available

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Oxidizing Properties: Not Available

SECTION 10. Stability and Reactivity
10.1 Reactivity
Not Available
10.2 Chemical Stability
Stable under normal conditions
10.3 Possibility of Hazardous Reactions
Hazardous Reactions: None under normal conditions
Hazardous Polymerization: Not known to occur
10.4 Conditions to Avoid
Protect from direct sunlight and excessive heat.
10.5 Incompatible Materials
Avoid contact with strong oxidizing agents, strong acids, strong bases
10.6 Hazardous Decomposition Products
None known under normal conditions of storage and use
SECTION 11. Toxicological Information
11.1 Information on Likely Routes of Exposure
Eye Contact: This product may release nuisance dust in handling or use. Dust may cause slight transient (temporary) eye
irritation.
11.2 Information on Toxicological Effects
Acute Toxicity
Oral, Rat LD50 : > 2,000 mg/kg-bw
Dermal, Rat LD50 : > 4,000 mg/kg-bw
3
Inhalation, Rat LC50 : > 5.0 g/m
Skin Corrosion/Irritation: Not a skin irritant
Serious Eye Damage/Irritation: Slight irritant
Skin Sensitization: Not a skin sensitizer
STOT – Single exposure No data is available to indicate product or any components present at greater than
0.1% present a specific target organ toxicity hazard from single exposure.
Chronic Toxicity/Effects
Germ Cell Mutagenicity: Not mutagenic
Carcinogenicity: Not carcinogenic. All components of this product are not classified as a carcinogen
by OSHA, IARC, NTP, or Prop. 65. Spinosad is not carcinogenic.
Reproductive Effects: No data is available to indicate product or any components present at greater
than 0.1% cause reproductive or teratogenic toxicity. For Spinosad: in
laboratory animal studies, effects on reproduction have been seen only at
doses that produced significant toxicity to the parent animals.

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STOT – Repeated Exposure: In animals, spinosad has been shown to cause vacuolation of cells in various
tissues. Dose levels producing these effects were many times higher than any
dose levels expected from exposure due to use.
SECTION 12. Ecological Information
12.1 Ecotoxicity
Product specific data is not available. Data referenced is in relation to the active ingredient, Spinosad. Spinosad is moderately
toxic to aquatic organisms on an acute basis (LC50/EC50 between 1 and 10 mg/L in the most sensitive species tested).

Toxicity to Fish: 96-hr Acute LC50 5.0 mg/L, Common Carp (Cyprinus carpio)
96-hr Acute LC50 5.9 mg/L, Bluegill Sunfish (Lepomis macrochirus)
96-hr Acute LC50 30 mg/L, Rainbow Trout (Oncorhynchus mykiss)
Toxicity to Aquatic Invertebrates: 48-hr Acute EC50 1.5-14.0 mg/L, Water Flea (Daphnia magna)
48-hr LC50 > 7.9 mg/L, Mysid Shrimp (Americamysis bahia)
Toxicity to Aquatic Plants: 5-d EC50 8.1 mg/L, Blue Green Algae (Anabaena flos-aquae)
12.1 Persistence and Degradability
Product specific data not available. Data referenced is in relation to the active ingredient, Spinosad.
Log Kow: Spinosyn A: 3.91; Spinosyn D: 4.38 (distilled water)
Bioaccumulation: Bioconcentration potential is low (BCF < 100)
Bioconcentration Factor: Spinosyn A: 19; Spinosyn D: 33 mL/g (fish)
Mobility in Soil: Potential for mobility in soil is low (Koc between 500 and 2000)
Partition Coefficient, Koc: 701
SECTION 13. Disposal Considerations
13.1 Waste Treatment and Disposal methods
Consult product label for disposal instructions. Avoid release to the environment. Improper disposal of excess product or rinsate
is a violation of the Federal law. If these wastes cannot be disposed of by use according to label instructions, contact your State
Pesticide or Environmental Control Agency, or the Hazardous Waste Representative at the nearest EPA regional office for
guidance.
SECTION 14. Transport Information
14.1 DOT (US)
Not regulated (Bulk and Non-Bulk Quantities)

14.2 IMDG (Vessel)

UN Number: 3077
Hazard Class: 9
Packing Group: III
Proper Shipping Name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE SOLID, N.O.S. (Spinosad)
Marine Pollutant: Yes

14.3 ICAO/IATA (Air transport)

UN Number: 3077
Hazard Class: 9
Packing Group: III
Proper Shipping Name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE SOLID, N.O.S.(Spinosad)

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Effective Date: 1 June 2015
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Environmental Hazard: Yes

SECTION 15. Regulatory Information
FIFRA Information: This chemical is a pesticide product regulated by the Environmental Protection Agency and is subject to
certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard
information for safety data sheet, and for workplace labels of non-pesticide chemicals. Following is the hazard information as
required on the pesticide label:
Signal Word: CAUTION
Keep Out Of Reach Of Children.
PRECAUTIONARY STATEMENTS: HAZARDS TO HUMANS AND DOMESTIC ANIMALS: CAUTION. Causes moderate eye
irritation. Avoid contact with eyes or clothing. Wear protective eyewear (such as goggles, face shield, or safety glasses). Wash
thoroughly with soap and water after handling and before eating, drinking, chewing gum, using tobacco or using the toilet.
Other Federal Regulations
SARA TITLE III CLASSIFICATION
Section 302: None
Section 311/312: Immediate (acute) hazard
Section 313: This product contains the following toxic chemicals subject to the reporting requirements of section
313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372

None
CERCLA RQ: None
OSHA HAZARD COMMUNICATION STANDARD: This product is not considered a “Hazardous Chemical” as defined by the
OSHA Hazard Communication Standard, 29 CFR 1910.1200.
U.S. California Proposition 65: Not listed
STATE RIGHT-TO-KNOW : National, state, provincial or local emergency planning, community right-to-know or other laws,
regulations or ordinances may be applicable--consult applicable national, state, provincial or local laws.
SECTION 16. Other Information

DISCLAIMER OF LIABILITY The information in this SDS was obtained from sources we believe to be reliable. However, the
information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of
handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other
reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any
way connected with the handling, storage, use or disposal of the product. This SDS was prepared as is to be used only for this
product. If the product is used as a component in another product, this SDS information may not be applicable.

™ NATULAR is a Trademark of Clarke Mosquito Control Products, Inc.

End of document

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