SAFETY DATA SHEET

Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II (453/2010) - Europe

Toprinse Jet Version : 1

SECTION 1: Identification of the substance/mixture and of the

company/undertaking
1.1 Product identifier
Product name : Toprinse Jet
Product code : 109894E
Product use : Rinse Additive
Product is for professional use only

1.2 Relevant identified uses of the substance or mixture and uses advised against
Identified uses
Rinse aid. Automatic process

1.3 Details of the supplier of the safety data sheet

Manufacturer/ Distributor/ : Ecolab Ltd.
Importer La Vallee House
Upper Dargle Road
Bray
Co. Wicklow
Ireland
Tel +353 (0)1 276 3500
Fax + 353 (0)1 2761900
[email protected]
1.4 Emergency telephone number
National advisory body/Poison Centre
Telephone number : 01 8379964
Manufacturer/ Distributor/ Importer
Telephone number : 01 8727322 Ref: DC2-909
SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
Product definition : Mixture
Classification according to Directive 1999/45/EC [DPD]
The product is not classified as dangerous according to Directive 1999/45/EC and its amendments.
Classification : Not classified.
Physical/chemical : Not applicable.
hazards
Human health hazards : Not applicable.
Environmental hazards : Not applicable.
See Section 16 for the full text of the R phrases or H statements declared above.
See Section 11 for more detailed information on health effects and symptoms.

2.2 Label elements

Risk phrases : This product is not classified according to EU legislation.
Safety phrases : Not applicable.
Supplemental label : Safety data sheet available for professional user on request.
elements

2.3 Other hazards

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SECTION 2: Hazards identification

Other hazards which do : Not applicable.
not result in classification

SECTION 3: Composition/information on ingredients

3.2 Mixtures
Classification
Product/ingredient Identifiers % 67/548/EEC Regulation (EC) No. Type
name 1272/2008 [CLP]
Fattyalcohol CAS: 68551-13-3 <25 N; R50 Aquatic Acute 1, H400 [1]
ethoxylates > C15 and
=/< 5EO
alcohol ethoxylate CAS: 111905-53-4 1-5 Xi; R36/38 Skin Irrit. 2, H315 [1]
Eye Irrit. 2, H319
See section 16 for See Section 16 for the
the full text of the R- full text of the H
phrases declared statements declared
above above.

There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this
section.
Type
[1] Substance classified with a health or environmental hazard
[2] Substance with a workplace exposure limit
[3] Substance meets the criteria for PBT according to Regulation (EC) No. 1207/2006, Annex XIII
[4] Substance meets the criteria for vPvB according to Regulation (EC) No. 1207/2006, Annex XIII
Occupational exposure limits, if available, are listed in Section 8.
SECTION 4: First aid measures
4.1 Description of first aid measures
Eye contact : Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Get medical attention if irritation
occurs.
Inhalation : Remove victim to fresh air and keep at rest in a position comfortable for breathing.
Get medical attention if symptoms occur.
Skin contact : Flush contaminated skin with plenty of water. Remove contaminated clothing and
shoes. Get medical attention if symptoms occur.
Ingestion : Wash out mouth with water. Remove victim to fresh air and keep at rest in a position
comfortable for breathing. Do not induce vomiting unless directed to do so by
medical personnel. Get medical attention if symptoms occur.
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training.

4.2 Most important symptoms and effects, both acute and delayed
Potential acute health effects
Eye contact : No known significant effects or critical hazards.
Inhalation : No known significant effects or critical hazards.
Skin contact : No known significant effects or critical hazards.
Ingestion : No known significant effects or critical hazards.
Over-exposure signs/symptoms
Eye contact : No specific data.
Inhalation : No specific data.
Skin contact : No specific data.
Ingestion : No specific data.

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SECTION 4: First aid measures

4.3 Indication of any immediate medical attention and special treatment needed
Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if large
quantities have been ingested or inhaled.
Specific treatments : No specific treatment.

SECTION 5: Firefighting measures

5.1 Extinguishing media
Suitable extinguishing : Use an extinguishing agent suitable for the surrounding fire.
media
Unsuitable extinguishing : None known.
media

5.2 Special hazards arising from the substance or mixture

Hazards from the : In a fire or if heated, a pressure increase will occur and the container may burst.
substance or mixture
Hazardous combustion : Decomposition products may include the following materials:
products carbon dioxide
carbon monoxide
sulfur oxides
metal oxide/oxides

5.3 Advice for firefighters

Special precautions for : Promptly isolate the scene by removing all persons from the vicinity of the incident if
fire-fighters there is a fire. No action shall be taken involving any personal risk or without suitable
training.
Special protective : Fire-fighters should wear proper protective equipment.
equipment for fire-fighters

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures
For non-emergency : No action shall be taken involving any personal risk or without suitable training.
personnel Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilt material. Put on appropriate personal
protective equipment.
For emergency responders : If specialised clothing is required to deal with the spillage, take note of any
information in Section 8 on suitable and unsuitable materials. See also Section 8 for
additional information on hygiene measures.

6.2 Environmental : Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains
precautions and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).

6.3 Methods and materials for containment and cleaning up

Small spill: : Dilute with water and mop up if water-soluble or absorb with an inert dry material and
place in an appropriate waste disposal container.
Large spill : Prevent entry into sewers, water courses, basements or confined areas. Contain
and collect spillage with non-combustible, absorbent material e.g. sand, earth,
vermiculite or diatomaceous earth and place in container for disposal according to
local regulations (see section 13).

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SECTION 6: Accidental release measures

6.4 Reference to other : See Section 1 for emergency contact information.
sections See Section 8 for information on appropriate personal protective equipment.
See Section 13 for additional waste treatment information.

SECTION 7: Handling and storage

The information in this section contains generic advice and guidance. The list of Identified Uses in Section 1 should be
consulted for any available use-specific information provided in the Exposure Scenario(s).
7.1 Precautions for safe handling
Protective measures : Put on appropriate personal protective equipment (see Section 8).
Advice on general : Eating, drinking and smoking should be prohibited in areas where this material is
occupational hygiene handled, stored and processed. Workers should wash hands and face before
eating, drinking and smoking. Remove contaminated clothing and protective
equipment before entering eating areas. See also Section 8 for additional
information on hygiene measures.

7.2 Conditions for safe : Store between the following temperatures: 0 to 40°C (32 to 104°F). Store in
storage, including any accordance with local regulations. Store in original container protected from direct
incompatibilities sunlight in a dry, cool and well-ventilated area, away from incompatible materials
(see section 10) and food and drink. Keep container tightly closed and sealed until
ready for use. Containers that have been opened must be carefully resealed and
kept upright to prevent leakage. Do not store in unlabelled containers. Use
appropriate containment to avoid environmental contamination.

7.3 Specific end use(s)

Recommendations : Not applicable.
Industrial sector specific : Not applicable.
solutions

SECTION 8: Exposure controls/personal protection

The information in this section contains generic advice and guidance. The list of Identified Uses in Section 1 should be
consulted for any available use-specific information provided in the Exposure Scenario(s).
8.1 Control parameters
Occupational exposure limits
Product/ingredient name Exposure limit values
No exposure limit value known.

Recommended monitoring : If this product contains ingredients with exposure limits, personal, workplace
procedures atmosphere or biological monitoring may be required to determine the effectiveness
of the ventilation or other control measures and/or the necessity to use respiratory
protective equipment. Reference should be made to European Standard EN 689 for
methods for the assessment of exposure by inhalation to chemical agents and
national guidance documents for methods for the determination of hazardous
substances.
Derived effect levels
No DELs available.

Predicted effect concentrations

No PECs available.

8.2 Exposure controls

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SECTION 8: Exposure controls/personal protection

Appropriate engineering : No special ventilation requirements. Good general ventilation should be sufficient to
controls control worker exposure to airborne contaminants. If this product contains
ingredients with exposure limits, use process enclosures, local exhaust ventilation or
other engineering controls to keep worker exposure below any recommended or
statutory limits.
Individual protection measures
Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and
safety showers are close to the workstation location.
Eye/face protection : No special recommendations.
(EN 166)
Skin protection
Hand protection : No special recommendations.
(EN 374)
Body protection : Personal protective equipment for the body should be selected based on the task
(EN 14605) being performed and the risks involved and should be approved by a specialist
before handling this product.
Other skin protection : Appropriate footwear and any additional skin protection measures should be
selected based on the task being performed and the risks involved and should be
approved by a specialist before handling this product.
Respiratory protection : A respirator is not needed under normal and intended conditions of product use.
(EN 143, 14387)
Environmental exposure : Emissions from ventilation or work process equipment should be checked to ensure
controls they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process
equipment will be necessary to reduce emissions to acceptable levels.

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties
Appearance
Physical state : Liquid.
Colour : Blue. [Dark]
Odour : Faint odour
Odour threshold : Not determined for the mixture.
pH : 4.5 to 5.5 [Conc. (% w/w): 100%]
Melting point/freezing point : Not determined for the mixture.
Initial boiling point and boiling : Not determined for the mixture.
range
Flash point : > 100°C
Evaporation rate : Not determined for the mixture.
Flammability (solid, gas) : Not determined for the mixture.
Burning time : Not determined for the mixture.
Burning rate : Not determined for the mixture.
Upper/lower flammability or : Not determined for the mixture.
explosive limits
Vapour pressure : Not determined for the mixture.
Vapour density : Not determined for the mixture.
Relative density : 1.015 to 1.035
Solubility(ies) : Easily soluble in the following materials: cold water and hot water.
Partition coefficient: n- : Not determined for the mixture.
octanol/water

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SECTION 9: Physical and chemical properties

Auto-ignition temperature : Not determined for the mixture.
Decomposition temperature : Not determined for the mixture.
Viscosity : Not determined for the mixture.
Explosive properties : Not applicable.
Oxidising properties : None.

9.2 Other information

No additional information.
SECTION 10: Stability and reactivity
10.1 Reactivity : No specific test data related to reactivity available for this product or its ingredients.

10.2 Chemical stability : The product is stable.

10.3 Possibility of : Under normal conditions of storage and use, hazardous reactions will not occur.
hazardous reactions

10.4 Conditions to avoid : No specific data.

10.5 Incompatible materials : No specific data.

10.6 Hazardous : Under normal conditions of storage and use, hazardous decomposition products
decomposition products should not be produced.

SECTION 11: Toxicological information

11.1 Information on toxicological effects
Acute toxicity
Product/ingredient name Result Species Dose Exposure
alcohols, c12-15, LD50 Oral Rat >2000 mg/kg -
ethoxylated propoxylated
Conclusion/Summary : Not determined for the mixture.
Irritation/Corrosion
Product/ingredient name Result Species Score Exposure Observation
alcohols, c12-15, ethoxylated Eyes - Severe irritant Rabbit - - -
propoxylated
Skin - Mild irritant Rabbit - - -
Conclusion/Summary : Not determined for the mixture.
Sensitiser
Conclusion/Summary : Not determined for the mixture.
Mutagenicity
Conclusion/Summary : Not determined for the mixture.
Carcinogenicity
Conclusion/Summary : Not determined for the mixture.
Reproductive toxicity
Conclusion/Summary : Not determined for the mixture.
Teratogenicity
Conclusion/Summary : Not determined for the mixture.
Information on the likely : Not determined for the mixture.
routes of exposure
Potential acute health effects

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SECTION 11: Toxicological information

Inhalation : No known significant effects or critical hazards.
Ingestion : No known significant effects or critical hazards.
Skin contact : No known significant effects or critical hazards.
Eye contact : No known significant effects or critical hazards.
Symptoms related to the physical, chemical and toxicological characteristics
Inhalation : No specific data.
Ingestion : No specific data.
Skin contact : No specific data.
Eye contact : No specific data.
Delayed and immediate effects and also chronic effects from short and long term exposure
Short term exposure
Potential immediate : Not determined for the mixture.
effects

Potential delayed effects : Not determined for the mixture.

Long term exposure
Potential immediate : Not determined for the mixture.
effects
Potential delayed effects : Not determined for the mixture.
Potential chronic health effects
Conclusion/Summary : Not determined for the mixture.
General : No known significant effects or critical hazards.
Carcinogenicity : No known significant effects or critical hazards.
Mutagenicity : No known significant effects or critical hazards.
Teratogenicity : No known significant effects or critical hazards.
Developmental effects : No known significant effects or critical hazards.
Fertility effects : No known significant effects or critical hazards.
Other information : Not determined for the mixture.

SECTION 12: Ecological information

12.1 Toxicity
Product/ingredient name Result Species Exposure
alcohols, c12-15, ethoxylated Acute EC50 1 mg/L Daphnia 48 hours
propoxylated
Acute IC50 0.1 to 1 mg/L Algae 72 hours
Acute LC50 1 to 10 mg/L Fish 96 hours
Conclusion/Summary : Not determined for the mixture.

12.2 Persistence and degradability

Conclusion/Summary : The surfactants contained in the product are biodegradable according to the
requirements of the detergent regulation 648/2004/EC

12.3 Bioaccumulative potential

Conclusion/Summary : Not determined for the mixture.

12.4 Mobility in soil

Soil/water partition : Not determined for the mixture.

coefficient (KOC)
Mobility : Not determined for the mixture.

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SECTION 12: Ecological information

12.5 Results of PBT and vPvB assessment
PBT : Not applicable.
vPvB : Not applicable.

12.6 Other adverse effects : No known significant effects or critical hazards.

SECTION 13: Disposal considerations

The information in this section contains generic advice and guidance. The list of Identified Uses in Section 1 should be
consulted for any available use-specific information provided in the Exposure Scenario(s).
13.1 Waste treatment methods
Product
Methods of disposal : The generation of waste should be avoided or minimised wherever possible. Empty
containers or liners may retain some product residues. This material and its
container must be disposed of in a safe way. Significant quantities of waste product
residues should not be disposed of via the foul sewer but processed in a suitable
effluent treatment plant. Dispose of surplus and non-recyclable products via a
licensed waste disposal contractor. Disposal of this product, solutions and any by-
products should at all times comply with the requirements of environmental
protection and waste disposal legislation and any regional local authority
requirements. Avoid dispersal of spilt material and runoff and contact with soil,
waterways, drains and sewers.
Hazardous waste : Within the present knowledge of the supplier, this product is not regarded as
hazardous waste, as defined by EU Directive 91/689/EEC.
European waste catalogue (EWC)
Waste code Waste designation
20 01 30 detergents other than those mentioned in 20 01 29
Packaging
Methods of disposal : The generation of waste should be avoided or minimised wherever possible. Waste
packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible.
Special precautions : This material and its container must be disposed of in a safe way. Empty containers
or liners may retain some product residues. Avoid dispersal of spilt material and
runoff and contact with soil, waterways, drains and sewers.

SECTION 14: Transport information

ADR/RID ADN/ADNR IMDG IATA
14.1 UN number Not regulated. Not regulated. Not regulated. Not regulated.

14.2 UN proper - - - -
shipping name
14.3 Transport - - - -
hazard class(es)

14.4 Packing - - - -
group
14.5 No. No. No. No.
Environmental
hazards

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SECTION 14: Transport information

14.6 Special None. None. None. None.
precautions for
user

14.7 Transport in bulk : Not applicable.

according to Annex II of
MARPOL 73/78 and the IBC
Code
SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
EU Regulation (EC) No. 1907/2006 (REACH)
Annex XIV - List of substances subject to authorisation
Substances of very high concern
None of the components are listed.
Annex XVII - Restrictions : Not applicable.
on the manufacture,
placing on the market and
use of certain dangerous
substances, mixtures and
articles
Other EU regulations
Ingredient declaration according to detergent regulation 648/2004/EC:

≥5 - <15% non-ionic surfactants

National regulations
Safety, Health and Welfare at Work Act, 2005
European Communities (Classification, Packaging, Labelling and Notification of Dangerous Preparations) Regulations
1995. (S.I. 272 of 1995) as amended
15.2 Chemical Safety : This product contains substances for which Chemical Safety Assessments are still
Assessment required.

SECTION 16: Other information

Indicates information that has changed from previously issued version.
Abbreviations and : ATE = Acute Toxicity Estimate
acronyms CLP = Classification, Labelling and Packaging Regulation [Regulation (EC) No.
1272/2008]
DNEL = Derived No Effect Level
EUH statement = CLP-specific Hazard statement
PNEC = Predicted No Effect Concentration
RRN = REACH Registration Number
Full text of abbreviated H : H315 Causes skin irritation.
statements H319 Causes serious eye irritation.
H400 Very toxic to aquatic life.
Full text of classifications : Aquatic Acute 1, H400 AQUATIC TOXICITY (ACUTE) - Category 1
[CLP/GHS] Eye Irrit. 2, H319 SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2
Skin Irrit. 2, H315 SKIN CORROSION/IRRITATION - Category 2
Full text of abbreviated R : R36/38- Irritating to eyes and skin.
phrases R50- Very toxic to aquatic organisms.
Full text of classifications : Xi - Irritant
[DSD/DPD] N - Dangerous for the environment
Date of printing : 2 March 2011

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SECTION 16: Other information

Date of issue/ Date of : 2 March 2011
revision
Date of previous issue : 1 March 2011
Version : 1
Notice to reader
The above information is believed to be correct with respect to the formula used to manufacture the product in
the country of origin. As data, standards, and regulations change, and conditions of use and handling are
beyond our control, NO WARRANTY, EXPRESS OR IMPLIED, IS MADE AS TO THE COMPLETENESS OR
CONTINUING ACCURACY OF THIS INFORMATION.

Date of issue/Date of revision : 2 March 2011 10/10