Safety Data Sheet Optimum Laundry Liquid Detergent
Safety Data Sheet Optimum Laundry Liquid Detergent
Safety Data Sheet Optimum Laundry Liquid Detergent
1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses Laundry detergent.
Uses advised against Not for direct contact with Food or Beverage stuffs. Not for oral consumption. Not for use by
hand.
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Pictogram
Detergent labelling 5 - < 15% anionic surfactants, 5 - < 15% non-ionic surfactants, < 5% amphoteric surfactants,
< 5% EDTA and salts thereof, < 5% polycarboxylates
3.2. Mixtures
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ETHANEDIOL <1%
CAS number: 107-21-1 EC number: 203-473-3 REACH registration number: 01-
2119456816-28-XXXX
The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16.
Composition comments To the best of our knowledge, all of the substances used in this product are being supported
for the relevent application in REACH.
Inhalation Remove affected person from source of contamination. Provide rest, warmth and fresh air. If
breathing stops, provide artificial respiration. Get medical attention if any discomfort
continues.
Ingestion Do not induce vomiting. Rinse mouth thoroughly. Place unconscious person on their side in
the recovery position and ensure breathing can take place. Get medical attention.
Skin contact Remove contaminated clothing that is not stuck to the skin. Flush area with clean water.
Continue to rinse for at least 15 minutes. Get medical attention if any discomfort continues.
Eye contact Remove any contact lenses and open eyelids wide apart. Promptly wash eyes with plenty of
water while lifting the eyelids. Continue to rinse for at least 15 minutes and get medical
attention.
Protection of first aiders First aid personnel should wear appropriate protective equipment during any rescue.
4.2. Most important symptoms and effects, both acute and delayed
General information Neat product may cause chemical burns and permanent eye damage. Dilute product may
cause irritation to the skin and eyes.
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Inhalation Inhalation of neat product is unlikely. However, inhalation of mists or vapours of diluted
product may result in soreness, irritation or burns to the mouth, nose and respiratory tract.
Ingestion Unlikely route of exposure without deliberate abuse. If neat chemical is ingested, chemical
burning of mouth, throat and GI tract will occur. If dilute chemical is ingested, soreness of
mouth, throat and GI tract may occur together with redness and blistering. Bleeding may
occur.
4.3. Indication of any immediate medical attention and special treatment needed
Notes for the doctor Contains Sodium Hydroxide (Caustic Soda) in Aqueous Solution Rinse well with water to
neutral pH.
Special protective equipment Wear positive-pressure self-contained breathing apparatus (SCBA) and appropriate protective
for firefighters clothing.
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Usage description This product is suitable for use in cleaning workwear used in food processing plants and
similar high care areas.
Ingredient comments As a requirement of REACH we have considered all of the components of this formulation.
We believe that Sodium Hydroxide (NaOH) is the most hazardous component of this
formulation. Sodium Hydroxide is not expected to be systemically available to the body under
normal handling and use conditions, therefore systemic effects of Sodium Hydroxide after
Dermal or Inhalation Exposure are not expected to occur. Based on data from our raw
material suppliers, we understand that if the risk management measures outlined in section
8.2 are followed , the inhalation exposure is below the DNEL of 1mg/m3. Where an exposure
level is quoted, a risk assessment should consider if there is a need to monitor the
atmosphere of the working environment. Results should be compared against the WEL and/or
DNEL information provided. The Long Term WEL refers to total exposure of a worker to a
specific substance averaged out over an 8 hour period.
The Short Term WEL refers to a single exposure of a worker to a specific substance over a 15
minute period.
If the Short Term WEL is exceeded and no Long Term Limit is set, further exposure during the
working shift is not permitted. Further controls should be implemented to ensure that future
exposure to the substance is reduced below the levels set before the activity is
repeated/continued. Where no Short Term WEL exists, guidance from the HSE is to use a
value of three times the Long Term WEL.
The WEL limits are laid down in the EH40 list as supplied by the HSE. This is taken from the
Chemical Agents Directive (98/24/EC). Where a worker is exposed to levels approaching a
limit, further exposure control measures should be considered to reduce exposure to the
substance. DNEL and/or PNEC information is supplied by manufacturers of substances in
accordance with REACH legislation (Regulation (EC) No 1907/2006) , and is used to provide
suitable risk reduction measures to limit exposure of the user of the substance to a non
hazardous level. If the measured level of exposure by a route divided by the DNEL for the
route is greater than 1, then further exposure controls should be implemented as described in
section 8.2. Where new information becomes available under REACH, this will be passed on
as revisions to the Safety Data Sheet.
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DNEL Professional - Dermal; Long term systemic effects: 12.5 mg/kg bw/day
Professional - Inhalation; Long term systemic effects: 44 mg/m³
Protective equipment
Appropriate engineering As this product contains ingredients with exposure limits, process enclosures, local exhaust
controls ventilation or other engineering controls should be used to keep worker exposure below any
statutory or recommended limits, if use generates dust, fumes, gas, vapour or mist.
Personal protection The PPE indicated above is not a COSHH assessment. It represents PPE that should be
considered during the manufacture, distribution, use and final disposal stages of this product's
life cycle. It is the responsibility of employers to conduct a COSHH/risk assessment to
determine appropriate PPE levels. The information given below should be used to support
this assessment. Where possible replace manual processes with automated or closed
processes to minimise contact with the product.
Eye/face protection If risk of splashing, wear safety goggles or face shield. Refer to EN Standard 166 to select
appropriate level of protection.
Hand protection Impervious Chemical Resistant Gloves of Butyl Rubber, PVC, Polychloroprene with a natural
latex liner, all with a minimum material thickness 0.5mm and a breakthrough time of
>480mins. Alternatively Nitrile Rubber, Fluorinated Rubber, both with a minimum thickness of
0.35 - 0.4mm and a breakthrough time of >480minutes. Refer to Standard EN 374.
Other skin and body Appropriate footwear and additional protective clothing complying with an approved standard
protection should be worn if a risk assessment indicates skin contamination is possible. Reference to EN
13832 and EN 943 is useful when selecting footwear and clothing.
Hygiene measures Promptly remove non-impervious clothing that has become contaminated, provided it is not
adhered to the skin. Contaminated clothing and shoes must be discarded. Provide eyewash
station and safety shower.
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Respiratory protection No specific recommendation made, but respiratory protection must be used if the general
level exceeds the Workplace Exposure Limit.
Environmental exposure Do not allow the substance to contaminate surface water/ground water. See points 6, 12 &13.
controls Discharge of solutions into effluent systems (including municipal drains) or to surface water
are expected to cause significant pH changes. Discharge of solutions should be carried out
such that pH changes are minimised. Where necessary pH buffering measures should be
adopted. Users of this product should consult local drainage and permitting authorities to
ensure that any restrictions or discharge consents are adhered to.
General Health and Safety The above classification relates to neat product.
Measures. Based on pH, "in use" solutions would still be classified as corrosive and use of gloves and
eye protection is recommended as minimum PPE.A full Risk Assessment should be carried
out before handling any chemical(s). Risk Assessments should refer to COSHH, and any
other relevant legislation or industry specific guidelines governing the use of chemicals.
Colour White.
Odour Detergent.
pH Concentrate pH >13
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Oxidising properties Does not meet the criteria for classification as oxidising.
10.1. Reactivity
Reactivity Not expected to react when correctly stored and used. Mixing with other chemicals may
produce unexpected reactions. The solution is strongly alkaline and reacts with strong acids
with heat generation.
General information Toxic effect linked with corrosive properties. See section 4.2.
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Inhalation Unlikely route of exposure. Inhalation of sprayed droplets may result in soreness of the throat,
mouth and nose. - See section 4.2.
Ingestion Causes severe burns. May cause chemical burns in mouth, oesophagus and stomach.
Eye contact Risk of serious damage to eyes. May cause permanent eye injury.
Ecotoxicity This product is not classified as environmentally hazardous. However, this does not exclude
the possibility that large or frequent spills can have a harmful or damaging effect on the
environment. Normal use is unlikely to pose a risk to the environment.
12.1. Toxicity
Acute toxicity - fish This mixture is not classified as toxic to aquatic organisms.
See note 12.0
Normal use of the diluted product is not expected to pose any risk.
Note:- pH values greater than 10.5 may be fatal to fish and other aquatic organisms, there
may also be damage to aquatic plants.
14.1. UN number
UN No. (ADR/RID) 1824
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ADR/RID label 8
IMDG class 8
ICAO class/division 8
Transport labels
14.7. Transport in bulk according to Annex II of MARPOL and the IBC Code
Transport in bulk according to Not applicable.
Annex II of MARPOL 73/78
and the IBC Code
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
EU legislation European Regulation (EC) No 1272/2008 on Classification, Labelling and Packaging of
Substances and Mixtures.
This replaces Directive 67/548/EEC - Classification, Packaging and Labelling of Dangerous
Substances and Regulation (EC) No. 453/2010 relating to the Classification, Packaging and
Labelling of Dangerous Preparations. Also considered is the REACH Regulation (EC)
No.1907/2006.
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Abbreviations and acronyms (EC) No. 1272/2008 : EU Regulation on Classification, Labelling and Packaging of
used in the safety data sheet Substances and Mixtures.
COSHH - Control of Substances Hazardous to Health.
DNEL - Derived No Effect Limit.
Industry - Refers in section 8 to application of the substance in an industrial process.
NPIS - National Poisons Information Service.
PBT - Persistent, Bioaccumulative & Toxic.
Professional - Refers in section 8 to application/use of the preparation/product in a skilled
trade premises.
REACH - Registration, Evaluation, Authorisation & restriction of CHemicals (Regulation EC
1907/2006).
vPvB - Very Persistent, Very bioaccumulative.
General information Only trained personnel should use this material. This document is a Safety Data Sheet, NOT
a CoSHH assessment. It is the customer's responsibility to conduct a full CoSHH
assessment, taking into account the information held within this document along with other
local factors considered in a risk assessment. The Risk and Hazard statements listed below
are the full text of abbreviations used in this document. They are not the final classification,
for this refer to section 2.
REACH extended MSDS REACH requires that persons handling chemicals should take the necessary risk
comments management measures, in accordance with assessments from manufacturers and importers
of chemical substances. The relevent recommendations must be passed along the supply
chain. These assessments are generally reported in Exposure Scenarios.
Where Exposure Scenarios have been provided for substances used in this product, the
relevent information is incorporated into the safety data sheet.
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This information relates only to the specific material designated and may not be valid for such material used in combination
with any other materials or in any process. Such information is, to the best of the company's knowledge and belief, accurate
and reliable as of the date indicated. However, no warranty guarantee or representation is made to its accuracy, reliability or
completeness. It is the user's responsibility to satisfy himself as to the suitability of such information for his own particular
use.All composition information is based on suppliers data.
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