Safety Data Sheet Optimum Laundry Liquid Detergent

Download as pdf or txt
Download as pdf or txt
You are on page 1of 14

Revision date: 09/05/2017

SAFETY DATA SHEET


OPTIMUM LAUNDRY LIQUID DETERGENT
According to Regulation (EC) No. 1272/2008 on Classification, Labelling and Packaging of Substances and
Mixtures.

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier


Product name OPTIMUM LAUNDRY LIQUID DETERGENT

Product number OPTL3

Container size 10L & 20L

1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses Laundry detergent.

Uses advised against Not for direct contact with Food or Beverage stuffs. Not for oral consumption. Not for use by
hand.

1.3. Details of the supplier of the safety data sheet


Supplier Holchem Laboratories Limited
Gateway House, Pilsworth Road,
Pilsworth Industrial Estate,
Bury, Lancashire (UK)
BL9 8RD
+44 (0) 1706 222288
+44 (0) 1706 221550
[email protected]

1.4. Emergency telephone number


Emergency telephone Out of Office Hours Emergency Information:-
For accidents and spillages involving this product that pose a threat to the environment, or
human health, or require immediate first aid advice call:- +44(0) 7050 265597.
Note:- This number will not accept order queries or calls dealing with equipment breakdowns.
This product is registered with the NPIS. UK Environment Agency 24hour Advisory Service
0800 807060. Irish Environmental Protection Agency 1890 335599 (This is a Lo Call Number)

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture


Classification (EC 1272/2008)
Physical hazards Met. Corr. 1 - H290

Health hazards Skin Corr. 1A - H314 Eye Dam. 1 - H318

Environmental hazards Not Classified

2.2. Label elements

1/14
Revision date: 09/05/2017

OPTIMUM LAUNDRY LIQUID DETERGENT

Pictogram

Signal word Danger

Hazard statements H290 May be corrosive to metals.


H314 Causes severe skin burns and eye damage.

Precautionary statements P234 Keep only in original container.


P280 Wear protective clothing, gloves, eye and face protection.
P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing.
Rinse skin with water/ shower.
P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P313 Get medical advice/ attention.

Contains SODIUM HYDROXIDE, ETHOXYLATED ALCOHOL, ETHYLENEDIAMINETETRAACETIC


ACID TETRASODIUM SALT, SODIUM ALKYL ETHER SULPHATE, SODIUM SALT OF
BENZENE SULPHONIC ACID MONO C10-14 ALKYL DERIVATIVES, SODIUM C14-C17
SECONDARY ALKYL SULPHONATE, COCOAMIDOPROPYL BETAINE

Detergent labelling 5 - < 15% anionic surfactants, 5 - < 15% non-ionic surfactants, < 5% amphoteric surfactants,
< 5% EDTA and salts thereof, < 5% polycarboxylates

Supplementary precautionary P404 Store in a closed container.


statements P501 Dispose of contents/ container in accordance with national regulations.

2.3. Other hazards


This product does not contain any substances classified as PBT or vPvB. Note:- H290 May be Corrosive to Metals
Classification relates to Soft Metals such as Aluminium and Copper, when used correctly this product is not expected to be
corrosive to 304 and 316 Stainless Steel.

SECTION 3: Composition/information on ingredients

3.2. Mixtures

SODIUM HYDROXIDE 5-10%


CAS number: 1310-73-2 EC number: 215-185-5 REACH registration number: 01-
2119457892-27

Classification Classification (67/548/EEC or 1999/45/EC)


Met. Corr. 1 - H290 C;R35
Skin Corr. 1A - H314
Eye Dam. 1 - H318

ETHOXYLATED ALCOHOL 1-5%


CAS number: 68131-39-5 EC number: 500-195-7
M factor (Acute) = 1

Classification Classification (67/548/EEC or 1999/45/EC)


Eye Dam. 1 - H318 Xi;R41. N;R50.
Aquatic Acute 1 - H400

2/14
Revision date: 09/05/2017

OPTIMUM LAUNDRY LIQUID DETERGENT

ETHYLENEDIAMINETETRAACETIC ACID TETRASODIUM 1-5%


SALT
CAS number: 64-02-8 EC number: 200-573-9 REACH registration number: 01-
2119486762-27

Classification Classification (67/548/EEC or 1999/45/EC)


Met. Corr. 1 - H290 Xn;R20,R22. Xi;R41.
Acute Tox. 4 - H302
Acute Tox. 4 - H332
Eye Dam. 1 - H318
STOT RE 2 - H373

SODIUM ALKYL ETHER SULPHATE 1-5%


CAS number: 68891-38-3 EC number: 500-234-8 REACH registration number: 01-
2119488639-16

Classification Classification (67/548/EEC or 1999/45/EC)


Skin Irrit. 2 - H315 Xi; R38, R41
Eye Dam. 1 - H318
Aquatic Chronic 3 - H412

SODIUM ARYL SULPHONATE 1-5%


CAS number: 1300-72-7 EC number: 215-090-9 REACH registration number: 01-
2119513350-56-XXXX

Classification Classification (67/548/EEC or 1999/45/EC)


Eye Irrit. 2 - H319 Xi; R36

SODIUM SALT OF BENZENE SULPHONIC ACID MONO 1-5%


C10-14 ALKYL DERIVATIVES
CAS number: 85117-50-6 EC number: 285-600-2

Classification Classification (67/548/EEC or 1999/45/EC)


Acute Tox. 4 - H302 Xn;R22. Xi;R38,R41.
Skin Irrit. 2 - H315
Eye Dam. 1 - H318

ALKOXLATED FATTY ALCOHOL 1-5%


CAS number: 103818-93-5

Classification Classification (67/548/EEC or 1999/45/EC)


Skin Irrit. 2 - H315 Xi;R38.

3/14
Revision date: 09/05/2017

OPTIMUM LAUNDRY LIQUID DETERGENT

SODIUM C14-C17 SECONDARY ALKYL SULPHONATE 1-5%


CAS number: 97489-15-1 EC number: 307-055-2 REACH registration number: 01-
2119489924-20-XXXX

Classification Classification (67/548/EEC or 1999/45/EC)


Acute Tox. 4 - H302 Xn;R22. Xi;R38,R41.
Skin Irrit. 2 - H315
Eye Dam. 1 - H318
Aquatic Chronic 3 - H412

COCOAMIDOPROPYL BETAINE 1-5%


CAS number: 61789-40-0 EC number: 263-058-8

Classification Classification (67/548/EEC or 1999/45/EC)


Eye Dam. 1 - H318 Xi;R41.
Aquatic Chronic 3 - H412

ETHANEDIOL <1%
CAS number: 107-21-1 EC number: 203-473-3 REACH registration number: 01-
2119456816-28-XXXX

Classification Classification (67/548/EEC or 1999/45/EC)


Acute Tox. 4 - H302 Xn;R22

The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16.
Composition comments To the best of our knowledge, all of the substances used in this product are being supported
for the relevent application in REACH.

SECTION 4: First aid measures

4.1. Description of first aid measures


General information When it is safe to do so, remove victim immediately from source of exposure. However,
consideration should be given as to whether moving the victim will cause further injury.

Inhalation Remove affected person from source of contamination. Provide rest, warmth and fresh air. If
breathing stops, provide artificial respiration. Get medical attention if any discomfort
continues.

Ingestion Do not induce vomiting. Rinse mouth thoroughly. Place unconscious person on their side in
the recovery position and ensure breathing can take place. Get medical attention.

Skin contact Remove contaminated clothing that is not stuck to the skin. Flush area with clean water.
Continue to rinse for at least 15 minutes. Get medical attention if any discomfort continues.

Eye contact Remove any contact lenses and open eyelids wide apart. Promptly wash eyes with plenty of
water while lifting the eyelids. Continue to rinse for at least 15 minutes and get medical
attention.

Protection of first aiders First aid personnel should wear appropriate protective equipment during any rescue.

4.2. Most important symptoms and effects, both acute and delayed
General information Neat product may cause chemical burns and permanent eye damage. Dilute product may
cause irritation to the skin and eyes.

4/14
Revision date: 09/05/2017

OPTIMUM LAUNDRY LIQUID DETERGENT

Inhalation Inhalation of neat product is unlikely. However, inhalation of mists or vapours of diluted
product may result in soreness, irritation or burns to the mouth, nose and respiratory tract.

Ingestion Unlikely route of exposure without deliberate abuse. If neat chemical is ingested, chemical
burning of mouth, throat and GI tract will occur. If dilute chemical is ingested, soreness of
mouth, throat and GI tract may occur together with redness and blistering. Bleeding may
occur.

Skin contact May cause serious chemical burns to the skin.

Eye contact May result in permanent eye damage.

4.3. Indication of any immediate medical attention and special treatment needed
Notes for the doctor Contains Sodium Hydroxide (Caustic Soda) in Aqueous Solution Rinse well with water to
neutral pH.

SECTION 5: Firefighting measures

5.1. Extinguishing media


Suitable extinguishing media This product will not support combustion and is not flammable. Use an extinguishing media
suitable for surrounding materials.

5.2. Special hazards arising from the substance or mixture


Specific hazards On heating corrosive fumes may be produced. In contact with some metals (Aluminium, Zinc
and their Alloys) Hydrogen Gas is formed, which may form an explosive mixture with air. Note
- Comment refers to neat product.

5.3. Advice for firefighters


Protective actions during Protective clothing and respiratory protection should be worn when tackling fires involving this
firefighting product. Control run-off water by containing and keeping it out of sewers and watercourses.

Special protective equipment Wear positive-pressure self-contained breathing apparatus (SCBA) and appropriate protective
for firefighters clothing.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures


Personal precautions Wear protective clothing as described in Section 8 of this safety data sheet.

6.2. Environmental precautions


Environmental precautions Spillages or uncontrolled discharges into watercourses must be reported immediately to the
Environmental Agency or other appropriate regulatory body.

6.3. Methods and material for containment and cleaning up


Methods for cleaning up Stop leak if possible without risk. Absorb in vermiculite, dry sand or earth and place into
containers. Collect spillage for reclamation or disposal in sealed containers via a licensed
waste contractor. Containers with collected spillage must be properly labelled with correct
contents and hazard symbol.

6.4. Reference to other sections


Reference to other sections See sections 8,12 & 13

SECTION 7: Handling and storage

7.1. Precautions for safe handling


Usage precautions Wear appropriate clothing to prevent any possibility of liquid contact and repeated or
prolonged vapour contact. Refer to section 8.

5/14
Revision date: 09/05/2017

OPTIMUM LAUNDRY LIQUID DETERGENT

7.2. Conditions for safe storage, including any incompatibilities


Storage precautions Keep container tightly closed. Keep only in the original container in a cool, well-ventilated
place. Store away from the following materials: Acids. Store between 0 and 40 Degrees C.

7.3. Specific end use(s)


Specific end use(s) Detergent, refer to Product Information Sheet for full details.

Usage description This product is suitable for use in cleaning workwear used in food processing plants and
similar high care areas.

SECTION 8: Exposure Controls/personal protection

8.1. Control parameters


Occupational exposure limits
SODIUM HYDROXIDE
Short-term exposure limit (15-minute): WEL 2 mg/m³
ETHANEDIOL
Long-term exposure limit (8-hour TWA): WEL 10 mg/m3(Sk)
Short-term exposure limit (15-minute): WEL 104 mg/m3(Sk)
WEL = Workplace Exposure Limit

Ingredient comments As a requirement of REACH we have considered all of the components of this formulation.
We believe that Sodium Hydroxide (NaOH) is the most hazardous component of this
formulation. Sodium Hydroxide is not expected to be systemically available to the body under
normal handling and use conditions, therefore systemic effects of Sodium Hydroxide after
Dermal or Inhalation Exposure are not expected to occur. Based on data from our raw
material suppliers, we understand that if the risk management measures outlined in section
8.2 are followed , the inhalation exposure is below the DNEL of 1mg/m3. Where an exposure
level is quoted, a risk assessment should consider if there is a need to monitor the
atmosphere of the working environment. Results should be compared against the WEL and/or
DNEL information provided. The Long Term WEL refers to total exposure of a worker to a
specific substance averaged out over an 8 hour period.
The Short Term WEL refers to a single exposure of a worker to a specific substance over a 15
minute period.
If the Short Term WEL is exceeded and no Long Term Limit is set, further exposure during the
working shift is not permitted. Further controls should be implemented to ensure that future
exposure to the substance is reduced below the levels set before the activity is
repeated/continued. Where no Short Term WEL exists, guidance from the HSE is to use a
value of three times the Long Term WEL.
The WEL limits are laid down in the EH40 list as supplied by the HSE. This is taken from the
Chemical Agents Directive (98/24/EC). Where a worker is exposed to levels approaching a
limit, further exposure control measures should be considered to reduce exposure to the
substance. DNEL and/or PNEC information is supplied by manufacturers of substances in
accordance with REACH legislation (Regulation (EC) No 1907/2006) , and is used to provide
suitable risk reduction measures to limit exposure of the user of the substance to a non
hazardous level. If the measured level of exposure by a route divided by the DNEL for the
route is greater than 1, then further exposure controls should be implemented as described in
section 8.2. Where new information becomes available under REACH, this will be passed on
as revisions to the Safety Data Sheet.

SODIUM HYDROXIDE (CAS: 1310-73-2)

6/14
Revision date: 09/05/2017

OPTIMUM LAUNDRY LIQUID DETERGENT

DNEL Industry - Inhalation; Long term local effects: 1.0 mg/m³


DNEL data for Professional users is not yet available, but it is assumed to be the
same as for Industrial users.
Industry - Dermal; Short term local effects: 2%

PNEC No information is available for PNEC data for Sodium Hydroxide

ETHYLENEDIAMINETETRAACETIC ACID TETRASODIUM SALT (CAS: 64-02-8)

DNEL Professional - Inhalation; Long term systemic effects: 1.5 mg/m³

PNEC - Fresh water; 2.86 mg/l


- Marine water; 0.286 mg/l
- Intermittent release; 1.56 mg/l
- Soil; 0.937 mg/kg, mg/kg dwt
- STP; 55.94 mg/kg

SODIUM ALKYL ETHER SULPHATE (CAS: 68891-38-3)

DNEL Professional - Dermal; Long term systemic effects: 2750 mg/kg/day


Professional - Inhalation; Long term systemic effects: 175 mg/m³
General population - Oral; Long term systemic effects: 15 mg/kg/day
General population - Dermal; Long term systemic effects: 1650 mg/kg/day
General population - Inhalation; Long term systemic effects: 52 mg/m³

PNEC - Fresh water; 0.24 mg/l


- Marine water; 0.024 mg/l
- Intermittent release; 0.071 mg/l
- Sediment (Freshwater); 5.45 mg/kg
- Sediment (Marinewater); 0.545 mg/kg
- Soil; 0.946 mg/kg
- STP; 10 g/l

SODIUM ARYL SULPHONATE (CAS: 1300-72-7)

DNEL Workers - Dermal; Long term systemic effects: 136.25 mg/kg/day


Workers - Inhalation; Long term systemic effects: 26.9 mg/m³
Workers - Dermal; Long term local effects: 0.096 mg/cm²
General population - Inhalation; Long term systemic effects: 6.6 mg/m³
General population - Dermal; Long term systemic effects: 68.1 mg/kg
General population - Dermal; Long term local effects: 0.048 mg/cm²
General population - Oral; Long term systemic effects: 3.8 mg/kg/day

PNEC - Fresh water; 0.23 mg/l


- Marine water; 0.023 mg/l
- Intermittent release; 2.3 mg/l
- Sediment, Fresh water; 0.862 mg/kg
- Sediment, Marine water; 0.0862 mg/kg
- Soil; 0.037 mg/kg
- STP; 100 mg/l

SODIUM C14-C17 SECONDARY ALKYL SULPHONATE (CAS: 97489-15-1)

7/14
Revision date: 09/05/2017

OPTIMUM LAUNDRY LIQUID DETERGENT

DNEL Professional - Dermal; Short term local effects: 2,8 mg/cm2


Professional - Dermal; Long term systemic effects: 5mg/Kg bw/day
Professional - Inhalation; Long term systemic effects: 35mg/m3
- Dermal; Long term local effects: 2.8 mg/cm²

PNEC - Sediment (Marinewater); 0.94 mg/kg dw


- Soil; 9.4mg/Kg dw
- Intermittent release; 0.06mg/l
- Sediment (Freshwater); 9.4 mg/Kg dw
- Fresh water; 0.04mg/l
- STP; 600mg/l
- Marine water; 0.004mg/l

COCOAMIDOPROPYL BETAINE (CAS: 61789-40-0)

DNEL Professional - Dermal; Long term systemic effects: 12.5 mg/kg bw/day
Professional - Inhalation; Long term systemic effects: 44 mg/m³

PNEC - Fresh water; 0.0135 mg/l


- Marine water; 0.00135 mg/l
- Sediment (Freshwater); 1 mg/kg
- Soil; 0.8 mg/kg
- STP; 300 mg/l
- Sediment (Marinewater); 0.1 mg/kg

8.2. Exposure controls

Protective equipment

Appropriate engineering As this product contains ingredients with exposure limits, process enclosures, local exhaust
controls ventilation or other engineering controls should be used to keep worker exposure below any
statutory or recommended limits, if use generates dust, fumes, gas, vapour or mist.

Personal protection The PPE indicated above is not a COSHH assessment. It represents PPE that should be
considered during the manufacture, distribution, use and final disposal stages of this product's
life cycle. It is the responsibility of employers to conduct a COSHH/risk assessment to
determine appropriate PPE levels. The information given below should be used to support
this assessment. Where possible replace manual processes with automated or closed
processes to minimise contact with the product.

Eye/face protection If risk of splashing, wear safety goggles or face shield. Refer to EN Standard 166 to select
appropriate level of protection.

Hand protection Impervious Chemical Resistant Gloves of Butyl Rubber, PVC, Polychloroprene with a natural
latex liner, all with a minimum material thickness 0.5mm and a breakthrough time of
>480mins. Alternatively Nitrile Rubber, Fluorinated Rubber, both with a minimum thickness of
0.35 - 0.4mm and a breakthrough time of >480minutes. Refer to Standard EN 374.

Other skin and body Appropriate footwear and additional protective clothing complying with an approved standard
protection should be worn if a risk assessment indicates skin contamination is possible. Reference to EN
13832 and EN 943 is useful when selecting footwear and clothing.

Hygiene measures Promptly remove non-impervious clothing that has become contaminated, provided it is not
adhered to the skin. Contaminated clothing and shoes must be discarded. Provide eyewash
station and safety shower.

8/14
Revision date: 09/05/2017

OPTIMUM LAUNDRY LIQUID DETERGENT

Respiratory protection No specific recommendation made, but respiratory protection must be used if the general
level exceeds the Workplace Exposure Limit.

Environmental exposure Do not allow the substance to contaminate surface water/ground water. See points 6, 12 &13.
controls Discharge of solutions into effluent systems (including municipal drains) or to surface water
are expected to cause significant pH changes. Discharge of solutions should be carried out
such that pH changes are minimised. Where necessary pH buffering measures should be
adopted. Users of this product should consult local drainage and permitting authorities to
ensure that any restrictions or discharge consents are adhered to.

General Health and Safety The above classification relates to neat product.
Measures. Based on pH, "in use" solutions would still be classified as corrosive and use of gloves and
eye protection is recommended as minimum PPE.A full Risk Assessment should be carried
out before handling any chemical(s). Risk Assessments should refer to COSHH, and any
other relevant legislation or industry specific guidelines governing the use of chemicals.

SECTION 9: Physical and Chemical Properties

9.1. Information on basic physical and chemical properties


Appearance Liquid

Colour White.

Odour Detergent.

Odour threshold Not applicable.

pH Concentrate pH >13

Melting point Not applicable.

Initial boiling point and range Not applicable.

Flash point Not applicable.

Evaporation rate Not applicable.

Evaporation factor Not applicable.

Flammability (solid, gas) Not applicable.

Upper/lower flammability or Not applicable.


explosive limits

Vapour pressure Not applicable.

Vapour density Not applicable.

Relative density 1.0 - 1.1 @ 20 Degrees C

Bulk density Not applicable.

Solubility(ies) Soluble in water.

Partition coefficient Not applicable.

Auto-ignition temperature Not applicable.

Decomposition Temperature Not applicable.

Viscosity Not determined.

Explosive properties Not applicable.

Explosive under the influence Not considered to be explosive.


of a flame

9/14
Revision date: 09/05/2017

OPTIMUM LAUNDRY LIQUID DETERGENT

Oxidising properties Does not meet the criteria for classification as oxidising.

9.2. Other information


Refractive index Not applicable.

Particle size Not applicable.

Molecular weight Not applicable.

Volatility Not applicable.

Saturation concentration Not applicable.

Critical temperature Not applicable.

Volatile organic compound Not applicable.

Explosive Properties Not Classified as Explosive

Storage Temperature Range 0 to + 40 Degree C

SECTION 10: Stability and reactivity

10.1. Reactivity
Reactivity Not expected to react when correctly stored and used. Mixing with other chemicals may
produce unexpected reactions. The solution is strongly alkaline and reacts with strong acids
with heat generation.

10.2. Chemical stability


Stability Stable at normal ambient temperatures and when used as recommended. - See note 10.6.

10.3. Possibility of hazardous reactions


Possibility of hazardous Refer to section 10.1. Do not mix with acids, this will generate heat and give off corrosive
reactions vapours.

10.4. Conditions to avoid


Conditions to avoid Avoid excessive heat for prolonged periods of time.

10.5. Incompatible materials


Materials to avoid Strong acids. Reaction with Aluminium, Zinc, Tin, Copper or their alloys produces flammable
Hydrogen Gas.

10.6. Hazardous decomposition products


Hazardous decomposition This material is not flammable, but heating in a fire may evolve harmful/irritating vapours.
products

SECTION 11: Toxicological information

11.1. Information on toxicological effects


Acute toxicity - oral
ATE oral (mg/kg) 16,611.3

Acute toxicity - inhalation


ATE inhalation (dusts/mists 49.34
mg/l)

General information Toxic effect linked with corrosive properties. See section 4.2.

10/14
Revision date: 09/05/2017

OPTIMUM LAUNDRY LIQUID DETERGENT

Inhalation Unlikely route of exposure. Inhalation of sprayed droplets may result in soreness of the throat,
mouth and nose. - See section 4.2.

Ingestion Causes severe burns. May cause chemical burns in mouth, oesophagus and stomach.

Skin contact Causes severe burns.

Eye contact Risk of serious damage to eyes. May cause permanent eye injury.

SECTION 12: Ecological Information

Ecotoxicity This product is not classified as environmentally hazardous. However, this does not exclude
the possibility that large or frequent spills can have a harmful or damaging effect on the
environment. Normal use is unlikely to pose a risk to the environment.

12.1. Toxicity
Acute toxicity - fish This mixture is not classified as toxic to aquatic organisms.
See note 12.0
Normal use of the diluted product is not expected to pose any risk.
Note:- pH values greater than 10.5 may be fatal to fish and other aquatic organisms, there
may also be damage to aquatic plants.

12.2. Persistence and degradability


Persistence and degradability This product consists mainly of inorganic components for which biodegradation assessment is
not applicable. The product meets the requirements of the European Detergents Regulation
648/2004 as amended.

12.3. Bioaccumulative potential


Bioaccumulative potential Not expected to bioaccumulate.

Partition coefficient Not applicable.

12.4. Mobility in soil


Mobility The product contains substances which are water-soluble and may spread in water systems.

12.5. Results of PBT and vPvB assessment


Results of PBT and vPvB This product does not contain any substances classified as PBT or vPvB.
assessment

12.6. Other adverse effects


Other adverse effects Not determined.

SECTION 13: Disposal considerations

13.1. Waste treatment methods


General information When handling waste, the safety precautions applying to handling of the product should be
considered. Do not mix with other chemicals. Disposal of this product, process solutions,
residues and by-products should at all times comply with the requirements of environmental
protection and waste disposal legislation and any local authority requirements.

Disposal methods Small volumes of use solution can be disposed of to sewers.

SECTION 14: Transport information

14.1. UN number
UN No. (ADR/RID) 1824

UN No. (IMDG) 1824

11/14
Revision date: 09/05/2017

OPTIMUM LAUNDRY LIQUID DETERGENT

UN No. (ICAO) 1824

14.2. UN proper shipping name


Proper shipping name SODIUM HYDROXIDE SOLUTION
(ADR/RID)

Proper shipping name (IMDG) SODIUM HYDROXIDE SOLUTION

Proper shipping name (ICAO) SODIUM HYDROXIDE SOLUTION

Proper shipping name (ADN) SODIUM HYDROXIDE SOLUTION

14.3. Transport hazard class(es)


ADR/RID class 8

ADR/RID label 8

IMDG class 8

ICAO class/division 8

Transport labels

14.4. Packing group


ADR/RID packing group II

IMDG packing group II

ICAO packing group II

14.5. Environmental hazards

Environmentally hazardous substance/marine pollutant


No.

14.6. Special precautions for user


EmS F-A, S-B

Emergency Action Code 2R

Hazard Identification Number 80


(ADR/RID)

14.7. Transport in bulk according to Annex II of MARPOL and the IBC Code
Transport in bulk according to Not applicable.
Annex II of MARPOL 73/78
and the IBC Code

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
EU legislation European Regulation (EC) No 1272/2008 on Classification, Labelling and Packaging of
Substances and Mixtures.
This replaces Directive 67/548/EEC - Classification, Packaging and Labelling of Dangerous
Substances and Regulation (EC) No. 453/2010 relating to the Classification, Packaging and
Labelling of Dangerous Preparations. Also considered is the REACH Regulation (EC)
No.1907/2006.

12/14
Revision date: 09/05/2017

OPTIMUM LAUNDRY LIQUID DETERGENT

15.2. Chemical safety assessment


Pcs Information

SECTION 16: Other information

Abbreviations and acronyms (EC) No. 1272/2008 : EU Regulation on Classification, Labelling and Packaging of
used in the safety data sheet Substances and Mixtures.
COSHH - Control of Substances Hazardous to Health.
DNEL - Derived No Effect Limit.
Industry - Refers in section 8 to application of the substance in an industrial process.
NPIS - National Poisons Information Service.
PBT - Persistent, Bioaccumulative & Toxic.
Professional - Refers in section 8 to application/use of the preparation/product in a skilled
trade premises.
REACH - Registration, Evaluation, Authorisation & restriction of CHemicals (Regulation EC
1907/2006).
vPvB - Very Persistent, Very bioaccumulative.

General information Only trained personnel should use this material. This document is a Safety Data Sheet, NOT
a CoSHH assessment. It is the customer's responsibility to conduct a full CoSHH
assessment, taking into account the information held within this document along with other
local factors considered in a risk assessment. The Risk and Hazard statements listed below
are the full text of abbreviations used in this document. They are not the final classification,
for this refer to section 2.

Revision comments Review of SDS data.

Revision date 09/05/2017

SDS number 24493

Risk phrases in full R22 Harmful if swallowed.


R35 Causes severe burns.
R38 Irritating to skin.
R41 Risk of serious damage to eyes.
R48/22 Harmful: danger of serious damage to health by prolonged exposure if swallowed.
R50 Very toxic to aquatic organisms.

Hazard statements in full H290 May be corrosive to metals.


H302 Harmful if swallowed.
H314 Causes severe skin burns and eye damage.
H315 Causes skin irritation.
H318 Causes serious eye damage.
H319 Causes serious eye irritation.
H332 Harmful if inhaled.
H373 May cause damage to organs through prolonged or repeated exposure.
H400 Very toxic to aquatic life.
H412 Harmful to aquatic life with long lasting effects.

REACH extended MSDS REACH requires that persons handling chemicals should take the necessary risk
comments management measures, in accordance with assessments from manufacturers and importers
of chemical substances. The relevent recommendations must be passed along the supply
chain. These assessments are generally reported in Exposure Scenarios.
Where Exposure Scenarios have been provided for substances used in this product, the
relevent information is incorporated into the safety data sheet.

END OF SAFETY DATA


SHEET

13/14
Revision date: 09/05/2017

OPTIMUM LAUNDRY LIQUID DETERGENT

This information relates only to the specific material designated and may not be valid for such material used in combination
with any other materials or in any process. Such information is, to the best of the company's knowledge and belief, accurate
and reliable as of the date indicated. However, no warranty guarantee or representation is made to its accuracy, reliability or
completeness. It is the user's responsibility to satisfy himself as to the suitability of such information for his own particular
use.All composition information is based on suppliers data.

14/14

You might also like