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Practical Organic Chemistry

This document discusses several chemical tests that can be used to identify organic compounds and detect certain functional groups or elements present. Some of the key tests mentioned include: 1. Sodium fusion test to detect cyanide (NaCN) which forms a deep blue color when reacted with iron. 2. Layer test using sodium halide solutions to detect the presence of halogens like bromine, iodine, or chlorine through color changes. 3. Tollens' reagent to distinguish between aldehydes and alkynes, forming a silver mirror with aldehydes but not alkynes.

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0% found this document useful (0 votes)
390 views14 pages

Practical Organic Chemistry

This document discusses several chemical tests that can be used to identify organic compounds and detect certain functional groups or elements present. Some of the key tests mentioned include: 1. Sodium fusion test to detect cyanide (NaCN) which forms a deep blue color when reacted with iron. 2. Layer test using sodium halide solutions to detect the presence of halogens like bromine, iodine, or chlorine through color changes. 3. Tollens' reagent to distinguish between aldehydes and alkynes, forming a silver mirror with aldehydes but not alkynes.

Uploaded by

PavithraBhishma
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
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PACTCALpAGNIC CHEMISTPY

dentiiai s,N, x , 3 , 3 ,
reMP Test
funciore
com pouels

LDEN TI FICATION

LASSAGNES TEST (9x


SoDHUMfisicn EsT
a albE
oranic Compeund

punged n o

Pec
org aniANa Hot
cmpa edex
Special s ue
+ule breas)
CPYe ue (4es
iHered
iterote
Sodiowm +usjo

Eyract

DETECTIONN OF N
Na CN
Lexcess
CmP
¢NeN Sceio w y a Y midE)
SronA

is used o peventomatio n o a , NCN


e
easer
Since detectien rem C

Na CN (C o, siveo byydraly cis)


NOE Na CN
Fe S4 Fesou

1 H , Alveila) previde
¥al Fe F]
CFe (C 3 Prussian blue
Coerial erd)

here omy rt afe Fe ST i rmed


Hso
t qas Sssoved. ese imid

okuoFe ce e Fe
Fe [Fe lC), a m peri
Hko acidi ficaticn Ht chol
TrUce lan 5ve
c a ,else fe d qreen) sll be fee
Na CN
a Soduion
pa nito loeuzaldehy de ottho dinito
oe # e ne

No
u n e n a d d e d

del t he sod usson etact na V


hen

o r ms deep blwe Cdourahen

DETECTION OF
S o d .h i r o

og cwmpd
NaS P r u s s i d e

Cdtcn co
H PbCCH Coo
Os)
Cas
Na CFe Cen
PoS s o d i u wM nitroS
yelleu fP
ro Hen eg eloc Prussd

vio let / pu ple


sme
mis
cescour
campiex.

very sta ble


de CNer avme

S N PeEsENT
F BOTH organiC Compound

inseiend
is usec
siciew+
N a s u s e d
Na SCN

( Sod. 4hio cyaw B ecD seln.


Na,S +Na

Fe s SocdPed slour

Fe, LEeCena
FeS Rron u e P.&lue
coleut)

Blac
BlecE
Fes wa s
Blac
lole doecn+7
Apoy hee ting J
Rrussia Blve
sevee
dN
sho wP,
isvisioeneud
DETECTIoN OF X
org Cmpd

Na Br Na
Nad
NOay) Agsa
AC Cahide ) ABr Cmi ld yella) Aa CYellb

Ag H),)a spArinaly in soly lble iy


selu lde in n ta
Seu e

NOTE
NaF Ca aF Nos CP
Cunile
F As
HALOGENs PPESENT LAYEP TEST

LooH -sl f Nad, NaBY, NaI


No I
NO To
HNo S mid oidisM wi v
Ane oy 1 can aoe to
ether y er owo
oe oridised

Coo PrOVae H t ethe r \yec


ronce edo
vou hs ether
yer rerove.d and res
eher
1ye s addec

-ethex
Plo
CHccoH
L2 net resent

B migte to ethev oyer inp


ed sish oranae coleur
out loy addi g
le
AgNO
Ac °3
NeCl Ag
wite

PETECTION OF P
smell awmt o P t is
during Sad fusion a
Lich ic Hese by He f e
eting bevaied,
produe black colou
u Ag
weistee
(silver phosphide)
matOn
e
Cediu m phosphate)

raanic
POu

Na PO
(NH2MoO4
amwoniom mely bdate
ok
Cconc: presev a n wolyb date

23H 3NH,
12M 4
HPO

(ruH4), LP(M, G4
Canery elleu ep
TONCTIONAL POUS
UNSATURATED (C=c) BoDS

solvent
ciRu dio xane
H, ct da

suH decolouYation
B r Ctedish o ranne )
Coution aldoses aso deceleurise

BAYEPS TEST
EMnO, Na,co
Mn
CBkc-rosn)
ic d

resut Purpe reslour disappsars b b c k lorown Pp

EST To DIST INGDSH BT TERMINAL S


NEN TER MInAL ALEYNES

Usia Tollens reoge


P-cEC-H
awwowMca\

R-cE A ser Akynide


AN Lshste
-L 4 Cu2
NHoH
CBrenze)

TEST FP ALPYL s ARYL HALIDES

BELSTEIN TEST
SNre

cooaied uih tro duced


Green edaed
ALy/Ary a lide into lame avne

una
t a revvoval oVlide ion leout Cohion isaramati
is oohG Wes.
me
NO
TES T AO HoL

6RoH+
alali RoM H2
metal CM)

coiatory acids wl ive

CAN TEST

Rel ce (N) RGH


(OM Ce Cnuo)
Ped ta
A m o n iuw ihee
Cec
uns
alole
is
(omplex
Colou remains only

loo
foeM TET

olcovel av

iodotoY
Cyellouret)

Not a test
CHd3 Cleaaa
sol

NaOCR oridisn anent


aboIt*R

N a OC ¥I
HOI oH

NaD cH
H is lo
Iedine olu lbi t y
NOTE storea in I
is
st Brous g)

tesT
LUCAS alceha
dis i nquich lot
,
Hest to

Co HC anhy Z
-reaaeni:
o s alkyl hlaide
Caocation vnec hais
wwcediate
aive
AK
id ty
G-10 wims
awe tto idiy a t
o ge t r loidi
ty
TEST fOR PHENDLS
feric Chleride Tes
Naxhal
Fe CMs)]
vCva
FeCks violert

eserci no

-creso violet /Le


Ch
P-cesol

w-cre se

Catechel
qeev become dar ker
ate Some me)

NO couY
-mapm 2-vapthe
D-napha -ha ptn)

Phalein est
Phenee Pthalie anhydridet M,o
PinE
u) Sao
Cauivioid
Pheno pthalein )

Coevnieo loenziro id form)


crtno -cxesol
red
mea tresol
uis pur ple
paxa-ccssl o colour
Coxtechol blue ateren me
resoiano twro Scend
reen
t wwe due Yed
TEST FOR ALPEHYDES erces
FEH LNGS TeEST

A
tehlia5s
Rochelle sat
Fehlings ae soln. of haate)
Polossium tar
Sedi unw
a l i p h a s t e
Brick ed

aldey des C Cu,o)

BENE aCTS TES

aq. Cu S o
Beredi&
A
Sodiuy potaselm
Benedit
B alE. se
A t r a t e

Orange Ped
Compound
Ccu)
ha ehligs
dense o
orms
Ben edicts
louy
6Ymo tton
enedcs Complex
i o
tehkngs
ic Yedues we
2 tFes p \ACe
Cn

chave

alE medio
Yo

eneraly

i ust aE
ea

Comp e jormetio

i eling H

C u A Pochelle

Salt 4

direfon
e for I u Complex )
eom
Cu
vlesc b 3et
cowe

aveuoered
vee ests is
-ydey
e
ones, rmic ced
aliphaiC aldeyes
hemiaceBn ls hydra Zi,hyd rey| amlne
ScFF TEsST
Coe ealourisina
Soh esiprepared
ide otm S°2 or)
a so
P-sanilne hy cdochlor
(sod Sal phie
PINE
resbre-he calcAY Prosoniline
all adehydes vyochere
d o vo. a c
ve loves

2.4 DNPIH TEST


BRADYS PEhGENNT
all ves pond this tesa
allehydes ke tones
caour:

Yello

ToLEN TST
Tollens S

essn Yesuts in rma Tion


dor brOn Tis is
dissd ve
NHHH e e s u Hing sln. i
Tales Teo

Ineerence Compoun len


(SLver mirox)

wis ae is
aiven
aldey des, dpKy e lone ormjc aci d

vemiacetal dkatine hydeyl amino

N a HSo TEST (dium s u e hite test


l aldehy des, all ethy ke lenes me cyclic es

resqond NaHS test


2Tnpevenceoddn.p dwct e formed hich is a
Cryctallime sat aviva sharp me t
TesT oR CARBOAY uc ACID

Bis teryescevce uoit Nalco or


NazCo
(scce c02
or
No Co
vce th a Hs02
G 2
Brisk evese

Sa H Co
2 ccoH ,
PccoH
a
H So

ESTEe F1CATIoN TST

ierication PoH s
Fischer
Sueet svnellig
cooH
ester

UTMUS PYlimi hary e


red
due

FoR AMINS
TET
CAeBL AMNE TEST
AMINE
FoR 1 PNC eul seli)
CHA+ B
Cisocyande)

No NO+ttClR

aine N
ali p ahc (etfervesevee)

(etterveeYce) (mevolic rder

yellots 6ily ui
2 am ine CN- ro So Amiwe
P -NO

no cvaccketishc chonp
3ame

Napthel teat
NN-

O Pvap th (Scar le
Sye)
tseER 1 TEST Mustardsi
T disthnquish o , 2 , 2 amiv Copt)
TeST FCP NITR PCUP
MoLIKENS TEST
Tolle ne Aa
-NO2 Z-H PHOH (eoae (Ner witTor

CAPBO Hy DPATE
TEST FOP
MoLIS CH
Conc

Soln. f arshy àaie e p violet


alcovelic solutiov

oVepth

TEST TO
DSTINGUISH MONO
E SACCHAPI DDE
BAP FOED` ST
veoaent Cupnc aetrie in CHCooH

Mono SacevaYees
CBrick red)

disancchatid e 7Jekes leraer iwme forw a


TEST To DSTIAUISH
ETOSES oseS
CBEL JANOF TeST
ocisitjed
reaent: oreind:

ketone:OSe Y e d celcn

etD pentose ace lue


-qeen celour
aldoee ss ake lonaer tme.

OBr/t,o TeT
adeses ecoleurise Br/Ho
keto p s de ott

TEsT STAPet+

Starch odine elue colour

Awny oie esronei de or


EST F6P PPo TEIN

si SOL BupeT TesT


Compouvwds havin wand S
Pep Hd
e (om Pe* wh ick is viclef cdoute
w
o i ur e h e :
- - s - -H2

compe

uialef.

DPIN
TEST
NIN Hy
ACID
-

AMINO
FOR
amimo Cd

R
PAYple
eumams

-violet)
niny drin CBue
h y d r e e

TEIN
TESt
THo PPo
XAN
Yellouw colou
Conc. HNU
tve preein )
CXan
T e cius

allbumi 1oM asH

Protein) e drops
(aouT

a wni
awwwe acd
me ee
etver
rous \he
the
phoPotein
avomahc

Umdergo aov
Hh conc. HNO2 .

hese dei vetiVes


s a t s s proteins havin abmaHe

onswced y
test i
Ao
SEPAR ATION
BINARY MTUPES

aqaH50
eter H er Hcho

SeeveovHung uwvel (AS) i ehe

s H So2
n eler
. ayer Ete yerCA
(e) derive hve
1 ) cdd elher
ieler -) w Ca)

ether ayer
C evAP

e+e
evaporatien

freshe4he

ether
evopox tion

CooH

er

(A)in ather
NaH CO

(A) ever ( ) sal


add eher
evop 2) H1

Pin ethey
enp
B)
ot

-ether ani unium i n

ete
&+ in eiev Ch +9) i
HC

CA) i e i n o r
Ay S a l t o
(B)in ether d d etre
ndede ther
a)olt
cvaP
ethe
A) ethe 1oy °r
eu

aniline 2- nep tho


contins
4-mety
ne
A mixture
3
dinito en Ee
3-chlero benzoc acidA md

sep
metved
S t a i red
The ollowing

nd lHer (s}ep-1)
add H

Pesi due
Herate
add . NaoH CStep 2)

PesicdUe
Compouvd
Heced e
addy Hc
l r Cstep
poundx
Pesi due

w
Hecade Com pound
X C

Compoundy

cthz

CAY be i t e r cvarged.
e rene step 2 E3
3-chloto bevm2oic ocA
Y
Are
4 e*hyl
aniine , 3 dinitro benzene vesp
WE
ASO cwtains amio oenoie ccid
or na wi* 4
Presewt i the t e r ate dstep 4 .
l e

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