Chemistry 9th CH 6
Chemistry 9th CH 6
Chemistry 9th CH 6
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SOLUTIONS
(Topic Wise Questions)
Q1. Write note on:
(a) Solution (b) Solute (c) Solvent
Ans: Solution:
A solution is a homogenous mixture of two or more than two substances the composition of which may
be varies within definite limits. In solution the composition and appearance of all parts are uniform and
there are no visible boundaries between the components of solution particles. The components of the
solution are atoms, ions and molecules. Solution are existing in three physical states in solid, liquid and
in gaseous form.
Example:
i. Gas solution: Air ii. Liquid Solution: Sea water iii. Solid Solution: Brass
Solute:
The component present in smaller proportion in a solution and dissolved in a solution is called solute.
It may exist in three physical states solid, liquid and gaseous form.
Examples:
Solid solute = in steel carbon is a solute
Liquid solute = in sea water salt is solute
Gas solute = in air O2 and CO2 are solute
Solvent:
The component present in the larger proportion in a solution and dissolved the solute is called solvent.
It may also exist in three physical state solid, liquid and gas.
Solid solvent = in steel iron is a solvent
Liquid solvent = in sea water, water is a solvent
Gas solvent = in air N2 are solvent.
Q2. Define the following:
i. Aqueous Solution ii. Binary Solution
iii. Dilute Solution iv. Concentrated Solution
Ans: Aqueous Solution:
The word aqueous is taken from “aqua” aqua means water. A solution in which water is used as a
solvent is called aqueous solution. In short cut way it is represented by (aq)
Examples:
Aqueous solution of Nacl is represented as NaCl (aq) similarly H2SO4 (aq), HCl (aq), NaOH (aq) etc.
Binary Solution:
Binary means two a solution which has two components one is solute and the other is solvent.
Examples:
i. NaCl + Water ii. Sugar + Water
Dilute Solution:
A solution in which less amount of solute is dissolved in a definite amount of solvent is called dilute
solution. In a short cut way, it is represented by “dil”
Examples:
Dilute solution of NaCl is represented as “NaCl (dil)”
Similarly, H2SO4 (dil) etc.
Concentrated Solution:
A solution in which more amount of solute is dissolved in a definite amount of solvent is called
concentrated solution.
Hence in a short cut way it is represented by “conc”
Examples:
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3 They cannot be separated on They cannot be separated Their particles are settling down
standing for long time on standing for ling on standing.
timing.
4 They cannot be separated by They cannot be separated They can be separated by
filtration. by filtration filtration
5 They do not scatter light They scatter light They may scatter light, but are
showing the Tyndall not transparent
effect
6 Their particles are so small that Their particles are big but Their particles are big enough to
they can’t be seen with naked can’t be seen with naked be seen with naked eye.
eye eye.
7 e.g. table salt in water e.g. milk in water e.g. flour in water
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SOLUTIONS
the solution increase. A greater number of solute molecules escape from the attraction of solvents
molecules and return to gas phase. At higher temperature, gases are generally less soluble.
The effect of temperature on the solubility of solids and liquids is more difficult to predict. It is often
observed that solubility of many solutes in solution generally increases with the increase in temperature,
but this not always happens. When a solute is added into solvent, there are different possibilities with
respect to temperature.
These possibilities are given below:
i. The solubility of some solutes in solution generally increases with the increase in temperature. For
example, the solubility of potassium nitrate (KNO3), CaCl2 and Pb (NO3)2.
ii. The solubility of some solutes decreases also with the increase in temperature. For example,
Ce2(SO4)3, Li2CO3 and CaO.
iii. The solubility of the NaCl and KBr is not affected by increase or decrease in temperature and
remains constant.
iv. The solubility of some solids increases up to a certain temperature and then decrease (Na2SO4.
10H2O) at 32.40C. Above this temperature, it forms anhydrous Na2SO4. The maximum solubility of
Sodium Sulphate is 32.40C.
Pressure:
Since solids and liquids are incompressible therefore the solubilities of solids and liquids are not
affected by changing the pressure. Solubility of gases increases with the increase in pressure.
Example:
CO2 is filled in soda water bottles under 4 atmospheric pressure. When a bottle of soda water is opened,
CO2, comes out with effervescence (bubbles) because pressure in the bottle is released and reduced to 1
atm resulting in decrease in the solubility of the gas.
Nature of solvent:
When the molecules of solute are similar in structure and properties to the molecules of the solvent, the
solubility is greater because “like dissolve like”.
For example:
Sodium chloride is an ionic compound. It has greater solubility in a polar solvent like water but low
solubility in a non-polar solvent like benzene.
Nature of Solute:
It also affects the solubility, if a solute is changed in the same solvent, the solubility changes. If a solute
is changed and solvent remain the same, the solubility also changes.
For example, sodium chloride has high solubility in water and sugar has comparatively low solubility.
“Like dissolve like” is the general principle of solubility. It means that:
i. The ionic and polar substances are soluble in polar solvents. Ionic solids and polar covalent compound
are soluble in water.
For example, Nacl, Kcl, Na2CO3, sugar, glucose and alcohol are soluble in water.
ii. Non-polar substances are not soluble in polar solvents. Non-polar covalent compounds are insoluble
in water such as benzene and petrol is insoluble in water.
iii. Non-polar covalent substances are soluble in non-polar solvents. Grease, paints are soluble in petrol,
ether or carbon tetrachloride etc.
Q3. a. What is the difference between a concentrated and dilute solutions? Give example of each.
Ans: a. Difference between a concentrated and dilute solutions:
Dilute Solution:
A solution in which less amount of solute is dissolved in a definite amount of solvent is called
dilute solution. In a short cut way it is represented by “dil”.
Example:
Dilute solution of NaCl is represented as “NaCl (dil)”.
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Now mixing of a little amount of sugar in glass of water, When the sugar is mixed into the glass, it
dissolved completely, which means that the individual particles of sugar cannot be seen in water. Hence
the mixture of sugar in water is a solution because:
i. It forms a homogenous mixture which has uniform composition.
ii. The sugar cannot be seen in glass of water by naked eyes.
iii. Sugar cannot be separated from water easily by means of simple mechanical methods. The only
separation method is mostly used is distillation.
Q5. Explain the following concentration units.
a. Percentage composition b. Molarity
Ans: a. Percentage composition:
The percentage composition of a solution can be expressed as:
i. Percentage Mass by Mass (Mass-Mass Relationship m/m):
It is the number of grams by mass of solute present in 100 grams by mass of a solution.
For example, 10% solution by mass means, 10 gram of sugar inn 90 grams of solvent, so that solution
weight 100 grams.
𝑚𝑚𝑚𝑚𝑚𝑚𝑚𝑚 𝑜𝑜𝑜𝑜 𝑠𝑠𝑠𝑠𝑠𝑠𝑠𝑠𝑠𝑠𝑠𝑠 (𝑔𝑔)
%mass / mass = (𝑔𝑔)+
x 100
𝑀𝑀𝑀𝑀𝑀𝑀𝑀𝑀 𝑜𝑜𝑜𝑜 𝑠𝑠𝑠𝑠𝑠𝑠𝑠𝑠𝑠𝑠𝑠𝑠 𝑚𝑚𝑚𝑚𝑚𝑚𝑚𝑚 𝑜𝑜𝑜𝑜 𝑠𝑠𝑠𝑠𝑠𝑠𝑠𝑠𝑠𝑠𝑠𝑠𝑠𝑠 (𝑔𝑔)
𝑚𝑚𝑚𝑚𝑚𝑚𝑚𝑚 𝑜𝑜𝑜𝑜 𝑠𝑠𝑠𝑠𝑠𝑠𝑠𝑠𝑡𝑡𝑒𝑒 (𝑔𝑔)
%mass / mass = x 100
𝑀𝑀𝑀𝑀𝑀𝑀𝑀𝑀 𝑜𝑜𝑜𝑜 𝑠𝑠𝑠𝑠𝑠𝑠𝑠𝑠𝑠𝑠𝑠𝑠𝑠𝑠𝑠𝑠 (𝑔𝑔)
ii. Percentage mass by volume (Mass-volume relationship m/v):
It is the number of grams by mass of solute present in 100 cm3 of solution.
For example, 10% solution of Nacl in solvent to make 100 cm3 of the solution. In this case, the total
mass of the solution is not considered.
𝑚𝑚𝑚𝑚𝑚𝑚𝑚𝑚 𝑜𝑜𝑜𝑜 𝑠𝑠𝑠𝑠𝑠𝑠𝑠𝑠𝑠𝑠𝑠𝑠 (𝑔𝑔)
% volume / mss = 3 × 100
𝑣𝑣𝑣𝑣𝑣𝑣𝑣𝑣𝑣𝑣𝑣𝑣 𝑜𝑜𝑜𝑜 𝑠𝑠𝑠𝑠𝑠𝑠𝑠𝑠𝑠𝑠𝑠𝑠𝑠𝑠𝑠𝑠 (𝑐𝑐𝑐𝑐)
iii. Percentage volume by mass (volume – mass relationship v/m):
It is the volume in cm3 of a solute dissolved in 100 grams of the solution.
For example, 10% solution of Alcohol by volume means, 10 cm3 of Alcohol in (unknown) volume of
water so that the total mass of the solution in 100 grams of solvent. In this case the total volume of the
solution is not considered.
𝑣𝑣𝑣𝑣𝑣𝑣𝑣𝑣𝑣𝑣𝑣𝑣 𝑜𝑜𝑜𝑜 𝑠𝑠𝑠𝑠𝑠𝑠𝑠𝑠𝑠𝑠𝑠𝑠 (𝑐𝑐𝑚𝑚3 )
% volume / mass = x 100
𝑣𝑣𝑣𝑣𝑣𝑣𝑣𝑣𝑣𝑣𝑣𝑣 𝑜𝑜𝑜𝑜 𝑠𝑠𝑠𝑠𝑠𝑠𝑠𝑠𝑠𝑠𝑠𝑠𝑠𝑠𝑠𝑠 (𝑔𝑔)
iv. Percentage volume by volume (volume – volume Relationship v / v):
It is the volume in cm3 of solute dissolved per 100 cm3 of the solution.
For example, 10% solution of alcohol by volume means, 10 cm3 of alcohol in sufficient volume of
solvent, so that volume of solution is 100 cm3.
𝑣𝑣𝑣𝑣𝑣𝑣𝑣𝑣𝑣𝑣𝑣𝑣 𝑜𝑜𝑜𝑜 𝑠𝑠𝑠𝑠𝑠𝑠𝑠𝑠𝑠𝑠𝑠𝑠 (𝑐𝑐𝑚𝑚3 )
% volume / volume = x 100
𝑣𝑣𝑣𝑣𝑣𝑣𝑣𝑣𝑣𝑣𝑣𝑣 𝑜𝑜𝑜𝑜 𝑠𝑠𝑠𝑠𝑠𝑠𝑠𝑠𝑠𝑠𝑠𝑠𝑠𝑠𝑠𝑠 (𝑐𝑐𝑚𝑚3 )
b. Molarity:
Molarity is the number of moles of solute present in one dm3 of the solution. It is defined as the
number of moles of solutes dissolved per dm3 of solution. Molarity is represented by M.
𝑁𝑁𝑁𝑁𝑁𝑁𝑁𝑁𝑁𝑁𝑁𝑁 𝑜𝑜𝑜𝑜 𝑚𝑚𝑚𝑚𝑚𝑚𝑚𝑚𝑚𝑚 𝑜𝑜𝑜𝑜 𝑠𝑠𝑠𝑠𝑙𝑙𝑙𝑙𝑙𝑙𝑙𝑙
M= 3
𝑣𝑣𝑣𝑣𝑣𝑣𝑣𝑣𝑣𝑣𝑣𝑣 𝑜𝑜𝑜𝑜 𝑠𝑠𝑠𝑠𝑠𝑠𝑠𝑠𝑠𝑠𝑠𝑠𝑠𝑠𝑠𝑠 𝑖𝑖𝑖𝑖 𝑑𝑑𝑚𝑚 𝑜𝑜𝑜𝑜 𝑙𝑙𝑙𝑙𝑙𝑙𝑙𝑙𝑙𝑙
By definition
𝐴𝐴𝐴𝐴𝐴𝐴𝐴𝐴𝐴𝐴𝐴𝐴 𝑜𝑜𝑜𝑜 𝑠𝑠𝑠𝑠𝑠𝑠𝑠𝑠𝑠𝑠𝑠𝑠 𝑖𝑖𝑖𝑖 𝑔𝑔𝑔𝑔𝑔𝑔𝑔𝑔
Mole =
𝑀𝑀𝑀𝑀𝑀𝑀𝑀𝑀𝑀𝑀𝑀𝑀𝑀𝑀𝑀𝑀𝑀𝑀 𝑤𝑤𝑤𝑤𝑤𝑤𝑤𝑤ℎ𝑡𝑡 𝑜𝑜𝑜𝑜 𝑠𝑠𝑠𝑠𝑠𝑠𝑠𝑠𝑠𝑠𝑠𝑠
So molarity can also be given as:
𝐴𝐴𝐴𝐴𝐴𝐴𝐴𝐴𝐴𝐴𝐴𝐴 𝑜𝑜𝑜𝑜 𝑠𝑠𝑠𝑠𝑠𝑠𝑠𝑠𝑠𝑠𝑠𝑠 𝑖𝑖𝑖𝑖 𝑔𝑔𝑔𝑔𝑔𝑔𝑔𝑔
M=
𝑀𝑀𝑀𝑀𝑀𝑀𝑀𝑀𝑀𝑀𝑀𝑀𝑀𝑀𝑀𝑀𝑀𝑀 𝑤𝑤𝑤𝑤𝑤𝑤𝑤𝑤ℎ𝑡𝑡 𝑜𝑜𝑜𝑜 𝑠𝑠𝑠𝑠𝑠𝑠𝑠𝑠𝑠𝑠𝑠𝑠 𝑥𝑥 𝑣𝑣𝑣𝑣𝑣𝑣𝑣𝑣𝑣𝑣𝑣𝑣 𝑜𝑜𝑜𝑜 𝑠𝑠𝑠𝑠𝑠𝑠𝑠𝑠𝑠𝑠𝑠𝑠𝑠𝑠𝑠𝑠 𝑖𝑖𝑖𝑖 𝑑𝑑𝑚𝑚3 𝑜𝑜𝑜𝑜 𝑙𝑙𝑙𝑙𝑙𝑙𝑙𝑙𝑙𝑙
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SOLUTIONS
(Short Questions Answers)
Q1. Is sea water a solution? How would you prove with a simple experiment whether it is pure
water or solution?
Ans: Yes, sea water is a solution of salts in water. We can differentiate between pure water and
solution by doing two simple experiments.
Experiment 1:
As we know that pure water is tasteless. Now simply taste a little water from sea. If it is tasteless
it is pure and if it has a taste then it is a solution.
Experiment 2:
Pure water is bad conductor of electricity. Now take a sample of water from the sea, allow the
current through the water. The current will passed “it means that the sea water is solution”.
Q2. A bottle in a drug store contains a label “3 percent Hydrogen peroxide”. What does it
mean?
Ans: It shows the percentage composition of Hydrogen peroxide solution i.e. percentage volume by
volume. 3 % Hydrogen peroxide by volume means 3 cm3 of Hydrogen peroxide in sufficient volume of
solvent, so that volume of solution in 100 cm3 i.e. 3% of hydrogen peroxide dissolve in 97% of water by
volume-volume composition.
Q3. Classify the following as a solution, colloids or suspension and explain why:
i. Milk ii. Hot cup of tea iii. Orange juice with pulp iv. Mayonnaise
v. Listerine mouthwash vi. Milk of Magnesia v. Cheese viii. Mist
ix. Bottled water
Ans:
SOLUTIONS COLLOIDS SUSPENSION
Listerine mouthwash bottled Milk Orange juice with pulp
water Hot cup of tea
Mayonnaise
Milk of magnesia
Cheese
Mist
Reason:
i. Solution is homogenous mixture of two or more components. Listerine mouthwash and Bottled water
are homogenous mixtures so they are solution.
ii. Colloids is solution in which particles are intermediate in size between those in solutions and
suspensions. Milk, Hot cup of tea, Mayonnaise, Milk of magnesia, Cheese and Mist have larger solute
particles than true solution but not enough than suspension so they are colloids.
iii. Suspension is a heterogeneous mixture of undissolved particles in a given medium. The solute
particles of Orange juice with pulp can be seen with naked eyes so it is suspension.
Q4. Why we stir paints thoroughly before using it?
Ans: Paint is a colloid, made of many components like pigments, colour in solvent. The solute
particles of paint are not homogenized with the solvent so, it is better to stir paints thoroughly with the
stirrer to get a uniform composition. By using it will cover the surface uniformly. So that’s why we stir
paints before using it.
Q5. Why suspension and solution do not show Tyndall effect, while colloids do?
Ans: When light is scattered by colloidal particles dispersed in a transparent medium is called Tyndall
effects.
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Reason:
In case of Colloids:
In colloids solute particles are intermediate in size between those in solutions and suspensions.
Hence the particles size is large comparable to that of wavelength of light. That’s the light rays are
scattered and produce Tyndall effect.
In case of Suspension:
In suspension the solute particles are large in size even they can be seen with naked eyes and the
wavelength of the visible is smaller than the solute particles. They block the light rays instead of
scattering it and hence do not shows the Tyndall effect.
In case of solution:
Solutions are the homogenous mixture of two or more substance in which the solute particles are
very small than the wavelength of the visible light. Due to very small solute particles the light rays are
passed in straight line without showing the Tyndall effect.