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Ghepristry 101 [ CH#4: Reactions in Aqueous Solutions oo Boe Molacity (M)! “setvt olarity (M): olwie. Ny. = mol mn Vsototion (vy Dae Solut % Solution: is a homegenovs mixture < ome Solvent KR Dilution | istheprocess of preparing a less concentroted solution From a more concentrated one. MM = M2V_ ¥ Titration! is addition OF © Solution of Knnwn concentrotion to esother of unknown concentration, #€ Stondonzation! is the determination oF the exact concentrohon of @ solvtian. Precipitation Reoctions: TAT ith, + at at ¥) Be, Ch T Se Ag’) Pb?" Hg E se ott ye at oat pot 2) S04 SB Ast, PET Hg Cal Se" Ba 3) ol OW Sotts except with AlKel) ond Bo™* a) on s* coz, CHOP 2 POU” except with A\Koli ond Mut K Precigttovion reoctions! Equotions: 4 W) mote cules Equowen 2) Complete ionic Equation 3) net {onic Equehon & [we ons osasosiovs Baw jemistry 101 || CH#4: Reactions in Aqueous Sol Acid and Bose Reoctions! # Strong Acids | HE, WBr, WT, HNO, Hy SOg HCO, ROVO y % Strong Boses! LiOH, Nablt, Kot, Bool, Ca(or), (Se (ov), Ba (or), , ¥ Deginition ag Acid one Base’ + Acid produces tk Arrhenius \ Base. produces of Disa proton (W') donor DBronsted apose: proton (y") acceptor & Acid ood Bose! tL) menopro Ke wa , Cor 2) dipottic ye 1 Ulery 2) ari probe yO , Tbs K Strong electrolyte’ strongaad 2X strongbose 2 soluble tonic composts. Oxidotion — Reduckon Reoction (Redox Reoction). % Oxidized —® \osses electrons KR Reducing Agent # Reduced gosas electrons & Oxidizing Agest ¥ Bolowcing Redd¥ Reock ons) Yin acrdic solution! —erile he deo halves of veockian = Bolonce oN elements excegt O = Bolonce © by odding W2O 40 Xhe Olver side $ H* te the otter side, = Bolence signs by adding J to higher sign side = incose of besicl odd Of to woth sides to concel W ions 2) in ne wesic solution! & |n. ona osacosior Sho shemistry 101 | CHi#4: Reactions Types of Redox Reactions: 1. Decomposition Reaction 2NaH — 2Na + Hy 2 Combination Reaction A4Fe+ 30;+2Fe,0; 3. Displacement Reaction CuSO,tZn—Cu+ZnSO, 4. Disproportionation Reactions P.+3NaOH + 3H,O — 3NaH,PO,+ PH; To determine an oxidation number, work through the following rules in the order given, 1. Atoms in their elemental form have an oxidation number of 0. 2. The sum of the oxidation numbers of all the atoms in the species is equal to its total charge. 3. Atoms of group 1: => +1. 4. Atoms of group 2: = +2 5. Hydrogen is > +1 in combination with nonmetals and is = -1 in combination with metals or B 6. Fluorine is always = -1, 7 Oxygen is > -2 unless combined with F = -1 and in peroxides O2* = -1 in superoxides Or = and -1/2 in ozonides Oy- = -1/9 8 Halogens are = -7 in most compounds, except when combined with O or F = positive # & [wn oon osssosrors Chemistry 101 STRONG ELECTROLYTES: 1. Strong acid solution 2. Strong base solution CHi#4: Reactions 3. Soulable ionic compound solution Bao Strong Electrolyte: ‘Weak Electrolyte: ‘Non-Electrolyte: Hydrocarbons, Organic Compound Strong Acid, Strong Base, Tonic | Weak Acid on Base ta (C#H+0), and Alcohol (CH+OH: ‘ompound that is soluble ompound that is insoluble | FCent CHCOOH carboxylle acid) HCI HF CH, ‘NaOH. NE CH 01 ‘NaCl ‘Agcl CeH0¢ KNOs CoHsNE (CH;OH (CH;COOH Which one of the following statements is NOT correct about the electrolytes? A) constituent elements. B) conducts electricity. Q D) E) An electrolyte is a water-soluble substance that dissociates in water to its An electrolyte is a substance that dissolves in water to yield a solution that An electrolyte is a substance that dissociates in water to its constituent ions. All water-soluble ionic compounds are strong electrolytes. Acids that partially ionize in water are weak electrolytes. F_un. oun 05000 Chemistry 101 | CH#4: Reactions in Aqueous Solutions & oe Activity Series: Br Thaw) Element Lithium Potassium Barium Calcium Sodium ‘Magnesium Aluminum Manganese Zine Chromium Iron (Cadmium Cobalt Nickel Tin Lead Hydrogen Copper Silver Mercury Platinum Gold Increasing ease of oxidation ‘Oxidation Halt-Reaction Li Litre K—Ktte Ba—+ Ba* +26” Ca— Ca + 2° Na—— Nate Mg ——> Mg** + 2e~ AL— AP +4 3° Mn—> Mn™ + 2e~ Zn—> Zn* + 20° Cr—+ Crt +32" Fe—> Fe +26” Cd — Ca¥ + 267 Co—+ Co* + 26° Ni—— Ni* +20" Sn— Sn + 2e7 Pb——+ Pb** + 2e~ H,—+ 2H* 4.26" Cu— Cu + 26° Ag—Agt ee Hg——> Hg** + 26" Pt— Pr + 267 Au——+ Au* +327 38) Based on the activity series. which one of the reactions below will occur? A)Fe (s) +ZnCl, (aq) > FeCl (aq) +Zn (8) B) Mn (s)+NiCl,(aq) > MnCl, (aq) +i (s) Pb (6) + Nil, (aq) —> PBI; (aq) +Ni (5) D)SaBr, (aq) +Cu (6) > CuBr (aq) +Sn (9) E) None of the reactions will occur. Chemistry 101 | CH#4: Reac in Aqueous Solutions & oe Based on the following electrochemical activity series, which of the reaction(s) listed below will occur as written? [Note: The ease of oxidation increases fiom bottom to top, ie. Nais the most easily oxidized and Ag is the most difficult to oxidize] L Cols) + Cu @q) —> ? 4 Nas) > Nag +e | TL. 2Ag) + Cu ? £) | rag —» zap + 20- WM Cag) + 2Nas) — ? 3 IV. Co%¥(aq) +2Ag(s)—> ? | | Co) —> Co™(aq + 2e- “4 ian i Hx) ——> 2H(aq) + 2e- C) Wand I only 3 Cus) ——» Cu*(aq) + 2e- D) Tony & E) 1 Wand IV only 4] | As@® —~» agao+e- , [wn ona oseaosion Chemistry 101 | cata Reactions in Aqueous Solutions & oe Calculate the molarity of a solution prepared by dissolving 11.5 g of solid NaOH in enough water to make 1.50 L of solution. iA. 0.192M 0.182 o.112M 0.312M 0.222 M moos mm , HS 20.2876 mole Mean = NS > 2? yy * Zale x Q12. Calculate the concentration of potassium ions. K™. in a 500. ml. solution containing 2.00 g KsP Ou, 1K) 5.65 x10°2M A)3.77x10°M C) 1.88 x10?7M D) 2.83 x107M. E) 141 x107M Veg OEE ”, m 7 Wie ksPo, = > Bro? an” Bendreat Uy age Sob h 1 x. - a ie ok agh = roland J Gena? DS My = TE = 22a Calculate the sodium ion (Na") concentration when 70.0 mL of 3.0 M NaCO3(aq) is added to 30.0 ml. of 1.0 M NaHCOs(aq). A) 45 M B) 0.45M ©) 003M D) 64 M FE) 83M Ag Hele, = OOFL v a f MTZ) DS Mga 2KO.2) 20-92 MUT Ny ra¥ryoe Mean Preees ud wid Blog Coy V = 0.0}+003 = otk ea A 20.03 D Hy? Fm SM sf = Re aM, == EH ms in | tice, Me ne Y Ne Hoos MR. OBAID 0557324624 Aqueous Solutions & oo Calculate the number of moles of CI” ions in 1.75 L of 1.0 X 107? M ZnCl, tA, 3.5x10° mole Cr B. 1.5x 10% mole CI ©. 25x10? mole Cr D. 4.5x10° mole cr E, 05x10" mole cr 3-Ed\0 ve bPee t Be nee ox Ley ele a Me room ‘What volume (in mL) of 0.21 M ammonium sulfate contains 3.07 g of ammonium ions? A) 405 (Nt, ), Soy B) 508 ce Cc) 102 D) 698 E) 203 mM 4= 3079 9 142 2A. ogy DS wig Nad iy M= 0214 ae Q12. How many grams of sodium sulfate NaxSO, are required to prepare a 250. mL w many g i req prep: solution whose concentration is 0.683 M NaySO4? [Molar Mass of Na»SOz = 142.07 g/mol] A) 2439 B) 122g C) 186g D)21g E)US8¢ Vz o2eu f Me Ms 06834 om 2 nahn =t71) [ne 4529 mW) = PATS Wa, Soy MR, OBAID 0557324624 Aqueous Solutions & oe CH#4: Reactions Zine dissolves in hydrochloric acid to yield hydrogen ges: Za(s) + 2HCI(aq) —> ZnCle(aq) + Ha(@) ‘What mass of hydrogen gas is produced when a 7.35 g of zinc dissolves in 500. mL of 1.200M HCI? A) 0.2278 B) 0.453 g C) 0.302g D) 0.113g E) 0.605 g ime 2p DME HCY de ty Bd Vomie Ha fe 2 BEE cone i mle By > ‘ ta” fin 65-38 oe 9 2? ona 3 No 2 Ory, =o Me, ae n= ole oa ee nw 206 RHEL 8s: exces am = beN (OM {2y hmehet * mee Ay "= [RT ‘What volume of 16 © sulfuric acid must be used to prepare 1.5 L of a 0.10 M HsSO, solution? 9.4x108L 84xt08L 7.4x10°L 6.4x10°L 5.4xt08L M,<1G™ My, = Mes BrofH We Sh ‘You have 10.00 L of a 0.350 M KCl stock solution. burt you need a solution that is 0.450 Min KCl. What volume of water. in L. would you evuporate from the stock solution? tA) 21 B) 438L ©) 3.501 D) 2851 E) 7.78L Us Jol M2 03S Vos FREL Me 20.45 14 4 av 210A? aul Yet cvepedey = 18778 ETAT MR. OBAID 0557324624 Which of the following directions correctly describes the preparation of 0.500 L of 0.150 M NaOH from a 6.00 M stock solution? + Dilute 12.5 mL of 6.00 M NaOH to a volume of 0.500 L. Dilute 0.200 L of 6.00 M NaOH to a volume of 0.500 L. Combine 0.200 L of 6.00 M NaOH with 0.500 L of water. Dilute 475 mL of 6.00 M NaOH to a volume of 0.500 L. Combine 12.5 mL of 6.00 MNaOH with 0.500 L of water. Vis age Wet § M22/514 M26M a dilate ta. sm GM te a Vole f ose. A 50.00 mL solution of CaCl: was diluted to 350.0 mL, and 25.00 mL. of this solution was then diluted to 2.000 L. The concentration of the final solution is 0.00333 M. Calculate the concentration of the original solution. A) 1865M B) 0.2664M C) 2331M ai D) 0.4757M Samar Uy 2M isle EB) 0.6660M — diluteet no fs Vz Asmb Meo w=? My =2 “ a, ee ar My=Han >| He MBGIBM Bye yy Mg zo.ace4n 2 He H,0, solution is 30% by mass and has a density of 1.11 g/mL. a.) Determine the molarity of the solution. b.) If 25 mL of this solution is diluted with 75 mL of HyO, what is the final concentration in moles/L of the diluted solution of hydrogen peroxide. Sinie, aes mesg = 189 oe 2 qocqme Lass daily, 2 WHIRL 2.0900] a a 2 Mee, 2 BRLY Ms ee 2 foams 4 By Wy s2S mL MaAPTGSH Ve stmL Mat , | un. on osasosi011 -¢+ Chemistry 101 | CH#4: Reactions in Aqueous Solutions lh ‘Which of the listed chlorides is insoluble in water at room temperature? LA) PbCh B) BaCh, C) CaCh D) MgCh, =) Kc Based on the solubility rules, which one of these compounds should be insoluble in water? ad vA) AgBr B) NaCl C) NaS D) KNOs E) NaxSO; Based on the solubility rules, which one of the following will occur when a 0.1 M Pb(NOs)2 aqueous solution is mixed with a 0.1 M of KI solution? LA) Polo will precipitate; K* and NOx are spectator ions. B) KNOs will precipitate; Pb® and I- are spectator ions. C) No precipitate will form. D) No reaction will occur. E) Pb(NOs)z will precipitate; K* and - are spectator ions. MR. OBAID 0557324624 Chemistry 101 | CH#4: Reactions in Aqueous Solutions & bo Which of the following compounds are likely to be soluble in water: Ni(OH)2, ZnCh, CuS, Fes(COs)3, AgCl, and Pb(NOs).? ia - YZaChend Pb(NO;): only Ni(OH) and ZnCh only Pb(NO3)2 and Fe,(COs); only AgCl and Pb(NOs)2 only ZnCh and CuS only Which one of the following aqueous solutions will react with aqueous potassium chloride to give precipitates? oe kel A) lead(II) nitrate PL (N°), ~ B) calcium chlorate ™ ©) iron(II1) bromide D) barium iodide E) sodium sulfate Give the complete fonic equation for the reaction that occurs when aqueous solutions of lithium sulfide and copper (II) nitrate are mixed, VA) 21K @qg+s* “ed + Cu (aq) +2 NO, (aq) —» CuS(s) +2 Li" (eq) +2 NOs (ea) B) 2Li"(aq) + $O4*(aq) + Cu (aq) + 2NO; (aq) + CuSO.(s) + 2Li"(aq) + ZNO; (aq) © Li @g+s (ea) +Cu( ‘@a) +NO; (aq) > Cus(s) + LiNO,(aq) D) 2Li (aq) +S" (aq) + Cu" (aq) +2NO5 (aq) —+ Cu" (aq) +S*(aq) +2 LINO,s) E) No reaction will occur LiSagy* Cu (Ws, “yy > Cody + Ula OT &. © tomy a + - bi . e Ding + Sey + Crag t 2 M0; wq) 2 CoS, + Bbing, 4 EMO ue, Cempte toe A As — (ikea + Say > Cody, We ion 8 & MR, OBAID 0557324624 CH#4: Reactions in Aqueous Solutions What mass of NaCrOs is required to precipitate all of the silver ions from 75.0 mL. of a 0.100 M solution of AgNO3? 0.603 ae aoe Na, Cg BhaMe, a Aglr a, 4S No, aq) C) 2.43 2 D) 16.2¢ + v ~ bo. E) 7.858 24 + Ga why, bo, ve oor ee 2 mle AS sb ml, Coe Heel AeNoz BOF SM 5 bOI Nz e00sIe a Nyg = NTE oa, Ne Co, se Magee, =a Nearesenuiiey = 0.6083 { Cax(PO4)x(5) zee > ‘caSOus) 4HtsPOsteq) Consider the following unbalanced reaction: a What mass of calcium sulfate will be prodliced from the reaction of 1.0 kg calcium phosphate with 980 g pure sulfuric acid? A ~ A) 13 kg G+ sa 3 GSo, B) 14ke “a (% w C) 16kg D) LT ke E) Likg NW « cy (M05), Seajrawarny 7] > bag, 24-66 me Mp Sera 166 hin 7) 20M O60) M.094 tote M6) Casey " Mesen im 780 = 44 3 ay eee 7 = haneg [3 | ans gz. How tany Bis of silver phosphate will precipitate when 306 mL of a 0.208 M solution of silver nitrate reacts with 146 mL of a 0.170 M solution of sodium phosphate? ‘The balanced reaction is: 3 ABNOs 4g) + NasPO4 (ay APO 9 + 3 NANOS cy A. 8 + i A isa te oe Re A tae 4a Fam dhe tote Ast, WOME n cowoe ) Se T yin (ane 38 a ie So aGil > fe soaya 2 Pay 28-22 SAD linking {0 ents (ERBQY 6 Poy I Bk A sample of 0.720 g of an unknown compound containing barium ions (Ba) is dissolved in water and treated with an excess of NaxSOx, If the mass of the BaSO4 precipitate formed is 0.5041 g. what is the percent by mass of barium in the original unknown compound? Chemistry 101 | CH#4: Reactions in Aqueous S LA) 412% Balk) + 4,50, > NsX + & So B) 25.7% va eZ] mo OQ 39% 2 2 D) 31.8% a + Sop 3 RaSoy E) 84.0% a ry a 2 O.cc22, ” See Bo5iy ~ an vo Pe = Oo02r m my crm = 0.3025 2 %bat Feyt * 16. A 22.02 mL solution containing 1.615 g of Mg(NOs)z is mixed with a 28.64 mL. solution containing 1.073 g NaOH, Calculate the concentration of OH_ ions remaining in the final total solution after the reaction is completed as shown below: a 7 wh A OW Mz(NO3):49)* 2NOOK ag) + Mg(OHD 2) + 2NGNO sa cern ‘ x [Molar Masses of Mg(NO3)2 and NaOH are148.33 g/mol and 39.998 g/mol. respectively). 1b A) 0.09968 M n = 4009 hi idl nlog, B) 0.00M Moller), ~ fab ~ e431 2(teeI43(G) my ©) 0.4298 M D) 0.005050M =n a7 lers oy = ee STS kg ane D2 > Oste® E) 0.04298 M Wao my a . 55 oh bk 1h a3 tm 0-0/0F « Pn 2 2 7 age Oe21B fe OH TS extess ei ao oor 0+ 0268-0. ot1% 20-005 > Me comet pea iM What is (are) the spectator ion(s) in the reaction between Mg(OH)2(aq) and HCI(aq)? h ie | Mg” and cr B) Mg ar 9° D) E) Chemistry 101 & ae ‘What volume of 0.0200 M Ca(OH); is required to neutralize 35.00 mL of 0.0500 M HNO;? A) 43.8mL Base. hed B) 175 mL. 7 C) 875 mL aly, ANI, D) 65.3 mL Ves5mb 00035L E) 120 mL 205 f Shp. yp, SHV = 0:08 05 2 nyt = 2:00 ng o.oo A 0.845 g sample of an unknown diprotic acid requires 26.66 mL of 0.117 MNaOH to be completely neutralized. Calculate\the approximate molar mass of the acid? LA) 542 g/mol LT B) 341 g/mol ©) 641 g/mol Acta Sess 271 g/mol _ Na “y 135 ai a) Yi 2G Lome = 0-2666L mn 208459 eee hee ATS septs ng yy soe ool Rap = O02 = Ny en 22888 2 cap ice i = 6.74 g of the monigrate acd RHP (Molar mass = 204.2 gimol) was dissolved into water. The sample was then tiated with a 0.703 M solution of calcium hydroxide to the equivalence pont. What volume of base was used? A) 23.5 mL B) 118mL Acta tae ©) 47.0 mL ku @ OW, ara me 6.79 A M ze.toty 7 Mz 284, 23/ma) vel shea! yp = 20-088 ere = Woy = a ZORS 7 Bk x A solution of 0.13110 g of potassium hydrogen phthalate (KHCsHiOs) in water required 27.2 mL of a calcium hydroxide (Ca(OH):) solution to be neutralized. The molarity of the Ca(OH): solution is: tA) 0.0118 M Chemistry 101 | CH#4: Reactions in Aqueous Solut B) 0.0236 M C) 0.0472 M D) 0.00390 M E) 0.118 M “4 | n m ofS ¥ He = = 2 ———_____—_—____. . 6.4 Sy Wy SAAMIo =n KuGihs, * Wn Saya Beer) NS > Mir cr “4 4 62x 2 3°21 Nie n e = GOW) = y a Pere oom. 2. Ee ona mane #-Q14. An aqueous solution containing 2.20 g sample of an unknown acid which has one acidic proton per molecule required 25.0 mL of 0.500 M NaOH to react completely. Calculate the molar mass of the acid. A) 176 gimol B) 27.5 g/mol C) 55.0 g/mol D) 89.0 g/mol E) 124 g/mol eee 2 asne aslee =" Me oS T Mast Mg = Oeste (me) m oye 2 Ey (MN IC aIma v ne BD Peng Nay Ine | Calculate the concentration of acid or base remaining in solution when 10.7 mL of 0.211 M HNOs is added to 16.3 mL of 0.258 M NaOH. LA) 0.0721M B) 0.0270M ©) 0.0268 M D) 0.0421M E) 0.0195M 2 WACKiD-22CENe 21 E mS" -2 ve eslOFL 2 y 2 2258 xX16 m2 o-2 my HNoq =2 A Mg 2 Q2cex v res ofeae, a ane Hz dH MR. OBAID 0557324624 ry 101_j CH#4: Reactions in Aqueous Solutions 26.7 mL of a 0.15 M aqueous solution of barium hydroxide are required to reach the end point in a titration of 17.3 mL of an aqueous phosphoric acid. What is the molarity of the phosphoric acid solution? =, 0. LA) 015M Ba(ch), 3P%s B) 018M ©) 0072M D) 0.077M E) 023M Vz 0ateR LD yy corxte ws 215 MY eaten, 3 2 2x WOKE a2 2 GojXw = M+ Yom ing agent in the following oxidation-reduction reaction is. 2Mn0j' + 5H)SO3 > 2Mn™* + 5S0,? + 4H” + 3E0 A) Mandy B) HaSO3 C) Mn™ D) soe EH eee + 54 49H + Bho Z\o 4 wk fone ee ag] a Mois wedlacen Had) is oniclveing agent Mas In the reaction. 16H™ + 2MnO.- + 10Br~ + SBm + 2Mn* + gH:0 The reducing agent is: LA) Bro B) Br ©) MnO D) Ho ae » - #, Bt Lge 108 9 5h 02H tlhe wH > J oe rr tl > ci Ig oxidliacd 3 BF fs redhdy agent a: ox ep a & MR, OBAID 0557324624 Chemistry 101 | CH#4: Reactions in Aqueous Solut Identify the reducing agent in the following reaction: 2 NO,(g) + 7 Hy(g) — 2 NHj(g) + 4 H,O(g) cA) HZ B) NOz ©) NH3 D) 20 8 +e E) There is no reducing agent. <3t 7 ° + WO 3 23 5 2 ils + he 2NQ + ane NO, fy oxic eng agent: Hy is erinciay ope Ne erta | oa is wdaced n Hi oxide fm His exelieeo Which compound in the reaction below undergoes reduction? SOx(g) + H20(1) + H2SOs(aq) ©None of the compounds is reduced ec H,0 HaSO3 ate both SO and Hx SO; s In which of the following does the chlorine atom (C1) have an oxidation number of’ +52 A) Clos cro,” B) Hcl < ©) clo- ey 2-t D) Helos haat E) Ci es) & [we oon osacostors Chemistry 101 | CHi#4: Reactions in Aqueous Solutions & ry ae QUO. Arrange the following species in order of increasing oxidation number of sulfur atom. 0 + 6 Ss, HRS. $05 5 Gi cor =) 7 6, 2A) HiS < Sp < SOs Sa Ms oar B) S3 NHs(g) + 2Al0¥ (aq). Which of the following statements is comeet? A) Alis a reducing agent. B) NOs is a reducing agent, C) HO is an oxidizing agent. D) OH isa reducing agent. E) The oxidation state of N in NOs is ~ He ey ens xed ie 2 Alo, oH rho + NOt ea 9 We FP Y ¥ “34 —~ Pi TV ge BOF a . he NS. 1S cxtshresng agree Ne onl | Mis Melee i os Ce Al i exelge f PAI Is exiclined SAL IS N ‘Which one of these equations does not represent an oxidation-reduetion reaction? A) 2NaCl+ P(NO;); >[PLCI]+2NaNO; B) 3Al+6HC1— 3H) + AIC re e:\pitrtion veae fin prep ©) 2hO > 2H) +0; D) 2Nal+ Br) 2NaBr+b E) Cu(NOs)2 + Zn + Zn(NOs))+ Cu &% [wr oun osaaosro%1 emistry 101 | CH#4: Reactions in Aqueous Solutions & bo QUI. When the following oxidation-reduction reaction that occurs in basic solution is balanced. aa MaOy + ClOy -» MnO» + ClO, the sum of all coefficients of the products and reactants is, L520 - - — Bewve i a ae YMno, ClO, = > YMnd, 810) alk ©)24 ne D)25 ate fi eer ea <6. SOM OL HIG. Cts see B) 30 ne, , 2h 1+ Mno guy MO + 2h 5 x@ 4 %, a > »*@) © Ss GS = 2 cloy 44H 4 ue = oo BEG 6 lets 3c + OHS 4 H,0,4 SID > 7e05, pete When the following on Gation-reduction reaction that occurs in basie solution is balanced, the mole ratio of S*(aq) to H20() is, 4: se Rete 2 % MnO 4 (aq) + $?(aq) >MnS(s) + S(s) t/ _ 4, as 14 + 20g Oe ans 1SU6 tH yor C) 7/2 = as S- fa | D) 13 { (ho rtd OF “Oh s +05, BH} E) 2/5 — — 2678 5 Mog — > nS + Me AP Som S S D> S$ +e xt ze , pei» 2a FS—D EMS + EMO ers INET + ok +hoH The oxidation-reduction reaction, Ch (g) — Cl-(aq) + OCI-(aq) wt . D> oceurs in abasic medium. On balancing this reaction the sum of the stoichiometric gif coefficients ofall the reactants and products is: = A) 6 Bas lery as 4 ( eg > oe a wikes os a D) 5 Se 57 Ze+Ci, sec) o +26 2the Cl, —20CT + 4H 2Cl, ¢ 2H9 > Ae +2 OT aie MR. OBAID 0557324624 istry 101_| CH#4: Reactions in Aqueous Solutions 17. Identify the Bronsted base in the following equation: Pri-on(H') accepter . HBr (aq) +NO> (aq) — HNOz(aq)_ + Br (aq) LA) NOx (aq) B) HBr (aq) C) HNOx(aq) D) Br (aq) E) none of the above Which of the followings is a weak base? vA) NHs B) NaOH C) HC2H302 D) KOH E) HCl 19, Which one of the following compounds is a strong electrolyte? A) NaF B) MgCO3 C) NEB D) HE E) PbBn Blk MR. OBAID 0557324624 Which one of the following compounds is a strong electrolyte in aqueous solution? LA) NaCl B) HF C) NE D) HO E) HCHO» (acetic acid) The following three reactions: 1, Pb2+42I- > Pblg 2, 2Ce4+ +21 Ip + 2Ce3+ 3. CHsCO:H + NH3 —> NH4+ + CHsCOr are examples of iA) precipitation, redox, and acid-base reactions, respectively. B) acid-base reactions. ©) precipitations. D) precipitation, acid-base, and redox reactions, respectively. E) redox, precipitation, and acid-base reactions, respectively. ‘Three different substances, A2X, A2Y, and A2Z, were dissolved in water with the following results. (Water molecules are omitted for clarity.) Which of the substances is the strongest electrolyte, and which is the weakest? Select the correct statement: Po io ese ° & ® 5 0 o @ Bl1%0 ® AQX AY Agz LA) A2Zis the strongest electrolyte and A2Y is the weakest electrolyte, B) ApX is the strongest electrolyte and A2Y is the weakest electrolyte. C) AY is the strongest electrolyte and A2X is the weakest electrolyte. D) A2V is the strongest electrolyte and A2Z is the weakest electrolyte. E) A2Z is the strongest electrolyte and AX is the weakest electrolyte. MR. OBAID 0557324624 . a 4h * “GheruiStry 101 | CH#4: Reactions in Aqueous Solutions & esos 0544081911 PERIODIC TABLE OF THE ELEMENTS cove VU He ins 10 Ne sa B 24 | 25 Cr | Mn 42 Mo 3 106 58 *Ce 90 “Th mot CH#4: Reactions in Aqueous Solu

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