Conforms: GHS (rev 6) (2015)

(This Safety Data Sheet conforms to the requirements of the Hazard Communication Standard (HCS)
(29 CFR 1910.1200(g)), revised in 2012.) - United States

Date of issue/ Date of revision : 02/19/2021

Date of previous issue : 00/00/0000
Version : 1.0

SAFETY DATA SHEET

Urea Liquid 40%

Section 1. Identification
GHS product identifier : Urea Liquid 40%
Product type : Liquid
Product code : PA50NL

Uses
Area of application : Professional applications
Material uses : Fertilizers.

Supplier
Supplier's details : Yara North America, Inc.

Address
Street : 100 North Tampa Street, Suite 3200
Postal code : 33602
City : TAMPA
Country : United States

Telephone number : +1 813 222 5700

Fax no. : +1 813 875 5735
e-mail address of person : [email protected]
responsible for this SDS
Emergency telephone number : US: Chemtrec 24-hours Emergency Response: 1-800-424-
(with hours of operation) 9300
Canada: 24 Hour Emergency Service, CHEMTREC 1-800-
424-9300

National advisory body/Poison Center

Name : The National Poisons Emergency number
Telephone number : 1 800 222 1222

Section 2. Hazards identification

OSHA/HCS status : This material is not considered hazardous by the OSHA
Hazard Communication Standard (29 CFR 1910.1200).

Classification of the : Not classified.

substance or mixture.
 Urea Liquid 40%

GHS label elements

Signal word : No signal word.

Hazard statements : Not applicable.

Precautionary statements
General : Not applicable.

Hazards not otherwise : None known.

classified
Additional information : None.

Section 3. Composition/information on ingredients

Substance/mixture : Mixture

Ingredient name CAS number %

Ammonia 7664-41-7 >= 0.1- <=0.2

Any concentration shown as a range is to protect confidentiality or is due to batch variation.

There are no additional ingredients present which, within the current knowledge of the supplier
and in the concentrations applicable, are classified as hazardous to health or the environment
and hence require reporting in this section.
Occupational exposure limits, if available, are listed in Section 8.

Section 4. First aid measures

Description of necessary first aid measures
Eye contact : Rinse with plenty of running water. Check for and remove any
contact lenses. Get medical attention if irritation occurs.
Inhalation : Avoid inhalation of vapor, spray or mist. If inhaled, remove to
fresh air. Get medical attention if you feel unwell.
Skin contact : Wash with soap and water. Get medical attention if irritation
develops.
Ingestion : Wash out mouth with water. If material has been swallowed
and the exposed person is conscious, give small quantities of
water to drink. Get medical attention if adverse health effects
persist or are severe.

Most important symptoms/effects, acute and delayed

Potential acute health effects
Eye contact : No known significant effects or critical hazards.
Inhalation : Exposure to decomposition products may cause a health
hazard. Serious effects may be delayed following exposure.
Skin contact : No known significant effects or critical hazards.
Ingestion : No known significant effects or critical hazards.

Over-exposure signs/symptoms
Eye contact : No specific data.
Inhalation : No specific data.
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 Urea Liquid 40%

Skin contact : No specific data.

Ingestion : No specific data.
Indication of immediate medical attention and special treatment needed, if necessary
Notes to physician : Treat symptomatically. Contact poison treatment specialist
immediately if large quantities have been ingested or inhaled.
In case of inhalation of decomposition products in a fire,
symptoms may be delayed. The exposed person may need to
be kept under medical surveillance for 48 hours.
Specific treatments : No specific treatment.
Protection of first-aiders : No action shall be taken involving any personal risk or without
suitable training.

See toxicological information (Section 11)

Section 5. Fire-fighting measures

Extinguishing media
Suitable extinguishing media : Use an extinguishing agent suitable for the surrounding fire.
Unsuitable extinguishing : None identified.
media
Specific hazards arising from : In a fire or if heated, a pressure increase will occur and the
the chemical container may burst.
Hazardous thermal : Decomposition products may include the following materials:
decomposition products nitrogen oxides, ammonia, Avoid breathing dusts, vapors or
fumes from burning materials., In case of inhalation of
decomposition products in a fire, symptoms may be delayed.

Special protective actions for : Promptly isolate the scene by removing all persons from the
fire-fighters vicinity of the incident if there is a fire. No action shall be taken
involving any personal risk or without suitable training.
Special protective equipment : Fire-fighters should wear appropriate protective equipment
for fire-fighters and self-contained breathing apparatus (SCBA) with a full
face-piece operated in positive pressure mode.

Section 6. Accidental release measures

Personal precautions, protective equipment and emergency procedures
For non-emergency personnel : No action shall be taken involving any personal risk or without
suitable training. Evacuate surrounding areas. Keep
unnecessary and unprotected personnel from entering. Do not
touch or walk through spilled material. Provide adequate
ventilation. Wear appropriate respirator when ventilation is
inadequate. Put on appropriate personal protective equipment
(see Section 8).

For emergency responders : If specialized clothing is required to deal with the spillage, take
note of any information in Section 8 on suitable and unsuitable
materials. See also the information in "For non-emergency
personnel".

Environmental precautions : Avoid dispersal of spilled material and runoff and contact with
soil, waterways, drains and sewers. Inform the relevant
authorities if the product has caused environmental pollution
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 Urea Liquid 40%

(sewers, waterways, soil or air).

Methods and materials for containment and cleaning up

Small spill : Stop leak if without risk. Move containers from spill area. Dilute
with water and mop up if water-soluble. Alternatively, or if
water-insoluble, absorb with an inert dry material and place in
an appropriate waste disposal container. Dispose of via a
licensed waste disposal contractor.
Large spill : Stop leak if without risk. Move containers from spill area.
Prevent entry into sewers, water courses, basements or
confined areas. Wash spillages into an effluent treatment plant
or proceed as follows. Contain and collect spillage with non-
combustible, absorbent material e.g. sand, earth, vermiculite or
diatomaceous earth and place in container for disposal
according to local regulations (see Section 13). Dispose of via
a licensed waste disposal contractor. Note: see Section 1 for
emergency contact information and Section 13 for waste
disposal.

Section 7. Handling and storage

Precautions for safe handling

Not for human or animal consumption.

Protective measures : Put on appropriate personal protective equipment (see

Section 8).
Advice on general : Eating, drinking and smoking should be prohibited in areas
occupational hygiene where this material is handled, stored and processed.
Workers should wash hands and face before eating, drinking
and smoking. Remove contaminated clothing and protective
equipment before entering eating areas. See also Section 8
for additional information on hygiene measures.

Conditions for safe storage, : Store in accordance with local regulations. Store in original
including any incompatibilities container protected from direct sunlight in a dry, cool and well-
ventilated area, away from incompatible materials (see
Section 10) and food and drink. Keep container tightly closed
and sealed until ready for use. Containers that have been
opened must be carefully resealed and kept upright to prevent
leakage. Do not store in unlabeled containers. Use
appropriate containment to avoid environmental
contamination. Bund storage facilities to prevent soil and
water pollution in the event of spillage.

Section 8. Exposure controls/personal protection

Control parameters
Occupational exposure limits
Ingredient name Exposure limits
Ammonia ACGIH TLV (1994-09-01)
TWA 17 mg/m3 25 ppm
STEL 24 mg/m3 35 ppm
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 Urea Liquid 40%

OSHA PEL 1989 (1989-03-01)

STEL 27 mg/m3 35 ppm
OSHA PEL (1993-06-30)
TWA 35 mg/m3 50 ppm
NIOSH REL (1994-06-01)
TWA 18 mg/m3 25 ppm
STEL 27 mg/m3 35 ppm

Appropriate engineering : Good general ventilation should be sufficient to control worker

controls exposure to airborne contaminants.
Environmental exposure : Emissions from ventilation or work process equipment should
controls be checked to ensure they comply with the requirements of
environmental protection legislation. In some cases, fume
scrubbers, filters or engineering modifications to the process
equipment will be necessary to reduce emissions to
acceptable levels.

Individual protection measures

Hygiene measures : A washing facility or water for eye and skin cleaning purposes
should be present. Wash hands, forearms and face thoroughly
after handling chemical products, before eating, smoking and
using the lavatory and at the end of the working period. Wash
contaminated clothing before reusing.
Eye/face protection : Safety eyewear complying with an approved standard should
be used when a risk assessment indicates this is necessary to
avoid exposure to liquid splashes, mists, gases or dusts.

Skin protection
Hand protection : Chemical-resistant, impervious gloves complying with an
approved standard should be worn at all times when handling
chemical products if a risk assessment indicates this is
necessary. For general applications, we recommend gloves
with a thickness typically greater than 0.35 mm. It should be
emphasized that glove thickness is not necessarily a good
predictor of glove resistance to a specific chemical, as the
permeation efficiency of the glove will be dependent on the
exact composition of the glove material.
Body protection : Personal protective equipment for the body should be selected
based on the task being performed and the risks involved.
Other skin protection : Appropriate footwear and any additional skin protection
measures should be selected based on the task being
performed and the risks involved and should be approved by a
specialist before handling this product.
Respiratory protection : In case of inadequate ventilation wear respiratory protection.

Personal protective equipment :

(Pictograms)

Section 9. Physical and chemical properties

Appearance
Physical state : Liquid
Color : Colorless.,

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 Urea Liquid 40%

Odor : Slight
Odor threshold : Not determined.
pH : 7.5 - 9.5 @ 20 °C (68 °F)

Melting/freezing point : Not determined.

Boiling/condensation point : Not determined.
Sublimation temperature : Not determined.
Flash point : Not determined.
Evaporation rate : Not determined.
Flammability (solid, gas) : Not determined.
Lower and upper explosive : Lower: Not determined.
(flammable) limits Upper: Not determined.
Vapor pressure : Not determined.
Vapor density : 1.113 [Air = 1]

Relative density : Not determined.

Solubility : Not determined.
Partition coefficient: n- : Not determined.
octanol/water
Auto-ignition temperature : Not determined.

Decomposition temperature : Not determined.

Viscosity : Dynamic: Not determined.
Kinematic: Not determined.
Explosive properties : Not determined.
Oxidizing properties : Not determined.

Section 10. Stability and reactivity

Reactivity : No specific test data related to reactivity available for this
product or its ingredients.

Chemical stability : The product is stable.

Possibility of hazardous : Under normal conditions of storage and use, hazardous

reactions reactions will not occur.

Conditions to avoid : Avoid contamination by any source including metals, dust and
organic materials.

Incompatible materials : Urea reacts with calcium hypochlorite or sodium hypochlorite

to form the explosive nitrogen trichloride.

Hazardous decomposition : Under normal conditions of storage and use, hazardous

products decomposition products should not be produced.

Section 11. Toxicological information

Information on toxicological effects

Acute toxicity
Product/ingredie Method Species Result Exposure References
nt name
Ammonia
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 Urea Liquid 40%

LC50 Inhalation Rat 9.85 mg/l 1h IUCLID 5

LC50 Inhalation Rat 7.939 mg/l 1h IUCLID 5

Conclusion/Summary : No known significant effects or critical hazards.

Irritation/Corrosion

Conclusion/Summary
Skin : No known significant effects or critical hazards.

Eyes : No known significant effects or critical hazards.

Respiratory : No known significant effects or critical hazards.

Sensitization

Conclusion/Summary
Skin : No known significant effects or critical hazards.
Respiratory : No known significant effects or critical hazards.

Mutagenicity

Conclusion/Summary : No known significant effects or critical hazards.

Carcinogenicity
Product/ingredient Method Species Result Exposure References
name
Ammonia
OECD 453 Rat Negative Not IUCLID 5
Oral NOAEL applicable.
67 mg/kg
bw/day

Conclusion/Summary : No known significant effects or critical hazards.

Reproductive toxicity
Product/ingredient Method Species Result Exposure References
name
Ammonia
OECD 422 Rat Fertility effects- 28 days IUCLID 5
Oral Negative
NOAEL
408 mg/kg
bw/day
OECD 414 Rabbit Developmental- 28 days IUCLID 5
Oral Negative
NOAEL
100 mg/kg
bw/day
Inhalation Pig Developmental- 6 weeks IUCLID 5

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 Urea Liquid 40%

Negative
NOAEC
25 mg/m³

Conclusion/Summary : No known significant effects or critical hazards.

Specific target organ toxicity (single exposure)

No known significant effects or critical hazards.

Specific target organ toxicity (repeated exposure)

No known significant effects or critical hazards.

Aspiration hazard
No known significant effects or critical hazards.

Information on the likely : Not available.

routes of exposure:

Potential acute health effects

Eye contact : No known significant effects or critical hazards.
Inhalation : Exposure to decomposition products may cause a health
hazard. Serious effects may be delayed following exposure.
Skin contact : No known significant effects or critical hazards.
Ingestion : No known significant effects or critical hazards.

Symptoms related to the physical, chemical and toxicological characteristics

Eye contact : No specific data.
Inhalation : No specific data.
Skin contact : No specific data.
Ingestion : No specific data.

Delayed and immediate effects and also chronic effects from short and long term exposure
Short term exposure
Potential immediate effects : Not available.
Potential delayed effects : Not available.

Long term exposure

Potential immediate effects : Not available.
Potential delayed effects : Not available.

Potential chronic health effects

Carcinogenicity : No known significant effects or critical hazards.

Mutagenicity : No known significant effects or critical hazards.

Fertility effects : No known significant effects or critical hazards.

Developmental effects : No known significant effects or critical hazards.

Effects on or via lactation : No known significant effects or critical hazards.

Other effects : No known significant effects or critical hazards.

Over-exposure signs/symptoms
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 Urea Liquid 40%

Eye contact : No specific data.

Inhalation : No specific data.
Skin contact : No specific data.
Ingestion : No specific data.

Numerical measures of toxicity

Acute toxicity estimates
Not available.

Section 12. Ecological information

Toxicity
Product/ingred Method Species Result Exposure References
ient name
Ammonia
Acute LC50 Fish 0.89 mg/l 96 h IUCLID 5
Fresh water
Acute LC50 Daphnia 101 mg/l 48 h IUCLID 5
Fresh water
Acute EC50 Algae 2,700 mg/l 18 d IUCLID 5
Fresh water
215 Fish, Channel < 0.048 mg/l 31 d IUCLID 5
Juvenile catfish
Growth Test
Chronic
NOEC
Fresh water
Chronic Daphnia 0.79 mg/l 96 h IUCLID 5
NOEC
Fresh water

Conclusion/Summary : No known significant effects or critical hazards.

Persistence and degradability

Conclusion/Summary : No known significant effects or critical hazards.

Bioaccumulative potential
Product/ingredient name LogPow BCF Potential
Ammonia 0.23 Not applicable. low

Conclusion/Summary : No known significant effects or critical hazards.

Mobility in soil
Soil/water partition : Not available.
coefficient (KOC)
Mobility : Not available.
Other adverse effects : No known significant effects or critical hazards.

Section 13. Disposal considerations

Product
Methods of disposal : The generation of waste should be avoided or minimized
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 Urea Liquid 40%

wherever possible. Disposal of this product, solutions and

any by-products should at all times comply with the
requirements of environmental protection and waste
disposal legislation and any regional local authority
requirements. Dispose of surplus and non-recyclable
products via a licensed waste disposal contractor. Waste
should not be disposed of untreated to the sewer unless
fully compliant with the requirements of all authorities with
jurisdiction. Waste packaging should be recycled.
Incineration or landfill should only be considered when
recycling is not feasible. This material and its container
must be disposed of in a safe way. Empty containers or
liners may retain some product residues. Avoid dispersal
of spilled material and runoff and contact with soil,
waterways, drains and sewers.

Section 14. Transport information

Regulation: UN Class
14.1 UN number Not regulated.
14.2 UN proper shipping name Not applicable.
14.3 Transport hazard class(es) Not applicable.

14.4 Packing group Not applicable.

14.5 Environmental hazards No.

Additional information
Environmental hazards : No.

Regulation: IMDG
14.1 UN number Not regulated.
14.2 UN proper shipping name Not applicable.
14.3 Transport hazard class(es) Not applicable.

14.4 Packing group Not applicable.

14.5 Environmental hazards No.
Additional information
Marine pollutant : No.

Regulation: IATA
14.1 UN number Not regulated.
14.2 UN proper shipping name Not applicable.
14.3 Transport hazard class(es) Not applicable.

14.4 Packing group Not applicable.

14.5 Environmental hazards No.
Additional information

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 Urea Liquid 40%

Marine pollutant : No.

Regulation: DOT Classification

14.1 UN number Not regulated.
14.2 UN proper shipping name Not applicable.
14.3 Transport hazard class(es) Not applicable.

14.4 Packing group Not applicable.

14.5 Environmental hazards No.
Additional information

Marine pollutant : Not available.

Regulation: TDG Class

14.1 UN number Not regulated.
14.2 UN proper shipping name Not applicable.
14.3 Transport hazard class(es) Not applicable.

14.4 Packing group Not applicable.

14.5 Environmental hazards No.
Additional information
Not applicable.

Environmental hazards : No.

14.6 Special precautions for : Transport within user’s premises: Ensure that persons
user transporting the product know what to do in the event of
an accident or spillage.

IMSBC : Not applicable.

Transport in bulk according to : Not available.

IMO instruments

Section 15. Regulatory information

United States
U.S. Federal regulations : TSCA 8(a) CDR Exempt/Partial exemption: Not
determined
United States - EPA Clean water act (CWA) section
311 - Hazardous substances: Ammonia;

Clean Air Act Section 112(b) : Not listed

Hazardous Air Pollutants
(HAPs)
Clean Air Act Section 602 : Not listed
Class I Substances
Clean Air Act Section 602 : Not listed
Class II Substances

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 Urea Liquid 40%

DEA List I Chemicals : Not listed

(Precursor Chemicals)
DEA List II Chemicals : Not listed
(Essential Chemicals)

SARA 302/304

Composition/information on ingredients

Name % EHS SARA 302/304

Ammonia >= 0.1 - <= 0.2 Yes. SARA 302 TPQ: 500 lb(s)
SARA 304 RQ: 100 lb(s)

SARA 304 RQ : 55555.6 lbs

SARA 311/312

Classification : Not applicable.

Composition/information on ingredients

No products were found.

State regulations
Massachusetts : None of the components are listed.
New York : None of the components are listed.
New Jersey : None of the components are listed.
Pennsylvania : None of the components are listed.

California Prop. 65

⚠ WARNING: Cancer and Reproductive Harm - www.P65Warnings.ca.gov.

Inventory list
New Zealand Inventory of Chemicals (NZIoC): All components are listed or exempted.
Korea inventory: All components are listed or exempted.
China inventory (IECSC): All components are listed or exempted.
Australia inventory (AICS): All components are listed or exempted.
Canada inventory: All components are listed or exempted.
Taiwan Chemical Substances Inventory (TCSI): All components are listed or exempted.
United States inventory (TSCA 8b): All components are active or exempted.
EC INVENTORY (EINECS/ELINCS): All components are listed or exempted.
Canada: All components are listed or exempted.
Viet Nam: All components are listed or exempted.

Section 16. Other information

Hazardous Material Information System (U.S.A.)

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 Urea Liquid 40%

Health / 0
Flammability 0
Physical hazards 0

Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or
risks, and 4 representing significant hazards or risks. Although HMIS® ratings and the
associated label are not required on MSDSs or products leaving a facility under 29 CFR
1910.1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully
implemented HMIS® program. HMIS® is a registered trademark and service mark of the
American Coatings Association, Inc.
The customer is responsible for determining the PPE code for this material. For more
information on HMIS® Personal Protective Equipment (PPE) codes, consult the HMIS®
Implementation Manual.

Chronic toxicity:
- : No data available.
* : Carcinogen, Target organs, Reproductive effects, Sensitizer to lungs

National Fire Protection Association (U.S.A.)

Flammability
0
Health 3 0 Instability/Reactivity

Special

Reprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for
Emergency Response Copyright ©1997, National Fire Protection Association, Quincy, MA
02269. This reprinted material is not the complete and official position of the National Fire
Protection Association, on the referenced subject which is represented only by the standard in
its entirety.
Copyright ©2001, National Fire Protection Association, Quincy, MA 02269. This warning system
is intended to be interpreted and applied only by properly trained individuals to identify fire,
health and reactivity hazards of chemicals. The user is referred to certain limited number of
chemicals with recommended classifications in NFPA 49 and NFPA 325, which would be used
as a guideline only. Whether the chemicals are classified by NFPA or not, anyone using the 704
systems to classify chemicals does so at their own risk.

Procedure used to derive the classification

Classification Justification
Not classified. Calculation method

History
Date of printing : 03/01/2021
Date of issue/Date of revision : 02/19/2021
Date of previous issue : 00/00/0000
Version : 1.0
Prepared by : Yara Chemical Compliance (YCC).
Key to abbreviations : ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and
Labelling of Chemicals
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 Urea Liquid 40%

IATA = International Air Transport Association

IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of
Pollution From Ships, 1973 as modified by the Protocol of
1978. ("Marpol" = marine pollution)
SGG = Segregation Group
UN = United Nations
Key data sources : EU REACH ECHA/IUCLID5 CSR.
National Institute for Occupational Safety and Health, U.S.
Dept. of Health, Education, and Welfare, Reports and
Memoranda Registry of Toxic Effects of Chemical
Substances.
Sphera Solutions Inc., 4777 Levy Street, St Laurent, Quebec
HAR 2P9, Canada.

|| Indicates information that has changed from previously issued version.

Notice to reader

To the best of our knowledge, the information contained herein is accurate. However, neither
the above-named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the
accuracy or completeness of the information contained herein. Final determination of
suitability of any material is the sole responsibility of the user. All materials may present
unknown hazards and should be used with caution. Although certain hazards are described
herein, we cannot guarantee that these are the only hazards that exist.

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